JPS5747304A - Novel tris bipyridyl ruthenium high polymeric complex and its preparation - Google Patents

Novel tris bipyridyl ruthenium high polymeric complex and its preparation

Info

Publication number
JPS5747304A
JPS5747304A JP55122990A JP12299080A JPS5747304A JP S5747304 A JPS5747304 A JP S5747304A JP 55122990 A JP55122990 A JP 55122990A JP 12299080 A JP12299080 A JP 12299080A JP S5747304 A JPS5747304 A JP S5747304A
Authority
JP
Japan
Prior art keywords
bipyridyl
polymer
units
high polymeric
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP55122990A
Other languages
Japanese (ja)
Other versions
JPS597721B2 (en
Inventor
Yoshimi Kurimura
Hiroshi Yokota
Junko Shigehara
Hidetoshi Tsuchida
Masao Kaneko
Akira Yamada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN Institute of Physical and Chemical Research
Original Assignee
RIKEN Institute of Physical and Chemical Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN Institute of Physical and Chemical Research filed Critical RIKEN Institute of Physical and Chemical Research
Priority to JP55122990A priority Critical patent/JPS597721B2/en
Publication of JPS5747304A publication Critical patent/JPS5747304A/en
Publication of JPS597721B2 publication Critical patent/JPS597721B2/en
Expired legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE: To obtain the titled novel high polymeric complex useful as a photochemical reaction catalyst used for an oxidation reduction reaction, etc., by reacting a polymer having aminostyrene units with a 2,2'-bipyridyl-4,4'-dicarboxylic acid, and reacting the reaction product with a specific ruthenium complex.
CONSTITUTION: A polymer having aminostyrene units expressed by formula I is dissolved in a solvent, e.g. dimethylformamide, and reacted with a solution of 2,2'- bipyridyl-4,4'-dicarboxylic acid in dimethylformamide in the presence of triethylamine to give a polymer having 2,2'-bipyridyl units. The resultant polymer is then reacted with bis(2,2'-bipyridyl)ruthenium complex to afford the aimed novel complex containing units expressed by formula II (R1 and R2 may be the same and 2,2'- bipyridyl compounds, etc.; p is 1 or 2; X is anion, n is an integer 0W20).
COPYRIGHT: (C)1982,JPO&Japio
JP55122990A 1980-09-05 1980-09-05 Novel tris(bipyridyl)ruthenium-type polymer complex and its production method Expired JPS597721B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55122990A JPS597721B2 (en) 1980-09-05 1980-09-05 Novel tris(bipyridyl)ruthenium-type polymer complex and its production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55122990A JPS597721B2 (en) 1980-09-05 1980-09-05 Novel tris(bipyridyl)ruthenium-type polymer complex and its production method

Publications (2)

Publication Number Publication Date
JPS5747304A true JPS5747304A (en) 1982-03-18
JPS597721B2 JPS597721B2 (en) 1984-02-20

Family

ID=14849549

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55122990A Expired JPS597721B2 (en) 1980-09-05 1980-09-05 Novel tris(bipyridyl)ruthenium-type polymer complex and its production method

Country Status (1)

Country Link
JP (1) JPS597721B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6274114B1 (en) * 1999-02-24 2001-08-14 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for on-site production of ultra-high-purity hydrogen peroxide for the electronics industry
WO2003076478A1 (en) * 2002-03-11 2003-09-18 Japan Science And Technology Agency Arene-ruthenium complexes immobilized on polymers, catalysts consisting of the complexes, and processes for organic syntheses with the same
JP2005336129A (en) * 2004-05-28 2005-12-08 Nippon Steel Corp Method for controlling characteristic of polymer complex
WO2014045732A1 (en) * 2012-09-19 2014-03-27 三菱瓦斯化学株式会社 Metal complex and method for producing hydrogen peroxide
CN109569722A (en) * 2017-09-28 2019-04-05 天津工业大学 The Photocatalytic Performance Study for the metal organic complex that 2,2 '-bipyridyls -4,4 '-dicarboxylic acids and rare earth metal Tb are constructed

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6274114B1 (en) * 1999-02-24 2001-08-14 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for on-site production of ultra-high-purity hydrogen peroxide for the electronics industry
WO2003076478A1 (en) * 2002-03-11 2003-09-18 Japan Science And Technology Agency Arene-ruthenium complexes immobilized on polymers, catalysts consisting of the complexes, and processes for organic syntheses with the same
US7348290B2 (en) 2002-03-11 2008-03-25 Japan Science And Technology Agency Arene-ruthenium complexes immobilized on polymers, catalysts consisting of the complexes, and processes for organic syntheses with the same
JP2005336129A (en) * 2004-05-28 2005-12-08 Nippon Steel Corp Method for controlling characteristic of polymer complex
WO2014045732A1 (en) * 2012-09-19 2014-03-27 三菱瓦斯化学株式会社 Metal complex and method for producing hydrogen peroxide
CN104640854A (en) * 2012-09-19 2015-05-20 三菱瓦斯化学株式会社 Metal complex and method for producing hydrogen peroxide
US9522824B2 (en) 2012-09-19 2016-12-20 Mitsubishi Gas Chemical Company, Inc. Metal complex and method for producing hydrogen peroxide
CN109569722A (en) * 2017-09-28 2019-04-05 天津工业大学 The Photocatalytic Performance Study for the metal organic complex that 2,2 '-bipyridyls -4,4 '-dicarboxylic acids and rare earth metal Tb are constructed

Also Published As

Publication number Publication date
JPS597721B2 (en) 1984-02-20

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