JPS6334461B2 - - Google Patents
Info
- Publication number
- JPS6334461B2 JPS6334461B2 JP59096352A JP9635284A JPS6334461B2 JP S6334461 B2 JPS6334461 B2 JP S6334461B2 JP 59096352 A JP59096352 A JP 59096352A JP 9635284 A JP9635284 A JP 9635284A JP S6334461 B2 JPS6334461 B2 JP S6334461B2
- Authority
- JP
- Japan
- Prior art keywords
- solution
- tank
- acid
- processing
- stabilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000000087 stabilizing effect Effects 0.000 claims description 41
- 238000012545 processing Methods 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 33
- 238000000909 electrodialysis Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 12
- 239000002738 chelating agent Substances 0.000 claims description 11
- -1 silver halide Chemical class 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- 239000013522 chelant Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000000243 solution Substances 0.000 description 55
- 230000006641 stabilisation Effects 0.000 description 25
- 238000011105 stabilization Methods 0.000 description 25
- 239000007788 liquid Substances 0.000 description 22
- 238000002474 experimental method Methods 0.000 description 16
- 239000008151 electrolyte solution Substances 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 239000003011 anion exchange membrane Substances 0.000 description 5
- 238000005341 cation exchange Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000005115 demineralization Methods 0.000 description 4
- 230000002328 demineralizing effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- XXAXVMUWHZHZMJ-UHFFFAOYSA-N Chymopapain Chemical compound OC1=CC(S(O)(=O)=O)=CC(S(O)(=O)=O)=C1O XXAXVMUWHZHZMJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 2
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 2
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- ZFSFDELZPURLKD-UHFFFAOYSA-N azanium;hydroxide;hydrate Chemical compound N.O.O ZFSFDELZPURLKD-UHFFFAOYSA-N 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- PBHVCRIXMXQXPD-UHFFFAOYSA-N chembl2369102 Chemical compound C1=CC(S(=O)(=O)O)=CC=C1C(C1=CC=C(N1)C(C=1C=CC(=CC=1)S(O)(=O)=O)=C1C=CC(=N1)C(C=1C=CC(=CC=1)S(O)(=O)=O)=C1C=CC(N1)=C1C=2C=CC(=CC=2)S(O)(=O)=O)=C2N=C1C=C2 PBHVCRIXMXQXPD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 2
- CLJDCQWROXMJAZ-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid Chemical compound OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 CLJDCQWROXMJAZ-UHFFFAOYSA-N 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- 235000010292 orthophenyl phenol Nutrition 0.000 description 2
- 239000004306 orthophenyl phenol Substances 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 2
- 235000019252 potassium sulphite Nutrition 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- WYMDDFRYORANCC-UHFFFAOYSA-N 2-[[3-[bis(carboxymethyl)amino]-2-hydroxypropyl]-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)CN(CC(O)=O)CC(O)=O WYMDDFRYORANCC-UHFFFAOYSA-N 0.000 description 1
- ZJOJXRSMJNWWRN-UHFFFAOYSA-N 3-amino-6-[2-(4-aminophenyl)ethenyl]benzene-1,2-disulfonic acid Chemical class C1=CC(N)=CC=C1C=CC1=CC=C(N)C(S(O)(=O)=O)=C1S(O)(=O)=O ZJOJXRSMJNWWRN-UHFFFAOYSA-N 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229920003934 Aciplex® Polymers 0.000 description 1
- 101100165177 Caenorhabditis elegans bath-15 gene Proteins 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000011272 standard treatment Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/395—Regeneration of photographic processing agents other than developers; Replenishers therefor
- G03C5/3956—Microseparation techniques using membranes, e.g. reverse osmosis, ion exchange, resins, active charcoal
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3046—Processing baths not provided for elsewhere, e.g. final or intermediate washings
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ãæè¡åéã
æ¬çºæã¯ããã²ã³åéã«ã©ãŒåçæå
ææïŒä»¥
äžãæå ææãšç¥ããïŒã®åŠçæ¹æ³ã«é¢ããç¹ã«
è±éå·¥çšã«ç¶ãæ°ŽæŽå·¥çšãå®è³ªçã«è¡ããªãå®å®
ååŠçæ¹æ³ã«é¢ããã ãåŸæ¥æè¡ã è¿å¹Žãæå ææã®çŸååŠçãèªåçã«äžã€é£ç¶
çã«è¡ãããªããã€ããã·ã€ãŒã«ãããŠãç°å¢ä¿
å šãšæ°Žè³æºã®åé¡ãéèŠèŠãããŠãããå®çåã¯
æŒçœå®çåŠçã«ç¶ãæ°ŽæŽå·¥çšã«ãããŠäœ¿çšããã
å€éã®æ°ŽæŽæ°Žãäœæžåã¯ãŒãã«ããããšãæãŸã
ãŠããããã®ããå®çåã¯æŒçœå®çã®åŠçã®åŸã
æ°ŽæŽãè¡ããªãã§çŽæ¥å®å®ååŠçããæè¡ãææ¡
ãããŠãããäŸãã°ç¹éæ57â8542å·ãå57â
132146å·ãå57â14834å·ãå58â18631å·åå ¬å ±
ã«ã¯ã€ãœãã¢ãŸãªã³èªå°äœããã³ãã€ãœãã¢ãŸãª
ã³èªå°äœãå¯æº¶æ§éé¯å¡©ãããªã«ã«ãã³é žãææ©
ãã¹ãã³é žãå«æããå®å®æ¶²ã§åŠçããæè¡ãèš
èŒãããŠããã æ°ŽæŽãå¿ èŠãšããªãå®å®æ¶²ã®è£å éã¯ç¹éæ58
â134636å·å ¬å ±çã«èšèŒãããŠããããã«ãåç
æå ææïŒm2åœã25mlã2.5ã§è£å ãããã奜
ãŸããã¯50mlãïŒãæŽã«å¥œãŸããã¯50mlã200
mlè£å ããã ãããã®æè¡ã¯ãå®å®æ¶²äžã«æå ææã«ãã€ãŠ
æã¡èŸŒãŸããå®çåã³æŒçœå®çæåã«ãã€ãŠçºç
ããåé¡ã®æå¶ããŸãã¯é²æ¢æ¹æ³ã«é¢ãããã®ã§
ããããããã®æè¡ã«ããŠãæã¡èŸŒãŸããå®çå
ã³æŒçœå®çæåãäžå®æ¿åºŠä»¥äžã§ã¯ãå®çšã«äŸã
åŸããå®å®æ¶²è£å éã¯äžå®éå¿ èŠã§ãã€ããç¹ã«
å®å®æ¶²ã®æçµæ§œã®å®çåã³æŒçœå®çæåæ¿åºŠãå¢
å ãããšãæå ææã®æªé²å éšåã®é·æä¿åã«ã
ãã€ãšããŒã¹ãã€ã³ãå¢å ããæ¬ ç¹ããã€ãã ãŸããå¥ã®åé¡ãšããŠãç¡æ°ŽæŽå®å®ååŠçãé·
æéã«äºã€ãŠé£ç¶ããŠè¡ããšå®çåã³æŒçœå®çæ
åã®æ··å ¥éãšã¯é¢ä¿ãªããæªé²å éšåã®åŠççŽåŸ
ã®ã¹ãã€ã³ãå¢å ãããšããæ¬ ç¹ãããããšãå€
ã€ãã ãçºæã®ç®çã åŸã€ãŠæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãå®å®æ¶²äžã®å®ç
åã³æŒçœå®çæåã®æ¿åºŠãæžå°ãããããšã«ãã€
ãŠãäœãåé¡ã®ãªãã«ã©ãŒå®å®ååŠçæ¹æ³ãæäŸ
ããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯é·æéãé£ç¶åŠçãè¡ã€
ãŠãæªé²å éšåã®åŠççŽåŸã®ã¹ãã€ã³ãå¢å ããª
ãã«ã©ãŒå®å®ååŠçæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãå®å®æ¶²äžã®æ害æåã
é€å»ããããšã«ãã€ãŠå®å®æ¶²ã®è£å éãæžå°ã
ããåå䜿çšã§ããæ¹æ³ãæäŸããããšã«ããã ãçºæã®èŠæšã æ¬çºæã®åŠçæ¹æ³ã¯ãæå ææãå®çèœãæã
ãåŠç液ã§åŠçããåŒãç¶ããŠå®è³ªçã«æ°ŽæŽãã
ããšãªãå®å®æ¶²ã§åŠçããæ¹æ³ã«ãããŠã該å®å®
液ãé»æ°éæåŠçãã該é»æ°éæåŠçãããå®å®
液ãšåã³å®å®æ¶²ãšããŠåŸªç°äœ¿çšããããšãç¹åŸŽãš
ããã æ¬çºæã®å¥œãŸããå®æœæ æ§ãšããŠã¯ãå®å®æ¶²ã
éïŒïŒã€ãªã³ãšã®ãã¬ãŒãå®å®åºŠå®æ°ãïŒä»¥äž
ã§ãããã¬ãŒãå€ãå«æããããšãæããããã ãæ¬çºæã®æ§æã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã éåžžã®æ°ŽæŽå·¥çšãæã€åŠçã§ã¯ãå®çåã³æŒçœ
å®çæåãæå ææããã®æº¶åºç©ãããã³ç²åŽæ
åçãå šãŠæ°ŽæŽå·¥çšã§æŽãæµãããŠãããã®ãã
æ°ŽæŽå·¥çšãçµãã«çŽæ¥å®å®ååŠçãè¡ããšãå šãŠ
å®å®æ¶²äžã«èç©ããé·æä¿åã§ã®ã€ãšããŒã¹ãã€
ã³ããã³åŠççŽåŸã®ã¹ãã€ã³ãçºçããã æ¬çºæè ã¯éæç 究ã®çµæãå®å®æ¶²ãé»æ°éæ
åŠçãã該é»æ°éæåŠçãããå®å®æ¶²ãåã³å®å®
液ãšããŠåŸªç°äœ¿çšããããšã«ãã€ãŠã¹ãã€ã³ã®çº
çãé²æ¢ã§ããããšãèŠåºãããã®ã§ããã æ¬çºæã®é»æ°éæåŠçãšã¯é»æ°éæ槜ã®é°æ¥µãš
éœæ¥µã®éãéèã§ä»åãããä»åããã宀ã«å®å®
液ãå ¥ãé»æ¥µã«çŽæµãéããããšã§ããã 奜ãŸããã¯éèãã€ãªã³äº€æèã§ããããšã§ã
ããæŽã«å¥œãŸããã¯ãé°æ¥µãšéœæ¥µãšã®éãé°ã€ãª
ã³äº€æèãšéœã€ãªã³äº€æèãšã«ãã亀äºã«ä»åã
ããŠãé°æ¥µå®€ãè€æ°ã®æ¿çž®å®€ïŒé°æ¥µåŽãé°ã€ãªã³
亀æèãéœæ¥µåŽãéœã€ãªã³äº€æèã§ä»åããã
宀ïŒãè€æ°ã®è±å¡©å®€ïŒé°æ¥µåŽãéœã€ãªã³äº€æèã
éœæ¥µåŽãé°ã€ãªã³äº€æèã§ä»åããã宀ïŒåã³éœ
極宀ãšãããªãããšã§ãããå®å®æ¶²ã¯å¥œãŸããã¯
è±å¡©å®€ã«å ¥ããããšã§ãããé°æ¥µå®€ãžå ¥ããããš
ã奜ãŸããããšã§ãããæ¿çž®å®€ãéœæ¥µå®€ã«å ¥ãã
é»è§£è³ªæº¶æ¶²ã¯å¥ã«éå®ããããã®ã§ãªããäŸãã°
äºç¡«é žãããªãŠã ãç¡«é žãããªãŠã ãå¡©åãããª
ãŠã ãç¡«é žã«ãªãŠã ãããªç¡«é žãããªãŠã çã®
0.1ã2Nã®æº¶æ¶²ã奜ãŸããçšããããšãã§ããã
ãã®ãšããå®çèœãæããåŠç液ãæ¿çž®å®€ãéœæ¥µ
宀ã«å ¥ããé»è§£è³ªæ¶²ãšããŠçšãããšãé»è§£è³ªæ¶²ã
å¿ èŠãšãããéåžžã«å¥œãŸããããŸãäžèšé»è§£è³ªæº¶
液ããéãååããããšãã§ããéååæ¹æ³ãšã
ãŠã¯ãé»è§£æ³ãã€ãªã³äº€ææš¹èæ³ãçšããããšã
ã§ããã äžèšã€ãªã³äº€æèãšããŠã¯åžè²©åããã®å ¥æã
å¯èœã§ãããäŸãã°æåæå·¥æ¥ç€Ÿè£œAciplexãæ
ç¡å瀟補Selemionã埳山æ¹é瀟補NEOSEPTAã
äžè±æ²¹å瀟補ãŠãã¬ãã¯ã¹ãDu Pont瀟補
Nafionçã®åååã§ç¥ãããŠããã é»æ°éæ槜åã³åãã€ãçã®ææãšããŠã¯ãã
ãªå¡©åããã«ãããªãããã¬ã³ãããªãšãã¬ã³å
ã³ãŽã ã©ã€ãã³ã°ããéçãæãããããé°æ¥µã®
ææãšããŠã¯ãéãããã±ã«ãéãäºéããã¿ã³
åéãã¹ãã³ã¬ã¹ã¹ããŒã«çãæãããããŸãéœ
極ã®ææãšããŠã¯ãçœéãçœéã¡ãããã¿ã³ãé»
éãéé žåéããã°ãã¿ã€ãçãæããããã æ¬çºæã®å®å®æ¶²ã¯éïŒïŒã€ãªã³ãšã®ãã¬ãŒã
å®å®åºŠå®æ°ãïŒä»¥äžã®ãã¬ãŒãå€ãå«æããããš
ã奜ãŸãããããã«ãã¬ãŒãå®å®åºŠå®æ°ãšã¯L.G.
Sillen.A.E.MartellèãâStability Conâstants
of Metalâion ComplexesâãThe Chemical
Society LondonïŒ1964ïŒã S.Chaberek.A.E.MartellèãâOrganic
Sequestering AgentsâãWileyïŒ1959ïŒãçã«ãã
äžè¬ã«ç¥ãããŠããæå³ã§ãããæ¬çºæã®é
ïŒïŒã€ãªã³ãšã®ãã¬ãŒãå®å®åºŠå®æ°ãïŒä»¥äžã§
ãããã¬ãŒãå€ãšããŠã¯ãææ©ã«ã«ãã³é žãã¬ãŒ
ãå€ãææ©ãªã³é žãã¬ãŒãå€ãçž®åãªã³é žãã¬ãŒ
ãå€ãããªããããã·ååç©çããããæ¬çºæã«
ãããŠå¥œãŸããã®ã¯éïŒïŒã€ãªã³ãšã®ãã¬ãŒã
å®å®åºŠå®æ°ã13以äžã§ãããã¬ãŒãå€ãçšããã
ãããšã§ãããããããã¬ãŒãå€ãšããŠã¯ããšã
ã¬ã³ãžã¢ãã³ãžãªã«ãããããã·ããšãã«é ¢é žã
ãããªãäžé ¢é žãããããã·ãšãã¬ã³ãžã¢ãã³äž
é ¢é žããžãšãã¬ã³ããªã¢ãã³äºé ¢é žãããããã·
ãšãã«ã€ããäºé ¢é žããžã¢ãããããããŒã«åé ¢
é žããã©ã³ã¹ã·ã¯ããããµã³ãžã¢ãã³åé ¢é žããš
ãã¬ã³ãžã¢ãã³ããã©ãã¹ã¡ãã¬ã³ãã¹ãã³é žã
ãããªãããªã¡ãã¬ã³ãã¹ãã³é žãïŒâãããã
ã·ãšããªãã³âïŒïŒïŒâäºãã¹ãã³é žãïŒïŒ1â²â
ãžãã¹ãããšã¿ã³âïŒâã«ã«ãã³é žãïŒâãã¹ã
ããã¿ã³âïŒïŒïŒïŒïŒâããªã«ã«ãã³é žãïŒâã
ãããã·âïŒâãã¹ãããããã³âïŒïŒïŒïŒïŒâ
ããªã«ã«ãã³é žãã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ã
ã³é žããããªã³é žãããªãŠã ãããã©ããªãªã³é ž
ãããªãŠã ããããµã¡ã¿ãªã³é žãããªãŠã ãã
ããæ¬çºæã®å¹æã®ããã«ç¹ã«å¥œãŸããã¯ãžãšã
ã¬ã³ããªã¢ãã³äºé ¢é žãïŒâããããã·ãšããªã
ã³âïŒïŒïŒâäºãã¹ãã³é žããããã®å¡©ã§ããã æŽã«ãæ¬çºæã®å®å®æ¶²ã«æ·»å ããã®ã«æãŸãã
ååç©ãšããŠã¯ãé ¢é žãç¡«é žãå¡©é žãç¡é žãã¹ã«
ãã¢ãã«é žãæ°Žé žåã«ãªãŠã ãæ°Žé žåãããªãŠ
ã ãæ°Žé žåã¢ã³ã¢ããŠã çã®PH調æŽå€ãå®æ¯éŠé ž
ãœãŒããããããã·å®æ¯éŠé žããã«ãæçç©è³ªã
ããããé ¢é žããœã«ãã³é žã«ãªãŠã ããµã€ã¢ãã³
ããŸãŒã«ããªã«ãâããšãã«ããšããŒã«çã®é²ã
ã€å€ãïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸ
ãªã³âïŒâãªã³ãïŒâãªã¯ãã«âïŒâã€ãœãã¢ãŸ
ãªã³âïŒâãªã³ãïŒâïŒâãã³ãã€ãœãã¢ãŸãªã³
âïŒâãªã³ã氎溶æ§éå±å¡©çã®ä¿æå€ããšãã¬ã³
ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãããªãã
ã«ãããªãã³çã®åæ£å€ããã«ããªã³çã®ç¡¬è
å€ãè¢å å¢çœå€çãæããããã æãæå¹ãªæ·»å ç©ã¯ç¹é¡æ58â58693å·æ现æž
ã«èšèŒãããã¢ã³ã¢ãã¢ååç©ã§ããã æ¬çºæã®å®å®æ¶²ã®PHå€ã¯PH0.1ã10ã«èª¿æŽãã
ã®ãããã奜ãŸããã¯PHïŒãïŒããã奜ãŸããã¯
PHïŒã8.5ã奜é©ãªç¯å²ã§ããã å®å®ååŠçã«éããŠã®åŠç枩床ã¯ã15âã60
âã奜ãŸããã¯20âã45âã®ç¯å²ãããããŸãåŠ
çæéãè¿ éåŠçã®èŠ³ç¹ããçæéã§ããã»ã©å¥œ
ãŸããããéåžž20ç§ã10åéãæã奜ãŸããã¯ïŒ
åãïŒåéã§ãããè€æ°æ§œå®å®ååŠçã®å Žåã¯å
段槜ã»ã©çæéã§åŠçããåŸæ®µæ§œã»ã©åŠçæéã
é·ãããšã奜ãŸãããç¹ã«å槜ã®20ïŒ ã50ïŒ å¢ã
ã®åŠçæéã§é 次åŠçããããšãæãŸããããŸ
ããå®å®ååŠçå·¥çšã¯å€æ®µæ§œãšããè£å 液ã¯æåŸ
段槜ããè£å ããé 次å段槜ã«ãªãŒããŒãããŒã
ãéæµæ¹åŒã«ããããšã奜ãŸãããæ¬çºæã«ãã
å®å®ååŠçã®åŸã«ã¯æ°ŽæŽåŠçãå šãå¿ èŠãšããªã
ãã極ãçæéå ã§ã®å°éæ°ŽæŽã«ãããªã³ã¹ãè¡š
é¢æŽæµãªã©ã¯å¿ èŠã«å¿ããŠä»»æã«è¡ãããšã¯ã§ã
ãã æ¬çºæã®å®çèœãæããåŠç液ãšã¯è±éã®ç®ç
ãæã€åŠç液ã§ãããå®ç液ãæŒçœå®ç液çãã
ããçšããããå®çå€ãšããŠã¯äŸãã°ãããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ãæ²åç©ãèåç©ãããªãšãŒ
ãã«ãããªå°¿çŽ çãããããªãã§ãäžè¬ã«çšãã
ããŠããå®çå€ã¯ããªç¡«é žå¡©ã§ããã æ¬çºæã®å®çèœãæããåŠç液ã§åŠçããåŒã
ç¶ããŠå®è³ªçã«æ°ŽæŽããããšãªãå®å®æ¶²ã§åŠçã
è¡ãããšã¯ãå®å®æ¶²ïŒæµŽïŒãããã¯æŒçœå®ç液
ïŒæµŽïŒã«ããåŠçãšå®å®æ¶²ã«ããåŠçãšã®éã«é
ååã®ããã®çæéã®éåå济ããªã³ã¹çãèšã
ãŠããããšããããšãæå³ããã æ¬çºæã®å®å®æ¶²ãæå ææãšæ¥è§Šãããæ¹æ³
ã¯ãäžè¬ã®åŠç液ãšåæ§ã«æ¶²äžã«æå ææã浞挬
ããã®ãããããã¹ãã³ãžãåæç¹ç¶åžçã«ãã
æå ææã®ä¹³å€é¢åã³æ¬éãªãŒããŒã®äž¡é¢ãæ¬é
ãã«ãã«å¡ãä»ããŠããããåã¹ãã¬ãŒçã«ãã
å¹ãä»ããŠãããã æ¬çºæã«ãããŠå®å®æ¶²ã¯é»æ°éæåŠçãããã
該åŠçæ¹æ³ãšããŠã¯ãå®å®æµŽäžã®å®å®æ¶²ãé»æ°é
æè£ çœ®ã«çŽçµããé£ç¶ããŠåŠçããæ¹æ³ãšãå®å®
济ã®ãªãŒããŒãããŒæ液ãé»æ°éæåŠçããŠå®å®
济ã«æ»ãæ¹æ³çãããããåè ã®æ¹æ³ããã奜ãŸ
ããããã®é»æ°éæåŠçãè¡ãå Žåãé»æ°éæè£
眮ã®èã«ãã€ãŠåå²ãããå宀ã«ãããŠæ¶²ã埪ç°
ããããšã奜ãŸãããæŽã«å¥œãŸããã¯ãåèšå®å®
济ã®çŽçµã®å Žåãå®å®æ¶²ãšè±å¡©å®€åã³é°æ¥µå®€ã§åžž
ã«åŸªç°ããããšã§ãããäžæ¹ãåèšãªãŒããŒãã
ãŒãåŠçããå Žåã¯ããªãŒããŒãããŒã®æºãã¿ã³
ã¯ãšè±å¡©å®€åã³é°æ¥µå®€ã§åžžã«åŸªç°ããããšã§ã
ãã æ¬çºæã«ãããå®å®ååŠçã¯ãïŒæ§œãªããã¯ïŒ
槜以äžã®å®å®ååŠç槜ã«ãã€ãŠè¡ãããããïŒæ§œ
以äžã®å Žåãé»æ°éæè£ çœ®ã¯å®çèœãæããåŠç
济ã«è¿ãæ¹ã®å®å®æ§œãšæ¥ç¶ããããšã奜ãŸããã
åããªãŒããŒãããŒãé»æ°éæåŠçããå Žåã«ã
ããŠããå®çèœãæããåŠç槜ã«è¿ãå®å®æ§œãã
ã®ãªãŒããŒãããŒãé»æ°éæåŠçããããšã奜ãŸ
ãããåŠçåŸã®å®å®æ¶²ãè£å 液ãšããŠäœ¿çšããã
ãšãå¯èœã§ãããããã®å Žåå®å®æ¶²æåãæ·»å ã
ãããšãæãŸããã å³ã¡ãæ¬çºæã«ãããŠé»æ°éæåŠçãããå®å®
液ãåã³å®å®æ¶²ãšããŠåŸªç°äœ¿çšãããšããããš
ã¯ãäžè¿°ã®ããã«å®å®æ¶²ãšããŠäœ¿çšããããšã¯å¿
è«ãå®å®æ¶²è£å 液ãšããŠçšããå ŽåïŒéåžžã溶解
æ°ŽãšããŠçšããããïŒãå«ããã®ã§ããã æŽã«ãæ¬çºæã®å®å®æ¶²ãé»æ°éæåŠçããåå
ã³ïŒåã¯åŠçåŸã«æŽ»æ§çãéœã€ãªã³äº€ææš¹èãé°
ã€ãªã³äº€ææš¹èããã¬ãŒãæš¹èåã¯åžçæš¹èãšæ¥
觊ãããŠåŠçããããé浞éåŠçãããããŠãã
ããåãããã®ïŒä»¥äžã䜵çšããŠãããã ãªããæ¬çºæã®åŠçæ¹æ³ã«å ç«ã€ãŠãæå ææ
ã¯çºè²çŸååŠçãããçºè²çŸåäž»è¬ã®é žåäœãšã«
ã©ãŒã«ãã©ãŒãšã®ã«ãããªã³ã°åå¿ã«ãã€ãŠã«ã©
ãŒè²ç»åã圢æãããããšããŸããæ¬çºæã«ä¿ã
ããå®çèœãæããåŠç液ããå®çæåãå«ã¿æŒ
çœæåãå«ãŸãªã液ã§ããå Žåã¯ãäžèšçºè²çŸå
åŠçã®åŸãæŒçœåŠçãããããšã¯å¿è«ã§ãããã
ããçºè²çŸåãªããæŒçœåŠçã«é¢ããŠã¯ãäžè¬ç
æè¡ãç¹å¥ã®å¶éãªãæ¡çšå¯èœã§ããããŸããæ¬
åºé¡äººã«ããç¹éæ58â14834å·ãå58â105145
å·ãå58â134634å·åã³å58â18631å·ããç¹é¡
æ58â2709å·çã«èšèŒã®æè¡ãåç §ã§ããããŸ
ããæ¬çºæã«çšããããå®å®æ¶²ã«é²ãã€å€ãå«æ
ããããããšã¯ç¹ã«å¥œãŸããããšã§ããã該é²ã
ã€å€ã«ã€ããŠã®æè¡çããã®ä»ã®çµæãªãã䜿çš
äŸã«ã€ããŠããåèšåå ¬å ±ãªããæ现æžã®èšèŒã
åç §ã§ããã ãå®æœäŸã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæã詳ãã説æãã
ããæ¬çºæããããã®å®æœäŸã«ãã€ãŠéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ æå ææãšããŠãµã¯ã©ã«ã©ãŒããŒããŒïŒå°è¥¿å
åçå·¥æ¥ç€Ÿè£œïŒã䜿çšããåŠç液ãšåŠçå·¥çšã«ã€
ããŠã¯äžèšã®æ¹æ³ã§å®éšãè¡ã€ãã åºæºåŠçå·¥çš ã1ã çºè²çŸå 38â ïŒå30ç§ ã2ã æŒçœå®ç 33â ïŒå30ç§ ã3ã å®å®ååŠç 25âã30â ïŒå ã4ã 也 ç¥ 75âã80â çŽïŒå åŠç液çµæ ïŒçºè²çŸåã¿ã³ã¯æ¶²ïŒ ãã³ãžã«ã¢ã«ã³ãŒã« 15ml ãšãã¬ã³ã°ãªã³ãŒã« 15ml äºç¡«é žã«ãªãŠã 2.0ïœ èåã«ãªãŠã 1.3ïœ å¡©åãããªãŠã 0.2ïœ çé žã«ãªãŠã 30.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 3.0ïœ ããªãªã³é žïŒTPPSïŒ 2.5ïœ ïŒâã¡ãã«âïŒâã¢ããââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.5ïœ è¢å å¢çœå€ïŒïŒïŒ4â²âãžã¢ããã¹ãã«ãã³ãºã¹
ã«ãã³é žèªå°äœ 1.0ïœ ã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ãã³é ž 0.3ïœ æ°Žãå ããŠå šéãïŒãšããKOHã§PH10.00ã«
調æŽããã ïŒçºè²çŸåè£å æ¶²ïŒ ãã³ãžã«ã¢ã«ã³ãŒã« 22ml ãšãã¬ã³ã°ãªã³ãŒã« 20ml äºç¡«é žã«ãªãŠã 3.0ïœ çé žã«ãªãŠã 30.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 4.0ïœ ããªãªã³é žïŒTPPSïŒ 3.0ïœ ïŒâã¡ãã«âïŒâã¢ããââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 7.5ïœ è¢å å¢çœå€ïŒïŒïŒ4â²âãžã¢ããã¹ãã«ãã³ãžã¹
ã«ãã³é žèªå°äœ 1.5ïœ ã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ãã³é ž 0.3ïœ æ°Žãå ããŠå šéãïŒãšããKOHã§PH10.50ã«
調æŽããã ïŒæŒçœå®çã¿ã³ã¯æ¶²ïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žç¬¬ïŒéã¢ã³ã¢ããŠ
ã ïŒæ°Žå¡© 60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 100ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 27.5ml çé žã«ãªãŠã ãŸãã¯æ°·é ¢é žã§PH7.1ã«èª¿æŽãã
ãšå ±ã«æ°Žãå ããŠå šéãïŒãšããã ïŒæŒçœå®çè£å æ¶²ïŒ¡ïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žç¬¬ïŒéã¢ã³ã¢ããŠ
ã ïŒæ°Žå¡© 260ïœ çé žã«ãªãŠã 42ïœ æ°Žãå ããŠå šéãïŒã«ããã ãã®æº¶æ¶²ã®PHã¯6.7±0.1ã§ããã ïŒæŒçœå®çè£å æ¶²ïŒ¢ïŒ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 500ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 150ml ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž 17ïœ æ°·é ¢é ž 85ml æ°Žãå ããŠå šéãïŒãšããã ãã®æº¶æ¶²ã®PHã¯4.6±0.1ã§ããã ïŒå®å®ã¿ã³ã¯æ¶²åã³å®å®è£å æ¶²ïŒ ïŒâããããã·ãšããªãã³âïŒïŒïŒâäºãã¹ã
ã³é ž 2.0ïœ ïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³
âïŒâãªã³ 0.03ïœ ïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.03ïœ æ°Žã§ïŒãšããŠPH4.0ã«èª¿æŽããã å®éšâïŒ èªåçŸåæ©ã«äžèšã®çºè²çŸåã¿ã³ã¯æ¶²ãæŒçœå®
çã¿ã³ã¯æ¶²ããã³å®å®ã¿ã³ã¯æ¶²ãæºããçµµçŒãé²
å ããã«ã©ãŒããŒããŒãåŠçããªããïŒåééæ¯
ã«äžèšããçºè²çŸåè£å 液ãšæŒçœå®çè£å 液ïŒ
ãšå®å®è£å 液ãå®éã«ãããéããŠè£å ããªã
ãé£ç¶åŠçãè¡ã€ããè£å éã¯ã«ã©ãŒããŒããŒïŒ
m2åœãããããçºè²çŸåã¿ã³ã¯ãžã®è£å éãšããŠ
170mlãæŒçœå®çã¿ã³ã¯ãžã®è£å éãšããŠæŒçœå®
çè£å 液ïŒïŒ¢åã 25mlãå®å®ååŠç济槜ãžã®è£
å éã¯100mlã300mlãïŒã®ïŒç¹ã«ã€ããŠè¡ã€
ãã èªåçŸåæ©ã®å®å®ååŠç济槜ã¯æå ææã®æµã
ã®æ¹åã«ç¬¬ïŒæ§œã第ïŒæ§œãšãªãå®å®æ§œãšããæçµ
槜ããè£å ãè¡ããæçµæ§œãããªãŒããŒãããŒã
ãã®å段ã®æ§œãžæµå ¥ãããããã«ãã®ãªãŒããŒã
ããŒæ¶²ããã®å段ã®æ§œã«æµå ¥ãããå€æ®µåæµæ¹åŒ
ãšããã é£ç¶åŠçã¯å®å®æ¶²ç·è£å éãå®å®æµŽã¿ã³ã¯å®¹é
ã®ïŒåãšãªãæç¹ãŸã§è¡ããæªé²å ã®ã«ã©ãŒããŒ
ããŒãåŠçããŠè©ŠæãšããããŸãæ¯èŒãšããŠå®å®
ååŠçãæµæ°Žæ°ŽæŽã«ä»£ããŠåŠçããè©Šæãäœè£œã
ãã åèšè©Šæãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ã®ãã
445nïœã§åå°çã枬å®ããçµæãè¡šâïŒã«ç€ºã
ããæŽã«çµæã®ã€ãšããŒã¹ãã€ã³ã®ãã70âã80
ïŒ RHã§25æ¥éä¿åããåŸãå åŠæ¿åºŠèšïŒPDAâ
65å°è¥¿å åçå·¥æ¥ç€Ÿè£œïŒãçšããŠãã«ãŒå ã«ãŠã€
ãšããŒã¹ãã€ã³ã枬å®ãè¡šâïŒã«ç€ºããã å®éšâïŒ å®éšâïŒã«ãããŠå®å®ååŠç济槜ã®ç¬¬ïŒæ§œïŒïŒ
ã«ç¬¬ïŒå³ã«ç€ºãããã«é»æ°éæè£ çœ®æ¬äœïŒãçŽçµ
ããé»è§£è³ªæº¶æ¶²ã«0.2Nã®ç¡«é žãããªãŠã ããé°
極ã«ãã¿ã³åéããéœæ¥µã«é»éãåã 䜿çšããŠé»
æ°éæåŠçãè¡ããªããå®éšâïŒãšåãå®éšãè¡
ããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡šâïŒ
ã«ç€ºããã ãªã第ïŒå³ã«ãããŠãïŒã¯é°æ¥µãïŒã¯éœæ¥µãïŒ
ã¯é°ã€ãªã³äº€æèãïŒã¯éœã€ãªã³äº€æèãïŒã¯é°
極宀ãïŒã¯è±å¡©å®€ãïŒã¯æ¿çž®å®€ãïŒã¯éœæ¥µå®€ãïŒ
ïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ã¿ã³ã¯ãïŒïŒã¯åŸªç°ãã³ãã
ïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ãã€ãã©ã€ã³ïŒäŸçµŠåŽïŒã
ïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒãïŒïŒã¯åŸª
ç°ãã³ããïŒïŒã¯å®å®æ¶²åŸªç°ãã€ãã©ã€ã³ïŒäŸçµŠ
åŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒã
åã 瀺ãã å®éšâïŒ å®éšâïŒã«ãããŠé»æ°éæè£ çœ®æ¬äœïŒãå®å®å
åŠç济槜ã®ç¬¬ïŒæ§œïŒïŒã«çŽçµãããŠãããã®ã第
ïŒæ§œïŒïŒâ²ã«å€æŽããå®éšâïŒãšåãå®éšãè¡ãã
ã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡šâïŒã«ç€º
ããã
äžãæå ææãšç¥ããïŒã®åŠçæ¹æ³ã«é¢ããç¹ã«
è±éå·¥çšã«ç¶ãæ°ŽæŽå·¥çšãå®è³ªçã«è¡ããªãå®å®
ååŠçæ¹æ³ã«é¢ããã ãåŸæ¥æè¡ã è¿å¹Žãæå ææã®çŸååŠçãèªåçã«äžã€é£ç¶
çã«è¡ãããªããã€ããã·ã€ãŒã«ãããŠãç°å¢ä¿
å šãšæ°Žè³æºã®åé¡ãéèŠèŠãããŠãããå®çåã¯
æŒçœå®çåŠçã«ç¶ãæ°ŽæŽå·¥çšã«ãããŠäœ¿çšããã
å€éã®æ°ŽæŽæ°Žãäœæžåã¯ãŒãã«ããããšãæãŸã
ãŠããããã®ããå®çåã¯æŒçœå®çã®åŠçã®åŸã
æ°ŽæŽãè¡ããªãã§çŽæ¥å®å®ååŠçããæè¡ãææ¡
ãããŠãããäŸãã°ç¹éæ57â8542å·ãå57â
132146å·ãå57â14834å·ãå58â18631å·åå ¬å ±
ã«ã¯ã€ãœãã¢ãŸãªã³èªå°äœããã³ãã€ãœãã¢ãŸãª
ã³èªå°äœãå¯æº¶æ§éé¯å¡©ãããªã«ã«ãã³é žãææ©
ãã¹ãã³é žãå«æããå®å®æ¶²ã§åŠçããæè¡ãèš
èŒãããŠããã æ°ŽæŽãå¿ èŠãšããªãå®å®æ¶²ã®è£å éã¯ç¹éæ58
â134636å·å ¬å ±çã«èšèŒãããŠããããã«ãåç
æå ææïŒm2åœã25mlã2.5ã§è£å ãããã奜
ãŸããã¯50mlãïŒãæŽã«å¥œãŸããã¯50mlã200
mlè£å ããã ãããã®æè¡ã¯ãå®å®æ¶²äžã«æå ææã«ãã€ãŠ
æã¡èŸŒãŸããå®çåã³æŒçœå®çæåã«ãã€ãŠçºç
ããåé¡ã®æå¶ããŸãã¯é²æ¢æ¹æ³ã«é¢ãããã®ã§
ããããããã®æè¡ã«ããŠãæã¡èŸŒãŸããå®çå
ã³æŒçœå®çæåãäžå®æ¿åºŠä»¥äžã§ã¯ãå®çšã«äŸã
åŸããå®å®æ¶²è£å éã¯äžå®éå¿ èŠã§ãã€ããç¹ã«
å®å®æ¶²ã®æçµæ§œã®å®çåã³æŒçœå®çæåæ¿åºŠãå¢
å ãããšãæå ææã®æªé²å éšåã®é·æä¿åã«ã
ãã€ãšããŒã¹ãã€ã³ãå¢å ããæ¬ ç¹ããã€ãã ãŸããå¥ã®åé¡ãšããŠãç¡æ°ŽæŽå®å®ååŠçãé·
æéã«äºã€ãŠé£ç¶ããŠè¡ããšå®çåã³æŒçœå®çæ
åã®æ··å ¥éãšã¯é¢ä¿ãªããæªé²å éšåã®åŠççŽåŸ
ã®ã¹ãã€ã³ãå¢å ãããšããæ¬ ç¹ãããããšãå€
ã€ãã ãçºæã®ç®çã åŸã€ãŠæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãå®å®æ¶²äžã®å®ç
åã³æŒçœå®çæåã®æ¿åºŠãæžå°ãããããšã«ãã€
ãŠãäœãåé¡ã®ãªãã«ã©ãŒå®å®ååŠçæ¹æ³ãæäŸ
ããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯é·æéãé£ç¶åŠçãè¡ã€
ãŠãæªé²å éšåã®åŠççŽåŸã®ã¹ãã€ã³ãå¢å ããª
ãã«ã©ãŒå®å®ååŠçæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãå®å®æ¶²äžã®æ害æåã
é€å»ããããšã«ãã€ãŠå®å®æ¶²ã®è£å éãæžå°ã
ããåå䜿çšã§ããæ¹æ³ãæäŸããããšã«ããã ãçºæã®èŠæšã æ¬çºæã®åŠçæ¹æ³ã¯ãæå ææãå®çèœãæã
ãåŠç液ã§åŠçããåŒãç¶ããŠå®è³ªçã«æ°ŽæŽãã
ããšãªãå®å®æ¶²ã§åŠçããæ¹æ³ã«ãããŠã該å®å®
液ãé»æ°éæåŠçãã該é»æ°éæåŠçãããå®å®
液ãšåã³å®å®æ¶²ãšããŠåŸªç°äœ¿çšããããšãç¹åŸŽãš
ããã æ¬çºæã®å¥œãŸããå®æœæ æ§ãšããŠã¯ãå®å®æ¶²ã
éïŒïŒã€ãªã³ãšã®ãã¬ãŒãå®å®åºŠå®æ°ãïŒä»¥äž
ã§ãããã¬ãŒãå€ãå«æããããšãæããããã ãæ¬çºæã®æ§æã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã éåžžã®æ°ŽæŽå·¥çšãæã€åŠçã§ã¯ãå®çåã³æŒçœ
å®çæåãæå ææããã®æº¶åºç©ãããã³ç²åŽæ
åçãå šãŠæ°ŽæŽå·¥çšã§æŽãæµãããŠãããã®ãã
æ°ŽæŽå·¥çšãçµãã«çŽæ¥å®å®ååŠçãè¡ããšãå šãŠ
å®å®æ¶²äžã«èç©ããé·æä¿åã§ã®ã€ãšããŒã¹ãã€
ã³ããã³åŠççŽåŸã®ã¹ãã€ã³ãçºçããã æ¬çºæè ã¯éæç 究ã®çµæãå®å®æ¶²ãé»æ°éæ
åŠçãã該é»æ°éæåŠçãããå®å®æ¶²ãåã³å®å®
液ãšããŠåŸªç°äœ¿çšããããšã«ãã€ãŠã¹ãã€ã³ã®çº
çãé²æ¢ã§ããããšãèŠåºãããã®ã§ããã æ¬çºæã®é»æ°éæåŠçãšã¯é»æ°éæ槜ã®é°æ¥µãš
éœæ¥µã®éãéèã§ä»åãããä»åããã宀ã«å®å®
液ãå ¥ãé»æ¥µã«çŽæµãéããããšã§ããã 奜ãŸããã¯éèãã€ãªã³äº€æèã§ããããšã§ã
ããæŽã«å¥œãŸããã¯ãé°æ¥µãšéœæ¥µãšã®éãé°ã€ãª
ã³äº€æèãšéœã€ãªã³äº€æèãšã«ãã亀äºã«ä»åã
ããŠãé°æ¥µå®€ãè€æ°ã®æ¿çž®å®€ïŒé°æ¥µåŽãé°ã€ãªã³
亀æèãéœæ¥µåŽãéœã€ãªã³äº€æèã§ä»åããã
宀ïŒãè€æ°ã®è±å¡©å®€ïŒé°æ¥µåŽãéœã€ãªã³äº€æèã
éœæ¥µåŽãé°ã€ãªã³äº€æèã§ä»åããã宀ïŒåã³éœ
極宀ãšãããªãããšã§ãããå®å®æ¶²ã¯å¥œãŸããã¯
è±å¡©å®€ã«å ¥ããããšã§ãããé°æ¥µå®€ãžå ¥ããããš
ã奜ãŸããããšã§ãããæ¿çž®å®€ãéœæ¥µå®€ã«å ¥ãã
é»è§£è³ªæº¶æ¶²ã¯å¥ã«éå®ããããã®ã§ãªããäŸãã°
äºç¡«é žãããªãŠã ãç¡«é žãããªãŠã ãå¡©åãããª
ãŠã ãç¡«é žã«ãªãŠã ãããªç¡«é žãããªãŠã çã®
0.1ã2Nã®æº¶æ¶²ã奜ãŸããçšããããšãã§ããã
ãã®ãšããå®çèœãæããåŠç液ãæ¿çž®å®€ãéœæ¥µ
宀ã«å ¥ããé»è§£è³ªæ¶²ãšããŠçšãããšãé»è§£è³ªæ¶²ã
å¿ èŠãšãããéåžžã«å¥œãŸããããŸãäžèšé»è§£è³ªæº¶
液ããéãååããããšãã§ããéååæ¹æ³ãšã
ãŠã¯ãé»è§£æ³ãã€ãªã³äº€ææš¹èæ³ãçšããããšã
ã§ããã äžèšã€ãªã³äº€æèãšããŠã¯åžè²©åããã®å ¥æã
å¯èœã§ãããäŸãã°æåæå·¥æ¥ç€Ÿè£œAciplexãæ
ç¡å瀟補Selemionã埳山æ¹é瀟補NEOSEPTAã
äžè±æ²¹å瀟補ãŠãã¬ãã¯ã¹ãDu Pont瀟補
Nafionçã®åååã§ç¥ãããŠããã é»æ°éæ槜åã³åãã€ãçã®ææãšããŠã¯ãã
ãªå¡©åããã«ãããªãããã¬ã³ãããªãšãã¬ã³å
ã³ãŽã ã©ã€ãã³ã°ããéçãæãããããé°æ¥µã®
ææãšããŠã¯ãéãããã±ã«ãéãäºéããã¿ã³
åéãã¹ãã³ã¬ã¹ã¹ããŒã«çãæãããããŸãéœ
極ã®ææãšããŠã¯ãçœéãçœéã¡ãããã¿ã³ãé»
éãéé žåéããã°ãã¿ã€ãçãæããããã æ¬çºæã®å®å®æ¶²ã¯éïŒïŒã€ãªã³ãšã®ãã¬ãŒã
å®å®åºŠå®æ°ãïŒä»¥äžã®ãã¬ãŒãå€ãå«æããããš
ã奜ãŸãããããã«ãã¬ãŒãå®å®åºŠå®æ°ãšã¯L.G.
Sillen.A.E.MartellèãâStability Conâstants
of Metalâion ComplexesâãThe Chemical
Society LondonïŒ1964ïŒã S.Chaberek.A.E.MartellèãâOrganic
Sequestering AgentsâãWileyïŒ1959ïŒãçã«ãã
äžè¬ã«ç¥ãããŠããæå³ã§ãããæ¬çºæã®é
ïŒïŒã€ãªã³ãšã®ãã¬ãŒãå®å®åºŠå®æ°ãïŒä»¥äžã§
ãããã¬ãŒãå€ãšããŠã¯ãææ©ã«ã«ãã³é žãã¬ãŒ
ãå€ãææ©ãªã³é žãã¬ãŒãå€ãçž®åãªã³é žãã¬ãŒ
ãå€ãããªããããã·ååç©çããããæ¬çºæã«
ãããŠå¥œãŸããã®ã¯éïŒïŒã€ãªã³ãšã®ãã¬ãŒã
å®å®åºŠå®æ°ã13以äžã§ãããã¬ãŒãå€ãçšããã
ãããšã§ãããããããã¬ãŒãå€ãšããŠã¯ããšã
ã¬ã³ãžã¢ãã³ãžãªã«ãããããã·ããšãã«é ¢é žã
ãããªãäžé ¢é žãããããã·ãšãã¬ã³ãžã¢ãã³äž
é ¢é žããžãšãã¬ã³ããªã¢ãã³äºé ¢é žãããããã·
ãšãã«ã€ããäºé ¢é žããžã¢ãããããããŒã«åé ¢
é žããã©ã³ã¹ã·ã¯ããããµã³ãžã¢ãã³åé ¢é žããš
ãã¬ã³ãžã¢ãã³ããã©ãã¹ã¡ãã¬ã³ãã¹ãã³é žã
ãããªãããªã¡ãã¬ã³ãã¹ãã³é žãïŒâãããã
ã·ãšããªãã³âïŒïŒïŒâäºãã¹ãã³é žãïŒïŒ1â²â
ãžãã¹ãããšã¿ã³âïŒâã«ã«ãã³é žãïŒâãã¹ã
ããã¿ã³âïŒïŒïŒïŒïŒâããªã«ã«ãã³é žãïŒâã
ãããã·âïŒâãã¹ãããããã³âïŒïŒïŒïŒïŒâ
ããªã«ã«ãã³é žãã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ã
ã³é žããããªã³é žãããªãŠã ãããã©ããªãªã³é ž
ãããªãŠã ããããµã¡ã¿ãªã³é žãããªãŠã ãã
ããæ¬çºæã®å¹æã®ããã«ç¹ã«å¥œãŸããã¯ãžãšã
ã¬ã³ããªã¢ãã³äºé ¢é žãïŒâããããã·ãšããªã
ã³âïŒïŒïŒâäºãã¹ãã³é žããããã®å¡©ã§ããã æŽã«ãæ¬çºæã®å®å®æ¶²ã«æ·»å ããã®ã«æãŸãã
ååç©ãšããŠã¯ãé ¢é žãç¡«é žãå¡©é žãç¡é žãã¹ã«
ãã¢ãã«é žãæ°Žé žåã«ãªãŠã ãæ°Žé žåãããªãŠ
ã ãæ°Žé žåã¢ã³ã¢ããŠã çã®PH調æŽå€ãå®æ¯éŠé ž
ãœãŒããããããã·å®æ¯éŠé žããã«ãæçç©è³ªã
ããããé ¢é žããœã«ãã³é žã«ãªãŠã ããµã€ã¢ãã³
ããŸãŒã«ããªã«ãâããšãã«ããšããŒã«çã®é²ã
ã€å€ãïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸ
ãªã³âïŒâãªã³ãïŒâãªã¯ãã«âïŒâã€ãœãã¢ãŸ
ãªã³âïŒâãªã³ãïŒâïŒâãã³ãã€ãœãã¢ãŸãªã³
âïŒâãªã³ã氎溶æ§éå±å¡©çã®ä¿æå€ããšãã¬ã³
ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãããªãã
ã«ãããªãã³çã®åæ£å€ããã«ããªã³çã®ç¡¬è
å€ãè¢å å¢çœå€çãæããããã æãæå¹ãªæ·»å ç©ã¯ç¹é¡æ58â58693å·æ现æž
ã«èšèŒãããã¢ã³ã¢ãã¢ååç©ã§ããã æ¬çºæã®å®å®æ¶²ã®PHå€ã¯PH0.1ã10ã«èª¿æŽãã
ã®ãããã奜ãŸããã¯PHïŒãïŒããã奜ãŸããã¯
PHïŒã8.5ã奜é©ãªç¯å²ã§ããã å®å®ååŠçã«éããŠã®åŠç枩床ã¯ã15âã60
âã奜ãŸããã¯20âã45âã®ç¯å²ãããããŸãåŠ
çæéãè¿ éåŠçã®èŠ³ç¹ããçæéã§ããã»ã©å¥œ
ãŸããããéåžž20ç§ã10åéãæã奜ãŸããã¯ïŒ
åãïŒåéã§ãããè€æ°æ§œå®å®ååŠçã®å Žåã¯å
段槜ã»ã©çæéã§åŠçããåŸæ®µæ§œã»ã©åŠçæéã
é·ãããšã奜ãŸãããç¹ã«å槜ã®20ïŒ ã50ïŒ å¢ã
ã®åŠçæéã§é 次åŠçããããšãæãŸããããŸ
ããå®å®ååŠçå·¥çšã¯å€æ®µæ§œãšããè£å 液ã¯æåŸ
段槜ããè£å ããé 次å段槜ã«ãªãŒããŒãããŒã
ãéæµæ¹åŒã«ããããšã奜ãŸãããæ¬çºæã«ãã
å®å®ååŠçã®åŸã«ã¯æ°ŽæŽåŠçãå šãå¿ èŠãšããªã
ãã極ãçæéå ã§ã®å°éæ°ŽæŽã«ãããªã³ã¹ãè¡š
é¢æŽæµãªã©ã¯å¿ èŠã«å¿ããŠä»»æã«è¡ãããšã¯ã§ã
ãã æ¬çºæã®å®çèœãæããåŠç液ãšã¯è±éã®ç®ç
ãæã€åŠç液ã§ãããå®ç液ãæŒçœå®ç液çãã
ããçšããããå®çå€ãšããŠã¯äŸãã°ãããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ãæ²åç©ãèåç©ãããªãšãŒ
ãã«ãããªå°¿çŽ çãããããªãã§ãäžè¬ã«çšãã
ããŠããå®çå€ã¯ããªç¡«é žå¡©ã§ããã æ¬çºæã®å®çèœãæããåŠç液ã§åŠçããåŒã
ç¶ããŠå®è³ªçã«æ°ŽæŽããããšãªãå®å®æ¶²ã§åŠçã
è¡ãããšã¯ãå®å®æ¶²ïŒæµŽïŒãããã¯æŒçœå®ç液
ïŒæµŽïŒã«ããåŠçãšå®å®æ¶²ã«ããåŠçãšã®éã«é
ååã®ããã®çæéã®éåå济ããªã³ã¹çãèšã
ãŠããããšããããšãæå³ããã æ¬çºæã®å®å®æ¶²ãæå ææãšæ¥è§Šãããæ¹æ³
ã¯ãäžè¬ã®åŠç液ãšåæ§ã«æ¶²äžã«æå ææã浞挬
ããã®ãããããã¹ãã³ãžãåæç¹ç¶åžçã«ãã
æå ææã®ä¹³å€é¢åã³æ¬éãªãŒããŒã®äž¡é¢ãæ¬é
ãã«ãã«å¡ãä»ããŠããããåã¹ãã¬ãŒçã«ãã
å¹ãä»ããŠãããã æ¬çºæã«ãããŠå®å®æ¶²ã¯é»æ°éæåŠçãããã
該åŠçæ¹æ³ãšããŠã¯ãå®å®æµŽäžã®å®å®æ¶²ãé»æ°é
æè£ çœ®ã«çŽçµããé£ç¶ããŠåŠçããæ¹æ³ãšãå®å®
济ã®ãªãŒããŒãããŒæ液ãé»æ°éæåŠçããŠå®å®
济ã«æ»ãæ¹æ³çãããããåè ã®æ¹æ³ããã奜ãŸ
ããããã®é»æ°éæåŠçãè¡ãå Žåãé»æ°éæè£
眮ã®èã«ãã€ãŠåå²ãããå宀ã«ãããŠæ¶²ã埪ç°
ããããšã奜ãŸãããæŽã«å¥œãŸããã¯ãåèšå®å®
济ã®çŽçµã®å Žåãå®å®æ¶²ãšè±å¡©å®€åã³é°æ¥µå®€ã§åžž
ã«åŸªç°ããããšã§ãããäžæ¹ãåèšãªãŒããŒãã
ãŒãåŠçããå Žåã¯ããªãŒããŒãããŒã®æºãã¿ã³
ã¯ãšè±å¡©å®€åã³é°æ¥µå®€ã§åžžã«åŸªç°ããããšã§ã
ãã æ¬çºæã«ãããå®å®ååŠçã¯ãïŒæ§œãªããã¯ïŒ
槜以äžã®å®å®ååŠç槜ã«ãã€ãŠè¡ãããããïŒæ§œ
以äžã®å Žåãé»æ°éæè£ çœ®ã¯å®çèœãæããåŠç
济ã«è¿ãæ¹ã®å®å®æ§œãšæ¥ç¶ããããšã奜ãŸããã
åããªãŒããŒãããŒãé»æ°éæåŠçããå Žåã«ã
ããŠããå®çèœãæããåŠç槜ã«è¿ãå®å®æ§œãã
ã®ãªãŒããŒãããŒãé»æ°éæåŠçããããšã奜ãŸ
ãããåŠçåŸã®å®å®æ¶²ãè£å 液ãšããŠäœ¿çšããã
ãšãå¯èœã§ãããããã®å Žåå®å®æ¶²æåãæ·»å ã
ãããšãæãŸããã å³ã¡ãæ¬çºæã«ãããŠé»æ°éæåŠçãããå®å®
液ãåã³å®å®æ¶²ãšããŠåŸªç°äœ¿çšãããšããããš
ã¯ãäžè¿°ã®ããã«å®å®æ¶²ãšããŠäœ¿çšããããšã¯å¿
è«ãå®å®æ¶²è£å 液ãšããŠçšããå ŽåïŒéåžžã溶解
æ°ŽãšããŠçšããããïŒãå«ããã®ã§ããã æŽã«ãæ¬çºæã®å®å®æ¶²ãé»æ°éæåŠçããåå
ã³ïŒåã¯åŠçåŸã«æŽ»æ§çãéœã€ãªã³äº€ææš¹èãé°
ã€ãªã³äº€ææš¹èããã¬ãŒãæš¹èåã¯åžçæš¹èãšæ¥
觊ãããŠåŠçããããé浞éåŠçãããããŠãã
ããåãããã®ïŒä»¥äžã䜵çšããŠãããã ãªããæ¬çºæã®åŠçæ¹æ³ã«å ç«ã€ãŠãæå ææ
ã¯çºè²çŸååŠçãããçºè²çŸåäž»è¬ã®é žåäœãšã«
ã©ãŒã«ãã©ãŒãšã®ã«ãããªã³ã°åå¿ã«ãã€ãŠã«ã©
ãŒè²ç»åã圢æãããããšããŸããæ¬çºæã«ä¿ã
ããå®çèœãæããåŠç液ããå®çæåãå«ã¿æŒ
çœæåãå«ãŸãªã液ã§ããå Žåã¯ãäžèšçºè²çŸå
åŠçã®åŸãæŒçœåŠçãããããšã¯å¿è«ã§ãããã
ããçºè²çŸåãªããæŒçœåŠçã«é¢ããŠã¯ãäžè¬ç
æè¡ãç¹å¥ã®å¶éãªãæ¡çšå¯èœã§ããããŸããæ¬
åºé¡äººã«ããç¹éæ58â14834å·ãå58â105145
å·ãå58â134634å·åã³å58â18631å·ããç¹é¡
æ58â2709å·çã«èšèŒã®æè¡ãåç §ã§ããããŸ
ããæ¬çºæã«çšããããå®å®æ¶²ã«é²ãã€å€ãå«æ
ããããããšã¯ç¹ã«å¥œãŸããããšã§ããã該é²ã
ã€å€ã«ã€ããŠã®æè¡çããã®ä»ã®çµæãªãã䜿çš
äŸã«ã€ããŠããåèšåå ¬å ±ãªããæ现æžã®èšèŒã
åç §ã§ããã ãå®æœäŸã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæã詳ãã説æãã
ããæ¬çºæããããã®å®æœäŸã«ãã€ãŠéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ æå ææãšããŠãµã¯ã©ã«ã©ãŒããŒããŒïŒå°è¥¿å
åçå·¥æ¥ç€Ÿè£œïŒã䜿çšããåŠç液ãšåŠçå·¥çšã«ã€
ããŠã¯äžèšã®æ¹æ³ã§å®éšãè¡ã€ãã åºæºåŠçå·¥çš ã1ã çºè²çŸå 38â ïŒå30ç§ ã2ã æŒçœå®ç 33â ïŒå30ç§ ã3ã å®å®ååŠç 25âã30â ïŒå ã4ã 也 ç¥ 75âã80â çŽïŒå åŠç液çµæ ïŒçºè²çŸåã¿ã³ã¯æ¶²ïŒ ãã³ãžã«ã¢ã«ã³ãŒã« 15ml ãšãã¬ã³ã°ãªã³ãŒã« 15ml äºç¡«é žã«ãªãŠã 2.0ïœ èåã«ãªãŠã 1.3ïœ å¡©åãããªãŠã 0.2ïœ çé žã«ãªãŠã 30.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 3.0ïœ ããªãªã³é žïŒTPPSïŒ 2.5ïœ ïŒâã¡ãã«âïŒâã¢ããââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 5.5ïœ è¢å å¢çœå€ïŒïŒïŒ4â²âãžã¢ããã¹ãã«ãã³ãºã¹
ã«ãã³é žèªå°äœ 1.0ïœ ã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ãã³é ž 0.3ïœ æ°Žãå ããŠå šéãïŒãšããKOHã§PH10.00ã«
調æŽããã ïŒçºè²çŸåè£å æ¶²ïŒ ãã³ãžã«ã¢ã«ã³ãŒã« 22ml ãšãã¬ã³ã°ãªã³ãŒã« 20ml äºç¡«é žã«ãªãŠã 3.0ïœ çé žã«ãªãŠã 30.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 4.0ïœ ããªãªã³é žïŒTPPSïŒ 3.0ïœ ïŒâã¡ãã«âïŒâã¢ããââãšãã«ââ
ïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããšãã«ïŒâã¢ããªã³
ç¡«é žå¡© 7.5ïœ è¢å å¢çœå€ïŒïŒïŒ4â²âãžã¢ããã¹ãã«ãã³ãžã¹
ã«ãã³é žèªå°äœ 1.5ïœ ã«ãã³ãŒã«âïŒïŒïŒâãžã¹ã«ãã³é ž 0.3ïœ æ°Žãå ããŠå šéãïŒãšããKOHã§PH10.50ã«
調æŽããã ïŒæŒçœå®çã¿ã³ã¯æ¶²ïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žç¬¬ïŒéã¢ã³ã¢ããŠ
ã ïŒæ°Žå¡© 60ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 100ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 27.5ml çé žã«ãªãŠã ãŸãã¯æ°·é ¢é žã§PH7.1ã«èª¿æŽãã
ãšå ±ã«æ°Žãå ããŠå šéãïŒãšããã ïŒæŒçœå®çè£å æ¶²ïŒ¡ïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žç¬¬ïŒéã¢ã³ã¢ããŠ
ã ïŒæ°Žå¡© 260ïœ çé žã«ãªãŠã 42ïœ æ°Žãå ããŠå šéãïŒã«ããã ãã®æº¶æ¶²ã®PHã¯6.7±0.1ã§ããã ïŒæŒçœå®çè£å æ¶²ïŒ¢ïŒ ããªç¡«é žã¢ã³ã¢ããŠã ïŒ70ïŒ æº¶æ¶²ïŒ 500ml äºç¡«é žã¢ã³ã¢ããŠã ïŒ40ïŒ æº¶æ¶²ïŒ 150ml ãšãã¬ã³ãžã¢ãã³ããã©é ¢é ž 17ïœ æ°·é ¢é ž 85ml æ°Žãå ããŠå šéãïŒãšããã ãã®æº¶æ¶²ã®PHã¯4.6±0.1ã§ããã ïŒå®å®ã¿ã³ã¯æ¶²åã³å®å®è£å æ¶²ïŒ ïŒâããããã·ãšããªãã³âïŒïŒïŒâäºãã¹ã
ã³é ž 2.0ïœ ïŒâã¯ããâïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³
âïŒâãªã³ 0.03ïœ ïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.03ïœ æ°Žã§ïŒãšããŠPH4.0ã«èª¿æŽããã å®éšâïŒ èªåçŸåæ©ã«äžèšã®çºè²çŸåã¿ã³ã¯æ¶²ãæŒçœå®
çã¿ã³ã¯æ¶²ããã³å®å®ã¿ã³ã¯æ¶²ãæºããçµµçŒãé²
å ããã«ã©ãŒããŒããŒãåŠçããªããïŒåééæ¯
ã«äžèšããçºè²çŸåè£å 液ãšæŒçœå®çè£å 液ïŒ
ãšå®å®è£å 液ãå®éã«ãããéããŠè£å ããªã
ãé£ç¶åŠçãè¡ã€ããè£å éã¯ã«ã©ãŒããŒããŒïŒ
m2åœãããããçºè²çŸåã¿ã³ã¯ãžã®è£å éãšããŠ
170mlãæŒçœå®çã¿ã³ã¯ãžã®è£å éãšããŠæŒçœå®
çè£å 液ïŒïŒ¢åã 25mlãå®å®ååŠç济槜ãžã®è£
å éã¯100mlã300mlãïŒã®ïŒç¹ã«ã€ããŠè¡ã€
ãã èªåçŸåæ©ã®å®å®ååŠç济槜ã¯æå ææã®æµã
ã®æ¹åã«ç¬¬ïŒæ§œã第ïŒæ§œãšãªãå®å®æ§œãšããæçµ
槜ããè£å ãè¡ããæçµæ§œãããªãŒããŒãããŒã
ãã®å段ã®æ§œãžæµå ¥ãããããã«ãã®ãªãŒããŒã
ããŒæ¶²ããã®å段ã®æ§œã«æµå ¥ãããå€æ®µåæµæ¹åŒ
ãšããã é£ç¶åŠçã¯å®å®æ¶²ç·è£å éãå®å®æµŽã¿ã³ã¯å®¹é
ã®ïŒåãšãªãæç¹ãŸã§è¡ããæªé²å ã®ã«ã©ãŒããŒ
ããŒãåŠçããŠè©ŠæãšããããŸãæ¯èŒãšããŠå®å®
ååŠçãæµæ°Žæ°ŽæŽã«ä»£ããŠåŠçããè©Šæãäœè£œã
ãã åèšè©Šæãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ã®ãã
445nïœã§åå°çã枬å®ããçµæãè¡šâïŒã«ç€ºã
ããæŽã«çµæã®ã€ãšããŒã¹ãã€ã³ã®ãã70âã80
ïŒ RHã§25æ¥éä¿åããåŸãå åŠæ¿åºŠèšïŒPDAâ
65å°è¥¿å åçå·¥æ¥ç€Ÿè£œïŒãçšããŠãã«ãŒå ã«ãŠã€
ãšããŒã¹ãã€ã³ã枬å®ãè¡šâïŒã«ç€ºããã å®éšâïŒ å®éšâïŒã«ãããŠå®å®ååŠç济槜ã®ç¬¬ïŒæ§œïŒïŒ
ã«ç¬¬ïŒå³ã«ç€ºãããã«é»æ°éæè£ çœ®æ¬äœïŒãçŽçµ
ããé»è§£è³ªæº¶æ¶²ã«0.2Nã®ç¡«é žãããªãŠã ããé°
極ã«ãã¿ã³åéããéœæ¥µã«é»éãåã 䜿çšããŠé»
æ°éæåŠçãè¡ããªããå®éšâïŒãšåãå®éšãè¡
ããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡šâïŒ
ã«ç€ºããã ãªã第ïŒå³ã«ãããŠãïŒã¯é°æ¥µãïŒã¯éœæ¥µãïŒ
ã¯é°ã€ãªã³äº€æèãïŒã¯éœã€ãªã³äº€æèãïŒã¯é°
極宀ãïŒã¯è±å¡©å®€ãïŒã¯æ¿çž®å®€ãïŒã¯éœæ¥µå®€ãïŒ
ïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ã¿ã³ã¯ãïŒïŒã¯åŸªç°ãã³ãã
ïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ãã€ãã©ã€ã³ïŒäŸçµŠåŽïŒã
ïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒãïŒïŒã¯åŸª
ç°ãã³ããïŒïŒã¯å®å®æ¶²åŸªç°ãã€ãã©ã€ã³ïŒäŸçµŠ
åŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒã
åã 瀺ãã å®éšâïŒ å®éšâïŒã«ãããŠé»æ°éæè£ çœ®æ¬äœïŒãå®å®å
åŠç济槜ã®ç¬¬ïŒæ§œïŒïŒã«çŽçµãããŠãããã®ã第
ïŒæ§œïŒïŒâ²ã«å€æŽããå®éšâïŒãšåãå®éšãè¡ãã
ã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡šâïŒã«ç€º
ããã
ãè¡šã
ã¹ãã€ã³ã匷ãã
è¡šâïŒããæãããªããã«ãåŸæ¥ã®å®å®æ¶²ã§
ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ãæ°ŽæŽããé«ããè£
å éãå°ãªãã»ã©ã€ãšããŒã¹ãã€ã³ã倧ãããä¿
åã«ããã€ãšããŒã¹ãã€ã³ã«ã€ããŠããè£å éã
ïŒm2åœãïŒã®ãšãã¯æ°ŽæŽã«æ¯èŒããŠäœããè£å
éãæŽã«æžå°ãããšã€ãšããŒã¹ãã€ã³ã¯å¢å ããŠ
ããŸããæ°Žã®äœ¿çšéã倧巟ã«æžå°ããå»æ¶²éãæž
å°ãããç®çãããå®çšã«äŸãåŸãªãã ããã«å¯Ÿããå®éšâïŒãïŒã®å®å®æ¶²ãé»æ°éæ
åŠçããæ¬çºæã§ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ã¯
å°ããããŸããä¿åã«ããã€ãšããŒã¹ãã€ã³ã«ã€
ããŠãããªãæå¶ãããŠããã極ããŠæå¹ã§ãã
ããšãå€ãã ãŸãé»æ°éæåŠçãå®çèœãæãã济ã«è¿ã第
ïŒæ§œã§è¡ã€ãå®éšâïŒã§ã¯å®éšâïŒã«æ¯èŒããŠé
åžžã«æå¹ã§ããããšãå€ãã å³ã¡æ¬çºæã¯å®å®æ¶²ã®è£å éãæžå°ãããŠãäœ
ãåé¡ãªã極ããŠæå¹ã§ããããšãå€ãã å®æœäŸ ïŒ ïŒå®å®ã¿ã³ã¯æ¶²åã³å®å®è£å æ¶²ïŒ ïŒâããããã·ãšããªãã³âïŒïŒïŒâäºãã¹ã
ã³é ž 0.5ïœ å¡©åãã¹ãã¹ïŒ45ïŒ æ°Žæº¶æ¶²ïŒ 0.1ïœ ç¡«é žãã°ãã·ãŠã 0.04ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ25ïŒ æ°Žæº¶æ¶²ïŒ 2.0ïœ ïŒâã¯ããâïŒã¡ãã«âïŒâã€ãœãã¢ãŸãªã³â
ïŒâãªã³ 0.02ïœ ïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.02ïœ ïŒâãªã¯ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.01ïœ ãªã«ãããšãã«ããšããŒã«ãããªãŠã å¡© 0.03ïœ æ°Žã§ïŒãšãç¡«é žã§PH7.0ã«èª¿æŽããã å®éšâïŒ å®æœäŸïŒã®å®å®ã¿ã³ã¯æ¶²åã³è£å 液ãäžèšå®å®
液ã«ä»£ããå®æœäŸïŒã«ãããå®éšâïŒãšåæ§ã®æ¹
æ³ã§å®å®æ¶²è£å éãã«ã©ãŒããŒããŒïŒm2åœã750
mlãšããé£ç¶åŠçãè¡ããéäžããå®å®æµŽãªãŒã
ãŒãããŒãå®å®è£å 液ã®æº¶è§£æ°ŽãšããŠäœ¿çšããå
çæ¹åŒã§é£ç¶åŠçãè¡ããå®æœäŸïŒãšåæ§ã®å®éš
ã«ãããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡š
âïŒã«ç€ºããã å®éšâïŒ å®æœäŸïŒã«ãããå®éšâïŒãïŒã®é»æ°éæè£ çœ®
ãçšããåŠçã«ãããŠãå®å®ååŠç济槜ã®ä»£ãã
ã«ã¿ã³ã¯ãèšãããã®ã¿ã³ã¯ã«å®å®æ¶²ãªãŒããŒã
ããŒãæºããé»æ°éæåŠçãè¡ããåŠçåŸã®å®å®
液ãè£å 液ã®æº¶è§£æ°ŽãšããŠäœ¿çšããåçæ¹åŒã®é£
ç¶åŠçãè¡ããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµ
æãè¡šâïŒã«ç€ºããã
è¡šâïŒããæãããªããã«ãåŸæ¥ã®å®å®æ¶²ã§
ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ãæ°ŽæŽããé«ããè£
å éãå°ãªãã»ã©ã€ãšããŒã¹ãã€ã³ã倧ãããä¿
åã«ããã€ãšããŒã¹ãã€ã³ã«ã€ããŠããè£å éã
ïŒm2åœãïŒã®ãšãã¯æ°ŽæŽã«æ¯èŒããŠäœããè£å
éãæŽã«æžå°ãããšã€ãšããŒã¹ãã€ã³ã¯å¢å ããŠ
ããŸããæ°Žã®äœ¿çšéã倧巟ã«æžå°ããå»æ¶²éãæž
å°ãããç®çãããå®çšã«äŸãåŸãªãã ããã«å¯Ÿããå®éšâïŒãïŒã®å®å®æ¶²ãé»æ°éæ
åŠçããæ¬çºæã§ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ã¯
å°ããããŸããä¿åã«ããã€ãšããŒã¹ãã€ã³ã«ã€
ããŠãããªãæå¶ãããŠããã極ããŠæå¹ã§ãã
ããšãå€ãã ãŸãé»æ°éæåŠçãå®çèœãæãã济ã«è¿ã第
ïŒæ§œã§è¡ã€ãå®éšâïŒã§ã¯å®éšâïŒã«æ¯èŒããŠé
åžžã«æå¹ã§ããããšãå€ãã å³ã¡æ¬çºæã¯å®å®æ¶²ã®è£å éãæžå°ãããŠãäœ
ãåé¡ãªã極ããŠæå¹ã§ããããšãå€ãã å®æœäŸ ïŒ ïŒå®å®ã¿ã³ã¯æ¶²åã³å®å®è£å æ¶²ïŒ ïŒâããããã·ãšããªãã³âïŒïŒïŒâäºãã¹ã
ã³é ž 0.5ïœ å¡©åãã¹ãã¹ïŒ45ïŒ æ°Žæº¶æ¶²ïŒ 0.1ïœ ç¡«é žãã°ãã·ãŠã 0.04ïœ ã¢ã³ã¢ãã¢æ°ŽïŒ25ïŒ æ°Žæº¶æ¶²ïŒ 2.0ïœ ïŒâã¯ããâïŒã¡ãã«âïŒâã€ãœãã¢ãŸãªã³â
ïŒâãªã³ 0.02ïœ ïŒâã¡ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.02ïœ ïŒâãªã¯ãã«âïŒâã€ãœãã¢ãŸãªã³âïŒâãªã³
0.01ïœ ãªã«ãããšãã«ããšããŒã«ãããªãŠã å¡© 0.03ïœ æ°Žã§ïŒãšãç¡«é žã§PH7.0ã«èª¿æŽããã å®éšâïŒ å®æœäŸïŒã®å®å®ã¿ã³ã¯æ¶²åã³è£å 液ãäžèšå®å®
液ã«ä»£ããå®æœäŸïŒã«ãããå®éšâïŒãšåæ§ã®æ¹
æ³ã§å®å®æ¶²è£å éãã«ã©ãŒããŒããŒïŒm2åœã750
mlãšããé£ç¶åŠçãè¡ããéäžããå®å®æµŽãªãŒã
ãŒãããŒãå®å®è£å 液ã®æº¶è§£æ°ŽãšããŠäœ¿çšããå
çæ¹åŒã§é£ç¶åŠçãè¡ããå®æœäŸïŒãšåæ§ã®å®éš
ã«ãããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµæãè¡š
âïŒã«ç€ºããã å®éšâïŒ å®æœäŸïŒã«ãããå®éšâïŒãïŒã®é»æ°éæè£ çœ®
ãçšããåŠçã«ãããŠãå®å®ååŠç济槜ã®ä»£ãã
ã«ã¿ã³ã¯ãèšãããã®ã¿ã³ã¯ã«å®å®æ¶²ãªãŒããŒã
ããŒãæºããé»æ°éæåŠçãè¡ããåŠçåŸã®å®å®
液ãè£å 液ã®æº¶è§£æ°ŽãšããŠäœ¿çšããåçæ¹åŒã®é£
ç¶åŠçãè¡ããã€ãšããŒã¹ãã€ã³ãæ±ãããã®çµ
æãè¡šâïŒã«ç€ºããã
ãè¡šã
è¡šâïŒããæãããªããã«ãåçãè¡ã€ãå®éš
âïŒïŒæ¯èŒäŸïŒã§ã¯å³æ¥ã®ã€ãšããŒã¹ãã€ã³ãä¿
åã«ããã€ãšããŒã¹ãã€ã³ãé«ããå®çšã«äŸãåŸ
ãªãã®ã«å¯ŸããŠãå®éšâïŒïŒæ¬çºæïŒã®é»æ°éæ
ãè¡ã€ããã®ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ãä¿å
ã«ããã€ãšããŒã¹ãã€ã³å ±ã«æ¥µããŠè¯å¥œã§ããã
å䜿çšãå¯èœã§ããããšãå€ãã å®æœäŸ ïŒ å®æœäŸïŒãšåãåŠç液ãåŠçå·¥çšåã³åŠçæ¹æ³
ã䜿çšããŠãå®å®ååŠç济ãïŒæ§œã«ä»£ããè¡šâïŒ
ã«ç€ºãNo.ïŒã12ã®å®å®æ¶²åŠæ¹ã䜿çšããã 第ïŒå³ã«ç€ºããé»æ°éæ槜ãå®æœäŸïŒã®å®éšâ
ïŒãšåæ§ã«ç¬¬ïŒæ§œã«çŽçµããé£ç¶åŠçãå®å®è£å
液ç·éãå®å®æµŽã¿ã³ã¯å®¹éã®ïŒåãšãªããŸã§è¡
ããæªé²å ã®ã«ã©ãŒããŒããŒãåŠçããè©Šæãšã
ãŠå®æœäŸïŒã®å®éšâïŒãšåæ§ã®å®éšãè¡ããã€ãš
ããŒã¹ãã€ã³ã«ã€ããŠæ±ãããã®çµæãè¡šâïŒã«
瀺ããã å°å®å®æ¶²è£å éã¯æå ææïŒm2åœã100mlãšãã
æ¯èŒãšããŠé»æ°éæåŠçãè¡ããªãã§è¡šâïŒã®No.
13ã®å®å®æ¶²åŠæ¹ã§åæ§ã®å®éšãè¡ããçµæãè¡šâ
ïŒã«ç€ºããã
âïŒïŒæ¯èŒäŸïŒã§ã¯å³æ¥ã®ã€ãšããŒã¹ãã€ã³ãä¿
åã«ããã€ãšããŒã¹ãã€ã³ãé«ããå®çšã«äŸãåŸ
ãªãã®ã«å¯ŸããŠãå®éšâïŒïŒæ¬çºæïŒã®é»æ°éæ
ãè¡ã€ããã®ã¯ãå³æ¥ã®ã€ãšããŒã¹ãã€ã³ãä¿å
ã«ããã€ãšããŒã¹ãã€ã³å ±ã«æ¥µããŠè¯å¥œã§ããã
å䜿çšãå¯èœã§ããããšãå€ãã å®æœäŸ ïŒ å®æœäŸïŒãšåãåŠç液ãåŠçå·¥çšåã³åŠçæ¹æ³
ã䜿çšããŠãå®å®ååŠç济ãïŒæ§œã«ä»£ããè¡šâïŒ
ã«ç€ºãNo.ïŒã12ã®å®å®æ¶²åŠæ¹ã䜿çšããã 第ïŒå³ã«ç€ºããé»æ°éæ槜ãå®æœäŸïŒã®å®éšâ
ïŒãšåæ§ã«ç¬¬ïŒæ§œã«çŽçµããé£ç¶åŠçãå®å®è£å
液ç·éãå®å®æµŽã¿ã³ã¯å®¹éã®ïŒåãšãªããŸã§è¡
ããæªé²å ã®ã«ã©ãŒããŒããŒãåŠçããè©Šæãšã
ãŠå®æœäŸïŒã®å®éšâïŒãšåæ§ã®å®éšãè¡ããã€ãš
ããŒã¹ãã€ã³ã«ã€ããŠæ±ãããã®çµæãè¡šâïŒã«
瀺ããã å°å®å®æ¶²è£å éã¯æå ææïŒm2åœã100mlãšãã
æ¯èŒãšããŠé»æ°éæåŠçãè¡ããªãã§è¡šâïŒã®No.
13ã®å®å®æ¶²åŠæ¹ã§åæ§ã®å®éšãè¡ããçµæãè¡šâ
ïŒã«ç€ºããã
ãè¡šã
ãè¡šã
è¡šâïŒããæãããªããã«ãæ¯èŒã®é»æ°éæã
ããªãåŠæ¹No.13ã®çµæã«å¯ŸããŠãæ¬çºæåŠæ¹No.ïŒ
ãNo.12ã®å®å®æ¶²ãé»æ°éæåŠçããå Žåãå³æ¥ã®
445nïœã§ã®åå°çãé«ããŠå¥œãŸãããçµæä¿å
ã«ããã€ãšããŒã¹ãã€ã³ã®çºçãå°ãªã極ããŠæ
å¹ã§ããã ãŸãæ¬çºæã«äœ¿çšããå®å®æ¶²ã«ãã¬ãŒãå€ãæ·»
å ããNo.ïŒãNo.12ã¯æ¬çºæå¹æãé¡èã§ããããª
ãã§ããNo.ïŒãïŒãïŒã®ãã¬ãŒãå€ã¯ãã奜ãŸã
ããNo.ïŒã®ïŒâããããã·ãšããªãã³âïŒïŒïŒâ
äºãã¹ãã³é žãæã奜ãŸããããšãå€ããæŽã«ã
ã¬ãŒãå€ã«ã¢ã³ã¢ãã¢æ°Žã䜵çšããNo.11ã12ã§ã¯
ãã奜ãŸãããã¢ã³ã¢ãã¢æ°ŽãšïŒâããããã·ãš
ããªãã³âïŒïŒïŒâäºãã¹ãã³é žã䜵çšããå Ž
åãç¹ã«å¥œãŸããããšãå€ãã å°ã第ïŒå³ã«ãããŠé»è§£è³ªæº¶æ¶²ã«ä»£ããŠãæŒçœ
å®çã¿ã³ã¯æ¶²ã䜿çšãããããé»æ°éæè£ çœ®æ¬äœ
ïŒãæŒçœå®ç槜ã«çŽçµãããŠãé»æ°éæãè¡ã€ã
æãæ¬çºæå¹æã«ã¯ã»ãšãã©å·®ããªããæŒçœå®ç
液ã®èœåã¯ã«ã©ãŒããŒããŒã®åŸ©è²ã¹ããŒããå¢å
ããé»è§£è³ªæº¶æ¶²ã®å»æ¶²ãåºã極ããŠè¯å¥œã§ãã€
ãã
ããªãåŠæ¹No.13ã®çµæã«å¯ŸããŠãæ¬çºæåŠæ¹No.ïŒ
ãNo.12ã®å®å®æ¶²ãé»æ°éæåŠçããå Žåãå³æ¥ã®
445nïœã§ã®åå°çãé«ããŠå¥œãŸãããçµæä¿å
ã«ããã€ãšããŒã¹ãã€ã³ã®çºçãå°ãªã極ããŠæ
å¹ã§ããã ãŸãæ¬çºæã«äœ¿çšããå®å®æ¶²ã«ãã¬ãŒãå€ãæ·»
å ããNo.ïŒãNo.12ã¯æ¬çºæå¹æãé¡èã§ããããª
ãã§ããNo.ïŒãïŒãïŒã®ãã¬ãŒãå€ã¯ãã奜ãŸã
ããNo.ïŒã®ïŒâããããã·ãšããªãã³âïŒïŒïŒâ
äºãã¹ãã³é žãæã奜ãŸããããšãå€ããæŽã«ã
ã¬ãŒãå€ã«ã¢ã³ã¢ãã¢æ°Žã䜵çšããNo.11ã12ã§ã¯
ãã奜ãŸãããã¢ã³ã¢ãã¢æ°ŽãšïŒâããããã·ãš
ããªãã³âïŒïŒïŒâäºãã¹ãã³é žã䜵çšããå Ž
åãç¹ã«å¥œãŸããããšãå€ãã å°ã第ïŒå³ã«ãããŠé»è§£è³ªæº¶æ¶²ã«ä»£ããŠãæŒçœ
å®çã¿ã³ã¯æ¶²ã䜿çšãããããé»æ°éæè£ çœ®æ¬äœ
ïŒãæŒçœå®ç槜ã«çŽçµãããŠãé»æ°éæãè¡ã€ã
æãæ¬çºæå¹æã«ã¯ã»ãšãã©å·®ããªããæŒçœå®ç
液ã®èœåã¯ã«ã©ãŒããŒããŒã®åŸ©è²ã¹ããŒããå¢å
ããé»è§£è³ªæº¶æ¶²ã®å»æ¶²ãåºã極ããŠè¯å¥œã§ãã€
ãã
第ïŒå³ã¯é»æ°éæè£
眮ãçšããæ¬çºæã®åŠçæ¹
æ³ã®äžå®æœäŸã瀺ãæŠç¥å³ã§ããã å³äžãïŒã¯é»æ°éæè£ çœ®æ¬äœãïŒã¯é°æ¥µãïŒã¯
éœæ¥µãïŒã¯é°ã€ãªã³äº€æèãïŒã¯éœã€ãªã³äº€æ
èãïŒã¯é°æ¥µå®€ãïŒã¯è±å¡©å®€ãïŒã¯æ¿çž®å®€ãïŒã¯
éœæ¥µå®€ãïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ã¿ã³ã¯ãïŒïŒã¯åŸª
ç°ãã³ããïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ãã€ãã©ã€ã³
ïŒäŸçµŠåŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒã
ïŒïŒã¯å®å®ååŠç济槜ïŒç¬¬ïŒæ§œïŒãïŒïŒâ²ã¯å第ïŒ
å±€ãïŒïŒã¯åŸªç°ãã³ããïŒïŒã¯å®å®æ¶²åŸªç°ãã€ã
ã©ã€ã³ïŒäŸçµŠåŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³
ïŒæµåºåŽïŒãåã 瀺ãã
æ³ã®äžå®æœäŸã瀺ãæŠç¥å³ã§ããã å³äžãïŒã¯é»æ°éæè£ çœ®æ¬äœãïŒã¯é°æ¥µãïŒã¯
éœæ¥µãïŒã¯é°ã€ãªã³äº€æèãïŒã¯éœã€ãªã³äº€æ
èãïŒã¯é°æ¥µå®€ãïŒã¯è±å¡©å®€ãïŒã¯æ¿çž®å®€ãïŒã¯
éœæ¥µå®€ãïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ã¿ã³ã¯ãïŒïŒã¯åŸª
ç°ãã³ããïŒïŒã¯é»è§£è³ªæº¶æ¶²åŸªç°ãã€ãã©ã€ã³
ïŒäŸçµŠåŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³ïŒæµåºåŽïŒã
ïŒïŒã¯å®å®ååŠç济槜ïŒç¬¬ïŒæ§œïŒãïŒïŒâ²ã¯å第ïŒ
å±€ãïŒïŒã¯åŸªç°ãã³ããïŒïŒã¯å®å®æ¶²åŸªç°ãã€ã
ã©ã€ã³ïŒäŸçµŠåŽïŒãïŒïŒã¯å埪ç°ãã€ãã©ã€ã³
ïŒæµåºåŽïŒãåã 瀺ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããã²ã³åéã«ã©ãŒåçæå ææãå®çèœã
æããåŠç液ã§åŠçããåŒãç¶ããŠå®è³ªçã«æ°ŽæŽ
ããããšãªãå®å®æ¶²ã§åŠçããæ¹æ³ã«ãããŠã該
å®å®æ¶²ãé»æ°éæåŠçãã該é»æ°éæåŠçããã
å®å®æ¶²ãåã³å®å®æ¶²ãšããŠåŸªç°äœ¿çšããããšãç¹
城ãšããããã²ã³åéã«ã©ãŒåçæå ææã®åŠç
æ¹æ³ã ïŒ å®å®æ¶²ãéïŒïŒã€ãªã³ãšã®ãã¬ãŒãå®å®åºŠ
å®æ°ãïŒä»¥äžã§ãããã¬ãŒãå€ãå«æããããšã
ç¹åŸŽãšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ããã²ã³
åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³ã
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9635284A JPS6128949A (ja) | 1984-05-16 | 1984-05-16 | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
DE19853517394 DE3517394A1 (de) | 1984-05-16 | 1985-05-14 | Verfahren zur behandlung farbphotographischer silberhalogenid-aufzeichnungsmaterialien |
AU42450/85A AU4245085A (en) | 1984-05-16 | 1985-05-14 | Electrodialytic replenishment of stabiliser solution |
GB08512342A GB2158959B (en) | 1984-05-16 | 1985-05-15 | Method for processing of silver halide color photographic material |
US07/236,321 US4859575A (en) | 1984-05-16 | 1988-08-24 | Method for processing of silver halide color photographic material with dialysis treatment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9635284A JPS6128949A (ja) | 1984-05-16 | 1984-05-16 | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6128949A JPS6128949A (ja) | 1986-02-08 |
JPS6334461B2 true JPS6334461B2 (ja) | 1988-07-11 |
Family
ID=14162601
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9635284A Granted JPS6128949A (ja) | 1984-05-16 | 1984-05-16 | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
Country Status (5)
Country | Link |
---|---|
US (1) | US4859575A (ja) |
JP (1) | JPS6128949A (ja) |
AU (1) | AU4245085A (ja) |
DE (1) | DE3517394A1 (ja) |
GB (1) | GB2158959B (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60260952A (ja) * | 1984-06-08 | 1985-12-24 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææã®åŠçæ¹æ³åã³åŠç液 |
JPS6278556A (ja) * | 1985-10-01 | 1987-04-10 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³åã³æ°ŽæŽä»£æ¿å®å®æ¶² |
JPS62127740A (ja) * | 1985-11-27 | 1987-06-10 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
DE3903024A1 (de) * | 1989-02-02 | 1990-08-16 | Hoechst Ag | Verfahren zur entsalzung von loesemittelhaltigen elektrolytloesungen durch elektrodialyse |
GB8909580D0 (en) * | 1989-04-26 | 1989-06-14 | Kodak Ltd | Method of forming a photographic colour image |
JPH0367257A (ja) * | 1989-04-28 | 1991-03-22 | Konica Corp | ããã²ã³åéåçæå ææçšå®å®æ¶²åã³è©²å®å®æ¶²ãçšããããã²ã³åéåçæå ææã®åŠçæ¹æ³ |
JP2769579B2 (ja) * | 1989-10-20 | 1998-06-25 | ã³ãã«æ ªåŒäŒç€Ÿ | æå ææåŠçè£ çœ® |
JP2904948B2 (ja) * | 1991-03-28 | 1999-06-14 | ã³ãã«æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³åã³å®å®æ¶² |
DE69920067D1 (de) * | 1998-01-22 | 2004-10-21 | Eastman Kodak Co | Verfahren und Vorrichtung zur RÃŒckfÃŒhrung von Waschwasser in photographischen Verarbeitungen |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5437731A (en) * | 1977-08-30 | 1979-03-20 | Fuji Photo Film Co Ltd | Method and apparatus for controlling halogen ion concentration in photographic processing solution |
JPS561048A (en) * | 1979-06-15 | 1981-01-08 | Fuji Photo Film Co Ltd | Regenerating method for waste photographic processing solution |
JPS5633644A (en) * | 1979-08-27 | 1981-04-04 | Fuji Photo Film Co Ltd | Regenerating method for photographic processing solution |
JPS578543A (en) * | 1980-06-18 | 1982-01-16 | Konishiroku Photo Ind Co Ltd | Processing method for color photographic sensitive silver halide material |
DE3412857A1 (de) * | 1983-04-05 | 1984-10-11 | Konishiroku Photo Industry Co., Ltd., Tokio/Tokyo | Verfahren zur behandlung von farbfotografischen silberhalogenid-materialien |
JPS6143741A (ja) * | 1984-07-13 | 1986-03-03 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææã®åŠçæ¹æ³ |
JPS6161160A (ja) * | 1984-08-31 | 1986-03-28 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
JPS61151650A (ja) * | 1984-12-26 | 1986-07-10 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
US4774169A (en) * | 1985-08-06 | 1988-09-27 | Konishiroku Photo Industry Co., Ltd. | Processing solution for developing a silver halide color photographic material and a method of developing the same |
EP0244177B1 (en) * | 1986-04-30 | 1994-05-04 | Konica Corporation | Method for processing light-sensitive silver halide color photographic material |
EP0251178B1 (en) * | 1986-06-27 | 1994-04-20 | Fuji Photo Film Co., Ltd. | Method of supplying replenishing solution in automatic developing machine |
-
1984
- 1984-05-16 JP JP9635284A patent/JPS6128949A/ja active Granted
-
1985
- 1985-05-14 AU AU42450/85A patent/AU4245085A/en not_active Abandoned
- 1985-05-14 DE DE19853517394 patent/DE3517394A1/de not_active Withdrawn
- 1985-05-15 GB GB08512342A patent/GB2158959B/en not_active Expired
-
1988
- 1988-08-24 US US07/236,321 patent/US4859575A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
GB8512342D0 (en) | 1985-06-19 |
US4859575A (en) | 1989-08-22 |
DE3517394A1 (de) | 1985-11-21 |
GB2158959A (en) | 1985-11-20 |
GB2158959B (en) | 1987-07-22 |
JPS6128949A (ja) | 1986-02-08 |
AU4245085A (en) | 1985-11-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6217742B2 (ja) | ||
JPH0435059B2 (ja) | ||
JPH0436376B2 (ja) | ||
JPS6120864B2 (ja) | ||
JPS6152459B2 (ja) | ||
JPS6334461B2 (ja) | ||
US4089760A (en) | Method for regenerating waste developers used for processing silver halide photographic materials and method for storing developers | |
US4217188A (en) | Method for storing developers | |
US4145271A (en) | Method for regenerating oxidized photographic developers | |
JPS6323528B2 (ja) | ||
JPS6341049B2 (ja) | ||
JPH0562975B2 (ja) | ||
JPH0548904B2 (ja) | ||
JPH0553259A (ja) | ããã²ã³åéæå ææã®åŠçæ¹æ³ | |
JPS6158029B2 (ja) | ||
US5922520A (en) | Photographic processing method and tank | |
JPH027451B2 (ja) | ||
JPH04250449A (ja) | åçåŠçæ¹æ³ | |
JPS6336492B2 (ja) | ||
JPS6320338B2 (ja) | ||
JPS60247241A (ja) | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ | |
JPH057468B2 (ja) | ||
JP2670928B2 (ja) | åçæå ææã®åŠçæ¹æ³åã³åŠçè£ çœ® | |
JPH0352617B2 (ja) | ||
JPS60263940A (ja) | ããã²ã³åéåçæå ææã®åŠçæ¹æ³ |