KR101407801B1 - 과산화물 경화를 사용하는 3차원 인쇄 물질 시스템 및 방법 - Google Patents
과산화물 경화를 사용하는 3차원 인쇄 물질 시스템 및 방법 Download PDFInfo
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- KR101407801B1 KR101407801B1 KR1020097014178A KR20097014178A KR101407801B1 KR 101407801 B1 KR101407801 B1 KR 101407801B1 KR 1020097014178 A KR1020097014178 A KR 1020097014178A KR 20097014178 A KR20097014178 A KR 20097014178A KR 101407801 B1 KR101407801 B1 KR 101407801B1
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Classifications
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/165—Processes of additive manufacturing using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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Families Citing this family (136)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001034371A2 (en) | 1999-11-05 | 2001-05-17 | Z Corporation | Material systems and methods of three-dimensional printing |
| EP2664442B1 (en) | 2006-12-08 | 2018-02-14 | 3D Systems Incorporated | Three dimensional printing material system |
| WO2008086033A1 (en) * | 2007-01-10 | 2008-07-17 | Z Corporation | Three-dimensional printing material system with improved color, article performance, and ease of use |
| US7968626B2 (en) | 2007-02-22 | 2011-06-28 | Z Corporation | Three dimensional printing material system and method using plasticizer-assisted sintering |
| US10226919B2 (en) | 2007-07-18 | 2019-03-12 | Voxeljet Ag | Articles and structures prepared by three-dimensional printing method |
| DE102007050953A1 (de) | 2007-10-23 | 2009-04-30 | Voxeljet Technology Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
| US8067305B2 (en) | 2008-09-03 | 2011-11-29 | Ultratech, Inc. | Electrically conductive structure on a semiconductor substrate formed from printing |
| DE102010006939A1 (de) | 2010-02-04 | 2011-08-04 | Voxeljet Technology GmbH, 86167 | Vorrichtung zum Herstellen dreidimensionaler Modelle |
| DE102010013732A1 (de) | 2010-03-31 | 2011-10-06 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
| DE102010014969A1 (de) | 2010-04-14 | 2011-10-20 | Voxeljet Technology Gmbh | Vorrichtung zum Herstellen dreidimensionaler Modelle |
| DE102010015451A1 (de) | 2010-04-17 | 2011-10-20 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Objekte |
| JP5890990B2 (ja) | 2010-11-01 | 2016-03-22 | 株式会社キーエンス | インクジェット光造形法における、光造形品形成用モデル材、光造形品の光造形時の形状支持用サポート材および光造形品の製造方法 |
| DE102010056346A1 (de) * | 2010-12-29 | 2012-07-05 | Technische Universität München | Verfahren zum schichtweisen Aufbau von Modellen |
| DE102011007957A1 (de) | 2011-01-05 | 2012-07-05 | Voxeljet Technology Gmbh | Vorrichtung und Verfahren zum Aufbauen eines Schichtenkörpers mit wenigstens einem das Baufeld begrenzenden und hinsichtlich seiner Lage einstellbaren Körper |
| US9156999B2 (en) * | 2011-07-28 | 2015-10-13 | Hewlett-Packard Development Company, L.P. | Liquid inkjettable materials for three-dimensional printing |
| DE102011111498A1 (de) | 2011-08-31 | 2013-02-28 | Voxeljet Technology Gmbh | Vorrichtung zum schichtweisen Aufbau von Modellen |
| US20130101729A1 (en) * | 2011-10-21 | 2013-04-25 | John J. Keremes | Real time cap flattening during heat treat |
| DE102012004213A1 (de) | 2012-03-06 | 2013-09-12 | Voxeljet Technology Gmbh | Verfahren und Vorrichtung zum Herstellen dreidimensionaler Modelle |
| DE102012010272A1 (de) | 2012-05-25 | 2013-11-28 | Voxeljet Technology Gmbh | Verfahren zum Herstellen dreidimensionaler Modelle mit speziellen Bauplattformen und Antriebssystemen |
| DE102012012363A1 (de) | 2012-06-22 | 2013-12-24 | Voxeljet Technology Gmbh | Vorrichtung zum Aufbauen eines Schichtenkörpers mit entlang des Austragbehälters bewegbarem Vorrats- oder Befüllbehälter |
| US8888480B2 (en) | 2012-09-05 | 2014-11-18 | Aprecia Pharmaceuticals Company | Three-dimensional printing system and equipment assembly |
| KR101697105B1 (ko) | 2012-09-05 | 2017-01-17 | 아프레시아 파마슈티칼스 컴퍼니 | 3차원 인쇄 시스템 및 장비 어셈블리 |
| WO2014041670A1 (ja) * | 2012-09-13 | 2014-03-20 | 富士機械製造株式会社 | 電子デバイスの製造装置及びその製造方法 |
| DE102012020000A1 (de) | 2012-10-12 | 2014-04-17 | Voxeljet Ag | 3D-Mehrstufenverfahren |
| DE102013004940A1 (de) | 2012-10-15 | 2014-04-17 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit temperiertem Druckkopf |
| DE102012022859A1 (de) | 2012-11-25 | 2014-05-28 | Voxeljet Ag | Aufbau eines 3D-Druckgerätes zur Herstellung von Bauteilen |
| DE102013003303A1 (de) | 2013-02-28 | 2014-08-28 | FluidSolids AG | Verfahren zum Herstellen eines Formteils mit einer wasserlöslichen Gussform sowie Materialsystem zu deren Herstellung |
| US9353284B2 (en) | 2013-03-15 | 2016-05-31 | 3D Systems, Inc. | Three dimensional printing material system and method |
| US9533451B2 (en) | 2013-03-15 | 2017-01-03 | 3D Systems, Inc. | Direct writing for additive manufacturing systems |
| US11077632B2 (en) | 2013-03-15 | 2021-08-03 | 3D Systems, Inc. | Microwave post-processing for additive manufacturing |
| HK1216513A1 (zh) | 2013-03-15 | 2016-11-18 | 阿普雷奇亚制药有限责任公司 | 包含左乙拉西坦的快速分散劑型 |
| CN105451950B (zh) | 2013-08-15 | 2019-03-12 | 哈利伯顿能源服务公司 | 支撑剂的加成制造 |
| WO2015056232A1 (en) * | 2013-10-17 | 2015-04-23 | Xjet Ltd. | Support ink for three dimensional (3d) printing |
| DE102013018182A1 (de) | 2013-10-30 | 2015-04-30 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von dreidimensionalen Modellen mit Bindersystem |
| DE102013018031A1 (de) | 2013-12-02 | 2015-06-03 | Voxeljet Ag | Wechselbehälter mit verfahrbarer Seitenwand |
| DE102013020491A1 (de) | 2013-12-11 | 2015-06-11 | Voxeljet Ag | 3D-Infiltrationsverfahren |
| EP2886307A1 (de) | 2013-12-20 | 2015-06-24 | Voxeljet AG | Vorrichtung, Spezialpapier und Verfahren zum Herstellen von Formteilen |
| WO2015100243A1 (en) * | 2013-12-23 | 2015-07-02 | 3D Systems, Inc. | Three dimensional printing materials, systems, and methods |
| WO2015108544A1 (en) * | 2014-01-16 | 2015-07-23 | Hewlett-Packard Development Company, L.P. | Polymeric powder composition for three-dimensional (3d) printing |
| US10583612B2 (en) | 2014-01-16 | 2020-03-10 | Hewlett-Packard Development Company, L.P. | Three-dimensional (3D) printing method |
| DE102014004692A1 (de) | 2014-03-31 | 2015-10-15 | Voxeljet Ag | Verfahren und Vorrichtung für den 3D-Druck mit klimatisierter Verfahrensführung |
| JP5911905B2 (ja) * | 2014-03-31 | 2016-04-27 | 株式会社東芝 | 積層造形物の製造方法 |
| DE102014007584A1 (de) | 2014-05-26 | 2015-11-26 | Voxeljet Ag | 3D-Umkehrdruckverfahren und Vorrichtung |
| US20150367415A1 (en) | 2014-06-20 | 2015-12-24 | Velo3D, Inc. | Apparatuses, systems and methods for three-dimensional printing |
| CN105295325B (zh) | 2014-06-27 | 2019-12-27 | 康廷南拓结构塑料有限公司 | 包括表面改性的微球体的低密度模塑料 |
| JP6459246B2 (ja) * | 2014-06-30 | 2019-01-30 | セイコーエプソン株式会社 | 三次元造形物の製造方法 |
| EP3174651B1 (de) | 2014-08-02 | 2020-06-17 | voxeljet AG | Verfahren und gussform, insbesondere zur verwendung in kaltgussverfahren |
| KR101504073B1 (ko) * | 2014-09-23 | 2015-03-19 | 박정동 | 박막적층 방식 및 경화성 물질을 이용하는 3d 프린팅 방법 |
| JP6471482B2 (ja) | 2014-12-04 | 2019-02-20 | 株式会社リコー | 立体造形用硬化液、及び立体造形材料セット、並びに立体造形物の製造方法 |
| DE102015006533A1 (de) | 2014-12-22 | 2016-06-23 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Schichtaufbautechnik |
| WO2016106062A1 (en) | 2014-12-23 | 2016-06-30 | Bridgestone Americas Tire Operations, Llc | Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes |
| WO2016149104A1 (en) * | 2015-03-13 | 2016-09-22 | Carbon3D, Inc. | Three-dimensional printing with flexible build plates |
| DE102015003372A1 (de) | 2015-03-17 | 2016-09-22 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Doppelrecoater |
| JP6516149B2 (ja) * | 2015-03-18 | 2019-05-22 | 株式会社リコー | 立体造形用粉末材料、立体造形用キット、及び立体造形物の製造方法 |
| JP6516201B2 (ja) * | 2015-03-30 | 2019-05-22 | 株式会社リコー | 立体造形用粉末材料、立体造形用キット、及び立体造形物の製造方法 |
| US10563292B2 (en) | 2015-04-09 | 2020-02-18 | Electronics And Telecommunications Research Institute | Metal material for 3-dimensional printing, method for manufacturing the same, and method for 3-dimensional printing using the same |
| US10612112B2 (en) | 2015-04-09 | 2020-04-07 | Electronics And Telecommunications Research Institute | Noble metal material for 3-dimensional printing, method for manufacturing the same, and method for 3-dimensional printing using the same |
| DE102015006363A1 (de) | 2015-05-20 | 2016-12-15 | Voxeljet Ag | Phenolharzverfahren |
| KR102037558B1 (ko) * | 2015-07-20 | 2019-10-28 | 주식회사 엘지화학 | 3d 프린팅 지지체용 잉크 조성물 및 이를 이용한 3d 프린팅 제조방법 |
| EP3130636A1 (en) * | 2015-08-13 | 2017-02-15 | 3M Innovative Properties Company | Polyolefin composition comprising hollow glass microspheres |
| CN116423825A (zh) | 2015-08-21 | 2023-07-14 | 阿普雷奇亚制药有限责任公司 | 三维打印系统和设备组件 |
| DE102015011503A1 (de) | 2015-09-09 | 2017-03-09 | Voxeljet Ag | Verfahren zum Auftragen von Fluiden |
| DE102015011790A1 (de) | 2015-09-16 | 2017-03-16 | Voxeljet Ag | Vorrichtung und Verfahren zum Herstellen dreidimensionaler Formteile |
| WO2017049047A1 (en) | 2015-09-17 | 2017-03-23 | 3Dbotics, Inc. | Material system and method for fabricating refractory material-based 3d printed objects |
| US10065270B2 (en) | 2015-11-06 | 2018-09-04 | Velo3D, Inc. | Three-dimensional printing in real time |
| DE102015015353A1 (de) | 2015-12-01 | 2017-06-01 | Voxeljet Ag | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Bauteilen mittels Überschussmengensensor |
| WO2017100695A1 (en) | 2015-12-10 | 2017-06-15 | Velo3D, Inc. | Skillful three-dimensional printing |
| WO2017105960A1 (en) | 2015-12-17 | 2017-06-22 | Bridgestone Americas Tire Operations, Llc | Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing |
| DE102015016464B4 (de) | 2015-12-21 | 2024-04-25 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen |
| WO2017143077A1 (en) | 2016-02-18 | 2017-08-24 | Velo3D, Inc. | Accurate three-dimensional printing |
| DE102016002777A1 (de) | 2016-03-09 | 2017-09-14 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Baufeldwerkzeugen |
| NO341465B1 (en) | 2016-05-03 | 2017-11-20 | Sintef Tto As | Method for manufacturing a porous foam support, and porous foam supports for catalytic reactors, adsorption processes and energy storage |
| US10765658B2 (en) | 2016-06-22 | 2020-09-08 | Mastix LLC | Oral compositions delivering therapeutically effective amounts of cannabinoids |
| US11691343B2 (en) | 2016-06-29 | 2023-07-04 | Velo3D, Inc. | Three-dimensional printing and three-dimensional printers |
| EP3492244A1 (en) | 2016-06-29 | 2019-06-05 | VELO3D, Inc. | Three-dimensional printing system and method for three-dimensional printing |
| US11613076B2 (en) | 2016-07-26 | 2023-03-28 | Ppg Industries Ohio, Inc. | Three-dimensional printing processes using 1,1-di-activated vinyl compounds |
| PT3519514T (pt) * | 2016-09-28 | 2021-04-13 | Evonik Roehm Gmbh | Produção e utilização de polímeros de grânulos porosos em impressão 3d de acordo com o processo de jateamento de ligante |
| US20180093418A1 (en) | 2016-09-30 | 2018-04-05 | Velo3D, Inc. | Three-dimensional objects and their formation |
| EP3532267B1 (en) | 2016-10-27 | 2023-03-01 | Bridgestone Americas Tire Operations, LLC | Processes for producing cured polymeric products by additive manufacturing |
| US20180126462A1 (en) | 2016-11-07 | 2018-05-10 | Velo3D, Inc. | Gas flow in three-dimensional printing |
| DE102016013610A1 (de) | 2016-11-15 | 2018-05-17 | Voxeljet Ag | Intregierte Druckkopfwartungsstation für das pulverbettbasierte 3D-Drucken |
| KR102202909B1 (ko) * | 2016-11-21 | 2021-01-14 | 주식회사 엘지화학 | 3d 프린팅용 조성물 |
| US10611092B2 (en) | 2017-01-05 | 2020-04-07 | Velo3D, Inc. | Optics in three-dimensional printing |
| US10357829B2 (en) | 2017-03-02 | 2019-07-23 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US20180281237A1 (en) | 2017-03-28 | 2018-10-04 | Velo3D, Inc. | Material manipulation in three-dimensional printing |
| CN107098715A (zh) * | 2017-04-26 | 2017-08-29 | 西安交通大学 | 一种基于双重固化体系粘接剂的陶瓷零件3d打印方法 |
| US10435576B2 (en) | 2017-05-26 | 2019-10-08 | Infinite Material Solutions, Llc | Water soluble polymer compositions |
| DE102017006860A1 (de) | 2017-07-21 | 2019-01-24 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mit Spektrumswandler |
| US11420384B2 (en) | 2017-10-03 | 2022-08-23 | General Electric Company | Selective curing additive manufacturing method |
| US11254052B2 (en) | 2017-11-02 | 2022-02-22 | General Electric Company | Vatless additive manufacturing apparatus and method |
| US11590691B2 (en) | 2017-11-02 | 2023-02-28 | General Electric Company | Plate-based additive manufacturing apparatus and method |
| US10272525B1 (en) | 2017-12-27 | 2019-04-30 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| EP3732044A1 (en) * | 2017-12-31 | 2020-11-04 | Stratasys Ltd. | Modeling material formulations usable in additive manufacturing of three-dimensional objects at low temperatures |
| US10144176B1 (en) | 2018-01-15 | 2018-12-04 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| US10821668B2 (en) | 2018-01-26 | 2020-11-03 | General Electric Company | Method for producing a component layer-by- layer |
| US10821669B2 (en) | 2018-01-26 | 2020-11-03 | General Electric Company | Method for producing a component layer-by-layer |
| WO2019245535A1 (en) | 2018-06-19 | 2019-12-26 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing |
| US11298876B2 (en) | 2018-06-19 | 2022-04-12 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing |
| US11426931B2 (en) | 2018-06-19 | 2022-08-30 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing |
| EP3824029A1 (en) * | 2018-07-18 | 2021-05-26 | Arkema France | Compositions and methods useful for forming sintered articles |
| DE102018006473A1 (de) | 2018-08-16 | 2020-02-20 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen durch Schichtaufbautechnik mittels Verschlussvorrichtung |
| CN110877427B (zh) * | 2018-09-06 | 2021-07-06 | 西安交通大学 | 一种含有空心陶瓷球的复合材料及其制备方法 |
| CN113329861A (zh) * | 2018-11-21 | 2021-08-31 | 适应3D技术公司 | 使用封堵流体增强增材制造工艺 |
| US11911956B2 (en) | 2018-11-21 | 2024-02-27 | Adaptive 3D Technologies | Using occluding fluids to augment additive manufacturing processes |
| US11820075B2 (en) | 2018-12-06 | 2023-11-21 | Jabil Inc. | Apparatus, system and method of imparting specified characteristics to additively manufactured foam |
| WO2020132425A1 (en) * | 2018-12-21 | 2020-06-25 | Braskem America, Inc. | Processing aid for high speed sintering, methods thereof, and articles therefrom |
| DE102019000796A1 (de) | 2019-02-05 | 2020-08-06 | Voxeljet Ag | Wechselbare Prozesseinheit |
| US11498283B2 (en) | 2019-02-20 | 2022-11-15 | General Electric Company | Method and apparatus for build thickness control in additive manufacturing |
| US11794412B2 (en) | 2019-02-20 | 2023-10-24 | General Electric Company | Method and apparatus for layer thickness control in additive manufacturing |
| US11179891B2 (en) | 2019-03-15 | 2021-11-23 | General Electric Company | Method and apparatus for additive manufacturing with shared components |
| US20220315495A1 (en) * | 2019-06-04 | 2022-10-06 | A&S Business Group Pty Ltd | Materials and processes for manufacturing carbon composite articles by three-dimensional printing |
| DE102019004176A1 (de) | 2019-06-14 | 2020-12-17 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mittels Schichtaufbautechnik und Beschichter mit Unterdruckverschluss |
| CA3148849A1 (en) | 2019-07-26 | 2021-02-04 | Velo3D, Inc. | Quality assurance in formation of three-dimensional objects |
| US12202039B2 (en) | 2019-09-16 | 2025-01-21 | Hewlett-Packard Development Company, L.P. | Circulation paths for fluid dispensing devices |
| DE102019007073A1 (de) | 2019-10-11 | 2021-04-15 | Voxeljet Ag | Verfahren und Vorrichtung zum Herstellen von 3D-Formteilen mittels Hochleistungsstrahler |
| DE102019007595A1 (de) | 2019-11-01 | 2021-05-06 | Voxeljet Ag | 3d-druckverfahren und damit hergestelltes formteil unter verwendung von ligninsulfat |
| CN110684401A (zh) * | 2019-11-25 | 2020-01-14 | 武汉绿之美铸造材料有限公司 | 一种丙烯酸3d打印用墨水 |
| US12371581B2 (en) | 2020-03-25 | 2025-07-29 | Infinite Material Solutions, Llc | High performance water soluble polymer compositions |
| EP3914043A1 (en) * | 2020-05-20 | 2021-11-24 | Henkel IP & Holding GmbH | Post processing of 3d printed materials via microwave enhanced chemistry |
| GB2612508B (en) * | 2020-07-10 | 2025-04-09 | Fosbel Wahl Holdings Llc | High emissivity refractory materials and refractory components formed thereof |
| US11707883B2 (en) | 2020-11-20 | 2023-07-25 | General Electric Company | Foil interaction device for additive manufacturing |
| US11865780B2 (en) | 2021-02-26 | 2024-01-09 | General Electric Company | Accumalator assembly for additive manufacturing |
| US11951679B2 (en) | 2021-06-16 | 2024-04-09 | General Electric Company | Additive manufacturing system |
| US11731367B2 (en) | 2021-06-23 | 2023-08-22 | General Electric Company | Drive system for additive manufacturing |
| US11958250B2 (en) | 2021-06-24 | 2024-04-16 | General Electric Company | Reclamation system for additive manufacturing |
| US11958249B2 (en) | 2021-06-24 | 2024-04-16 | General Electric Company | Reclamation system for additive manufacturing |
| US11826950B2 (en) | 2021-07-09 | 2023-11-28 | General Electric Company | Resin management system for additive manufacturing |
| US12172379B2 (en) | 2021-08-11 | 2024-12-24 | General Electric Company | Cleaning system for additive manufacturing |
| US12370741B2 (en) | 2021-08-13 | 2025-07-29 | General Electric Company | Material deposition assembly for additive manufacturing |
| US12296535B2 (en) | 2021-08-24 | 2025-05-13 | General Electric Company | Attachment structure for additive manufacturing |
| US11813799B2 (en) | 2021-09-01 | 2023-11-14 | General Electric Company | Control systems and methods for additive manufacturing |
| CN114534740B (zh) * | 2022-01-17 | 2023-01-31 | 广州广钢气体能源股份有限公司 | 一种三维多孔结构铜锰复合催化剂及其制备方法和应用 |
| EP4249216A1 (en) | 2022-03-23 | 2023-09-27 | General Electric Company | Systems and methods for additive manufacturing |
| US12403654B2 (en) | 2022-09-30 | 2025-09-02 | General Electric Company | Systems and methods for additive manufacturing |
| CN120642070A (zh) * | 2023-02-17 | 2025-09-12 | 松下知识产权经营株式会社 | 电极的制造方法、电极和非水电解质二次电池 |
| CN117417191B (zh) * | 2023-11-10 | 2025-10-28 | 北京理工大学 | 一种微点阵结构先驱体转化陶瓷的高精度光固化3d打印方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004330730A (ja) | 2003-05-12 | 2004-11-25 | Fuji Photo Film Co Ltd | 三次元造形物の製造方法 |
| JP2005067197A (ja) | 2003-08-25 | 2005-03-17 | Hewlett-Packard Development Co Lp | 非反応性粉末を利用した立体自由形状成形の方法とシステム |
Family Cites Families (399)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2156242A (en) | 1935-05-09 | 1939-04-25 | Lilly Co Eli | Ergot derivative and process of obtaining it |
| US2296636A (en) | 1938-12-08 | 1942-09-22 | Du Pont | High surface hiding pigment material and process of making the same |
| US2522548A (en) | 1946-10-03 | 1950-09-19 | Thoger G Jungersen | Method of making a phosphate gel and mold with phosphate gel binder |
| US2662024A (en) | 1951-03-01 | 1953-12-08 | Kaiser Gypsum Company Inc | Cementitious compositions |
| DE1109891B (de) | 1955-08-25 | 1961-06-29 | American Sealants Company | Unter Luftausschluss polymerisierende fluessige Gemische |
| US3303147A (en) | 1963-01-15 | 1967-02-07 | Nat Gypsum Co | Dry powder for wallboard joint treatment |
| US3297601A (en) | 1963-08-13 | 1967-01-10 | United States Gypsum Co | Substantially dry joint compound comprising calcium sulfate, polyvinyl acetate and starch |
| US3309328A (en) | 1964-06-03 | 1967-03-14 | Allied Chem | High strength adhesive for building materials |
| CH423346A (de) | 1964-08-27 | 1966-10-31 | Jacques Dr Jenny | Verfahren zur Herstellung eines Hufbelages, und nach diesem hergestellter Belag |
| US4041476A (en) | 1971-07-23 | 1977-08-09 | Wyn Kelly Swainson | Method, medium and apparatus for producing three-dimensional figure product |
| US3525632A (en) | 1967-11-08 | 1970-08-25 | Resco Products Inc | Method for forming a concrete cement composition |
| GB1250631A (enExample) | 1968-01-25 | 1971-10-20 | ||
| US3821006A (en) | 1971-04-16 | 1974-06-28 | Dentsply Int Inc | Patching method |
| CH1917171A4 (enExample) | 1971-12-30 | 1975-04-30 | ||
| US3852083A (en) | 1972-03-30 | 1974-12-03 | J Yang | Manufacture of plaster of paris products containing latex |
| US3930872A (en) | 1973-04-17 | 1976-01-06 | Ashland Oil, Inc. | Binder compositions |
| US3835074A (en) | 1973-04-26 | 1974-09-10 | Hercules Inc | Joint cement compositions |
| US3870538A (en) | 1973-05-07 | 1975-03-11 | Nat Gypsum Co | Gypsum set accelerator |
| US3926870A (en) | 1973-10-15 | 1975-12-16 | Warner Lambert Co | Denture adhesive preparation containing an anionic protein material |
| US3932923A (en) | 1974-10-21 | 1976-01-20 | Dynell Electronics Corporation | Method of generating and constructing three-dimensional bodies |
| US4078229A (en) | 1975-01-27 | 1978-03-07 | Swanson Wyn K | Three dimensional systems |
| GB1498057A (en) | 1975-04-17 | 1978-01-18 | Ass Portland Cement | Hydraulic cements |
| US4303556A (en) | 1977-11-02 | 1981-12-01 | The Procter & Gamble Company | Spray-dried detergent compositions |
| US4288861A (en) | 1977-12-01 | 1981-09-08 | Formigraphic Engine Corporation | Three-dimensional systems |
| CH621597A5 (enExample) | 1978-02-13 | 1981-02-13 | Epsi Brevets & Participations | |
| GB2048235A (en) | 1979-04-25 | 1980-12-10 | Bpb Industries Ltd | Improved Joint Cement |
| US4247508B1 (en) | 1979-12-03 | 1996-10-01 | Dtm Corp | Molding process |
| US4310996A (en) | 1980-04-23 | 1982-01-19 | General Electric Co. | Cement reinforced gypsum foam with mineral wool |
| US4327156A (en) | 1980-05-12 | 1982-04-27 | Minnesota Mining And Manufacturing Company | Infiltrated powdered metal composite article |
| DE3041794A1 (de) | 1980-11-06 | 1982-05-13 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zum herstellen von dessinierten formkoerpern aus einer haertbaren masse auf basis duroplastischer kunststoffe |
| DE3048506C2 (de) | 1980-12-22 | 1986-09-11 | Rigips GmbH, 3452 Bodenwerder | Trockene pulverförmige Putzmischung und Verfahren zu ihrer Herstellung |
| EP0077618B1 (en) | 1981-10-15 | 1986-12-17 | Ciba Specialty Chemicals Water Treatments Limited | Adhesives for prepasted wallcoverings |
| EP0091262B1 (en) | 1982-04-07 | 1986-03-05 | Adnovum Ag | Heat-activatable multi-component sheet material and process for making same |
| US4444594A (en) | 1982-12-09 | 1984-04-24 | Armstrong World Industries, Inc. | Acid cured inorganic binder compositions which are compatible with mineral wool |
| US4613627A (en) | 1982-12-13 | 1986-09-23 | Usg Acoustical Products Company | Process for the manufacture of shaped fibrous products and the resultant product |
| US4618390A (en) | 1983-06-13 | 1986-10-21 | Ashland Oil, Inc. | Method for preparing laminated articles |
| US4755227A (en) | 1983-08-11 | 1988-07-05 | Stauffer Chemical Company | Production of solid phosphorus pentioxide containing materials for fast-setting cements |
| DE3439493A1 (de) | 1984-10-27 | 1986-05-07 | Wuertex Maschinenbau Hofmann G | Verfahren zur kontinuierlichen herstellung von formkoerpern, insbesondere von platten, aus einer mischung von gips- und faserstoff sowie vorrichtung zur durchfuehrung des verfahrens |
| GB2155944B (en) | 1984-03-16 | 1988-04-27 | Building Adhesives Ltd | Powder compositions for producing tile adhesives and grouts |
| US4665492A (en) | 1984-07-02 | 1987-05-12 | Masters William E | Computer automated manufacturing process and system |
| US5344298A (en) | 1984-08-08 | 1994-09-06 | 3D Systems, Inc. | Apparatus for making three-dimensional objects by stereolithography |
| US5174943A (en) | 1984-08-08 | 1992-12-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
| US4575330A (en) | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
| US4929402A (en) | 1984-08-08 | 1990-05-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
| US5554336A (en) | 1984-08-08 | 1996-09-10 | 3D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
| US5236637A (en) | 1984-08-08 | 1993-08-17 | 3D Systems, Inc. | Method of and apparatus for production of three dimensional objects by stereolithography |
| JPS62260754A (ja) | 1986-05-07 | 1987-11-13 | 三井東圧化学株式会社 | 石こうボ−ドの製造方法 |
| US5263130A (en) | 1986-06-03 | 1993-11-16 | Cubital Ltd. | Three dimensional modelling apparatus |
| IL84936A (en) | 1987-12-23 | 1997-02-18 | Cubital Ltd | Three-dimensional modelling apparatus |
| US4961154A (en) | 1986-06-03 | 1990-10-02 | Scitex Corporation Ltd. | Three dimensional modelling apparatus |
| US4752352A (en) | 1986-06-06 | 1988-06-21 | Michael Feygin | Apparatus and method for forming an integral object from laminations |
| US5076869A (en) | 1986-10-17 | 1991-12-31 | Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
| US5147587A (en) | 1986-10-17 | 1992-09-15 | Board Of Regents, The University Of Texas System | Method of producing parts and molds using composite ceramic powders |
| US4863538A (en) | 1986-10-17 | 1989-09-05 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
| US5017753A (en) | 1986-10-17 | 1991-05-21 | Board Of Regents, The University Of Texas System | Method and apparatus for producing parts by selective sintering |
| US5296062A (en) | 1986-10-17 | 1994-03-22 | The Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
| US5155324A (en) | 1986-10-17 | 1992-10-13 | Deckard Carl R | Method for selective laser sintering with layerwise cross-scanning |
| US4944817A (en) | 1986-10-17 | 1990-07-31 | Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
| BR8707510A (pt) | 1986-10-17 | 1989-02-21 | Univ Texas | Metodo e aparelhagem para produzir pecas por sinterizacao seletiva |
| US4758278A (en) | 1986-11-28 | 1988-07-19 | E. I. Du Pont De Nemours And Company | Magnesium oxide powder for workable, rapid-setting phosphate-containing cement compositions |
| US4801477A (en) | 1987-09-29 | 1989-01-31 | Fudim Efrem V | Method and apparatus for production of three-dimensional objects by photosolidification |
| US4752498A (en) | 1987-03-02 | 1988-06-21 | Fudim Efrem V | Method and apparatus for production of three-dimensional objects by photosolidification |
| US5386500A (en) | 1987-06-02 | 1995-01-31 | Cubital Ltd. | Three dimensional modeling apparatus |
| US5287435A (en) | 1987-06-02 | 1994-02-15 | Cubital Ltd. | Three dimensional modeling |
| US5015312A (en) | 1987-09-29 | 1991-05-14 | Kinzie Norman F | Method and apparatus for constructing a three-dimensional surface of predetermined shape and color |
| IL84752A (en) | 1987-12-08 | 1991-11-21 | Elscint Ltd | Anatomical models and methods for manufacturing such models |
| US4942001A (en) | 1988-03-02 | 1990-07-17 | Inc. DeSoto | Method of forming a three-dimensional object by stereolithography and composition therefore |
| US4996282A (en) | 1988-03-24 | 1991-02-26 | Desoto, Inc. | Cationically curable polyurethane compositions having vinyl ether functionality |
| US4945032A (en) | 1988-03-31 | 1990-07-31 | Desoto, Inc. | Stereolithography using repeated exposures to increase strength and reduce distortion |
| WO1989009687A1 (en) | 1988-04-11 | 1989-10-19 | Austral Asian Lasers Pty. Ltd. | Laser based plastic model making workstation |
| US5015424A (en) | 1988-04-18 | 1991-05-14 | 3D Systems, Inc. | Methods and apparatus for production of three-dimensional objects by stereolithography |
| EP0354637B1 (en) | 1988-04-18 | 1997-06-25 | 3D Systems, Inc. | CAD/CAM stereolithographic data conversion |
| US5059359A (en) | 1988-04-18 | 1991-10-22 | 3 D Systems, Inc. | Methods and apparatus for production of three-dimensional objects by stereolithography |
| US5609813A (en) | 1988-04-18 | 1997-03-11 | 3D Systems, Inc. | Method of making a three-dimensional object by stereolithography |
| US5137662A (en) | 1988-11-08 | 1992-08-11 | 3-D Systems, Inc. | Method and apparatus for production of three-dimensional objects by stereolithography |
| US5141680A (en) | 1988-04-18 | 1992-08-25 | 3D Systems, Inc. | Thermal stereolighography |
| WO1989010801A1 (en) | 1988-04-18 | 1989-11-16 | 3D Systems, Inc. | Stereolithographic curl reduction |
| US5184307A (en) | 1988-04-18 | 1993-02-02 | 3D Systems, Inc. | Method and apparatus for production of high resolution three-dimensional objects by stereolithography |
| US5495328A (en) | 1988-04-18 | 1996-02-27 | 3D Systems, Inc. | Apparatus and method for calibrating and normalizing a stereolithographic apparatus |
| US5772947A (en) | 1988-04-18 | 1998-06-30 | 3D Systems Inc | Stereolithographic curl reduction |
| US5256340A (en) | 1988-04-18 | 1993-10-26 | 3D Systems, Inc. | Method of making a three-dimensional object by stereolithography |
| US5076974A (en) | 1988-04-18 | 1991-12-31 | 3 D Systems, Inc. | Methods of curing partially polymerized parts |
| US5182055A (en) | 1988-04-18 | 1993-01-26 | 3D Systems, Inc. | Method of making a three-dimensional object by stereolithography |
| US5130064A (en) | 1988-04-18 | 1992-07-14 | 3D Systems, Inc. | Method of making a three dimensional object by stereolithography |
| US5267013A (en) | 1988-04-18 | 1993-11-30 | 3D Systems, Inc. | Apparatus and method for profiling a beam |
| KR0178873B1 (ko) | 1988-04-18 | 1999-05-15 | 찰스 윌리엄 헐 | 스테레오리소그래픽 커얼 감소 |
| US4996010A (en) | 1988-04-18 | 1991-02-26 | 3D Systems, Inc. | Methods and apparatus for production of three-dimensional objects by stereolithography |
| US4999143A (en) | 1988-04-18 | 1991-03-12 | 3D Systems, Inc. | Methods and apparatus for production of three-dimensional objects by stereolithography |
| US5182056A (en) | 1988-04-18 | 1993-01-26 | 3D Systems, Inc. | Stereolithography method and apparatus employing various penetration depths |
| ES2043958T3 (es) | 1988-06-24 | 1994-01-01 | Pro Mineral Ges | Procedimiento para la preparacion de un agente aglutinante hidraulico que solidifica rapidamente despues de amasar con agua. |
| US4844144A (en) | 1988-08-08 | 1989-07-04 | Desoto, Inc. | Investment casting utilizing patterns produced by stereolithography |
| US5385772A (en) | 1988-09-19 | 1995-01-31 | Adco Products, Inc. | Pressure-sensitive adhesive systems with filler |
| US4943928A (en) | 1988-09-19 | 1990-07-24 | Campbell Albert E | Elongated carrier with a plurality of spot-sources of heat for use with stereolithographic system |
| US5174931A (en) | 1988-09-26 | 1992-12-29 | 3D Systems, Inc. | Method of and apparatus for making a three-dimensional product by stereolithography |
| US5258146A (en) | 1988-09-26 | 1993-11-02 | 3D Systems, Inc. | Method of and apparatus for measuring and controlling fluid level in stereolithography |
| US5637175A (en) | 1988-10-05 | 1997-06-10 | Helisys Corporation | Apparatus for forming an integral object from laminations |
| IL88359A (en) | 1988-11-10 | 1993-06-10 | Cubital Ltd | Method and apparatus for volumetric digitization of 3-dimensional objects |
| US5135379A (en) | 1988-11-29 | 1992-08-04 | Fudim Efrem V | Apparatus for production of three-dimensional objects by photosolidification |
| US5171490A (en) | 1988-11-29 | 1992-12-15 | Fudim Efrem V | Method and apparatus for production of three-dimensional objects by irradiation of photopolymers |
| GB8827952D0 (en) | 1988-11-30 | 1989-01-05 | Screen Form Inc | Display device |
| IL88626A0 (en) | 1988-12-07 | 1989-07-31 | N C T Limited | Method and apparatus for making three-dimensional objects |
| US5089184A (en) | 1989-01-18 | 1992-02-18 | Mitsui Engineering And Shipbuilding Co., Ltd. | Optical molding method |
| US5038014A (en) | 1989-02-08 | 1991-08-06 | General Electric Company | Fabrication of components by layered deposition |
| US5352310A (en) | 1989-02-17 | 1994-10-04 | Natter Marc D | Actinic activation shaping system and method |
| JP2794444B2 (ja) | 1989-03-07 | 1998-09-03 | 日本石油化学株式会社 | ジベンジルベンゼン類の製造方法 |
| JP2715527B2 (ja) | 1989-03-14 | 1998-02-18 | ソニー株式会社 | 立体形状形成方法 |
| US5128235A (en) | 1989-04-21 | 1992-07-07 | E. I. Du Pont De Nemours And Company | Method of forming a three-dimensional object comprising additives imparting reduction of shrinkage to photohardenable compositions |
| US4942060A (en) | 1989-04-21 | 1990-07-17 | E. I. Du Pont De Nemours And Company | Solid imaging method utilizing photohardenable compositions of self limiting thickness by phase separation |
| US5051334A (en) | 1989-04-21 | 1991-09-24 | E. I. Du Pont De Nemours And Company | Solid imaging method using photohardenable compositions containing hollow spheres |
| US5011635A (en) | 1989-05-18 | 1991-04-30 | Desoto, Inc. | Stereolithographic method and apparatus in which a membrane separates phases |
| GB2233928B (en) | 1989-05-23 | 1992-12-23 | Brother Ind Ltd | Apparatus and method for forming three-dimensional article |
| US5143663A (en) | 1989-06-12 | 1992-09-01 | 3D Systems, Inc. | Stereolithography method and apparatus |
| US5248456A (en) | 1989-06-12 | 1993-09-28 | 3D Systems, Inc. | Method and apparatus for cleaning stereolithographically produced objects |
| US5134569A (en) | 1989-06-26 | 1992-07-28 | Masters William E | System and method for computer automated manufacturing using fluent material |
| US5216616A (en) | 1989-06-26 | 1993-06-01 | Masters William E | System and method for computer automated manufacture with reduced object shape distortion |
| JPH0336019A (ja) | 1989-07-03 | 1991-02-15 | Brother Ind Ltd | 三次元成形方法およびその装置 |
| JPH0624773B2 (ja) | 1989-07-07 | 1994-04-06 | 三井造船株式会社 | 光学的造形法 |
| US5096491A (en) | 1989-07-19 | 1992-03-17 | Honshu Paper Co., Ltd. | Aqueous starch slurry adhesive |
| US5053090A (en) | 1989-09-05 | 1991-10-01 | Board Of Regents, The University Of Texas System | Selective laser sintering with assisted powder handling |
| JPH03244528A (ja) | 1989-09-28 | 1991-10-31 | Three D Syst Inc | 実質的に平担な立体平版加工面の形成装置および方法 |
| US5234636A (en) | 1989-09-29 | 1993-08-10 | 3D Systems, Inc. | Methods of coating stereolithographic parts |
| US5632848A (en) | 1989-10-12 | 1997-05-27 | Georgia-Pacific Corporation | Continuous processing equipment for making fiberboard |
| US5088047A (en) | 1989-10-16 | 1992-02-11 | Bynum David K | Automated manufacturing system using thin sections |
| US5182715A (en) | 1989-10-27 | 1993-01-26 | 3D Systems, Inc. | Rapid and accurate production of stereolighographic parts |
| DE59007720D1 (de) | 1989-10-27 | 1994-12-22 | Ciba Geigy Ag | Verfahren zur Abstimmung der Strahlungsempfindlichkeit von photopolymerisierbaren Zusammensetzungen. |
| US5133987A (en) | 1989-10-27 | 1992-07-28 | 3D Systems, Inc. | Stereolithographic apparatus and method |
| US5121329A (en) | 1989-10-30 | 1992-06-09 | Stratasys, Inc. | Apparatus and method for creating three-dimensional objects |
| US5135695A (en) | 1989-12-04 | 1992-08-04 | Board Of Regents The University Of Texas System | Positioning, focusing and monitoring of gas phase selective beam deposition |
| US5169579A (en) | 1989-12-04 | 1992-12-08 | Board Of Regents, The University Of Texas System | Catalyst and plasma assisted nucleation and renucleation of gas phase selective laser deposition |
| US5017317A (en) | 1989-12-04 | 1991-05-21 | Board Of Regents, The Uni. Of Texas System | Gas phase selective beam deposition |
| US5204055A (en) | 1989-12-08 | 1993-04-20 | Massachusetts Institute Of Technology | Three-dimensional printing techniques |
| US5387380A (en) | 1989-12-08 | 1995-02-07 | Massachusetts Institute Of Technology | Three-dimensional printing techniques |
| US5009585A (en) | 1989-12-18 | 1991-04-23 | Mitsui Engineering & Shipbuilding Co., Ltd. | Optical molding apparatus and movable base device therefor |
| US5143817A (en) | 1989-12-22 | 1992-09-01 | E. I. Du Pont De Nemours And Company | Solid imaging system |
| US5139711A (en) | 1989-12-25 | 1992-08-18 | Matsushita Electric Works, Ltd. | Process of and apparatus for making three dimensional objects |
| US5236812A (en) | 1989-12-29 | 1993-08-17 | E. I. Du Pont De Nemours And Company | Solid imaging method and apparatus |
| DE59100537D1 (de) | 1990-02-06 | 1993-12-02 | Biopac Biolog Verpackungssyste | Verfahren zur herstellung von verrottbaren, dünnwandigen formkörpern auf stärkebasis. |
| US5358673A (en) | 1990-02-15 | 1994-10-25 | 3D Systems, Inc. | Applicator device and method for dispensing a liquid medium in a laser modeling machine |
| US5071337A (en) | 1990-02-15 | 1991-12-10 | Quadrax Corporation | Apparatus for forming a solid three-dimensional article from a liquid medium |
| US5338611A (en) | 1990-02-20 | 1994-08-16 | Aluminum Company Of America | Method of welding thermoplastic substrates with microwave frequencies |
| US5626919A (en) | 1990-03-01 | 1997-05-06 | E. I. Du Pont De Nemours And Company | Solid imaging apparatus and method with coating station |
| US5693144A (en) | 1990-03-19 | 1997-12-02 | 3D Systems, Inc. | Vibrationally enhanced stereolithographic recoating |
| FR2659971B1 (fr) | 1990-03-20 | 1992-07-10 | Dassault Avions | Procede de production d'objets a trois dimensions par photo-transformation et appareillage de mise en óoeuvre d'un tel procede. |
| DE4012044A1 (de) | 1990-04-13 | 1991-10-17 | Heidelberger Zement Ag | Verfahren zur herstellung von formen, modellen und werkzeugen zur formgebung |
| US5094935A (en) | 1990-06-26 | 1992-03-10 | E. I. Dupont De Nemours And Company | Method and apparatus for fabricating three dimensional objects from photoformed precursor sheets |
| GB9123070D0 (en) | 1991-10-30 | 1991-12-18 | Domino Printing Sciences Plc | Ink |
| US5096530A (en) | 1990-06-28 | 1992-03-17 | 3D Systems, Inc. | Resin film recoating method and apparatus |
| US5158858A (en) | 1990-07-05 | 1992-10-27 | E. I. Du Pont De Nemours And Company | Solid imaging system using differential tension elastomeric film |
| US5175077A (en) | 1990-07-05 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Solid imaging system using photohardening inhibition |
| US5248249A (en) | 1990-07-27 | 1993-09-28 | Sony Corporation | Three-dimensional structure forming apparatus provided with a liquid-level control system for a main resin tank |
| US5127037A (en) | 1990-08-15 | 1992-06-30 | Bynum David K | Apparatus for forming a three-dimensional reproduction of an object from laminations |
| US5342566A (en) | 1990-08-23 | 1994-08-30 | Carl Schenck Ag | Method of manufacturing fiber gypsum board |
| US5192559A (en) | 1990-09-27 | 1993-03-09 | 3D Systems, Inc. | Apparatus for building three-dimensional objects with sheets |
| US5569349A (en) | 1990-10-04 | 1996-10-29 | 3D Systems, Inc. | Thermal stereolithography |
| US5198159A (en) | 1990-10-09 | 1993-03-30 | Matsushita Electric Works, Ltd. | Process of fabricating three-dimensional objects from a light curable resin liquid |
| US5204124A (en) | 1990-10-09 | 1993-04-20 | Stanley Secretan | Continuous extruded bead object fabrication apparatus |
| US5122441A (en) | 1990-10-29 | 1992-06-16 | E. I. Du Pont De Nemours And Company | Method for fabricating an integral three-dimensional object from layers of a photoformable composition |
| US5209878A (en) | 1990-10-30 | 1993-05-11 | 3D Systems, Inc. | Surface resolution in three-dimensional objects by inclusion of thin fill layers |
| US5192469A (en) | 1990-10-30 | 1993-03-09 | 3D Systems, Inc. | Simultaneous multiple layer curing in stereolithography |
| US5597520A (en) | 1990-10-30 | 1997-01-28 | Smalley; Dennis R. | Simultaneous multiple layer curing in stereolithography |
| US5238639A (en) | 1990-10-31 | 1993-08-24 | 3D Systems, Inc. | Method and apparatus for stereolithographic curl balancing |
| US5155321A (en) | 1990-11-09 | 1992-10-13 | Dtm Corporation | Radiant heating apparatus for providing uniform surface temperature useful in selective laser sintering |
| US5328539A (en) | 1990-11-28 | 1994-07-12 | H. B. Fuller Licensing & Financing Inc. | Radio frequency heating of thermoplastic receptor compositions |
| US5167882A (en) | 1990-12-21 | 1992-12-01 | Loctite Corporation | Stereolithography method |
| US5182134A (en) | 1990-11-28 | 1993-01-26 | H. B. Fuller Licensing & Financing Inc. | Radio frequency cure of thermoset-receptor compositions |
| US5286573A (en) | 1990-12-03 | 1994-02-15 | Fritz Prinz | Method and support structures for creation of objects by layer deposition |
| DE4141648C2 (de) | 1990-12-17 | 1997-01-09 | Toshiba Kawasaki Kk | Keramischer Kondensator |
| US5460758A (en) | 1990-12-21 | 1995-10-24 | Eos Gmbh Electro Optical Systems | Method and apparatus for production of a three-dimensional object |
| JP2597778B2 (ja) | 1991-01-03 | 1997-04-09 | ストラタシイス,インコーポレイテッド | 三次元対象物組み立てシステム及び組み立て方法 |
| US5740051A (en) | 1991-01-25 | 1998-04-14 | Sanders Prototypes, Inc. | 3-D model making |
| US5506607A (en) | 1991-01-25 | 1996-04-09 | Sanders Prototypes Inc. | 3-D model maker |
| ES2081564T3 (es) | 1991-01-31 | 1996-03-16 | Texas Instruments Inc | Metodo y sistema para la fabricacion, controlada por ordenador, de objetos tridimensionales a partir de datos de ordenador. |
| US5594652A (en) | 1991-01-31 | 1997-01-14 | Texas Instruments Incorporated | Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data |
| US5176188A (en) | 1991-02-14 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Investment casting method and pattern material comprising thermally-collapsible expanded microspheres |
| US5474719A (en) | 1991-02-14 | 1995-12-12 | E. I. Du Pont De Nemours And Company | Method for forming solid objects utilizing viscosity reducible compositions |
| US5217653A (en) | 1991-02-18 | 1993-06-08 | Leonid Mashinsky | Method and apparatus for producing a stepless 3-dimensional object by stereolithography |
| WO1992015620A1 (en) | 1991-02-27 | 1992-09-17 | Allied-Signal Inc. | Stereolithography using vinyl ether based polymers |
| US5204823A (en) | 1991-03-20 | 1993-04-20 | Calcomp Inc. | Method and apparatus for high-speed layer thickness curing in 3-D model making |
| DE69208712T2 (de) | 1991-04-19 | 1996-10-17 | Fuji Photo Film Co Ltd | Vorläufer für eine Flachdruckplatte des Direktbildtyps |
| US5173220A (en) | 1991-04-26 | 1992-12-22 | Motorola, Inc. | Method of manufacturing a three-dimensional plastic article |
| US5510226A (en) | 1991-05-01 | 1996-04-23 | Alliedsignal Inc. | Stereolithography using vinyl ether-epoxide polymers |
| NL193122C (nl) | 1991-05-01 | 1998-11-03 | Allied Signal Inc | Stereolithografie onder gebruikmaking van vinyletherepoxydepolymeren. |
| US5157423A (en) | 1991-05-08 | 1992-10-20 | Cubital Ltd. | Apparatus for pattern generation on a dielectric substrate |
| US5238614A (en) | 1991-05-28 | 1993-08-24 | Matsushita Electric Words, Ltd., Japan | Process of fabricating three-dimensional objects from a light curable resin liquid |
| US5154762A (en) | 1991-05-31 | 1992-10-13 | Minnesota Mining And Manufacturing Company | Universal water-based medical and dental cement |
| US5278442A (en) | 1991-07-15 | 1994-01-11 | Prinz Fritz B | Electronic packages and smart structures formed by thermal spray deposition |
| JPH0525898A (ja) | 1991-07-23 | 1993-02-02 | Yayoi Kagaku Kogyo Kk | 下地調整剤及び該下地調整剤の施工法 |
| US5207371A (en) | 1991-07-29 | 1993-05-04 | Prinz Fritz B | Method and apparatus for fabrication of three-dimensional metal articles by weld deposition |
| US5677107A (en) | 1991-10-02 | 1997-10-14 | Spectra Group Limited, Inc. | Production of three-dimensional objects |
| US5203944A (en) | 1991-10-10 | 1993-04-20 | Prinz Fritz B | Method for fabrication of three-dimensional articles by thermal spray deposition using masks as support structures |
| DE4134265C2 (de) | 1991-10-16 | 1993-11-25 | Eos Electro Optical Syst | Vorrichtung und Verfahren zur Herstellung eines dreidimensionalen Objekts mittels Stereographie |
| US5279665A (en) | 1991-10-30 | 1994-01-18 | Ashland Oil, Inc. | Inorganic foundry binder systems and their uses |
| US5252264A (en) | 1991-11-08 | 1993-10-12 | Dtm Corporation | Apparatus and method for producing parts with multi-directional powder delivery |
| US5348693A (en) | 1991-11-12 | 1994-09-20 | Advanced Cardiovascular Systems, Inc. | Formation of three dimensional objects and assemblies |
| US5314003A (en) | 1991-12-24 | 1994-05-24 | Microelectronics And Computer Technology Corporation | Three-dimensional metal fabrication using a laser |
| US5247180A (en) | 1991-12-30 | 1993-09-21 | Texas Instruments Incorporated | Stereolithographic apparatus and method of use |
| US5345414A (en) | 1992-01-27 | 1994-09-06 | Rohm Co., Ltd. | Semiconductor memory device having ferroelectric film |
| US5545367A (en) | 1992-04-15 | 1996-08-13 | Soane Technologies, Inc. | Rapid prototype three dimensional stereolithography |
| US5432045A (en) | 1992-05-28 | 1995-07-11 | Cmet, Inc. | Photo-solidification modeling apparatus and photo-solidification modeling method having an improved recoating process |
| FR2691818B1 (fr) | 1992-06-02 | 1997-01-03 | Alsthom Cge Alcatel | Procede de fabrication d'un objet fractal par stereolithographie et objet fractal obtenu par un tel procede. |
| FR2692065A1 (fr) | 1992-06-05 | 1993-12-10 | Laser Int Sa | Procédé de production de pièces industrielles par action de la lumière sur une matière polymérisable ou réticulable liquide sans nécessiter de supports. |
| US5365996A (en) | 1992-06-10 | 1994-11-22 | Amei Technologies Inc. | Method and apparatus for making customized fixation devices |
| US5306446A (en) | 1992-07-10 | 1994-04-26 | Howe Robert J | Apparatus with roller and for irradiation of photopolymers |
| DE69315003T2 (de) | 1992-07-17 | 1998-03-12 | Ethicon Inc | Strahlenhärtbare Urethan-Acrylatprepolymere und vernetzte Polymere |
| US5281789A (en) | 1992-07-24 | 1994-01-25 | Robert Merz | Method and apparatus for depositing molten metal |
| US5783126A (en) | 1992-08-11 | 1998-07-21 | E. Khashoggi Industries | Method for manufacturing articles having inorganically filled, starch-bound cellular matrix |
| US5506046A (en) | 1992-08-11 | 1996-04-09 | E. Khashoggi Industries | Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix |
| NZ314299A (en) | 1992-08-11 | 1998-08-26 | E | Containers formed from a hydraulically settable mixture including a binder, a rheology-modifying agent, fibres and water |
| US5512162A (en) | 1992-08-13 | 1996-04-30 | Massachusetts Institute Of Technology | Method for photo-forming small shaped metal containing articles from porous precursors |
| US5370692A (en) | 1992-08-14 | 1994-12-06 | Guild Associates, Inc. | Rapid, customized bone prosthesis |
| JPH06114948A (ja) | 1992-10-01 | 1994-04-26 | Shiimetsuto Kk | 未硬化液排出口付光硬化造形物とその造形法 |
| DE4233812C1 (de) | 1992-10-07 | 1993-11-04 | Eos Electro Optical Syst | Verfahren und vorrichtung zum herstellen von dreidimensionalen objekten |
| US5264061A (en) | 1992-10-22 | 1993-11-23 | Motorola, Inc. | Method of forming a three-dimensional printed circuit assembly |
| US5603797A (en) | 1992-11-16 | 1997-02-18 | E-Systems, Inc. | Flexible reinforced rubber part manufacturing process utilizing stereolithography tooling |
| US5648450A (en) | 1992-11-23 | 1997-07-15 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therein |
| US5527877A (en) | 1992-11-23 | 1996-06-18 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
| US5342919A (en) | 1992-11-23 | 1994-08-30 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
| US5490882A (en) | 1992-11-30 | 1996-02-13 | Massachusetts Institute Of Technology | Process for removing loose powder particles from interior passages of a body |
| US5430666A (en) | 1992-12-18 | 1995-07-04 | Dtm Corporation | Automated method and apparatus for calibration of laser scanning in a selective laser sintering apparatus |
| US5352405A (en) | 1992-12-18 | 1994-10-04 | Dtm Corporation | Thermal control of selective laser sintering via control of the laser scan |
| TW259797B (enExample) | 1992-12-23 | 1995-10-11 | Ciba Geigy | |
| DE4300478C2 (de) | 1993-01-11 | 1998-05-20 | Eos Electro Optical Syst | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
| JP2558431B2 (ja) | 1993-01-15 | 1996-11-27 | ストラタシイス,インコーポレイテッド | 3次元構造体を製造するシステムを作動する方法及び3次元構造体製造装置 |
| DE4302418A1 (de) | 1993-01-28 | 1994-08-11 | Eos Electro Optical Syst | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
| US5514378A (en) | 1993-02-01 | 1996-05-07 | Massachusetts Institute Of Technology | Biocompatible polymer membranes and methods of preparation of three dimensional membrane structures |
| US5296335A (en) | 1993-02-22 | 1994-03-22 | E-Systems, Inc. | Method for manufacturing fiber-reinforced parts utilizing stereolithography tooling |
| TW418346B (en) | 1993-03-05 | 2001-01-11 | Ciba Sc Holding Ag | Photopolymerisable compositions containing tetraacrylates |
| JP2805674B2 (ja) | 1993-03-22 | 1998-09-30 | ソニー株式会社 | 光学的造形方法および光学的造形装置 |
| US5429908A (en) | 1993-04-12 | 1995-07-04 | E. I. Du Pont De Nemours And Company | Exposure method for reducing distortion in models produced through solid imaging by forming a non-continuous image of a pattern which is then imaged to form a continuous hardened image of the pattern |
| KR970011573B1 (ko) | 1993-04-14 | 1997-07-12 | 마쯔시다덴기산교 가부시기가이샤 | 3차원 조형방법 |
| DE4316184A1 (de) | 1993-05-14 | 1994-11-17 | Hoechst Ag | Verfahren zur Herstellung keramischer Mikrostrukturen aus polymeren Precursoren |
| US5450205A (en) | 1993-05-28 | 1995-09-12 | Massachusetts Institute Of Technology | Apparatus and method for real-time measurement of thin film layer thickness and changes thereof |
| DE4319128C1 (de) | 1993-06-09 | 1995-02-23 | Fraunhofer Ges Forschung | Verfahren und Einrichtung zur freiformenden Herstellung dreidimensionaler Bauteile einer vorgegebenen Form |
| US5684713A (en) | 1993-06-30 | 1997-11-04 | Massachusetts Institute Of Technology | Method and apparatus for the recursive design of physical structures |
| US5391460A (en) | 1993-07-12 | 1995-02-21 | Hughes Aircraft Company | Resin composition and process for investment casting using stereolithography |
| ATE195510T1 (de) | 1993-08-09 | 2000-09-15 | Ciba Sc Holding Ag | Neue urethangruppenhaltige (meth)acrylate |
| US5738921A (en) | 1993-08-10 | 1998-04-14 | E. Khashoggi Industries, Llc | Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix |
| US5458825A (en) | 1993-08-12 | 1995-10-17 | Hoover Universal, Inc. | Utilization of blow molding tooling manufactured by sterolithography for rapid container prototyping |
| US5608814A (en) | 1993-08-26 | 1997-03-04 | General Electric Company | Method of dynamic thresholding for flaw detection in ultrasonic C-scan images |
| DE59407524D1 (de) | 1993-08-26 | 1999-02-04 | Ciba Geigy Ag | Flüssige strahlungshärtbare Zusammensetzung, insbesondere für die Stereolithographie |
| US5439622A (en) | 1993-09-07 | 1995-08-08 | Motorola, Inc. | Method and apparatus for producing molded parts |
| US5498782A (en) | 1993-09-08 | 1996-03-12 | Union Carbide Chemicals & Plastics Technology Corporation | Distortion control additives for ultraviolet-curable compositions |
| US5426722A (en) | 1993-09-09 | 1995-06-20 | Stratasys, Inc. | Method for optimizing the motion of a multi-axis robot |
| US5741215A (en) | 1993-09-10 | 1998-04-21 | The University Of Queensland | Stereolithographic anatomical modelling process |
| DE59409385D1 (de) | 1993-09-16 | 2000-07-06 | Ciba Sc Holding Ag | Vinyletherverbindungen mit zusätzlichen von Vinylethergruppen verschiedenen funktionellen Gruppen und deren Verwendung zur Formulierung härtbarer Zusammensetzungen |
| US5382289A (en) | 1993-09-17 | 1995-01-17 | Ashland Oil, Inc. | Inorganic foundry binder systems and their uses |
| JPH0788966A (ja) | 1993-09-22 | 1995-04-04 | Matsushita Electric Works Ltd | 三次元形状の形成方法 |
| US5976339A (en) | 1993-10-01 | 1999-11-02 | Andre, Sr.; Larry Edward | Method of incremental layered object fabrication |
| US5435902A (en) | 1993-10-01 | 1995-07-25 | Andre, Sr.; Larry E. | Method of incremental object fabrication |
| JP2706611B2 (ja) | 1993-10-14 | 1998-01-28 | 帝人製機株式会社 | 光造形方法および光造形装置 |
| US5490962A (en) | 1993-10-18 | 1996-02-13 | Massachusetts Institute Of Technology | Preparation of medical devices by solid free-form fabrication methods |
| US5518680A (en) | 1993-10-18 | 1996-05-21 | Massachusetts Institute Of Technology | Tissue regeneration matrices by solid free form fabrication techniques |
| US5418112A (en) | 1993-11-10 | 1995-05-23 | W. R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
| US5555481A (en) | 1993-11-15 | 1996-09-10 | Rensselaer Polytechnic Institute | Method of producing solid parts using two distinct classes of materials |
| US5514232A (en) | 1993-11-24 | 1996-05-07 | Burns; Marshall | Method and apparatus for automatic fabrication of three-dimensional objects |
| JP3287683B2 (ja) | 1993-12-28 | 2002-06-04 | 日本たばこ産業株式会社 | 葉たばこ自動供給装置 |
| FR2714668B1 (fr) | 1993-12-31 | 1996-01-26 | Rhone Poulenc Chimie | Préparation de ciments phosphomagnésiens. |
| US5703138A (en) | 1994-01-12 | 1997-12-30 | Dymax Corporation | Oxygen-curable coating composition |
| US5491643A (en) | 1994-02-04 | 1996-02-13 | Stratasys, Inc. | Method for optimizing parameters characteristic of an object developed in a rapid prototyping system |
| JPH07214675A (ja) | 1994-02-07 | 1995-08-15 | Matsushita Electric Ind Co Ltd | 樹脂造形体の形成方法および形成装置 |
| US5665118A (en) | 1994-02-18 | 1997-09-09 | Johnson & Johnson Professional, Inc. | Bone prostheses with direct cast macrotextured surface regions and method for manufacturing the same |
| BE1008128A3 (nl) | 1994-03-10 | 1996-01-23 | Materialise Nv | Werkwijze voor het ondersteunen van een voorwerp vervaardigd door stereolithografie of een andere snelle prototypevervaardigingswerkwijze en voor het vervaardigen van de daarbij gebruikte steunkonstruktie. |
| US5433280A (en) | 1994-03-16 | 1995-07-18 | Baker Hughes Incorporated | Fabrication method for rotary bits and bit components and bits and components produced thereby |
| US5429788A (en) | 1994-03-28 | 1995-07-04 | Kimberly-Clark Corporation | Apparatus and method for depositing particulate material in a composite substrate |
| JP3520310B2 (ja) | 1994-05-13 | 2004-04-19 | イーオーエス ゲゼルシャフト ミット ベシュレンクテル ハフツング イレクトロ オプティカル システムズ | 3次元物体の製造方法及び装置 |
| US5503785A (en) | 1994-06-02 | 1996-04-02 | Stratasys, Inc. | Process of support removal for fused deposition modeling |
| US5705116A (en) | 1994-06-27 | 1998-01-06 | Sitzmann; Eugene Valentine | Increasing the useful range of cationic photoinitiators in stereolithography |
| US5494618A (en) | 1994-06-27 | 1996-02-27 | Alliedsignal Inc. | Increasing the useful range of cationic photoinitiators in stereolithography |
| US5639402A (en) | 1994-08-08 | 1997-06-17 | Barlow; Joel W. | Method for fabricating artificial bone implant green parts |
| TW381106B (en) | 1994-09-02 | 2000-02-01 | Ciba Sc Holding Ag | Alkoxyphenyl-substituted bisacylphosphine oxides |
| JP2615429B2 (ja) | 1994-09-13 | 1997-05-28 | 工業技術院長 | 3次元立体形状の創成法 |
| JP3523338B2 (ja) | 1994-09-14 | 2004-04-26 | 富士通株式会社 | 立体モデル作成方法および装置 |
| US5717599A (en) | 1994-10-19 | 1998-02-10 | Bpm Technology, Inc. | Apparatus and method for dispensing build material to make a three-dimensional article |
| US5633021A (en) | 1994-10-19 | 1997-05-27 | Bpm Technology, Inc. | Apparatus for making a three-dimensional article |
| US5555176A (en) | 1994-10-19 | 1996-09-10 | Bpm Technology, Inc. | Apparatus and method for making three-dimensional articles using bursts of droplets |
| US5572431A (en) | 1994-10-19 | 1996-11-05 | Bpm Technology, Inc. | Apparatus and method for thermal normalization in three-dimensional article manufacturing |
| US5593531A (en) | 1994-11-09 | 1997-01-14 | Texas Instruments Incorporated | System, method and process for fabrication of 3-dimensional objects by a static electrostatic imaging and lamination device |
| US5482659A (en) | 1994-12-22 | 1996-01-09 | United Technologies Corporation | Method of post processing stereolithographically produced objects |
| JP2871500B2 (ja) | 1994-12-28 | 1999-03-17 | 竹本油脂株式会社 | 光学的立体造形用樹脂及び光学的立体造形用樹脂組成物 |
| JPH08183820A (ja) | 1994-12-28 | 1996-07-16 | Takemoto Oil & Fat Co Ltd | 光学的立体造形用樹脂及び光学的立体造形用樹脂組成物 |
| US5611883A (en) | 1995-01-09 | 1997-03-18 | Board Of Regents, The University Of Texas System | Joining ceramics and attaching fasteners to ceramics by gas phase selective beam deposition |
| US5507336A (en) | 1995-01-17 | 1996-04-16 | The Procter & Gamble Company | Method of constructing fully dense metal molds and parts |
| BR9607005A (pt) | 1995-02-01 | 1997-10-28 | 3D Systems Inc | Revestímento rápido de objetos tridimensionais formados em uma base transversal seccional |
| US5529471A (en) | 1995-02-03 | 1996-06-25 | University Of Southern California | Additive fabrication apparatus and method |
| US5573721A (en) | 1995-02-16 | 1996-11-12 | Hercules Incorporated | Use of a support liquid to manufacture three-dimensional objects |
| US5659478A (en) | 1995-02-21 | 1997-08-19 | Motorola, Inc. | Rapid product realization process |
| US5616293A (en) | 1995-03-03 | 1997-04-01 | General Motors Corporation | Rapid making of a prototype part or mold using stereolithography model |
| US5728345A (en) | 1995-03-03 | 1998-03-17 | General Motors Corporation | Method for making an electrode for electrical discharge machining by use of a stereolithography model |
| TW418215B (en) | 1995-03-13 | 2001-01-11 | Ciba Sc Holding Ag | A process for the production of three-dimensional articles in a stereolithography bath comprising the step of sequentially irradiating a plurality of layers of a liquid radiation-curable composition |
| US5534059A (en) | 1995-03-20 | 1996-07-09 | United States Gypsum Co. | Machinable plaster |
| DE19511772C2 (de) | 1995-03-30 | 1997-09-04 | Eos Electro Optical Syst | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes |
| US5639413A (en) | 1995-03-30 | 1997-06-17 | Crivello; James Vincent | Methods and compositions related to stereolithography |
| US5733497A (en) | 1995-03-31 | 1998-03-31 | Dtm Corporation | Selective laser sintering with composite plastic material |
| US5596504A (en) | 1995-04-10 | 1997-01-21 | Clemson University | Apparatus and method for layered modeling of intended objects represented in STL format and adaptive slicing thereof |
| DE19514740C1 (de) | 1995-04-21 | 1996-04-11 | Eos Electro Optical Syst | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes |
| DE19515165C2 (de) | 1995-04-25 | 1997-03-06 | Eos Electro Optical Syst | Vorrichtung zum Herstellen eines Objektes mittels Stereolithographie |
| US5707780A (en) | 1995-06-07 | 1998-01-13 | E. I. Du Pont De Nemours And Company | Photohardenable epoxy composition |
| US5746967A (en) | 1995-06-26 | 1998-05-05 | Fox Lite, Inc. | Method of curing thermoset resin with visible light |
| US5663883A (en) | 1995-08-21 | 1997-09-02 | University Of Utah Research Foundation | Rapid prototyping method |
| US5622577A (en) | 1995-08-28 | 1997-04-22 | Delco Electronics Corp. | Rapid prototyping process and cooling chamber therefor |
| US5746844A (en) | 1995-09-08 | 1998-05-05 | Aeroquip Corporation | Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of molten metal and using a stress-reducing annealing process on the deposited metal |
| US5653925A (en) | 1995-09-26 | 1997-08-05 | Stratasys, Inc. | Method for controlled porosity three-dimensional modeling |
| US5943235A (en) | 1995-09-27 | 1999-08-24 | 3D Systems, Inc. | Rapid prototyping system and method with support region data processing |
| US5749041A (en) | 1995-10-13 | 1998-05-05 | Dtm Corporation | Method of forming three-dimensional articles using thermosetting materials |
| DE69633143T2 (de) | 1995-11-09 | 2005-08-04 | Toyota Jidosha K.K., Toyota | Verfahren und Vorrichtung zur Herstellung einer 3-D Sandform mit Kern durch Ausbildung von Sandschichten |
| US5640667A (en) | 1995-11-27 | 1997-06-17 | Board Of Regents, The University Of Texas System | Laser-directed fabrication of full-density metal articles using hot isostatic processing |
| US6077887A (en) | 1995-11-29 | 2000-06-20 | Akzo Nobel Surface Chemistry Ab | Polyelectrolyte composition |
| FR2742142B1 (fr) | 1995-12-08 | 1998-01-16 | Rhone Poulenc Chimie | Nouvelle phase liante pour ciments phosphomagnesiens et leur utilisation pour la preparation de mortiers |
| US5660621A (en) | 1995-12-29 | 1997-08-26 | Massachusetts Institute Of Technology | Binder composition for use in three dimensional printing |
| US5738817A (en) | 1996-02-08 | 1998-04-14 | Rutgers, The State University | Solid freeform fabrication methods |
| US5705117A (en) | 1996-03-01 | 1998-01-06 | Delco Electronics Corporaiton | Method of combining metal and ceramic inserts into stereolithography components |
| US5641448A (en) | 1996-03-11 | 1997-06-24 | National Research Council Of Canada | Method of producing plastic injection molds for prototype parts |
| US5730817A (en) | 1996-04-22 | 1998-03-24 | Helisys, Inc. | Laminated object manufacturing system |
| US5700406A (en) | 1996-04-26 | 1997-12-23 | Bpm Technology, Inc. | Process of and apparatus for making a three-dimensional article |
| US5697043A (en) | 1996-05-23 | 1997-12-09 | Battelle Memorial Institute | Method of freeform fabrication by selective gelation of powder suspensions |
| US5707578A (en) | 1996-06-14 | 1998-01-13 | Hach Company | Method for making mold inserts |
| ES2251024T3 (es) | 1996-06-25 | 2006-04-16 | Hexion Specialty Chemicals, Inc. | Aglutinantes para machos y moldes. |
| US7332537B2 (en) | 1996-09-04 | 2008-02-19 | Z Corporation | Three dimensional printing material system and method |
| US5902441A (en) | 1996-09-04 | 1999-05-11 | Z Corporation | Method of three dimensional printing |
| US6989115B2 (en) | 1996-12-20 | 2006-01-24 | Z Corporation | Method and apparatus for prototyping a three-dimensional object |
| US6007318A (en) | 1996-12-20 | 1999-12-28 | Z Corporation | Method and apparatus for prototyping a three-dimensional object |
| US7037382B2 (en) | 1996-12-20 | 2006-05-02 | Z Corporation | Three-dimensional printer |
| US5940674A (en) | 1997-04-09 | 1999-08-17 | Massachusetts Institute Of Technology | Three-dimensional product manufacture using masks |
| DE19715582B4 (de) | 1997-04-15 | 2009-02-12 | Ederer, Ingo, Dr. | Verfahren und System zur Erzeugung dreidimensionaler Körper aus Computerdaten |
| SE509088C2 (sv) | 1997-04-30 | 1998-12-07 | Ralf Larsson | Sätt och anordning för framställning av volymkroppar |
| NL1006059C2 (nl) | 1997-05-14 | 1998-11-17 | Geest Adrianus F Van Der | Werkwijze en inrichting voor het vervaardigen van een vormlichaam. |
| DE19723892C1 (de) | 1997-06-06 | 1998-09-03 | Rainer Hoechsmann | Verfahren zum Herstellen von Bauteilen durch Auftragstechnik |
| BR9810454A (pt) | 1997-06-26 | 2000-09-05 | Dow Chemical Co | Processo melhorado de polimerizacao catalisada por ácido |
| DE19727677A1 (de) | 1997-06-30 | 1999-01-07 | Huels Chemische Werke Ag | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Objekten |
| US6136088A (en) | 1997-10-09 | 2000-10-24 | Mbt Holding Ag | Rapid setting, high early strength binders |
| US6753108B1 (en) | 1998-02-24 | 2004-06-22 | Superior Micropowders, Llc | Energy devices and methods for the fabrication of energy devices |
| US6348679B1 (en) | 1998-03-17 | 2002-02-19 | Ameritherm, Inc. | RF active compositions for use in adhesion, bonding and coating |
| US6821462B2 (en) | 1998-07-10 | 2004-11-23 | Jeneric/Pentron, Inc. | Mass production of shells and models for dental restorations produced by solid free-form fabrication methods |
| US6378974B1 (en) | 1998-09-14 | 2002-04-30 | Agfa-Gevaert | Ink jet method with improved tonal range |
| US6363606B1 (en) | 1998-10-16 | 2002-04-02 | Agere Systems Guardian Corp. | Process for forming integrated structures using three dimensional printing techniques |
| KR100650089B1 (ko) | 1998-10-29 | 2006-11-27 | 제트 코포레이션 | 3차원 인쇄 물질 시스템과 방법 |
| DE19853834A1 (de) | 1998-11-21 | 2000-05-31 | Ingo Ederer | Verfahren zum Herstellen von Bauteilen durch Auftragstechnik |
| US6433038B1 (en) | 1999-03-16 | 2002-08-13 | Seiko Epson Corporation | Photocurable ink composition for ink jet recording and ink jet recording method using the same |
| US6071675A (en) | 1999-06-05 | 2000-06-06 | Teng; Gary Ganghui | On-press development of a lithographic plate comprising dispersed solid particles |
| JP2001015613A (ja) | 1999-06-29 | 2001-01-19 | Sony Corp | 不揮発性半導体記憶装置およびその製造方法 |
| US6401001B1 (en) | 1999-07-22 | 2002-06-04 | Nanotek Instruments, Inc. | Layer manufacturing using deposition of fused droplets |
| US6884311B1 (en) | 1999-09-09 | 2005-04-26 | Jodi A. Dalvey | Method of image transfer on a colored base |
| JP2001150556A (ja) | 1999-09-14 | 2001-06-05 | Minolta Co Ltd | 三次元造形装置および三次元造形方法 |
| EP1415792B1 (en) * | 1999-11-05 | 2014-04-30 | 3D Systems Incorporated | Methods and compositions for three-dimensional printing |
| WO2001034371A2 (en) | 1999-11-05 | 2001-05-17 | Z Corporation | Material systems and methods of three-dimensional printing |
| US20030173695A1 (en) | 1999-11-12 | 2003-09-18 | Therics, Inc. | Rapid prototyping and manufacturing process |
| JP3212581B2 (ja) | 1999-12-08 | 2001-09-25 | 株式会社筒井プラスチック | 含浸液体の化学結合により補強された粉体造形品の製造方法 |
| US20050104241A1 (en) | 2000-01-18 | 2005-05-19 | Objet Geometried Ltd. | Apparatus and method for three dimensional model printing |
| JP2001207584A (ja) | 2000-01-31 | 2001-08-03 | Nichiha Corp | 着色建築板及びその製造方法 |
| US20030207959A1 (en) | 2000-03-13 | 2003-11-06 | Eduardo Napadensky | Compositions and methods for use in three dimensional model printing |
| AU2000238145A1 (en) | 2000-03-24 | 2001-10-08 | Generis Gmbh | Method for manufacturing a structural part by a multi-layer deposition technique |
| US20010050031A1 (en) | 2000-04-14 | 2001-12-13 | Z Corporation | Compositions for three-dimensional printing of solid objects |
| WO2001078969A2 (en) * | 2000-04-14 | 2001-10-25 | Z Corporation | Compositions for three-dimensional printing of solid objects |
| DE10018987A1 (de) | 2000-04-17 | 2001-10-31 | Envision Technologies Gmbh | Vorrichtung und Verfahren zum Herstellen von dreidimensionalen Objekten |
| US6397922B1 (en) | 2000-05-24 | 2002-06-04 | Massachusetts Institute Of Technology | Molds for casting with customized internal structure to collapse upon cooling and to facilitate control of heat transfer |
| DE10026955A1 (de) | 2000-05-30 | 2001-12-13 | Daimler Chrysler Ag | Materialsystem zur Verwendung beim 3D-Drucken |
| EP1301177A2 (en) | 2000-07-10 | 2003-04-16 | Therics, Inc. | Method and materials for controlling migration of binder liquid in a powder |
| GB0103754D0 (en) | 2001-02-15 | 2001-04-04 | Vantico Ltd | Three-dimensional structured printing |
| US6780368B2 (en) | 2001-04-10 | 2004-08-24 | Nanotek Instruments, Inc. | Layer manufacturing of a multi-material or multi-color 3-D object using electrostatic imaging and lamination |
| GB0112675D0 (en) | 2001-05-24 | 2001-07-18 | Vantico Ltd | Three-dimensional structured printing |
| DE10158233A1 (de) | 2001-08-23 | 2003-03-13 | Rolf Muelhaupt | Reaktivsystem für das 3D-Drucken |
| US7011783B2 (en) | 2001-10-24 | 2006-03-14 | 3D Systems, Inc. | Cooling techniques in solid freeform fabrication |
| JP4845340B2 (ja) | 2001-10-29 | 2011-12-28 | マサチューセッツ インスティテュート オブ テクノロジー | 三次元プリント投薬形態のような物品の一軸圧縮のためのシステムおよび方法 |
| US6713125B1 (en) | 2002-03-13 | 2004-03-30 | 3D Systems, Inc. | Infiltration of three-dimensional objects formed by solid freeform fabrication |
| US20040038009A1 (en) | 2002-08-21 | 2004-02-26 | Leyden Richard Noel | Water-based material systems and methods for 3D printing |
| US7087109B2 (en) | 2002-09-25 | 2006-08-08 | Z Corporation | Three dimensional printing material system and method |
| US6742456B1 (en) | 2002-11-14 | 2004-06-01 | Hewlett-Packard Development Company, L.P. | Rapid prototyping material systems |
| ITGE20020104A1 (it) | 2002-11-22 | 2004-05-23 | Fabrizio Parodi | Composizioni polimeriche rapidamente riscaldabili |
| AU2003900180A0 (en) | 2003-01-16 | 2003-01-30 | Silverbrook Research Pty Ltd | Method and apparatus (dam001) |
| DE10306886A1 (de) | 2003-02-18 | 2004-09-02 | Daimlerchrysler Ag | Verfahren und Vorrichtung zur Herstellung von Körpern durch sequentiellen Materialschichtaufbau |
| DE10310385B4 (de) | 2003-03-07 | 2006-09-21 | Daimlerchrysler Ag | Verfahren zur Herstellung von dreidimensionalen Körpern mittels pulverbasierter schichtaufbauender Verfahren |
| EP1459871B1 (de) | 2003-03-15 | 2011-04-06 | Evonik Degussa GmbH | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Objekten mittels Mikrowellenstrahlung sowie dadurch hergestellter Formkörper |
| JP2004330679A (ja) * | 2003-05-09 | 2004-11-25 | Fuji Photo Film Co Ltd | 三次元造形物の製造方法 |
| EP1475220A3 (en) | 2003-05-09 | 2009-07-08 | FUJIFILM Corporation | Process for producing three-dimensional model, and three-dimensional model |
| EP1475221A3 (en) * | 2003-05-09 | 2008-12-03 | FUJIFILM Corporation | Process for producing three-dimensional model |
| JP4662942B2 (ja) | 2003-05-21 | 2011-03-30 | ズィー コーポレイション | 3d印刷システムから外観モデルを形成するための熱可塑性粉末材料系 |
| US7807077B2 (en) | 2003-06-16 | 2010-10-05 | Voxeljet Technology Gmbh | Methods and systems for the manufacture of layered three-dimensional forms |
| US6930144B2 (en) * | 2003-06-24 | 2005-08-16 | Hewlett-Packard Development Company, L.P. | Cement system including a binder for use in freeform fabrication |
| US20050014005A1 (en) * | 2003-07-18 | 2005-01-20 | Laura Kramer | Ink-jettable reactive polymer systems for free-form fabrication of solid three-dimensional objects |
| GB0317387D0 (en) | 2003-07-25 | 2003-08-27 | Univ Loughborough | Method and apparatus for combining particulate material |
| WO2005021248A1 (ja) | 2003-08-27 | 2005-03-10 | Fuji Photo Film Co., Ltd. | 三次元造形物の製造方法 |
| WO2005023524A2 (en) | 2003-08-29 | 2005-03-17 | Z Corporation | Absorbent fillers for three-dimensional printing |
| US20070029698A1 (en) | 2003-09-11 | 2007-02-08 | Rynerson Michael L | Layered manufactured articles having small-diameter fluid conduction vents and method of making same |
| US7365129B2 (en) | 2003-10-14 | 2008-04-29 | Hewlett-Packard Development Company, L.P. | Polymer systems with reactive and fusible properties for solid freeform fabrication |
| ITVA20030040A1 (it) | 2003-10-27 | 2005-04-28 | Lamberti Spa | Fotoiniziatore solido bianco in polvere e procedimento per la sua preparazione. |
| US7381360B2 (en) | 2003-11-03 | 2008-06-03 | Hewlett-Packard Development Company, L.P. | Solid free-form fabrication of three-dimensional objects |
| JP2005144870A (ja) * | 2003-11-14 | 2005-06-09 | Noritake Co Ltd | 三次元造形体の製造方法および製造装置 |
| US7608672B2 (en) | 2004-02-12 | 2009-10-27 | Illinois Tool Works Inc. | Infiltrant system for rapid prototyping process |
| DE102004012682A1 (de) | 2004-03-16 | 2005-10-06 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels Lasertechnik und Auftragen eines Absorbers per Inkjet-Verfahren |
| DE102004014806B4 (de) | 2004-03-24 | 2006-09-14 | Daimlerchrysler Ag | Rapid-Technologie-Bauteil |
| DE102004020452A1 (de) | 2004-04-27 | 2005-12-01 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels elektromagnetischer Strahlung und Auftragen eines Absorbers per Inkjet-Verfahren |
| US7389154B2 (en) | 2004-09-29 | 2008-06-17 | Hewlett-Packard Development Company, L.P. | Fabricating a three-dimensional object |
| KR20080086428A (ko) | 2005-09-20 | 2008-09-25 | 피티에스 소프트웨어 비브이 | 3차원 아티클의 구축 장치 및 3차원 아티클의 구축 방법 |
| CN100344440C (zh) | 2005-12-19 | 2007-10-24 | 南京师范大学 | 彩色三维物体的制作方法 |
| EP2001656B1 (en) | 2006-04-06 | 2014-10-15 | 3D Systems Incorporated | KiT FOR THE PRODUCTION OF THREE-DIMENSIONAL OBJECTS BY USE OF ELECTROMAGNETIC RADIATION |
| CN1857930A (zh) | 2006-05-22 | 2006-11-08 | 西安交通大学 | 三维彩色打印快速成型装置及方法 |
| EP2664442B1 (en) | 2006-12-08 | 2018-02-14 | 3D Systems Incorporated | Three dimensional printing material system |
| WO2008086033A1 (en) | 2007-01-10 | 2008-07-17 | Z Corporation | Three-dimensional printing material system with improved color, article performance, and ease of use |
| US7968626B2 (en) | 2007-02-22 | 2011-06-28 | Z Corporation | Three dimensional printing material system and method using plasticizer-assisted sintering |
-
2007
- 2007-12-07 EP EP13175521.7A patent/EP2664442B1/en not_active Not-in-force
- 2007-12-07 CN CN2007800480350A patent/CN101568422B/zh not_active Expired - Fee Related
- 2007-12-07 JP JP2009540311A patent/JP5189598B2/ja not_active Expired - Fee Related
- 2007-12-07 EP EP07862625.6A patent/EP2089215B1/en active Active
- 2007-12-07 US US11/952,727 patent/US7905951B2/en active Active
- 2007-12-07 KR KR1020097014178A patent/KR101407801B1/ko active Active
- 2007-12-07 WO PCT/US2007/025075 patent/WO2008073297A2/en not_active Ceased
-
2011
- 2011-01-28 US US13/016,189 patent/US8157908B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004330730A (ja) | 2003-05-12 | 2004-11-25 | Fuji Photo Film Co Ltd | 三次元造形物の製造方法 |
| JP2005067197A (ja) | 2003-08-25 | 2005-03-17 | Hewlett-Packard Development Co Lp | 非反応性粉末を利用した立体自由形状成形の方法とシステム |
Also Published As
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|---|---|
| EP2664442B1 (en) | 2018-02-14 |
| EP2664442A1 (en) | 2013-11-20 |
| WO2008073297A2 (en) | 2008-06-19 |
| EP2089215B1 (en) | 2015-02-18 |
| US8157908B2 (en) | 2012-04-17 |
| CN101568422A (zh) | 2009-10-28 |
| US7905951B2 (en) | 2011-03-15 |
| US20110130489A1 (en) | 2011-06-02 |
| WO2008073297A3 (en) | 2008-08-21 |
| EP2089215A2 (en) | 2009-08-19 |
| CN101568422B (zh) | 2013-02-13 |
| HK1135065A1 (en) | 2010-05-28 |
| US20080138515A1 (en) | 2008-06-12 |
| JP2010512255A (ja) | 2010-04-22 |
| JP5189598B2 (ja) | 2013-04-24 |
| KR20090090372A (ko) | 2009-08-25 |
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