KR20140039317A - 캐소드 전극 물질 - Google Patents
캐소드 전극 물질 Download PDFInfo
- Publication number
- KR20140039317A KR20140039317A KR1020147001817A KR20147001817A KR20140039317A KR 20140039317 A KR20140039317 A KR 20140039317A KR 1020147001817 A KR1020147001817 A KR 1020147001817A KR 20147001817 A KR20147001817 A KR 20147001817A KR 20140039317 A KR20140039317 A KR 20140039317A
- Authority
- KR
- South Korea
- Prior art keywords
- medium
- fuel cell
- cathode electrode
- cell cathode
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- 238000000034 method Methods 0.000 claims abstract description 165
- 239000000446 fuel Substances 0.000 claims abstract description 145
- 230000001965 increasing effect Effects 0.000 claims abstract description 32
- 230000004913 activation Effects 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 103
- 229910052799 carbon Inorganic materials 0.000 claims description 72
- 239000000463 material Substances 0.000 claims description 43
- 230000004048 modification Effects 0.000 claims description 32
- 238000012986 modification Methods 0.000 claims description 32
- 230000008569 process Effects 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- 230000001590 oxidative effect Effects 0.000 claims description 18
- 238000007906 compression Methods 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 14
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 230000006835 compression Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 10
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
- 238000007385 chemical modification Methods 0.000 claims description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000004544 sputter deposition Methods 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 229910021397 glassy carbon Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 238000001020 plasma etching Methods 0.000 claims description 6
- 239000013354 porous framework Substances 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 238000005229 chemical vapour deposition Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000004375 physisorption Methods 0.000 claims description 5
- 238000009832 plasma treatment Methods 0.000 claims description 5
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- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
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- 238000000151 deposition Methods 0.000 claims description 2
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- 239000012071 phase Substances 0.000 claims 3
- 239000012808 vapor phase Substances 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 96
- 239000012528 membrane Substances 0.000 description 21
- 229910002804 graphite Inorganic materials 0.000 description 15
- 239000010439 graphite Substances 0.000 description 15
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 210000003850 cellular structure Anatomy 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000010306 acid treatment Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
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- 230000006870 function Effects 0.000 description 2
- -1 platinum group metals Chemical class 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 150000001722 carbon compounds Chemical group 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000007833 carbon precursor Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
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- 238000011069 regeneration method Methods 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8626—Porous electrodes characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/8814—Temporary supports, e.g. decal
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8817—Treatment of supports before application of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1097—Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
- H01M8/1226—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material characterised by the supporting layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1110585.5A GB201110585D0 (en) | 2011-06-22 | 2011-06-22 | Cathode electrode modification |
| GB1110585.5 | 2011-06-22 | ||
| PCT/GB2012/051474 WO2012175997A2 (en) | 2011-06-22 | 2012-06-22 | Cathode electrode material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20140039317A true KR20140039317A (ko) | 2014-04-01 |
Family
ID=44454484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147001817A Withdrawn KR20140039317A (ko) | 2011-06-22 | 2012-06-22 | 캐소드 전극 물질 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10541422B2 (enExample) |
| EP (1) | EP2724407A2 (enExample) |
| JP (2) | JP6557007B2 (enExample) |
| KR (1) | KR20140039317A (enExample) |
| CN (1) | CN103733402A (enExample) |
| BR (1) | BR112013033172A2 (enExample) |
| GB (1) | GB201110585D0 (enExample) |
| IN (1) | IN2013MN02401A (enExample) |
| WO (1) | WO2012175997A2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2503475A (en) | 2012-06-27 | 2014-01-01 | Acal Energy Ltd | Fuel Cells for use at elevated temperatures and pressures |
| GB2515725A (en) | 2013-05-01 | 2015-01-07 | Acal Energy Ltd | Fuel cells |
| JP6606271B2 (ja) * | 2015-04-09 | 2019-11-13 | ユナイテッド テクノロジーズ コーポレイション | 炭素電極を処理する方法 |
| JP2017027920A (ja) * | 2015-07-28 | 2017-02-02 | 東洋紡株式会社 | レドックス電池用電極材 |
| ES2817083T3 (es) * | 2015-11-13 | 2021-04-06 | Invinity Energy Systems Canada Corp | Electrodo mejorado para batería de flujo redox |
| JP6897572B2 (ja) * | 2016-01-08 | 2021-06-30 | 東洋紡株式会社 | 水処理装置、吸着素子、および水処理方法 |
Family Cites Families (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1662597A (en) * | 1926-12-09 | 1928-03-13 | Arthur S Baldwin | Internal-combustion motor |
| US3077507A (en) * | 1960-05-16 | 1963-02-12 | Union Carbide Corp | Fuel cell electrode |
| US3400019A (en) * | 1961-12-26 | 1968-09-03 | Pullman Inc | Electrode including nonmetallic substrate |
| US3242011A (en) * | 1962-11-01 | 1966-03-22 | Union Carbide Corp | Method of making fuel cell electrodes |
| US3378406A (en) | 1965-12-30 | 1968-04-16 | Leesona Corp | Metal-oxygen-containing electro-chemical battery |
| US3425875A (en) * | 1966-09-15 | 1969-02-04 | Engelhard Ind Inc | Method of preparing fuel cell electrode containing fluorocarbon polymer and carbon black-supported platinum group metal |
| US3660165A (en) * | 1970-04-22 | 1972-05-02 | Leesona Corp | Electrodes comprising fluorinated phosphonitrile polymer and fuel cell in combination therewith |
| JPS58163440A (ja) | 1982-03-24 | 1983-09-28 | Agency Of Ind Science & Technol | 炭素触媒の表面処理方法 |
| JPS5925180A (ja) * | 1982-08-03 | 1984-02-09 | Asahi Glass Co Ltd | ガス拡散電極用材 |
| US4677092A (en) * | 1983-01-17 | 1987-06-30 | International Fuel Cells Corporation | Ordered ternary fuel cell catalysts containing platinum and cobalt and method for making the catalysts |
| US5126216A (en) | 1990-11-27 | 1992-06-30 | Universite Du Quebec A Montreal | Ternary alloy electrocatalysts |
| GB2298955B (en) * | 1995-03-16 | 1999-04-07 | British Nuclear Fuels Plc | Fuel cells |
| JPH11502052A (ja) * | 1995-03-16 | 1999-02-16 | ブリティッシュ ヌークリア フューエルズ ピーエルシー | 特定の電極層を持つ固体酸化物燃料電池 |
| US6312845B1 (en) | 1995-10-06 | 2001-11-06 | The Dow Chemical Company | Macroporous flow field assembly |
| US6103393A (en) | 1998-02-24 | 2000-08-15 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
| US5879828A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
| US6136412A (en) | 1997-10-10 | 2000-10-24 | 3M Innovative Properties Company | Microtextured catalyst transfer substrate |
| FR2788168A1 (fr) | 1998-12-30 | 2000-07-07 | Messier Bugatti | Electrode a diffusion gazeuse supportant un catalyseur de reaction electrochimique |
| US6579639B1 (en) * | 1999-06-07 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell |
| US6258476B1 (en) * | 1999-09-02 | 2001-07-10 | International Fuel Cells, Llc | Porous carbon body with increased wettability by water |
| AU2001279308A1 (en) | 2000-07-25 | 2002-02-05 | Apollo Energy Systems, Incorporated | Electrodes for alkaline fuel cells with circulating electrolyte |
| US6781817B2 (en) * | 2000-10-02 | 2004-08-24 | Biosource, Inc. | Fringe-field capacitor electrode for electrochemical device |
| KR20020080449A (ko) * | 2000-12-28 | 2002-10-23 | 소니 가부시끼 가이샤 | 가스 확산성 전극, 전기 전도성 이온 전도체 및 이들의제조방법, 및 전기화학 장치 |
| US20020176927A1 (en) | 2001-03-29 | 2002-11-28 | Kodas Toivo T. | Combinatorial synthesis of material systems |
| US20030003341A1 (en) * | 2001-06-29 | 2003-01-02 | Kinkelaar Mark R. | Liquid fuel cell reservoir for water and/or fuel management |
| NL1019953C2 (nl) | 2002-02-12 | 2002-12-19 | Mecal Applied Mechanics B V | Geprefabriceerde toren of mast, alsmede een methode voor het samenvoegen en/of naspannen van segmenten die één constructie moeten vormen, alsmede een werkwijze voor het opbouwen van een toren of mast bestaande uit segmenten. |
| JP2003308850A (ja) * | 2002-04-18 | 2003-10-31 | Toyobo Co Ltd | 電極材及びその製造方法 |
| JP2003308851A (ja) * | 2002-04-18 | 2003-10-31 | Toyobo Co Ltd | 電極材及びその製造方法 |
| EP1546251A2 (en) * | 2002-10-03 | 2005-06-29 | Powerzyme, Inc. | Fuel cells including biocompatible membranes and metal anodes |
| JP2004152593A (ja) | 2002-10-30 | 2004-05-27 | Asahi Glass Co Ltd | 固体高分子型燃料電池用膜・電極接合体の製造方法 |
| TW200427126A (en) * | 2003-02-18 | 2004-12-01 | Nec Corp | Electrode for fuel cell, fuel cell and manufacturing method thereof |
| JPWO2004075331A1 (ja) * | 2003-02-18 | 2006-06-01 | 日本電気株式会社 | 燃料電池およびその製造方法 |
| JP2006529054A (ja) * | 2003-05-09 | 2006-12-28 | フォーメックス エル ピー | 炭素粒子混合物を有するガス拡散層 |
| KR100696463B1 (ko) | 2003-09-27 | 2007-03-19 | 삼성에스디아이 주식회사 | 고농도 탄소 담지 촉매, 그 제조방법, 상기 촉매를 이용한촉매전극 및 이를 이용한 연료전지 |
| US20070134531A1 (en) * | 2003-11-06 | 2007-06-14 | Hidekazu Kimura | Fuel cell and method for fabricating same |
| KR100708642B1 (ko) * | 2003-11-21 | 2007-04-18 | 삼성에스디아이 주식회사 | 중형다공성 탄소 분자체 및 이를 사용한 담지촉매 |
| US20060024535A1 (en) | 2004-02-04 | 2006-02-02 | Figueroa Juan C | CO tolerant catalyst |
| US20050221141A1 (en) * | 2004-03-15 | 2005-10-06 | Hampden-Smith Mark J | Modified carbon products, their use in proton exchange membranes and similar devices and methods relating to the same |
| JP2005267981A (ja) * | 2004-03-17 | 2005-09-29 | Aisin Seiki Co Ltd | 固体高分子型燃料電池用ガス拡散層の製造方法、固体高分子型燃料電池用膜電極接合体、固体高分子型燃料電池 |
| US20060233692A1 (en) * | 2004-04-26 | 2006-10-19 | Mainstream Engineering Corp. | Nanotube/metal substrate composites and methods for producing such composites |
| US20070003820A1 (en) * | 2004-06-15 | 2007-01-04 | Alexander Kraytsberg | Direct methanol fuel cell with 3-D anode |
| KR100590555B1 (ko) | 2004-07-08 | 2006-06-19 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| KR100831659B1 (ko) * | 2004-10-06 | 2008-05-22 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | 연료전지용 탄소 나노 튜브, 이를 포함한 나노복합체, 그제조 방법 및 이를 채용한 연료전지 |
| KR100658675B1 (ko) * | 2004-11-26 | 2006-12-15 | 삼성에스디아이 주식회사 | 연료전지용 전극, 이를 포함하는 연료전지 및 연료전지용전극의 제조방법 |
| TWI243507B (en) * | 2004-12-30 | 2005-11-11 | Ind Tech Res Inst | Hollow mesocarbon electrode-catalyst for direct methanol fuel cell and preparation thereof |
| US7422994B2 (en) * | 2005-01-05 | 2008-09-09 | Symyx Technologies, Inc. | Platinum-copper-tungsten fuel cell catalyst |
| US20080044719A1 (en) * | 2005-02-02 | 2008-02-21 | Symyx Technologies, Inc. | Platinum-copper-titanium fuel cell catalyst |
| JP2006216447A (ja) * | 2005-02-04 | 2006-08-17 | Hitachi Ltd | 燃料電池電源システム及びその運転方法 |
| KR100647700B1 (ko) | 2005-09-14 | 2006-11-23 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| US20070092784A1 (en) | 2005-10-20 | 2007-04-26 | Dopp Robert B | Gas diffusion cathode using nanometer sized particles of transition metals for catalysis |
| KR101223630B1 (ko) | 2005-11-11 | 2013-01-17 | 삼성에스디아이 주식회사 | 연료 전지의 캐소드 전극용 촉매, 이의 제조 방법, 이를포함하는 연료 전지용 막-전극 어셈블리 및 이를 포함하는연료 전지 시스템 |
| KR100717796B1 (ko) | 2005-11-30 | 2007-05-11 | 삼성에스디아이 주식회사 | 연료 전지용 캐소드 촉매, 이를 포함하는 연료 전지용막-전극 어셈블리 및 연료 전지 시스템 |
| JP4567588B2 (ja) * | 2005-12-14 | 2010-10-20 | アイシン精機株式会社 | ガス拡散部材の製造方法、ガス拡散素材の製造方法、ガス拡散素材 |
| CA2531942A1 (en) * | 2005-12-27 | 2007-06-27 | The University Of Western Ontario | Fuel cell bioreactor |
| US20070178310A1 (en) * | 2006-01-31 | 2007-08-02 | Rudyard Istvan | Non-woven fibrous materials and electrodes therefrom |
| JP2008047473A (ja) * | 2006-08-18 | 2008-02-28 | Nissan Motor Co Ltd | 電極触媒 |
| US8329356B2 (en) * | 2006-09-07 | 2012-12-11 | GM Global Technology Operations LLC | Fuel cell microporous layer including particles with a controlled pore size distribution |
| US7968248B2 (en) * | 2007-01-31 | 2011-06-28 | Junli Liu | Liquid-liquid fuel cell systems having flow-through anodes and flow-by cathodes |
| KR20080076173A (ko) | 2007-02-15 | 2008-08-20 | 삼성전자주식회사 | 금속 산화막 패턴 형성 방법 및 이를 이용한 반도체 소자의형성 방법 |
| KR100805527B1 (ko) * | 2007-02-15 | 2008-02-20 | 삼성에스디아이 주식회사 | 소형 이동전원용 연료 전지 및 이 연료전지에 사용되는막-전극 어셈블리 |
| KR100901846B1 (ko) * | 2007-09-11 | 2009-06-09 | 한국에너지기술연구원 | 탄소나노튜브 직접성장법과 백금 나노촉매의 담지를 위한화학기상증착법을 적용한 연료전지용 셀룰로스 전극의제조방법, 셀룰로스 전극 및 셀룰로스 섬유의 연료전지용전극으로서의 용도 |
| KR101483125B1 (ko) * | 2008-02-05 | 2015-01-15 | 삼성에스디아이 주식회사 | 연료전지용 막전극 접합체, 그 제조방법 및 이를 채용한연료전지 |
| JP5262156B2 (ja) * | 2008-02-07 | 2013-08-14 | 凸版印刷株式会社 | 固体高分子型燃料電池およびその製造方法 |
| EP2257602B1 (en) * | 2008-02-19 | 2018-10-17 | Cabot Corporation | Mesoporous carbon black with a large bet-surface and processes for making same |
| US9017837B2 (en) * | 2008-02-19 | 2015-04-28 | Cabot Corporation | High surface area graphitized carbon and processes for making same |
| JP2009295441A (ja) * | 2008-06-05 | 2009-12-17 | Seizo Miyata | 炭素触媒、炭素触媒の製造方法、膜電極接合体、及び、燃料電池 |
| JP5463639B2 (ja) * | 2008-09-25 | 2014-04-09 | 三菱マテリアル株式会社 | 金属多孔質板の製造方法 |
| JP5439791B2 (ja) * | 2008-10-14 | 2014-03-12 | 三菱マテリアル株式会社 | 金属多孔質体の製造方法 |
| JP5332554B2 (ja) * | 2008-11-27 | 2013-11-06 | 日産自動車株式会社 | 燃料電池用ガス拡散層及びその製造方法、並びにこれを用いた燃料電池 |
| EP2228857A1 (de) * | 2009-03-06 | 2010-09-15 | Basf Se | Verbesserte Membran-Elektrodeneinheiten |
| JP2011028849A (ja) * | 2009-07-21 | 2011-02-10 | Tomoegawa Paper Co Ltd | 固体高分子型燃料電池用ガス拡散電極及びその製造方法 |
| JP2012146460A (ja) * | 2011-01-11 | 2012-08-02 | Sony Corp | 燃料電池、燃料電池の製造方法、電子機器、酵素固定化電極、バイオセンサー、エネルギー変換素子、細胞、細胞小器官および細菌 |
| JP5899885B2 (ja) * | 2011-01-31 | 2016-04-06 | ソニー株式会社 | 燃料電池、燃料電池の製造方法、電子機器、ニコチンアミドアデニンジヌクレオチド固定化電極、ニコチンアミドアデニンジヌクレオチド固定化担体、酵素反応利用装置、タンパク質固定化電極およびタンパク質固定化担体 |
-
2011
- 2011-06-22 GB GBGB1110585.5A patent/GB201110585D0/en not_active Ceased
-
2012
- 2012-06-22 WO PCT/GB2012/051474 patent/WO2012175997A2/en not_active Ceased
- 2012-06-22 CN CN201280030919.4A patent/CN103733402A/zh active Pending
- 2012-06-22 IN IN2401MUN2013 patent/IN2013MN02401A/en unknown
- 2012-06-22 JP JP2014516446A patent/JP6557007B2/ja not_active Expired - Fee Related
- 2012-06-22 EP EP12730253.7A patent/EP2724407A2/en not_active Withdrawn
- 2012-06-22 BR BR112013033172A patent/BR112013033172A2/pt not_active IP Right Cessation
- 2012-06-22 KR KR1020147001817A patent/KR20140039317A/ko not_active Withdrawn
- 2012-06-22 US US14/127,764 patent/US10541422B2/en not_active Expired - Fee Related
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2018
- 2018-02-27 JP JP2018033142A patent/JP2018137228A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012175997A3 (en) | 2013-03-21 |
| JP2018137228A (ja) | 2018-08-30 |
| JP6557007B2 (ja) | 2019-08-07 |
| GB201110585D0 (en) | 2011-08-03 |
| EP2724407A2 (en) | 2014-04-30 |
| US20140205931A1 (en) | 2014-07-24 |
| BR112013033172A2 (pt) | 2017-03-01 |
| JP2014517494A (ja) | 2014-07-17 |
| CN103733402A (zh) | 2014-04-16 |
| WO2012175997A2 (en) | 2012-12-27 |
| US10541422B2 (en) | 2020-01-21 |
| IN2013MN02401A (enExample) | 2015-06-12 |
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