JPS6451434A - Aniline polymer and its production - Google Patents
Aniline polymer and its productionInfo
- Publication number
- JPS6451434A JPS6451434A JP20644387A JP20644387A JPS6451434A JP S6451434 A JPS6451434 A JP S6451434A JP 20644387 A JP20644387 A JP 20644387A JP 20644387 A JP20644387 A JP 20644387A JP S6451434 A JPS6451434 A JP S6451434A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- solvent
- formula
- phenylenediamine
- 30min
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
PURPOSE:To obtain the title polymer which is soluble in a solvent, excellent in moldability, capable of forming an electroconductive polymer film and useful in the filed of electrical and electronic industries, by oxidizing a polymer obtained by reacting a dialkylsuccinyl succinate with phenylenediamine. CONSTITUTION:A polymer of formula II (wherein n=2-100) is obtained by dissolving a dialkylsuccinyl succinate of formula I (wherein R1 and R2 are each H or a 1-12C alkyl and, when it is H, this polymer may be in the form of a carboxylate with a basic component or a metal) and phenylenediamine at a molar ratio of 1:1 in a solvent such as ethanol in a concentration of 10-40wt.%, and reacting this solution at a temperature of 0 deg.C to the b.p. of the solvent for 30min-24hr. This polymer is oxidized with an oxidizing agent such as chloranil or p-chloronitrobenzene at a temperature of 0 deg.C to the b.p. of the solvent for 30min-24hr in a solvent such as dimethylacetamide to obtain the title polymer having a polyaniline structure of formula III as a repeating structural unit.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20644387A JPS6451434A (en) | 1987-08-21 | 1987-08-21 | Aniline polymer and its production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20644387A JPS6451434A (en) | 1987-08-21 | 1987-08-21 | Aniline polymer and its production |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6451434A true JPS6451434A (en) | 1989-02-27 |
Family
ID=16523459
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP20644387A Pending JPS6451434A (en) | 1987-08-21 | 1987-08-21 | Aniline polymer and its production |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6451434A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020078926A (en) * | 2001-04-11 | 2002-10-19 | 오응주 | Method for manufacturing the soluble polyaniline salt |
CN115433084A (en) * | 2022-09-14 | 2022-12-06 | 天津科技大学 | Method for preparing 2, 5-dihydroxy terephthalic acid dialkyl ester by continuous flow oxidation |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4827759A (en) * | 1971-08-11 | 1973-04-12 | ||
JPS6339916A (en) * | 1986-03-24 | 1988-02-20 | Showa Denko Kk | Electric onductor having self-dopability and novel polymeric compound |
JPH01500835A (en) * | 1986-09-29 | 1989-03-23 | 昭和電工株式会社 | Water-soluble self-doped conductive polymer and method for producing the same |
-
1987
- 1987-08-21 JP JP20644387A patent/JPS6451434A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4827759A (en) * | 1971-08-11 | 1973-04-12 | ||
JPS6339916A (en) * | 1986-03-24 | 1988-02-20 | Showa Denko Kk | Electric onductor having self-dopability and novel polymeric compound |
JPH01500835A (en) * | 1986-09-29 | 1989-03-23 | 昭和電工株式会社 | Water-soluble self-doped conductive polymer and method for producing the same |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020078926A (en) * | 2001-04-11 | 2002-10-19 | 오응주 | Method for manufacturing the soluble polyaniline salt |
CN115433084A (en) * | 2022-09-14 | 2022-12-06 | 天津科技大学 | Method for preparing 2, 5-dihydroxy terephthalic acid dialkyl ester by continuous flow oxidation |
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