JPH0424831B2 - - Google Patents
Info
- Publication number
- JPH0424831B2 JPH0424831B2 JP61103785A JP10378586A JPH0424831B2 JP H0424831 B2 JPH0424831 B2 JP H0424831B2 JP 61103785 A JP61103785 A JP 61103785A JP 10378586 A JP10378586 A JP 10378586A JP H0424831 B2 JPH0424831 B2 JP H0424831B2
- Authority
- JP
- Japan
- Prior art keywords
- active material
- battery
- secondary battery
- positive electrode
- negative electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003575 carbonaceous material Substances 0.000 claims description 46
- 239000011149 active material Substances 0.000 claims description 30
- 238000002441 X-ray diffraction Methods 0.000 claims description 16
- 239000002131 composite material Substances 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- 238000004438 BET method Methods 0.000 claims description 6
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- 239000005519 non-carbonaceous material Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 48
- 238000007600 charging Methods 0.000 description 35
- 229910002804 graphite Inorganic materials 0.000 description 27
- 239000010439 graphite Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 22
- 238000007599 discharging Methods 0.000 description 21
- 238000009830 intercalation Methods 0.000 description 20
- 229910052799 carbon Inorganic materials 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 18
- 230000002687 intercalation Effects 0.000 description 18
- -1 Metal oxide compounds Chemical class 0.000 description 17
- 239000007772 electrode material Substances 0.000 description 17
- 238000011156 evaluation Methods 0.000 description 16
- 239000002134 carbon nanofiber Substances 0.000 description 14
- 239000000843 powder Substances 0.000 description 14
- 229920001971 elastomer Polymers 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000011295 pitch Substances 0.000 description 11
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 229910001416 lithium ion Inorganic materials 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 239000007773 negative electrode material Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 150000001450 anions Chemical class 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 229920000620 organic polymer Polymers 0.000 description 8
- 229920000049 Carbon (fiber) Polymers 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- 239000004917 carbon fiber Substances 0.000 description 7
- 238000003763 carbonization Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910044991 metal oxide Inorganic materials 0.000 description 6
- 229910020366 ClO 4 Inorganic materials 0.000 description 5
- 229910013684 LiClO 4 Inorganic materials 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 238000001354 calcination Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 5
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920002239 polyacrylonitrile Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229910018871 CoO 2 Inorganic materials 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 229920001940 conductive polymer Polymers 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical class O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910000953 kanthal Inorganic materials 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000011331 needle coke Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000011310 petroleum-based needle coke Substances 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- KXJGSNRAQWDDJT-UHFFFAOYSA-N 1-acetyl-5-bromo-2h-indol-3-one Chemical compound BrC1=CC=C2N(C(=O)C)CC(=O)C2=C1 KXJGSNRAQWDDJT-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- FYELSNVLZVIGTI-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-5-ethylpyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C=NN(C=1CC)CC(=O)N1CC2=C(CC1)NN=N2 FYELSNVLZVIGTI-UHFFFAOYSA-N 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- CMJLMPKFQPJDKP-UHFFFAOYSA-N 3-methylthiolane 1,1-dioxide Chemical compound CC1CCS(=O)(=O)C1 CMJLMPKFQPJDKP-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910001558 CF3SO3Li Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000925 Cd alloy Inorganic materials 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910021135 KPF6 Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229910020808 NaBF Inorganic materials 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- RFFFKMOABOFIDF-UHFFFAOYSA-N Pentanenitrile Chemical compound CCCCC#N RFFFKMOABOFIDF-UHFFFAOYSA-N 0.000 description 1
- 229920006282 Phenolic fiber Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- SSWIVUPIIWJGCS-UHFFFAOYSA-N [Cd].[Sn].[Pb].[Bi] Chemical compound [Cd].[Sn].[Pb].[Bi] SSWIVUPIIWJGCS-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000011304 carbon pitch Substances 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011294 coal tar pitch Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 238000010277 constant-current charging Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
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- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 229910021469 graphitizable carbon Inorganic materials 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 1
- 229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SKECXRFZFFAANN-UHFFFAOYSA-N n,n-dimethylmethanethioamide Chemical compound CN(C)C=S SKECXRFZFFAANN-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60-97695 | 1985-05-10 | ||
JP9769585 | 1985-05-10 | ||
JP60-100102 | 1985-05-11 | ||
JP60-100101 | 1985-05-11 | ||
JP60-130678 | 1985-06-18 | ||
JP60-130676 | 1985-06-18 | ||
JP60-130677 | 1985-06-18 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6216743A Division JP2704841B2 (ja) | 1985-05-10 | 1994-08-19 | 二次電池 |
JP6216744A Division JP2727301B2 (ja) | 1985-05-10 | 1994-08-19 | 二次電池電極の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6290863A JPS6290863A (ja) | 1987-04-25 |
JPH0424831B2 true JPH0424831B2 (fr) | 1992-04-28 |
Family
ID=14199076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61103785A Granted JPS6290863A (ja) | 1985-05-10 | 1986-05-08 | 二次電池 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6290863A (fr) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995028011A1 (fr) * | 1994-04-08 | 1995-10-19 | Sony Corporation | Cellule electrolytique secondaire non aqueuse |
WO2009038093A1 (fr) | 2007-09-18 | 2009-03-26 | Nippon Oil Corporation | Matériau de carbone amorphe pour une électrode négative de batterie secondaire au lithium ion et procédé pour le produire |
WO2009044789A1 (fr) | 2007-10-02 | 2009-04-09 | Nippon Oil Corporation | Graphite artificiel pour électrode négative d'une batterie secondaire lithium-ion, et son procédé de fabrication |
WO2009060891A1 (fr) | 2007-11-08 | 2009-05-14 | Nippon Oil Corporation | Composition de charbon de matière première pour matériau d'électrode négative d'une batterie secondaire lithium-ion et son procédé de fabrication |
WO2010074247A1 (fr) | 2008-12-26 | 2010-07-01 | 新日本石油株式会社 | Composition d'huile brute pour matériau d'électrode négative pour batterie secondaire au lithium-ion |
WO2013005739A1 (fr) | 2011-07-06 | 2013-01-10 | 昭和電工株式会社 | Électrode pour batteries secondaires au lithium, batterie secondaire au lithium et procédé de production d'électrode pour batteries secondaires au lithium |
WO2013153916A1 (fr) | 2012-04-09 | 2013-10-17 | 昭和電工株式会社 | Procédé de production de collecteur pour éléments électrochimiques, procédé de production d'électrode pour éléments électrochimiques, collecteur pour éléments électrochimiques, élément électrochimique, et liquide de recouvrement pour formation de collecteur pour éléments électrochimiques |
Families Citing this family (59)
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JPS6290863A (ja) * | 1985-05-10 | 1987-04-25 | Asahi Chem Ind Co Ltd | 二次電池 |
JP2556840B2 (ja) * | 1986-03-27 | 1996-11-27 | シャープ株式会社 | 非水リチウム2次電池用負極 |
JPS63279562A (ja) * | 1987-05-11 | 1988-11-16 | Sanyo Electric Co Ltd | 電池 |
JPS63285872A (ja) * | 1987-05-19 | 1988-11-22 | Mitsubishi Petrochem Co Ltd | 非水溶媒二次電池 |
JP2611265B2 (ja) * | 1987-10-17 | 1997-05-21 | ソニー株式会社 | 非水電解液二次電池 |
JPH01213963A (ja) * | 1988-02-22 | 1989-08-28 | Fuji Elelctrochem Co Ltd | 電池 |
JP2638919B2 (ja) * | 1988-04-30 | 1997-08-06 | ソニー株式会社 | 非水電解液二次電池 |
JP2674793B2 (ja) * | 1988-08-31 | 1997-11-12 | ソニー 株式会社 | 非水電解液電池 |
JP2957589B2 (ja) * | 1989-02-20 | 1999-10-04 | 三洋電機株式会社 | 非水系二次電池 |
JP2582893B2 (ja) * | 1989-03-31 | 1997-02-19 | 日立マクセル株式会社 | 有機電解液電池 |
JP2548460B2 (ja) * | 1991-01-30 | 1996-10-30 | 松下電器産業株式会社 | 非水電解質二次電池用負極 |
US5219680A (en) * | 1991-07-29 | 1993-06-15 | Ultracell Incorporated | Lithium rocking-chair rechargeable battery and electrode therefor |
US5494762A (en) * | 1992-01-16 | 1996-02-27 | Nippondenso Co., Ltd. | Non-aqueous electrolyte lithium secondary cell |
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US5393622A (en) * | 1992-02-07 | 1995-02-28 | Matsushita Electric Industrial Co., Ltd. | Process for production of positive electrode active material |
EP0627776B1 (fr) * | 1993-05-14 | 1997-08-13 | Sharp Kabushiki Kaisha | Batterie secondaire au lithium |
US5571638A (en) * | 1993-09-30 | 1996-11-05 | Sumitomo Chemical Company Limited | Lithium secondary battery |
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US5776208A (en) * | 1994-03-16 | 1998-07-07 | Kabushiki Kaisha Toshiba | Apparatus and method for assembling battery |
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JPH08213052A (ja) | 1994-08-04 | 1996-08-20 | Seiko Instr Inc | 非水電解質二次電池 |
CA2156675C (fr) | 1994-08-23 | 1999-03-09 | Naohiro Sonobe | Electrode carbonee pour batterie secondaire |
JP3222022B2 (ja) | 1994-10-27 | 2001-10-22 | シャープ株式会社 | リチウム二次電池および負極活物質の製造方法 |
CA2162456C (fr) | 1994-11-09 | 2008-07-08 | Keijiro Takanishi | Materiau pour cathode; methode de preparation et batterie secondaire de type a solvant non aqueux, comportant une cathode a base de ce materiau |
JP2006128135A (ja) * | 1994-11-22 | 2006-05-18 | Sumitomo Chemical Co Ltd | 正極用活物質および正極の製造方法 |
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JPH09231977A (ja) | 1996-02-27 | 1997-09-05 | Elf Atochem Japan Kk | 電極およびその製法 |
WO1999000001A2 (fr) * | 1997-06-27 | 1999-01-07 | Lg Chemical, Ltd. | Accumulateur electrique a ions lithium et procede de fabrication |
US6316146B1 (en) | 1998-01-09 | 2001-11-13 | Matsushita Electric Industrial Co., Ltd. | Carbon materials for negative electrode of secondary battery and manufacturing process |
US6528211B1 (en) | 1998-03-31 | 2003-03-04 | Showa Denko K.K. | Carbon fiber material and electrode materials for batteries |
US6413486B2 (en) | 1998-06-05 | 2002-07-02 | Matsushita Electric Industrial Co., Ltd. | Nonaqueous secondary battery, constituent elements of battery, and materials thereof |
US6686093B1 (en) | 1999-06-14 | 2004-02-03 | Kabushiki Kaisha Toshiba | Positive electrode active material for nonaqueous electrolytic solution secondary battery and nonaqueous electrolytic solution secondary battery therewith |
US6579475B2 (en) | 1999-12-10 | 2003-06-17 | Fmc Corporation | Lithium cobalt oxides and methods of making same |
JP4789330B2 (ja) | 2001-02-22 | 2011-10-12 | 株式会社クレハ | 非水溶媒二次電池用電極材料、電極および二次電池 |
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JPS57208079A (en) * | 1981-06-18 | 1982-12-21 | Sanyo Electric Co Ltd | Rechargeable lithium cell |
JPS5893176A (ja) * | 1981-11-30 | 1983-06-02 | Toray Ind Inc | 二次電池 |
US4423125A (en) * | 1982-09-13 | 1983-12-27 | Bell Telephone Laboratories, Incorporated | Ambient temperature rechargeable battery |
JPS5918579A (ja) * | 1982-07-22 | 1984-01-30 | Kao Corp | 電気化学電池 |
JPS59154763A (ja) * | 1983-02-22 | 1984-09-03 | Sanyo Chem Ind Ltd | リチウム二次電池用負極材 |
JPS6054181A (ja) * | 1983-09-02 | 1985-03-28 | Toray Ind Inc | 充放電可能な電池 |
JPS60235372A (ja) * | 1984-05-07 | 1985-11-22 | Sanyo Chem Ind Ltd | 二次電池 |
JPS61111907A (ja) * | 1984-11-02 | 1986-05-30 | Mitsubishi Petrochem Co Ltd | 電極材 |
JPS6290863A (ja) * | 1985-05-10 | 1987-04-25 | Asahi Chem Ind Co Ltd | 二次電池 |
JPS62122066A (ja) * | 1985-04-30 | 1987-06-03 | Mitsubishi Petrochem Co Ltd | 非水溶媒二次電池 |
JPH0424831A (ja) * | 1990-05-18 | 1992-01-28 | Fujitsu Ltd | 試験装置 |
-
1986
- 1986-05-08 JP JP61103785A patent/JPS6290863A/ja active Granted
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JPS57208079A (en) * | 1981-06-18 | 1982-12-21 | Sanyo Electric Co Ltd | Rechargeable lithium cell |
JPS5893176A (ja) * | 1981-11-30 | 1983-06-02 | Toray Ind Inc | 二次電池 |
JPS5918579A (ja) * | 1982-07-22 | 1984-01-30 | Kao Corp | 電気化学電池 |
US4423125A (en) * | 1982-09-13 | 1983-12-27 | Bell Telephone Laboratories, Incorporated | Ambient temperature rechargeable battery |
JPS59154763A (ja) * | 1983-02-22 | 1984-09-03 | Sanyo Chem Ind Ltd | リチウム二次電池用負極材 |
JPS6054181A (ja) * | 1983-09-02 | 1985-03-28 | Toray Ind Inc | 充放電可能な電池 |
JPS60235372A (ja) * | 1984-05-07 | 1985-11-22 | Sanyo Chem Ind Ltd | 二次電池 |
JPS61111907A (ja) * | 1984-11-02 | 1986-05-30 | Mitsubishi Petrochem Co Ltd | 電極材 |
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JPH0424831A (ja) * | 1990-05-18 | 1992-01-28 | Fujitsu Ltd | 試験装置 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995028011A1 (fr) * | 1994-04-08 | 1995-10-19 | Sony Corporation | Cellule electrolytique secondaire non aqueuse |
WO2009038093A1 (fr) | 2007-09-18 | 2009-03-26 | Nippon Oil Corporation | Matériau de carbone amorphe pour une électrode négative de batterie secondaire au lithium ion et procédé pour le produire |
WO2009044789A1 (fr) | 2007-10-02 | 2009-04-09 | Nippon Oil Corporation | Graphite artificiel pour électrode négative d'une batterie secondaire lithium-ion, et son procédé de fabrication |
WO2009060891A1 (fr) | 2007-11-08 | 2009-05-14 | Nippon Oil Corporation | Composition de charbon de matière première pour matériau d'électrode négative d'une batterie secondaire lithium-ion et son procédé de fabrication |
WO2010074247A1 (fr) | 2008-12-26 | 2010-07-01 | 新日本石油株式会社 | Composition d'huile brute pour matériau d'électrode négative pour batterie secondaire au lithium-ion |
WO2013005739A1 (fr) | 2011-07-06 | 2013-01-10 | 昭和電工株式会社 | Électrode pour batteries secondaires au lithium, batterie secondaire au lithium et procédé de production d'électrode pour batteries secondaires au lithium |
WO2013153916A1 (fr) | 2012-04-09 | 2013-10-17 | 昭和電工株式会社 | Procédé de production de collecteur pour éléments électrochimiques, procédé de production d'électrode pour éléments électrochimiques, collecteur pour éléments électrochimiques, élément électrochimique, et liquide de recouvrement pour formation de collecteur pour éléments électrochimiques |
Also Published As
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---|---|
JPS6290863A (ja) | 1987-04-25 |
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