JPH0768543B2 - 洗浄漂白組成物 - Google Patents
洗浄漂白組成物Info
- Publication number
- JPH0768543B2 JPH0768543B2 JP4317228A JP31722892A JPH0768543B2 JP H0768543 B2 JPH0768543 B2 JP H0768543B2 JP 4317228 A JP4317228 A JP 4317228A JP 31722892 A JP31722892 A JP 31722892A JP H0768543 B2 JPH0768543 B2 JP H0768543B2
- Authority
- JP
- Japan
- Prior art keywords
- optionally substituted
- composition
- tacn
- weight
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 62
- 238000004061 bleaching Methods 0.000 title claims description 43
- 238000004140 cleaning Methods 0.000 title claims description 16
- 239000007844 bleaching agent Substances 0.000 claims description 40
- 239000011572 manganese Substances 0.000 claims description 40
- 239000003054 catalyst Substances 0.000 claims description 34
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 claims description 27
- -1 hydroperoxide compound Chemical class 0.000 claims description 25
- 239000002736 nonionic surfactant Substances 0.000 claims description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 239000003945 anionic surfactant Substances 0.000 claims description 16
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 15
- 229910052748 manganese Inorganic materials 0.000 claims description 15
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 13
- 239000000344 soap Substances 0.000 claims description 12
- 125000003107 substituted aryl group Chemical group 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 150000002978 peroxides Chemical class 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 239000003446 ligand Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 229910020366 ClO 4 Inorganic materials 0.000 claims description 2
- GEANMIJCJBPZNC-UHFFFAOYSA-N 1,2-dimethyl-1,4,7-triazonane Chemical compound CC1CNCCNCCN1C GEANMIJCJBPZNC-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 description 16
- 239000000126 substance Substances 0.000 description 16
- 239000002253 acid Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 13
- 230000003197 catalytic effect Effects 0.000 description 12
- 239000002243 precursor Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 150000004965 peroxy acids Chemical class 0.000 description 10
- 239000003599 detergent Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000011976 maleic acid Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002696 manganese Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229960001922 sodium perborate Drugs 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 3
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical group COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000004967 organic peroxy acids Chemical class 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 229940077386 sodium benzenesulfonate Drugs 0.000 description 2
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- NVPHAZUOWKQGLE-UHFFFAOYSA-N (11-oxo-11-phenoxyundecyl)azanium;chloride Chemical compound [Cl-].[NH3+]CCCCCCCCCCC(=O)OC1=CC=CC=C1 NVPHAZUOWKQGLE-UHFFFAOYSA-N 0.000 description 1
- ZVZXNYFQDXOOOA-UHFFFAOYSA-N 1,2,2,4,7-pentamethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CC(C)(C)N(C)CC1 ZVZXNYFQDXOOOA-UHFFFAOYSA-N 0.000 description 1
- UYXFOIMFLBVYDL-UHFFFAOYSA-N 1,2,4,7-tetramethyl-1,4,7-triazonane Chemical compound CC1CN(C)CCN(C)CCN1C UYXFOIMFLBVYDL-UHFFFAOYSA-N 0.000 description 1
- ITIURFCAPKNNCK-UHFFFAOYSA-N 1,4,7-triazecane Chemical compound C1CNCCNCCNC1 ITIURFCAPKNNCK-UHFFFAOYSA-N 0.000 description 1
- DEKIYHATMYCZIN-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazecane Chemical compound CN1CCCN(C)CCN(C)CC1 DEKIYHATMYCZIN-UHFFFAOYSA-N 0.000 description 1
- RITZWEITCIOIEB-UHFFFAOYSA-N 1,4,8-triazacycloundecane Chemical compound C1CNCCCNCCNC1 RITZWEITCIOIEB-UHFFFAOYSA-N 0.000 description 1
- WXOJYXXWQZRWHB-UHFFFAOYSA-N 1,4,8-trimethyl-1,4,8-triazacycloundecane Chemical compound CN1CCCN(C)CCN(C)CCC1 WXOJYXXWQZRWHB-UHFFFAOYSA-N 0.000 description 1
- VQFZKDXSJZVGDA-UHFFFAOYSA-N 1,5,9-triazacyclododecane Chemical compound C1CNCCCNCCCNC1 VQFZKDXSJZVGDA-UHFFFAOYSA-N 0.000 description 1
- LRPVVAOGGZFVFO-UHFFFAOYSA-N 1,5,9-trimethyl-1,5,9-triazacyclododecane Chemical compound CN1CCCN(C)CCCN(C)CCC1 LRPVVAOGGZFVFO-UHFFFAOYSA-N 0.000 description 1
- JJICBMPGGOIYHR-UHFFFAOYSA-N 1-[2-(4,7-dimethyl-1,4,7-triazonan-1-yl)ethyl]-4,7-dimethyl-1,4,7-triazonane Chemical compound C1CN(C)CCN(C)CCN1CCN1CCN(C)CCN(C)CC1 JJICBMPGGOIYHR-UHFFFAOYSA-N 0.000 description 1
- CLDUIVDUCSZOAA-UHFFFAOYSA-N 1-[bis(triazol-1-yl)methyl]triazole Chemical compound N1=NC=CN1C(N1N=NC=C1)N1N=NC=C1 CLDUIVDUCSZOAA-UHFFFAOYSA-N 0.000 description 1
- QOHVIMQQEFHOLE-UHFFFAOYSA-N 1-[di(pyrazol-1-yl)methyl]pyrazole Chemical compound C1=CC=NN1C(N1N=CC=C1)N1N=CC=C1 QOHVIMQQEFHOLE-UHFFFAOYSA-N 0.000 description 1
- KJYFLKGZJHSMBW-UHFFFAOYSA-N 1-n,1-n',1-n"-trimethylethane-1,1,1-triamine Chemical compound CNC(C)(NC)NC KJYFLKGZJHSMBW-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- KOGZGHWZQGNJAJ-UHFFFAOYSA-N 2-(dipyridin-2-ylmethyl)pyridine Chemical compound N1=CC=CC=C1C(C=1N=CC=CC=1)C1=CC=CC=N1 KOGZGHWZQGNJAJ-UHFFFAOYSA-N 0.000 description 1
- HHPPJYFDKGABES-UHFFFAOYSA-N 2-[bis(1h-imidazol-2-yl)methyl]-1h-imidazole Chemical compound C1=CNC(C(C=2NC=CN=2)C=2NC=CN=2)=N1 HHPPJYFDKGABES-UHFFFAOYSA-N 0.000 description 1
- YMZSLCSDMHLNPW-UHFFFAOYSA-N 2-benzyl-1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1CC1=CC=CC=C1 YMZSLCSDMHLNPW-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- UTMYFCFWEQRTOM-UHFFFAOYSA-N 3-(carboxymethylperoxy)-3-oxopropanoic acid Chemical compound OC(=O)COOC(=O)CC(O)=O UTMYFCFWEQRTOM-UHFFFAOYSA-N 0.000 description 1
- FCZZQVBGZFNATF-UHFFFAOYSA-N 6-(octylamino)-6-oxohexaneperoxoic acid Chemical compound CCCCCCCCNC(=O)CCCCC(=O)OO FCZZQVBGZFNATF-UHFFFAOYSA-N 0.000 description 1
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000012425 OXONE® Substances 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 150000001218 Thorium Chemical class 0.000 description 1
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- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000004973 alkali metal peroxides Chemical class 0.000 description 1
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- 229940025131 amylases Drugs 0.000 description 1
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- 125000003710 aryl alkyl group Chemical group 0.000 description 1
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- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 1
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
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- 230000006835 compression Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- UYAUGHKQCCCFDK-UHFFFAOYSA-N cyclohexane-1,3,5-triamine Chemical compound NC1CC(N)CC(N)C1 UYAUGHKQCCCFDK-UHFFFAOYSA-N 0.000 description 1
- UNWDCFHEVIWFCW-UHFFFAOYSA-N decanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCC(=O)OO UNWDCFHEVIWFCW-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 description 1
- BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000004966 inorganic peroxy acids Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000013580 millipore water Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003007 phosphonic acid derivatives Chemical class 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- YDLQSTFHBCVEJV-UHFFFAOYSA-M sodium;2-(3,5,5-trimethylhexanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1S([O-])(=O)=O YDLQSTFHBCVEJV-UHFFFAOYSA-M 0.000 description 1
- GHKCMSLSUYMTNI-UHFFFAOYSA-M sodium;3-benzoyloxy-4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1OC(=O)C1=CC=CC=C1 GHKCMSLSUYMTNI-UHFFFAOYSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- JMAYRNRPJTZKLX-UHFFFAOYSA-M sodium;4-methyl-3-phenoxybenzoate Chemical compound [Na+].CC1=CC=C(C([O-])=O)C=C1OC1=CC=CC=C1 JMAYRNRPJTZKLX-UHFFFAOYSA-M 0.000 description 1
- UVJHZDCPNOXCSI-UHFFFAOYSA-M sodium;4-phenoxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC1=CC=CC=C1 UVJHZDCPNOXCSI-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- 125000005650 substituted phenylene group Chemical group 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 125000005490 tosylate group Chemical group 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- SWUFZSQHKFLQTM-UHFFFAOYSA-N tripyrazol-1-yl borate Chemical compound C1=CC=NN1OB(ON1N=CC=C1)ON1C=CC=N1 SWUFZSQHKFLQTM-UHFFFAOYSA-N 0.000 description 1
- ABZXVOOVPSZQRN-UHFFFAOYSA-N tripyridin-2-yl borate Chemical compound C=1C=CC=NC=1OB(OC=1N=CC=CC=1)OC1=CC=CC=N1 ABZXVOOVPSZQRN-UHFFFAOYSA-N 0.000 description 1
- LBDVZFHBNFGYDL-UHFFFAOYSA-N tris(1h-imidazol-2-yl) borate Chemical compound N=1C=CNC=1OB(OC=1NC=CN=1)OC1=NC=CN1 LBDVZFHBNFGYDL-UHFFFAOYSA-N 0.000 description 1
- LCORTBULURHQHJ-UHFFFAOYSA-N tris(1h-imidazol-2-yl)phosphane Chemical compound C1=CNC(P(C=2NC=CN=2)C=2NC=CN=2)=N1 LCORTBULURHQHJ-UHFFFAOYSA-N 0.000 description 1
- MJYTZAQGBQAGAG-UHFFFAOYSA-N tris(triazol-1-yl) borate Chemical compound C1=CN=NN1OB(ON1N=NC=C1)ON1C=CN=N1 MJYTZAQGBQAGAG-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP91203078 | 1991-11-26 | ||
| NL91203078.0 | 1991-11-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0641586A JPH0641586A (ja) | 1994-02-15 |
| JPH0768543B2 true JPH0768543B2 (ja) | 1995-07-26 |
Family
ID=8208033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4317228A Expired - Lifetime JPH0768543B2 (ja) | 1991-11-26 | 1992-11-26 | 洗浄漂白組成物 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0544490A1 (OSRAM) |
| JP (1) | JPH0768543B2 (OSRAM) |
| KR (1) | KR960000205B1 (OSRAM) |
| CN (1) | CN1031647C (OSRAM) |
| AU (1) | AU661522B2 (OSRAM) |
| BR (1) | BR9204549A (OSRAM) |
| CA (1) | CA2083661A1 (OSRAM) |
| MX (1) | MX9206779A (OSRAM) |
| TR (1) | TR27075A (OSRAM) |
| TW (1) | TW234144B (OSRAM) |
| ZA (1) | ZA928188B (OSRAM) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078459A1 (ja) | 2007-12-19 | 2009-06-25 | Lion Corporation | 漂白用酸化触媒、並びにこれを用いた漂白性組成物 |
Families Citing this family (164)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994019445A1 (en) * | 1993-02-22 | 1994-09-01 | Unilever N.V. | Machine dishwashing composition |
| GB9305599D0 (en) * | 1993-03-18 | 1993-05-05 | Unilever Plc | Detergent compositions |
| US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
| CA2187175A1 (en) * | 1994-04-07 | 1995-10-19 | Stefano Scialla | Bleach compositions comprising metal-containing bleach catalysts and antioxidants |
| US5560748A (en) * | 1994-06-10 | 1996-10-01 | The Procter & Gamble Company | Detergent compositions comprising large pore size redox catalysts |
| WO1995034628A1 (en) * | 1994-06-13 | 1995-12-21 | Unilever N.V. | Bleach activation |
| ATE269392T1 (de) * | 1994-07-21 | 2004-07-15 | Ciba Sc Holding Ag | Bleichmittelzusammensetzung für gewebe |
| AU3077495A (en) * | 1994-08-19 | 1996-03-14 | Unilever Plc | Detergent bleach composition |
| ZA956914B (en) * | 1994-08-19 | 1997-02-18 | Unilever Plc | Detergent bleach composition. |
| US5578136A (en) | 1994-08-31 | 1996-11-26 | The Procter & Gamble Company | Automatic dishwashing compositions comprising quaternary substituted bleach activators |
| US5968881A (en) * | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
| MX9705985A (es) * | 1995-02-02 | 1997-11-29 | Procter & Gamble | Composiciones de lavado de vajilla automatico que comprenden catalizadores de cobalto quelatados. |
| JPH10513215A (ja) * | 1995-02-02 | 1998-12-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | コバルト▲ｉｉｉ▼触媒を含む自動皿洗い組成物 |
| GB2297978A (en) | 1995-02-15 | 1996-08-21 | Procter & Gamble | Detergent compositions containing amylase |
| ES2158320T3 (es) * | 1995-06-16 | 2001-09-01 | Procter & Gamble | Composiciones para lavavajillas automaticos que comprenden catalizadores de cobalto. |
| WO1997000311A1 (en) * | 1995-06-16 | 1997-01-03 | The Procter & Gamble Company | Bleach compositions comprising cobalt catalysts |
| DE19523891C1 (de) * | 1995-06-30 | 1996-11-21 | Hoechst Ag | Chirale Mangan-triazanonankomplexe und Verfahren zu ihrer Herstellung |
| DE19535082A1 (de) | 1995-09-21 | 1997-03-27 | Henkel Ecolab Gmbh & Co Ohg | Pastenförmiges Wasch- und Reinigungsmittel |
| US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
| GB9523654D0 (en) * | 1995-11-18 | 1996-01-17 | Ciba Geigy Ag | Fabric bleaching composition |
| DE19545729A1 (de) | 1995-12-08 | 1997-06-12 | Henkel Kgaa | Bleich- und Waschmittel mit enzymatischem Bleichsystem |
| DE19605688A1 (de) * | 1996-02-16 | 1997-08-21 | Henkel Kgaa | Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen |
| GB2311078A (en) * | 1996-03-16 | 1997-09-17 | Procter & Gamble | Bleaching composition containing cellulolytic enzyme |
| WO1997036986A1 (de) * | 1996-04-01 | 1997-10-09 | Henkel Kommanditgesellschaft Auf Aktien | Reinigungsmittel mit oligoamminaktivatorkomplexen für persauerstoffverbindungen |
| DE19620411A1 (de) | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen |
| CZ355098A3 (cs) | 1996-05-03 | 1999-04-14 | The Procter & Gamble Company | Detergentové prostředky s lepší dispergací nečistot, které obsahují polyaminové polymery |
| DE19620241A1 (de) * | 1996-05-20 | 1997-11-27 | Patt R Prof Dr | Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators |
| BR9709798A (pt) * | 1996-06-19 | 1999-08-10 | Unilever Nv | Catalisador de alvejamento e oxidacão sistema de oxidacão catalítica e composicão de alvejamento |
| US5850086A (en) * | 1996-06-21 | 1998-12-15 | Regents Of The University Of Minnesota | Iron complexes for bleach activation and stereospecific oxidation |
| DE19636035A1 (de) | 1996-09-05 | 1998-03-12 | Henkel Ecolab Gmbh & Co Ohg | Pastenförmiges Wasch- und Reinigungsmittel |
| DE19649375A1 (de) | 1996-11-29 | 1998-06-04 | Henkel Kgaa | Acetonitril-Derivate als Bleichaktivatoren in Reinigungsmitteln |
| DE19703364A1 (de) | 1997-01-30 | 1998-08-06 | Henkel Ecolab Gmbh & Co Ohg | Pastenförmiges Wasch- und Reinigungsmittel |
| DE19714122A1 (de) * | 1997-04-05 | 1998-10-08 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
| DE19719397A1 (de) * | 1997-05-07 | 1998-11-12 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
| DE19728021A1 (de) * | 1997-07-01 | 1999-01-07 | Clariant Gmbh | Metall-Komplexe als Bleichaktivatoren |
| DE19732750A1 (de) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | Glucanasehaltiges Reinigungsmittel für harte Oberflächen |
| DE19732751A1 (de) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | Neue Beta-Glucanase aus Bacillus |
| DE19732749A1 (de) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | Glucanasehaltiges Waschmittel |
| AR016969A1 (es) | 1997-10-23 | 2001-08-01 | Procter & Gamble | VARIANTE DE PROTEASA, ADN, VECTOR DE EXPRESIoN, MICROORGANISMO HUESPED, COMPOSICIoN DE LIMPIEZA, ALIMENTO PARA ANIMALES Y COMPOSICIoN PARA TRATAR UN TEXTIL |
| US6410500B1 (en) | 1997-12-30 | 2002-06-25 | Henkel Kommanditgesellschaft Auf Aktien | Moulded body dishwasher detergents with soil release polymers |
| US6992056B1 (en) | 1997-12-30 | 2006-01-31 | Henkel Kgaa | Process for preparing detergent tablets having two or more regions |
| DE19758262A1 (de) | 1997-12-31 | 1999-07-08 | Henkel Kgaa | Alkylaminotriazolhaltige, granulare Komponente für den Einsatz in Maschinengeschirrspülmitteln (MGSM) und Verfahren zu dessen Herstellung |
| DE19819187A1 (de) | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Festes maschinelles Geschirrspülmittel mit Phosphat und kristallinen schichtförmigen Silikaten |
| DE19850100A1 (de) | 1998-10-29 | 2000-05-04 | Henkel Kgaa | Polymer-Granulate durch Wirbelschichtgranulation |
| KR100555040B1 (ko) * | 1998-12-29 | 2006-05-16 | 주식회사 엘지생활건강 | 트리스(2-피리딜메틸)아민 망간 착화합물과 이를 함유한 표백제및 표백세제 조성물 |
| DE19908051A1 (de) | 1999-02-25 | 2000-08-31 | Henkel Kgaa | Verfahren zur Herstellung compoundierter Acetonitril-Derivate |
| DE19914811A1 (de) | 1999-03-31 | 2000-10-05 | Henkel Kgaa | Enzym- und bleichaktivatorhaltige Wasch- und Reinigungsmittel |
| DE19943254A1 (de) * | 1999-09-10 | 2001-03-15 | Clariant Gmbh | Bleichaktive Metallkomplexe |
| DE19944218A1 (de) | 1999-09-15 | 2001-03-29 | Cognis Deutschland Gmbh | Waschmitteltabletten |
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Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9003741D0 (en) * | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
| EP0458397B1 (en) * | 1990-05-21 | 1997-03-26 | Unilever N.V. | Bleach activation |
-
1992
- 1992-11-24 EP EP92310719A patent/EP0544490A1/en not_active Withdrawn
- 1992-11-24 CA CA002083661A patent/CA2083661A1/en not_active Abandoned
- 1992-11-25 BR BR9204549A patent/BR9204549A/pt not_active Application Discontinuation
- 1992-11-25 MX MX9206779A patent/MX9206779A/es not_active Application Discontinuation
- 1992-11-25 AU AU29620/92A patent/AU661522B2/en not_active Ceased
- 1992-11-25 CN CN92111815A patent/CN1031647C/zh not_active Expired - Fee Related
- 1992-11-26 KR KR1019920022431A patent/KR960000205B1/ko not_active Expired - Fee Related
- 1992-11-26 TR TR01152/92A patent/TR27075A/xx unknown
- 1992-11-26 JP JP4317228A patent/JPH0768543B2/ja not_active Expired - Lifetime
- 1992-11-26 ZA ZA928188A patent/ZA928188B/xx unknown
- 1992-12-04 TW TW081109741A patent/TW234144B/zh active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078459A1 (ja) | 2007-12-19 | 2009-06-25 | Lion Corporation | 漂白用酸化触媒、並びにこれを用いた漂白性組成物 |
| US8993504B2 (en) | 2007-12-19 | 2015-03-31 | Lion Corporation | Oxidation catalyst for bleaching, and bleaching composition using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| AU661522B2 (en) | 1995-07-27 |
| KR930010171A (ko) | 1993-06-22 |
| BR9204549A (pt) | 1993-06-01 |
| TW234144B (OSRAM) | 1994-11-11 |
| JPH0641586A (ja) | 1994-02-15 |
| EP0544490A1 (en) | 1993-06-02 |
| KR960000205B1 (ko) | 1996-01-03 |
| ZA928188B (en) | 1994-05-26 |
| TR27075A (tr) | 1994-10-18 |
| CA2083661A1 (en) | 1993-05-27 |
| CN1031647C (zh) | 1996-04-24 |
| AU2962092A (en) | 1993-06-17 |
| MX9206779A (es) | 1993-05-01 |
| CN1073714A (zh) | 1993-06-30 |
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