KR101894709B1 - 에폭사이드로부터의 아크릴레이트의 생성방법 - Google Patents

에폭사이드로부터의 아크릴레이트의 생성방법 Download PDF

Info

Publication number
KR101894709B1
KR101894709B1 KR1020147013829A KR20147013829A KR101894709B1 KR 101894709 B1 KR101894709 B1 KR 101894709B1 KR 1020147013829 A KR1020147013829 A KR 1020147013829A KR 20147013829 A KR20147013829 A KR 20147013829A KR 101894709 B1 KR101894709 B1 KR 101894709B1
Authority
KR
South Korea
Prior art keywords
stream
acrylic acid
product stream
certain embodiments
metal carbonyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020147013829A
Other languages
English (en)
Korean (ko)
Other versions
KR20140084257A (ko
Inventor
리차드 브이. 포셀리
제이 제이. 파머
로버트 이. 라포인트
Original Assignee
노보머, 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 노보머, 인코포레이티드 filed Critical 노보머, 인코포레이티드
Publication of KR20140084257A publication Critical patent/KR20140084257A/ko
Application granted granted Critical
Publication of KR101894709B1 publication Critical patent/KR101894709B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/81—Preparation processes using solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020147013829A 2011-10-26 2012-10-25 에폭사이드로부터의 아크릴레이트의 생성방법 Active KR101894709B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161551496P 2011-10-26 2011-10-26
US61/551,496 2011-10-26
PCT/US2012/061791 WO2013063191A1 (en) 2011-10-26 2012-10-25 Process for production of acrylates from epoxides

Publications (2)

Publication Number Publication Date
KR20140084257A KR20140084257A (ko) 2014-07-04
KR101894709B1 true KR101894709B1 (ko) 2018-09-05

Family

ID=48168463

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147013829A Active KR101894709B1 (ko) 2011-10-26 2012-10-25 에폭사이드로부터의 아크릴레이트의 생성방법

Country Status (17)

Country Link
US (3) US9096510B2 (https=)
EP (2) EP3375769B1 (https=)
JP (3) JP6219834B2 (https=)
KR (1) KR101894709B1 (https=)
CN (2) CN103987682B (https=)
CY (1) CY1120779T1 (https=)
DK (1) DK2771307T3 (https=)
ES (1) ES2684970T3 (https=)
HK (1) HK1245240B (https=)
HR (1) HRP20181284T1 (https=)
HU (1) HUE039449T2 (https=)
LT (1) LT2771307T (https=)
PL (1) PL2771307T3 (https=)
PT (1) PT2771307T (https=)
SI (1) SI2771307T1 (https=)
SM (1) SMT201800438T1 (https=)
WO (1) WO2013063191A1 (https=)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2757835A1 (en) 2009-04-08 2010-10-14 Novomer, Inc. Process for beta-lactone production
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
CN103987682B (zh) * 2011-10-26 2017-06-16 诺沃梅尔公司 用于由环氧化物制备丙烯酸酯的工艺
US9403788B2 (en) 2012-02-13 2016-08-02 Novomer, Inc. Process for the production of acid anhydrides from epoxides
EP3077091A4 (en) 2013-12-07 2017-12-20 Novomer, Inc. Nanofiltration membranes and methods of use
CA2941714A1 (en) 2014-03-14 2015-09-17 Novomer, Inc. Catalysts for epoxide carbonylation
WO2015171372A1 (en) 2014-05-05 2015-11-12 Novomer, Inc. Catalyst recycle methods
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
CN104014227B (zh) * 2014-06-05 2016-03-09 万华化学集团股份有限公司 一种含环氧丙烷或环氧乙烷有机废气的净化方法
EP3171976B1 (en) * 2014-07-25 2023-09-06 Novomer, Inc. Synthesis of metal complexes and uses thereof
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
MA41514A (fr) * 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
US20180029005A1 (en) 2015-02-13 2018-02-01 Novomer, Inc. Flexible chemical production platform
HK1245308A1 (zh) * 2015-02-13 2018-08-24 诺沃梅尔公司 聚丙内酯生产方法和系统
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
US10221150B2 (en) 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
HK1247606A1 (zh) 2015-07-01 2018-09-28 诺沃梅尔公司 由环氧乙烷共同制造对苯二甲酸和苯乙烯的方法
WO2017004349A2 (en) 2015-07-01 2017-01-05 Novomer, Inc. Methods for production of terephthalic acid from ethylene oxide
KR20180027631A (ko) 2015-07-31 2018-03-14 노보머, 인코포레이티드 아크릴산 및 이의 전구체를 위한 제조 시스템/제조 방법
US20180305286A1 (en) 2016-03-21 2018-10-25 Novomer, Inc. Systems and Processes for Producing Organic Acids Direct from Beta-Lactones
JP6997459B2 (ja) * 2016-03-21 2022-02-04 ノボマー， インコーポレイテッド 改良されたアクリル酸製造プロセス
KR20180127429A (ko) * 2016-03-21 2018-11-28 노보머, 인코포레이티드 초흡수성 중합체의 제조를 위한 시스템 및 방법
US20180282251A1 (en) * 2017-03-21 2018-10-04 Novomer, Inc. Systems and processes for producing organic acids direct from beta-lactones
KR20190025574A (ko) * 2016-06-30 2019-03-11 제이엔씨 주식회사 에틸렌성 불포화기 함유 γ-부티로락톤 유도체의 제조 방법
CA3042253A1 (en) * 2016-11-02 2018-05-11 Han Lee Absorbent polymers, and methods and systems of producing thereof and uses thereof
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
KR20190126412A (ko) 2017-03-17 2019-11-11 노보머, 인코포레이티드 폴리아미드 및 이의 제조방법
US10065914B1 (en) 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10899622B2 (en) * 2017-06-30 2021-01-26 Novomer, Inc. Biobased carbon fibers and carbon black and methods of making the same
US10781156B2 (en) 2017-06-30 2020-09-22 Novomer, Inc. Compositions for improved production of acrylic acid
US10590099B1 (en) 2017-08-10 2020-03-17 Novomer, Inc. Processes for producing beta-lactone with heterogenous catalysts
US10961209B2 (en) * 2017-08-10 2021-03-30 Novomer, Inc. Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts
CN111094237A (zh) * 2017-09-09 2020-05-01 诺沃梅尔公司 酰胺化合物和腈化合物及其生产与使用方法
EP3691785A4 (en) * 2017-10-05 2021-08-04 Novomer, Inc. ISOCYANATES, DERIVATIVES AND METHOD FOR THEIR MANUFACTURING
CN112384299A (zh) 2018-06-29 2021-02-19 诺沃梅尔公司 直接由β-内酯生产有机酸的系统和方法
CN112423962A (zh) 2018-07-13 2021-02-26 诺沃梅尔公司 聚内酯发泡体及其制造方法
WO2020033248A1 (en) * 2018-08-07 2020-02-13 Novomer, Inc. Processes for producing beta-lactone and beta-lactone derivatives with heterogenous catalysts
CN113614064A (zh) 2019-03-08 2021-11-05 诺沃梅尔公司 用于产生酰胺和腈化合物的集成方法和系统
US11401251B2 (en) 2019-03-18 2022-08-02 Novomer, Inc. Membrane separation system, and uses thereof
US20220380330A1 (en) * 2019-11-01 2022-12-01 Exxonmobil Research And Engineering Company Process for Producing Substituted Lactones
FR3110570B1 (fr) * 2020-05-19 2022-05-20 Commissariat Energie Atomique PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE
EP4015077A1 (de) * 2020-12-15 2022-06-22 Covestro Deutschland AG Verfahren zur carbonylierung von epoxiden
EP4298147A1 (en) 2021-02-26 2024-01-03 Novomer, Inc. Methods for production of biodegradable polyesters
KR20230170697A (ko) 2021-04-16 2023-12-19 노보머, 인코포레이티드 폴리프로피오락톤 및 제조 방법
WO2023003890A1 (en) 2021-07-21 2023-01-26 Novomer, Inc. Methods for beta-lactone copolymerization
CN113786864A (zh) * 2021-09-07 2021-12-14 安徽建筑大学 一种催化剂及其催化乙酰丙酸加氢制γ-戊内酯的方法
CN115850065B (zh) * 2022-10-14 2024-12-20 水燃宝(北京)新能源有限公司 一种以硫酸氢钠为催化剂催化聚3-羟基丁酸酯降解制备r-3-羟基丁酸酯的方法
JP2026504450A (ja) 2023-02-02 2026-02-05 ノボマー， インコーポレイテッド ポリプロピオラクトン及びイオン性液体を使用した調製方法
CN116273120B (zh) * 2023-03-07 2024-07-05 青岛国恩科技股份有限公司 一种碳氮掺杂负载型钴基催化剂及其制备方法与应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050240032A1 (en) 2002-08-01 2005-10-27 Basf Aktiengesellschaft Catalyst for the carbonylation of oxiranes
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid
WO2010118128A1 (en) 2009-04-08 2010-10-14 Novomer, Inc. Process for beta-lactone production

Family Cites Families (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2361036A (en) 1941-07-31 1944-10-24 Goodrich Co B F Preparation of alpha-beta unsaturated carboxylic acids
US2352641A (en) 1941-08-05 1944-07-04 Goodrich Co B F Preparation of beta-alkoxy monocarboxylic acids
US2376704A (en) 1943-10-01 1945-05-22 Goodrich Co B F Preparation of esters of alpha-beta unsaturated monocarboxylic acids
US2422728A (en) 1945-10-05 1947-06-24 Goodrich Co B F Reaction of beta-lactone, alcohol and hydrogen halide
US2449995A (en) 1945-11-28 1948-09-28 Goodrich Co B F Preparation of esters of alpha beta unsaturated carboxylic acids
US2485510A (en) 1946-02-13 1949-10-18 American Cyanamid Co Preparation of acrylic acid and esters thereof
US2469704A (en) 1946-04-06 1949-05-10 Eastman Kodak Co Continuous process of producing beta lactones at reduced pressure
US2466501A (en) * 1947-03-31 1949-04-05 Goodrich Co B F Preparation of alpha-beta unsaturated monocarboxylic acid esters
US2510423A (en) 1948-02-09 1950-06-06 Goodrich Co B F Method of producing alkyl esters of alpha-beta unsaturated monocarboxylic acids froma beta-lactone and an alcohol
US2548155A (en) 1948-10-02 1951-04-10 Goodrich Co B F Preparation of amides
US2623067A (en) 1950-01-10 1952-12-23 Goodrich Co B F Preparation of beta-substituted acrylic acids
US3169945A (en) 1956-04-13 1965-02-16 Union Carbide Corp Lactone polyesters
US3176042A (en) 1959-10-20 1965-03-30 Celanese Corp Treating propiolactone with heated phosphoric acid to produce acrylic acid
DE1443433A1 (de) 1962-02-22 1968-10-31 Basf Ag Verfahren zur kontinuierlichen Herstellung von Acrylestern
US3326938A (en) 1962-11-09 1967-06-20 Du Pont Beta-lactone production
US3678069A (en) 1968-12-04 1972-07-18 Phillips Petroleum Co Lactone polymerization with a dicarboxylic acid-water initiator
NL7002062A (https=) 1970-02-13 1970-04-22
US4590293A (en) 1982-01-18 1986-05-20 Ashland Oil, Inc. Process and apparatus for further processing of pressurized exothermic reactions
US4873378A (en) 1986-08-20 1989-10-10 Hoechst Celanese Corporation Process for making 1,3-diols from epoxides
CA1339317C (en) * 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
CA2034971A1 (en) * 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
EP0577206B1 (en) 1992-06-29 1998-08-26 Shell Internationale Researchmaatschappij B.V. Carbonylation of epoxides
KR940005525A (ko) * 1992-06-29 1994-03-21 알베르투스 빌헬무스, 요아네스 쩨스트 라텐 에폭시드의 카르보닐화 방법
JPH083333A (ja) 1994-06-22 1996-01-09 Tokuyama Corp 生分解性脂肪族ポリエステルの溶融押出フィルムおよびそれからなる袋
CA2181794C (en) 1994-01-28 2000-08-01 Lee Arnold Schechtman Polymerization of beta-substituted-beta-propiolactones initiated by alkylzinc alkoxides
CN1041591C (zh) 1995-03-24 1999-01-13 袁鸿泰 聚丙烯丝网藻类附着基及加工方法
JPH09169753A (ja) * 1995-12-21 1997-06-30 Tokuyama Corp ２−オキセタノン類化合物の製造方法
US6133402A (en) 1998-08-04 2000-10-17 Cornell Research Foundation, Inc. Polycarbonates made using high activity catalysts
US6608170B1 (en) 1999-03-31 2003-08-19 Cornell Research Foundation, Inc. Syndiotactic poly(lactic acid)
US6316590B1 (en) 1999-11-10 2001-11-13 Cornell Research Foundation, Inc. Synthesis of stereospecific and atactic poly(lactic acid)s
US6392078B1 (en) 2000-06-12 2002-05-21 Catalytic Distillation Technologies Process and catalyst for making dialkyl carbonates
US6538101B2 (en) 2000-10-24 2003-03-25 Cornell Research Foundation, Inc. Preparing isotactic stereoblock poly(lactic acid)
KR100447932B1 (ko) 2001-10-19 2004-09-08 한국화학연구원 실리콘이 함유된 내유기용매성 폴리아미드 나노복합막과 이의 제조방법
ATE437854T1 (de) * 2001-12-06 2009-08-15 Cornell Res Foundation Inc Katalytische carbonylierung von drei- und viergliedrigen heterocyklen
EP1501779B1 (en) 2002-05-06 2009-12-23 Eastman Chemical Company Continuous carbonylation process
ITMI20021358A1 (it) 2002-06-19 2003-12-19 Lonza Spa Catalizzatore per la preparazione di anidride ftalica
DE10235317A1 (de) * 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
JP2006524213A (ja) * 2003-04-09 2006-10-26 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ エポキシドのカルボニル化法
MXPA06009440A (es) 2004-02-17 2007-03-15 Thomas E Johnson Metodos, composiciones y aparatos para la formacion de compuestos macrociclicos.
DE102005017049A1 (de) 2005-04-12 2006-10-19 Basf Ag Verfahren zur Herstellung von Polyhydroxyalkanoaten
US7582792B2 (en) * 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
EP2325214B1 (en) * 2009-11-20 2015-11-18 King Saud University Synthesis of acrylic or methacrylic acid/acrylate or methacrylate ester polymers using pervaporation
EP2609090A4 (en) 2010-08-28 2013-12-25 Novomer Inc AMMONIC ACID ANHYDRIDE FROM ETHYLENE OXIDE
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
US20110319849A1 (en) * 2011-07-01 2011-12-29 Dimitris Ioannis Collias Absorbent article comprising a synthetic polymer derived from a renewable resource and methods of producing said article
CN103987682B (zh) 2011-10-26 2017-06-16 诺沃梅尔公司 用于由环氧化物制备丙烯酸酯的工艺
US9403788B2 (en) 2012-02-13 2016-08-02 Novomer, Inc. Process for the production of acid anhydrides from epoxides
RS58521B1 (sr) 2012-02-22 2019-04-30 Novomer Inc Postupci dobijanja akrilne kiseline
JP5843659B2 (ja) 2012-02-24 2016-01-13 株式会社日本触媒 エポキシドのラクトン化用触媒及びそれを用いたラクトン化方法
JP2015522091A (ja) 2012-06-27 2015-08-03 ノボマー， インコーポレイテッド ポリエステル生成のための触媒および方法
BR112015000002A2 (pt) 2012-07-02 2017-06-27 Novomer Inc processo para produção de acrilato
EP3077091A4 (en) 2013-12-07 2017-12-20 Novomer, Inc. Nanofiltration membranes and methods of use
CA2941714A1 (en) 2014-03-14 2015-09-17 Novomer, Inc. Catalysts for epoxide carbonylation
WO2015171372A1 (en) 2014-05-05 2015-11-12 Novomer, Inc. Catalyst recycle methods
EP3148959B1 (en) 2014-05-30 2023-11-22 Novomer Inc. Integrated methods for chemical synthesis
EP3171976B1 (en) 2014-07-25 2023-09-06 Novomer, Inc. Synthesis of metal complexes and uses thereof
MA41513A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de distillation pour la production d'acide acrylique
MA41514A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédés intégrés de synthèse chimique
US20180029005A1 (en) 2015-02-13 2018-02-01 Novomer, Inc. Flexible chemical production platform
MA41507A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production de polymères
MA41510A (fr) 2015-02-13 2017-12-19 Novomer Inc Procédé de production d'acide acrylique
US10221150B2 (en) 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
MA41508A (fr) 2015-02-13 2017-12-19 Novomer Inc Systèmes et procédés de production d'acide polyacrylique
HK1245308A1 (zh) 2015-02-13 2018-08-24 诺沃梅尔公司 聚丙内酯生产方法和系统

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050240032A1 (en) 2002-08-01 2005-10-27 Basf Aktiengesellschaft Catalyst for the carbonylation of oxiranes
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid
WO2010118128A1 (en) 2009-04-08 2010-10-14 Novomer, Inc. Process for beta-lactone production

Also Published As

Publication number Publication date
EP3375769A1 (en) 2018-09-19
PL2771307T3 (pl) 2019-06-28
EP2771307B1 (en) 2018-05-30
US9096510B2 (en) 2015-08-04
CN107382699A (zh) 2017-11-24
US20140309399A1 (en) 2014-10-16
US20150299083A1 (en) 2015-10-22
SMT201800438T1 (it) 2018-11-09
WO2013063191A1 (en) 2013-05-02
JP6486992B2 (ja) 2019-03-20
EP3375769B1 (en) 2022-03-09
CN103987682A (zh) 2014-08-13
EP2771307A4 (en) 2015-06-24
US20170247309A1 (en) 2017-08-31
US9914689B2 (en) 2018-03-13
JP2018119010A (ja) 2018-08-02
HRP20181284T1 (hr) 2018-10-05
LT2771307T (lt) 2018-09-25
CY1120779T1 (el) 2019-12-11
PT2771307T (pt) 2018-10-09
JP2017171681A (ja) 2017-09-28
JP2014532650A (ja) 2014-12-08
SI2771307T1 (sl) 2018-10-30
JP6219834B2 (ja) 2017-10-25
EP2771307A1 (en) 2014-09-03
DK2771307T3 (en) 2018-08-13
CN107382699B (zh) 2019-02-22
HUE039449T2 (hu) 2018-12-28
CN103987682B (zh) 2017-06-16
HK1245240B (zh) 2020-04-09
KR20140084257A (ko) 2014-07-04
ES2684970T3 (es) 2018-10-05

Similar Documents

Publication Publication Date Title
KR101894709B1 (ko) 에폭사이드로부터의 아크릴레이트의 생성방법
HK1245240A1 (en) Process for production of acrylates from epoxides
JP7072295B2 (ja) ポリプロピオラクトンの生成のためのプロセスおよびシステム
CN104245659B (zh) 由环氧化物生产酸酐的方法
CN102421821B (zh) β-内酯的制造方法
KR20150027766A (ko) 아크릴레이트 제조 방법
KR102112497B1 (ko) 치환된 살리실알데하이드 유도체의 합성
HK1261068A1 (en) Process for the preparation of acrylates from epoxides
Buckley et al. A rapid and highly diastereoselective synthesis of enantiomerically pure (4R, 5R)-and (4S, 5S)-isocytoxazone

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

A201 Request for examination
A302 Request for accelerated examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PA0302 Request for accelerated examination

St.27 status event code: A-1-2-D10-D17-exm-PA0302

St.27 status event code: A-1-2-D10-D16-exm-PA0302

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

FPAY Annual fee payment

Payment date: 20210813

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20220812

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 8