KR100309769B1 - 리튬 이차 전지용 양극 활물질과 그 제조 방법 - Google Patents
리튬 이차 전지용 양극 활물질과 그 제조 방법 Download PDFInfo
- Publication number
- KR100309769B1 KR100309769B1 KR1019990022765A KR19990022765A KR100309769B1 KR 100309769 B1 KR100309769 B1 KR 100309769B1 KR 1019990022765 A KR1019990022765 A KR 1019990022765A KR 19990022765 A KR19990022765 A KR 19990022765A KR 100309769 B1 KR100309769 B1 KR 100309769B1
- Authority
- KR
- South Korea
- Prior art keywords
- active material
- lithium secondary
- metal
- liani1
- ycoxmyo2
- Prior art date
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 33
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000007774 positive electrode material Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 54
- 239000002184 metal Substances 0.000 claims abstract description 54
- 150000004703 alkoxides Chemical class 0.000 claims abstract description 23
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 23
- 238000004381 surface treatment Methods 0.000 claims abstract description 23
- 239000006182 cathode active material Substances 0.000 claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 17
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 16
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 15
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 14
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 14
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 14
- 229910014909 LiaNi1-x-yCoxMyO2 Inorganic materials 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 17
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000007664 blowing Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 150000001868 cobalt Chemical class 0.000 claims description 3
- 150000002815 nickel Chemical class 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 238000003487 electrochemical reaction Methods 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 13
- 238000000975 co-precipitation Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000011149 active material Substances 0.000 description 5
- -1 chalcogenide compound Chemical class 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000011812 mixed powder Substances 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000003618 dip coating Methods 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910003005 LiNiO2 Inorganic materials 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910017044 Ni0.89Co0.1La0.01(OH)2 Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910032387 LiCoO2 Inorganic materials 0.000 description 2
- 229910014063 LiNi1-xCoxO2 Inorganic materials 0.000 description 2
- 229910014114 LiNi1-xMxO2 Inorganic materials 0.000 description 2
- 229910014402 LiNi1—xCoxO2 Inorganic materials 0.000 description 2
- 229910014907 LiNi1−xMxO2 Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 150000002500 ions Chemical group 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910002993 LiMnO2 Inorganic materials 0.000 description 1
- 229910016104 LiNi1 Inorganic materials 0.000 description 1
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019990022765A KR100309769B1 (ko) | 1999-06-17 | 1999-06-17 | 리튬 이차 전지용 양극 활물질과 그 제조 방법 |
US09/595,075 US6749965B1 (en) | 1999-02-10 | 2000-06-16 | Positive active material for lithium secondary batteries and method of preparing the same |
CNB001240218A CN1171335C (zh) | 1999-06-17 | 2000-06-17 | 用于锂二次电池的正极活性材料及其制备方法 |
JP2000182921A JP2001028265A (ja) | 1999-06-17 | 2000-06-19 | リチウム二次電池用正極活物質とその製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019990022765A KR100309769B1 (ko) | 1999-06-17 | 1999-06-17 | 리튬 이차 전지용 양극 활물질과 그 제조 방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010002784A KR20010002784A (ko) | 2001-01-15 |
KR100309769B1 true KR100309769B1 (ko) | 2001-11-01 |
Family
ID=19593130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019990022765A KR100309769B1 (ko) | 1999-02-10 | 1999-06-17 | 리튬 이차 전지용 양극 활물질과 그 제조 방법 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2001028265A (ja) |
KR (1) | KR100309769B1 (ja) |
CN (1) | CN1171335C (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100975191B1 (ko) | 2005-06-16 | 2010-08-10 | 파나소닉 주식회사 | 리튬이온 이차전지 |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100560534B1 (ko) * | 2000-09-25 | 2006-03-15 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질 및 그의 제조방법 |
KR100406816B1 (ko) * | 2001-06-05 | 2003-11-21 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 활물질의 제조 방법 |
KR100542184B1 (ko) * | 2001-07-19 | 2006-01-10 | 삼성에스디아이 주식회사 | 전지용 활물질 및 그의 제조 방법 |
TW565961B (en) * | 2001-11-30 | 2003-12-11 | Sanyo Electric Co | Nonaqueous electrolyte secondary battery and its manufacturing method |
CN100459243C (zh) * | 2002-02-15 | 2009-02-04 | 清美化学股份有限公司 | 锂二次电池用粒状正极活性物质 |
KR101131479B1 (ko) * | 2003-09-16 | 2012-03-30 | 에이지씨 세이미 케미칼 가부시키가이샤 | 리튬-니켈-코발트-망간-불소 함유 복합 산화물 및 그제조방법과 그것을 사용한 리튬 이차 전지 |
US8117595B2 (en) | 2004-03-23 | 2012-02-14 | Microsoft Corporation | Method for updating data in accordance with rights management policy |
JP4794866B2 (ja) * | 2004-04-08 | 2011-10-19 | パナソニック株式会社 | 非水電解質二次電池用正極活物質およびその製造方法ならびにそれを用いた非水電解質二次電池 |
KR100751746B1 (ko) | 2004-04-30 | 2007-08-27 | 에이지씨 세이미 케미칼 가부시키가이샤 | 리튬 2차 전지 정극용 리튬 함유 복합 산화물의 제조 방법 |
JP4838989B2 (ja) * | 2004-07-13 | 2011-12-14 | パナソニック株式会社 | 非水電解液二次電池用正極活物質の製造方法 |
CN100420088C (zh) * | 2004-11-08 | 2008-09-17 | 深圳市比克电池有限公司 | 具有镍基正极活性材料的锂离子二次电池及其制备方法 |
CN100416895C (zh) * | 2004-12-09 | 2008-09-03 | 比亚迪股份有限公司 | 一种锂离子电池正极活性材料及其制备方法 |
JP5034305B2 (ja) * | 2005-04-28 | 2012-09-26 | 住友化学株式会社 | 非水二次電池用活物質およびその製造方法 |
US9240593B2 (en) | 2005-04-28 | 2016-01-19 | Sumitomo Chemical Company, Limited | Active material for nonaqueous secondary battery and method for producing same |
EP1879248A4 (en) * | 2005-04-28 | 2011-07-13 | Sumitomo Chemical Co | ACTIVE MATERIAL FOR NONAQUEOUS SECONDARY CELL AND METHOD FOR PRODUCING SAME |
WO2006136050A1 (fr) * | 2005-06-20 | 2006-12-28 | Shenzhen Bak Battery Co., Ltd | Oxyde de lithium composite a composants multiples contenant du nickel et du cobalt, procede pour sa fabrication, son utilisation en tant que matiere active d'electrode positive pour une batterie secondaire au lithium et pile secondaire au lithium |
JP5260821B2 (ja) * | 2005-07-11 | 2013-08-14 | パナソニック株式会社 | リチウムイオン二次電池 |
WO2007052712A1 (ja) * | 2005-11-02 | 2007-05-10 | Agc Seimi Chemical Co., Ltd. | リチウム含有複合酸化物及びその製造方法 |
JP5076332B2 (ja) * | 2006-03-06 | 2012-11-21 | ソニー株式会社 | 正極活物質の製造方法、および非水電解質二次電池の製造方法 |
US9614220B2 (en) | 2007-01-29 | 2017-04-04 | Umicore | Doped and island-covered lithium cobaltite oxides |
US9608266B2 (en) | 2007-01-29 | 2017-03-28 | Umicore | Cathode material for lithium-ion rechargeable batteries |
US9177689B2 (en) | 2007-01-29 | 2015-11-03 | Umicore | High density and high voltage stable cathode materials for secondary batteries |
EP2178800B1 (en) | 2007-08-10 | 2013-03-06 | Umicore | Doped lithium transition metal oxides containing sulfur |
CN101471441B (zh) * | 2007-12-27 | 2011-07-06 | 比亚迪股份有限公司 | 一种锂离子电池正极活性物质及其制备方法 |
JP2009193745A (ja) | 2008-02-13 | 2009-08-27 | Sony Corp | 正極活物質の製造方法 |
CN102119128A (zh) | 2008-08-04 | 2011-07-06 | 尤米科尔公司 | 高度结晶性的锂过渡金属氧化物 |
JP5434278B2 (ja) * | 2009-05-29 | 2014-03-05 | Tdk株式会社 | 活物質及び電極の製造方法、活物質及び電極 |
EP2442385A1 (en) * | 2009-06-08 | 2012-04-18 | Sumitomo Chemical Company, Limited | Electrode mix, electrode mix paste, electrode, and non-aqueous electrolyte secondary battery |
KR101560519B1 (ko) * | 2010-06-29 | 2015-10-15 | 유미코르 | 2차 전지용 고밀도 및 고전압 안정성 캐소드 물질 |
CN101901906A (zh) * | 2010-07-22 | 2010-12-01 | 东莞新能源科技有限公司 | 锂离子二次电池及其正极材料 |
JP5999090B2 (ja) | 2011-07-13 | 2016-09-28 | 日本電気株式会社 | 二次電池用活物質 |
CN102306751B (zh) * | 2011-08-04 | 2016-01-20 | 深圳市天骄科技开发有限公司 | 锂离子电池正极材料湿法包覆铝的制备方法 |
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JP3355126B2 (ja) * | 1998-01-30 | 2002-12-09 | 同和鉱業株式会社 | リチウムイオン二次電池用正極活物質とその製造方法およびリチウムイオン二次電池 |
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KR100975191B1 (ko) | 2005-06-16 | 2010-08-10 | 파나소닉 주식회사 | 리튬이온 이차전지 |
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KR20010002784A (ko) | 2001-01-15 |
CN1171335C (zh) | 2004-10-13 |
CN1280397A (zh) | 2001-01-17 |
JP2001028265A (ja) | 2001-01-30 |
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