JP6557007B2 - カソード電極材料 - Google Patents
カソード電極材料 Download PDFInfo
- Publication number
- JP6557007B2 JP6557007B2 JP2014516446A JP2014516446A JP6557007B2 JP 6557007 B2 JP6557007 B2 JP 6557007B2 JP 2014516446 A JP2014516446 A JP 2014516446A JP 2014516446 A JP2014516446 A JP 2014516446A JP 6557007 B2 JP6557007 B2 JP 6557007B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- carbon
- fuel cell
- metal structure
- porous metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007772 electrode material Substances 0.000 title description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 85
- 239000000446 fuel Substances 0.000 claims description 78
- 229910052799 carbon Inorganic materials 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 43
- 230000001965 increasing effect Effects 0.000 claims description 25
- 230000004048 modification Effects 0.000 claims description 25
- 238000012986 modification Methods 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 16
- 230000004913 activation Effects 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 230000001590 oxidative effect Effects 0.000 claims description 11
- 238000007385 chemical modification Methods 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 238000004544 sputter deposition Methods 0.000 claims description 6
- 238000005229 chemical vapour deposition Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000001020 plasma etching Methods 0.000 claims description 4
- 238000009832 plasma treatment Methods 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 description 94
- 239000003792 electrolyte Substances 0.000 description 24
- 239000000463 material Substances 0.000 description 22
- 239000012528 membrane Substances 0.000 description 21
- 238000011282 treatment Methods 0.000 description 21
- 229910002804 graphite Inorganic materials 0.000 description 16
- 239000010439 graphite Substances 0.000 description 16
- 230000010287 polarization Effects 0.000 description 15
- 239000000523 sample Substances 0.000 description 14
- 239000004744 fabric Substances 0.000 description 13
- 230000006835 compression Effects 0.000 description 12
- 238000007906 compression Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 239000000376 reactant Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 239000013068 control sample Substances 0.000 description 8
- 229910017604 nitric acid Inorganic materials 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- 239000008151 electrolyte solution Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 239000003570 air Substances 0.000 description 5
- 210000003850 cellular structure Anatomy 0.000 description 5
- 238000003487 electrochemical reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000013460 polyoxometalate Substances 0.000 description 5
- 239000013354 porous framework Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910021397 glassy carbon Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000010306 acid treatment Methods 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004966 Carbon aerogel Substances 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000007833 carbon precursor Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- -1 stainless steel Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8626—Porous electrodes characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/8814—Temporary supports, e.g. decal
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8817—Treatment of supports before application of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1097—Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
- H01M8/1226—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material characterised by the supporting layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1110585.5 | 2011-06-22 | ||
| GBGB1110585.5A GB201110585D0 (en) | 2011-06-22 | 2011-06-22 | Cathode electrode modification |
| PCT/GB2012/051474 WO2012175997A2 (en) | 2011-06-22 | 2012-06-22 | Cathode electrode material |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018033142A Division JP2018137228A (ja) | 2011-06-22 | 2018-02-27 | カソード電極材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014517494A JP2014517494A (ja) | 2014-07-17 |
| JP6557007B2 true JP6557007B2 (ja) | 2019-08-07 |
Family
ID=44454484
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014516446A Expired - Fee Related JP6557007B2 (ja) | 2011-06-22 | 2012-06-22 | カソード電極材料 |
| JP2018033142A Pending JP2018137228A (ja) | 2011-06-22 | 2018-02-27 | カソード電極材料 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018033142A Pending JP2018137228A (ja) | 2011-06-22 | 2018-02-27 | カソード電極材料 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10541422B2 (enExample) |
| EP (1) | EP2724407A2 (enExample) |
| JP (2) | JP6557007B2 (enExample) |
| KR (1) | KR20140039317A (enExample) |
| CN (1) | CN103733402A (enExample) |
| BR (1) | BR112013033172A2 (enExample) |
| GB (1) | GB201110585D0 (enExample) |
| IN (1) | IN2013MN02401A (enExample) |
| WO (1) | WO2012175997A2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2503475A (en) * | 2012-06-27 | 2014-01-01 | Acal Energy Ltd | Fuel Cells for use at elevated temperatures and pressures |
| GB2515725A (en) | 2013-05-01 | 2015-01-07 | Acal Energy Ltd | Fuel cells |
| WO2016164017A1 (en) * | 2015-04-09 | 2016-10-13 | United Technologies Corporation | Method of treating carbon electrode |
| JP2017027920A (ja) * | 2015-07-28 | 2017-02-02 | 東洋紡株式会社 | レドックス電池用電極材 |
| CN108352507A (zh) * | 2015-11-13 | 2018-07-31 | 阿瓦隆电池(加拿大)公司 | 用于氧化还原液流电池的改进电极 |
| WO2017119441A1 (ja) * | 2016-01-08 | 2017-07-13 | 東洋紡株式会社 | 水処理装置、吸着素子、および水処理方法 |
Family Cites Families (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1662597A (en) * | 1926-12-09 | 1928-03-13 | Arthur S Baldwin | Internal-combustion motor |
| US3077507A (en) * | 1960-05-16 | 1963-02-12 | Union Carbide Corp | Fuel cell electrode |
| US3400019A (en) * | 1961-12-26 | 1968-09-03 | Pullman Inc | Electrode including nonmetallic substrate |
| US3242011A (en) | 1962-11-01 | 1966-03-22 | Union Carbide Corp | Method of making fuel cell electrodes |
| US3378406A (en) | 1965-12-30 | 1968-04-16 | Leesona Corp | Metal-oxygen-containing electro-chemical battery |
| US3425875A (en) | 1966-09-15 | 1969-02-04 | Engelhard Ind Inc | Method of preparing fuel cell electrode containing fluorocarbon polymer and carbon black-supported platinum group metal |
| US3660165A (en) | 1970-04-22 | 1972-05-02 | Leesona Corp | Electrodes comprising fluorinated phosphonitrile polymer and fuel cell in combination therewith |
| JPS58163440A (ja) * | 1982-03-24 | 1983-09-28 | Agency Of Ind Science & Technol | 炭素触媒の表面処理方法 |
| JPS5925180A (ja) * | 1982-08-03 | 1984-02-09 | Asahi Glass Co Ltd | ガス拡散電極用材 |
| US4677092A (en) | 1983-01-17 | 1987-06-30 | International Fuel Cells Corporation | Ordered ternary fuel cell catalysts containing platinum and cobalt and method for making the catalysts |
| US5126216A (en) * | 1990-11-27 | 1992-06-30 | Universite Du Quebec A Montreal | Ternary alloy electrocatalysts |
| NZ304057A (en) * | 1995-03-16 | 1999-04-29 | British Nuclear Fuels Plc | Solid solution separator of zirconia urania and yttria for fuel cell |
| GB2298955B (en) | 1995-03-16 | 1999-04-07 | British Nuclear Fuels Plc | Fuel cells |
| US6312845B1 (en) * | 1995-10-06 | 2001-11-06 | The Dow Chemical Company | Macroporous flow field assembly |
| US6103393A (en) * | 1998-02-24 | 2000-08-15 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
| US6136412A (en) | 1997-10-10 | 2000-10-24 | 3M Innovative Properties Company | Microtextured catalyst transfer substrate |
| US5879828A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
| FR2788168A1 (fr) | 1998-12-30 | 2000-07-07 | Messier Bugatti | Electrode a diffusion gazeuse supportant un catalyseur de reaction electrochimique |
| US6579639B1 (en) | 1999-06-07 | 2003-06-17 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell |
| US6258476B1 (en) | 1999-09-02 | 2001-07-10 | International Fuel Cells, Llc | Porous carbon body with increased wettability by water |
| AU2001279308A1 (en) | 2000-07-25 | 2002-02-05 | Apollo Energy Systems, Incorporated | Electrodes for alkaline fuel cells with circulating electrolyte |
| AU2001296470A1 (en) * | 2000-10-02 | 2002-04-15 | Marc D. Andelman | Fringe-field capacitor electrode for electrochemical device |
| CN1406399A (zh) | 2000-12-28 | 2003-03-26 | 索尼公司 | 气体扩散电极和导电的离子导体及其制备方法以及电化学装置 |
| US20020176927A1 (en) * | 2001-03-29 | 2002-11-28 | Kodas Toivo T. | Combinatorial synthesis of material systems |
| US20030003341A1 (en) | 2001-06-29 | 2003-01-02 | Kinkelaar Mark R. | Liquid fuel cell reservoir for water and/or fuel management |
| NL1019953C2 (nl) | 2002-02-12 | 2002-12-19 | Mecal Applied Mechanics B V | Geprefabriceerde toren of mast, alsmede een methode voor het samenvoegen en/of naspannen van segmenten die één constructie moeten vormen, alsmede een werkwijze voor het opbouwen van een toren of mast bestaande uit segmenten. |
| JP2003308850A (ja) * | 2002-04-18 | 2003-10-31 | Toyobo Co Ltd | 電極材及びその製造方法 |
| JP2003308851A (ja) * | 2002-04-18 | 2003-10-31 | Toyobo Co Ltd | 電極材及びその製造方法 |
| WO2004032306A2 (en) * | 2002-10-03 | 2004-04-15 | Powerzyme, Inc. | Fuel cells including biocompatible membranes and metal anodes |
| JP2004152593A (ja) | 2002-10-30 | 2004-05-27 | Asahi Glass Co Ltd | 固体高分子型燃料電池用膜・電極接合体の製造方法 |
| WO2004075331A1 (ja) * | 2003-02-18 | 2004-09-02 | Nec Corporation | 燃料電池およびその製造方法 |
| CN1781203A (zh) * | 2003-02-18 | 2006-05-31 | 日本电气株式会社 | 燃料电池用电极,燃料电池及其制造方法 |
| EP1627444A2 (en) | 2003-05-09 | 2006-02-22 | Foamex L.P. | Gas diffusion layer having carbon particle mixture |
| KR100696463B1 (ko) | 2003-09-27 | 2007-03-19 | 삼성에스디아이 주식회사 | 고농도 탄소 담지 촉매, 그 제조방법, 상기 촉매를 이용한촉매전극 및 이를 이용한 연료전지 |
| US20070134531A1 (en) * | 2003-11-06 | 2007-06-14 | Hidekazu Kimura | Fuel cell and method for fabricating same |
| KR100708642B1 (ko) * | 2003-11-21 | 2007-04-18 | 삼성에스디아이 주식회사 | 중형다공성 탄소 분자체 및 이를 사용한 담지촉매 |
| US20060024535A1 (en) | 2004-02-04 | 2006-02-02 | Figueroa Juan C | CO tolerant catalyst |
| US20050221141A1 (en) | 2004-03-15 | 2005-10-06 | Hampden-Smith Mark J | Modified carbon products, their use in proton exchange membranes and similar devices and methods relating to the same |
| JP2005267981A (ja) | 2004-03-17 | 2005-09-29 | Aisin Seiki Co Ltd | 固体高分子型燃料電池用ガス拡散層の製造方法、固体高分子型燃料電池用膜電極接合体、固体高分子型燃料電池 |
| US20060233692A1 (en) * | 2004-04-26 | 2006-10-19 | Mainstream Engineering Corp. | Nanotube/metal substrate composites and methods for producing such composites |
| US20070003820A1 (en) | 2004-06-15 | 2007-01-04 | Alexander Kraytsberg | Direct methanol fuel cell with 3-D anode |
| KR100590555B1 (ko) | 2004-07-08 | 2006-06-19 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| KR100831659B1 (ko) * | 2004-10-06 | 2008-05-22 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | 연료전지용 탄소 나노 튜브, 이를 포함한 나노복합체, 그제조 방법 및 이를 채용한 연료전지 |
| KR100658675B1 (ko) * | 2004-11-26 | 2006-12-15 | 삼성에스디아이 주식회사 | 연료전지용 전극, 이를 포함하는 연료전지 및 연료전지용전극의 제조방법 |
| TWI243507B (en) * | 2004-12-30 | 2005-11-11 | Ind Tech Res Inst | Hollow mesocarbon electrode-catalyst for direct methanol fuel cell and preparation thereof |
| US7422994B2 (en) * | 2005-01-05 | 2008-09-09 | Symyx Technologies, Inc. | Platinum-copper-tungsten fuel cell catalyst |
| US20080044719A1 (en) | 2005-02-02 | 2008-02-21 | Symyx Technologies, Inc. | Platinum-copper-titanium fuel cell catalyst |
| JP2006216447A (ja) * | 2005-02-04 | 2006-08-17 | Hitachi Ltd | 燃料電池電源システム及びその運転方法 |
| KR100647700B1 (ko) | 2005-09-14 | 2006-11-23 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| US20070092784A1 (en) | 2005-10-20 | 2007-04-26 | Dopp Robert B | Gas diffusion cathode using nanometer sized particles of transition metals for catalysis |
| KR101223630B1 (ko) | 2005-11-11 | 2013-01-17 | 삼성에스디아이 주식회사 | 연료 전지의 캐소드 전극용 촉매, 이의 제조 방법, 이를포함하는 연료 전지용 막-전극 어셈블리 및 이를 포함하는연료 전지 시스템 |
| KR100717796B1 (ko) | 2005-11-30 | 2007-05-11 | 삼성에스디아이 주식회사 | 연료 전지용 캐소드 촉매, 이를 포함하는 연료 전지용막-전극 어셈블리 및 연료 전지 시스템 |
| JP4567588B2 (ja) | 2005-12-14 | 2010-10-20 | アイシン精機株式会社 | ガス拡散部材の製造方法、ガス拡散素材の製造方法、ガス拡散素材 |
| CA2531942A1 (en) * | 2005-12-27 | 2007-06-27 | The University Of Western Ontario | Fuel cell bioreactor |
| US20070178310A1 (en) | 2006-01-31 | 2007-08-02 | Rudyard Istvan | Non-woven fibrous materials and electrodes therefrom |
| JP2008047473A (ja) * | 2006-08-18 | 2008-02-28 | Nissan Motor Co Ltd | 電極触媒 |
| US8329356B2 (en) | 2006-09-07 | 2012-12-11 | GM Global Technology Operations LLC | Fuel cell microporous layer including particles with a controlled pore size distribution |
| US7968248B2 (en) | 2007-01-31 | 2011-06-28 | Junli Liu | Liquid-liquid fuel cell systems having flow-through anodes and flow-by cathodes |
| KR20080076173A (ko) | 2007-02-15 | 2008-08-20 | 삼성전자주식회사 | 금속 산화막 패턴 형성 방법 및 이를 이용한 반도체 소자의형성 방법 |
| KR100805527B1 (ko) * | 2007-02-15 | 2008-02-20 | 삼성에스디아이 주식회사 | 소형 이동전원용 연료 전지 및 이 연료전지에 사용되는막-전극 어셈블리 |
| KR100901846B1 (ko) * | 2007-09-11 | 2009-06-09 | 한국에너지기술연구원 | 탄소나노튜브 직접성장법과 백금 나노촉매의 담지를 위한화학기상증착법을 적용한 연료전지용 셀룰로스 전극의제조방법, 셀룰로스 전극 및 셀룰로스 섬유의 연료전지용전극으로서의 용도 |
| KR101483125B1 (ko) | 2008-02-05 | 2015-01-15 | 삼성에스디아이 주식회사 | 연료전지용 막전극 접합체, 그 제조방법 및 이를 채용한연료전지 |
| JP5262156B2 (ja) * | 2008-02-07 | 2013-08-14 | 凸版印刷株式会社 | 固体高分子型燃料電池およびその製造方法 |
| US9017837B2 (en) * | 2008-02-19 | 2015-04-28 | Cabot Corporation | High surface area graphitized carbon and processes for making same |
| CN102007186B (zh) | 2008-02-19 | 2014-01-22 | 卡伯特公司 | 中孔炭黑及其制造方法 |
| JP2009295441A (ja) * | 2008-06-05 | 2009-12-17 | Seizo Miyata | 炭素触媒、炭素触媒の製造方法、膜電極接合体、及び、燃料電池 |
| JP5463639B2 (ja) * | 2008-09-25 | 2014-04-09 | 三菱マテリアル株式会社 | 金属多孔質板の製造方法 |
| JP5439791B2 (ja) * | 2008-10-14 | 2014-03-12 | 三菱マテリアル株式会社 | 金属多孔質体の製造方法 |
| JP5332554B2 (ja) | 2008-11-27 | 2013-11-06 | 日産自動車株式会社 | 燃料電池用ガス拡散層及びその製造方法、並びにこれを用いた燃料電池 |
| EP2228857A1 (de) | 2009-03-06 | 2010-09-15 | Basf Se | Verbesserte Membran-Elektrodeneinheiten |
| JP2011028849A (ja) * | 2009-07-21 | 2011-02-10 | Tomoegawa Paper Co Ltd | 固体高分子型燃料電池用ガス拡散電極及びその製造方法 |
| JP2012146460A (ja) * | 2011-01-11 | 2012-08-02 | Sony Corp | 燃料電池、燃料電池の製造方法、電子機器、酵素固定化電極、バイオセンサー、エネルギー変換素子、細胞、細胞小器官および細菌 |
| JP5899885B2 (ja) * | 2011-01-31 | 2016-04-06 | ソニー株式会社 | 燃料電池、燃料電池の製造方法、電子機器、ニコチンアミドアデニンジヌクレオチド固定化電極、ニコチンアミドアデニンジヌクレオチド固定化担体、酵素反応利用装置、タンパク質固定化電極およびタンパク質固定化担体 |
-
2011
- 2011-06-22 GB GBGB1110585.5A patent/GB201110585D0/en not_active Ceased
-
2012
- 2012-06-22 IN IN2401MUN2013 patent/IN2013MN02401A/en unknown
- 2012-06-22 EP EP12730253.7A patent/EP2724407A2/en not_active Withdrawn
- 2012-06-22 JP JP2014516446A patent/JP6557007B2/ja not_active Expired - Fee Related
- 2012-06-22 BR BR112013033172A patent/BR112013033172A2/pt not_active IP Right Cessation
- 2012-06-22 KR KR1020147001817A patent/KR20140039317A/ko not_active Withdrawn
- 2012-06-22 US US14/127,764 patent/US10541422B2/en not_active Expired - Fee Related
- 2012-06-22 WO PCT/GB2012/051474 patent/WO2012175997A2/en not_active Ceased
- 2012-06-22 CN CN201280030919.4A patent/CN103733402A/zh active Pending
-
2018
- 2018-02-27 JP JP2018033142A patent/JP2018137228A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN103733402A (zh) | 2014-04-16 |
| KR20140039317A (ko) | 2014-04-01 |
| IN2013MN02401A (enExample) | 2015-06-12 |
| US20140205931A1 (en) | 2014-07-24 |
| BR112013033172A2 (pt) | 2017-03-01 |
| WO2012175997A2 (en) | 2012-12-27 |
| GB201110585D0 (en) | 2011-08-03 |
| US10541422B2 (en) | 2020-01-21 |
| JP2018137228A (ja) | 2018-08-30 |
| EP2724407A2 (en) | 2014-04-30 |
| WO2012175997A3 (en) | 2013-03-21 |
| JP2014517494A (ja) | 2014-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Jourdin et al. | A novel carbon nanotube modified scaffold as an efficient biocathode material for improved microbial electrosynthesis | |
| JP2018137228A (ja) | カソード電極材料 | |
| US11271220B2 (en) | Multilayer structure incorporating a mat of carbon nanotubes as diffusion layer in a PEMFC | |
| Li et al. | Recent advances and perspectives of practical modifications of vanadium redox flow battery electrodes | |
| JP6328114B2 (ja) | 触媒材料を調製するための方法 | |
| CN103022507B (zh) | 改进的气体扩散电极及其制造方法 | |
| CN104797742A (zh) | 电解电催化剂 | |
| JP6172276B2 (ja) | 燃料電池用金属製ガス拡散層の製造方法 | |
| CN106207201B (zh) | 一种含氧官能团梯度分布的还原氧化石墨烯/石墨烯泡沫复合材料及其在钒电池中的应用 | |
| JP2012252955A (ja) | 酵素燃料電池 | |
| EP4128394A1 (en) | Carbon electrodes having improved electrocatalytic activity | |
| Pan et al. | High‐Performance Porous Electrodes for Flow Batteries: Improvements of Specific Surface Areas and Reaction Kinetics | |
| CN101008087A (zh) | 一种固体聚合物电解质水电解用膜电极的制备方法 | |
| KR20100127577A (ko) | 그라핀이 코팅된 연료전지용 분리판 및 이의 제조방법 | |
| JPH06330367A (ja) | ガス電極の製造方法 | |
| CN113308707A (zh) | 用于电化学还原二氧化碳的气体扩散电极 | |
| TW200937710A (en) | Electrode for fuel cell having two kinds of hydrophilicity and method for preparing the same and membrane electrode assembly and fuel cell comprising the same | |
| CN115101771A (zh) | 燃料电池气体扩散层及其制备方法、燃料电池膜电极 | |
| JP2001338653A (ja) | 燃料電池用セパレータ | |
| CN106283104A (zh) | 非晶二氧化钛/纳米氧化铱/多孔硅阳极及其制备方法 | |
| KR102650338B1 (ko) | 탄소나노튜브 매트의 제조방법 및 이를 이용한 막 전극 접합체의 제조방법 | |
| CN119372708B (zh) | 一种aem电解槽阴极用析氢电极及其制备方法 | |
| Lee et al. | Miniature H2/O2 fuel cells using TiO2 nanotube substrates and sputtered Pt catalyst | |
| CN108539237A (zh) | 银/铂纳米催化剂修饰的Nafion复合膜及制备方法 | |
| CN101884128A (zh) | 催化剂层、膜电极组件、燃料电池和该催化剂层的制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140226 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20150618 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160316 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160405 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20160601 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161004 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170404 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20171031 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180227 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20180306 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20180330 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190426 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190711 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6557007 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |