KR101687055B1 - 중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질 - Google Patents

중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질 Download PDF

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KR101687055B1
KR101687055B1 KR1020130055885A KR20130055885A KR101687055B1 KR 101687055 B1 KR101687055 B1 KR 101687055B1 KR 1020130055885 A KR1020130055885 A KR 1020130055885A KR 20130055885 A KR20130055885 A KR 20130055885A KR 101687055 B1 KR101687055 B1 KR 101687055B1
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hollow
particles
silicon
sio
silicone
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KR20140135512A (ko
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한기범
박홍규
정왕모
강성중
조치호
류지훈
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주식회사 엘지화학
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Priority to EP14789764.9A priority patent/EP2835350B1/en
Priority to IN10284DEN2014 priority patent/IN2014DN10284A/en
Priority to PCT/KR2014/004370 priority patent/WO2014185730A1/ko
Priority to JP2015525386A priority patent/JP6024073B2/ja
Priority to CN201480001449.8A priority patent/CN104334496B/zh
Priority to TW103117304A priority patent/TWI546255B/zh
Priority to US14/464,802 priority patent/US9722242B2/en
Publication of KR20140135512A publication Critical patent/KR20140135512A/ko
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/02—Silicon
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/02—Silicon
    • C01B33/021—Preparation
    • C01B33/023—Preparation by reduction of silica or free silica-containing material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/02—Silicon
    • C01B33/021—Preparation
    • C01B33/027—Preparation by decomposition or reduction of gaseous or vaporised silicon compounds other than silica or silica-containing material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Silicon Compounds (AREA)
KR1020130055885A 2013-05-16 2013-05-16 중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질 Active KR101687055B1 (ko)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020130055885A KR101687055B1 (ko) 2013-05-16 2013-05-16 중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질
IN10284DEN2014 IN2014DN10284A (enExample) 2013-05-16 2014-05-15
PCT/KR2014/004370 WO2014185730A1 (ko) 2013-05-16 2014-05-15 중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질
JP2015525386A JP6024073B2 (ja) 2013-05-16 2014-05-15 中空型シリコン系粒子、その製造方法
EP14789764.9A EP2835350B1 (en) 2013-05-16 2014-05-15 Hollow silicon-based particles, preparation method therefor, and anode active material for lithium secondary battery, containing same
CN201480001449.8A CN104334496B (zh) 2013-05-16 2014-05-15 中空型硅类粒子及其制备方法和包括该粒子的锂二次电池用负极活性物质
TW103117304A TWI546255B (zh) 2013-05-16 2014-05-16 中空以矽爲底質之顆粒，其製法和用於含有彼之鋰二次電池的陽極活性材料
US14/464,802 US9722242B2 (en) 2013-05-16 2014-08-21 Hollow silicon-based particle, preparation method thereof and anode active material for lithium secondary battery including the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020130055885A KR101687055B1 (ko) 2013-05-16 2013-05-16 중공형 실리콘계 입자, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지용 음극 활물질

Publications (2)

Publication Number Publication Date
KR20140135512A KR20140135512A (ko) 2014-11-26
KR101687055B1 true KR101687055B1 (ko) 2016-12-15

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Country Status (8)

Country Link
US (1) US9722242B2 (enExample)
EP (1) EP2835350B1 (enExample)
JP (1) JP6024073B2 (enExample)
KR (1) KR101687055B1 (enExample)
CN (1) CN104334496B (enExample)
IN (1) IN2014DN10284A (enExample)
TW (1) TWI546255B (enExample)
WO (1) WO2014185730A1 (enExample)

Cited By (2)

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KR20230019530A (ko) 2021-08-02 2023-02-09 주식회사 한솔케미칼 음극 활물질 조성물, 그의 제조방법 및 이를 포함하는 리튬 이차전지
KR20240066309A (ko) 2022-11-07 2024-05-14 국립한국교통대학교산학협력단 카테콜 유도체로 표면 개질된 2차원 맥신쉘의 중공 실리콘계 입자, 그 입자를 이용한 리튬 이차전지 음극활물질 및 그 제조 방법

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CN105226260B (zh) * 2015-10-19 2017-11-24 中南大学 一种锂离子电池用硅基负极材料的制备方法
CN106129411B (zh) * 2016-09-19 2020-01-24 深圳市贝特瑞新能源材料股份有限公司 一种空心硅基复合材料、制备方法及包含该复合材料的锂离子电池
KR102118551B1 (ko) 2017-03-13 2020-06-03 주식회사 엘지화학 음극 활물질의 제조 방법
KR102101007B1 (ko) * 2017-03-16 2020-05-15 주식회사 엘지화학 실리콘계 음극 활물질, 이를 포함하는 음극, 이차 전지, 및 상기 실리콘계 음극 활물질의 제조 방법
KR102201589B1 (ko) * 2017-06-12 2021-01-11 주식회사 엘지화학 중공형 실리콘계 입자의 제조 방법
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CN116053452B (zh) * 2019-12-31 2024-11-15 华为技术有限公司 硅基负极材料及其制备方法、电池和终端
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JP2022190387A (ja) * 2021-06-14 2022-12-26 東ソー株式会社 リチウム二次電池用複合活物質およびその製造方法
CN114275823B (zh) * 2021-12-15 2024-02-13 欣旺达惠州动力新能源有限公司 一种中空纳米球复合材料、其制备方法和锂电池
KR102762004B1 (ko) * 2022-09-02 2025-02-05 주식회사 케이씨텍 중공실리카 입자, 그의 제조방법 및 중공실리카 분산액
KR102882718B1 (ko) * 2022-10-26 2025-11-05 국민대학교산학협력단 이차전지용 음극 및 이의 제조방법
CN116314674A (zh) * 2023-03-04 2023-06-23 珠海冠宇电池股份有限公司 负极材料、负极片和电池
KR20250134699A (ko) 2023-03-22 2025-09-11 스미토모덴키고교가부시키가이샤 비수계 전해질 2차 전지용 부극 활물질, 비수계 전해질 2차 전지용 부극, 비수계 전해질 2차 전지
KR102620101B1 (ko) * 2023-05-26 2024-01-03 주식회사 에버인더스 중공구조를 갖는 전기화학소자용 실리콘계 음극 활물질, 이를 포함하는 전기화학소자 및 이의 제조방법
CN117476902B (zh) * 2023-11-24 2024-04-02 湖北美赛尔科技有限公司 一种超低温高循环稳定性的硅基负极材料及其锂离子电池
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KR20140135512A (ko) 2014-11-26
EP2835350A1 (en) 2015-02-11
JP6024073B2 (ja) 2016-11-09
US20140356726A1 (en) 2014-12-04
JP2015530342A (ja) 2015-10-15
US9722242B2 (en) 2017-08-01
WO2014185730A1 (ko) 2014-11-20
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