JP6923439B2 - 悪臭低減組成物を含む送達系 - Google Patents
悪臭低減組成物を含む送達系 Download PDFInfo
- Publication number
- JP6923439B2 JP6923439B2 JP2017515911A JP2017515911A JP6923439B2 JP 6923439 B2 JP6923439 B2 JP 6923439B2 JP 2017515911 A JP2017515911 A JP 2017515911A JP 2017515911 A JP2017515911 A JP 2017515911A JP 6923439 B2 JP6923439 B2 JP 6923439B2
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- JP
- Japan
- Prior art keywords
- methyl
- ene
- dimethyl
- isopropyl
- dimethylocta
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 153
- 230000009467 reduction Effects 0.000 title description 18
- 239000000126 substance Substances 0.000 claims description 111
- -1 polysiloxane Polymers 0.000 claims description 100
- 239000002304 perfume Substances 0.000 claims description 56
- 229920000642 polymer Polymers 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 45
- 239000002245 particle Substances 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 24
- 238000004140 cleaning Methods 0.000 claims description 22
- 239000011257 shell material Substances 0.000 claims description 19
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 claims description 18
- 239000011162 core material Substances 0.000 claims description 16
- 229920000877 Melamine resin Polymers 0.000 claims description 14
- 230000009286 beneficial effect Effects 0.000 claims description 13
- 150000004676 glycans Chemical class 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 229920001282 polysaccharide Polymers 0.000 claims description 12
- 239000005017 polysaccharide Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 9
- 229920006317 cationic polymer Polymers 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000004368 Modified starch Substances 0.000 claims description 4
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 229920006318 anionic polymer Polymers 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- FPCCDPXRNNVUOM-UHFFFAOYSA-N Hydroxycitronellol Chemical compound OCCC(C)CCCC(C)(C)O FPCCDPXRNNVUOM-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- 235000019426 modified starch Nutrition 0.000 claims description 3
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Polymers C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 5
- MRFSMUAOLWGDKP-NTCAYCPXSA-N (4E)-5,9-dimethyl-2-phenyldeca-4,8-dienoic acid Chemical compound CC(C)=CCC\C(C)=C\CC(C(O)=O)C1=CC=CC=C1 MRFSMUAOLWGDKP-NTCAYCPXSA-N 0.000 claims 4
- NVIPUOMWGQAOIT-RQOWECAXSA-N (Z)-7-Hexadecen-1,16-olide Chemical compound O=C1CCCCC\C=C/CCCCCCCCO1 NVIPUOMWGQAOIT-RQOWECAXSA-N 0.000 claims 4
- SCCDQYPEOIRVGX-UHFFFAOYSA-N Acetyleugenol Chemical compound COC1=CC(CC=C)=CC=C1OC(C)=O SCCDQYPEOIRVGX-UHFFFAOYSA-N 0.000 claims 4
- UUIQMZJEGPQKFD-UHFFFAOYSA-N Methyl butyrate Chemical compound CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 claims 4
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 claims 4
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 claims 4
- ZOZIRNMDEZKZHM-UHFFFAOYSA-N Phenethyl phenylacetate Chemical compound C=1C=CC=CC=1CCOC(=O)CC1=CC=CC=C1 ZOZIRNMDEZKZHM-UHFFFAOYSA-N 0.000 claims 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 4
- LSQXNMXDFRRDSJ-UHFFFAOYSA-N Thymol methyl ether Chemical compound COC1=CC(C)=CC=C1C(C)C LSQXNMXDFRRDSJ-UHFFFAOYSA-N 0.000 claims 4
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims 4
- OSOIQJGOYGSIMF-UHFFFAOYSA-N cyclopentadecanone Chemical compound O=C1CCCCCCCCCCCCCC1 OSOIQJGOYGSIMF-UHFFFAOYSA-N 0.000 claims 4
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims 4
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 claims 4
- MMKRHZKQPFCLLS-UHFFFAOYSA-N ethyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OCC MMKRHZKQPFCLLS-UHFFFAOYSA-N 0.000 claims 4
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims 4
- WHWDWIHXSPCOKZ-UHFFFAOYSA-N hexahydrofarnesyl acetone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)=O WHWDWIHXSPCOKZ-UHFFFAOYSA-N 0.000 claims 4
- OJEQSSJFSNLMLB-UHFFFAOYSA-N p-Tolyl phenylacetate Chemical compound C1=CC(C)=CC=C1OC(=O)CC1=CC=CC=C1 OJEQSSJFSNLMLB-UHFFFAOYSA-N 0.000 claims 4
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims 4
- HUYXPANWJVOYCI-UHFFFAOYSA-N 2,2,6,6,7,8,8-heptamethyl-3,3a,4,5,5a,7,8a,8b-octahydrocyclopenta[g][1]benzofuran Chemical compound CC1C(C)(C)C2CCC3CC(C)(C)OC3C2C1(C)C HUYXPANWJVOYCI-UHFFFAOYSA-N 0.000 claims 3
- GEPCDOWRWODJEY-UHFFFAOYSA-N 3-(3,3-dimethyl-1,2-dihydroinden-5-yl)propanal Chemical compound C1=C(CCC=O)C=C2C(C)(C)CCC2=C1 GEPCDOWRWODJEY-UHFFFAOYSA-N 0.000 claims 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims 3
- GBOYWPAUISQQSW-UHFFFAOYSA-N CCC1=C(CC(C)(C)CO)C=CC=C1 Chemical compound CCC1=C(CC(C)(C)CO)C=CC=C1 GBOYWPAUISQQSW-UHFFFAOYSA-N 0.000 claims 3
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims 3
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 claims 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims 3
- ALHUZKCOMYUFRB-UHFFFAOYSA-N muskone Natural products CC1CCCCCCCCCCCCC(=O)C1 ALHUZKCOMYUFRB-UHFFFAOYSA-N 0.000 claims 3
- UOGMZEGKCNHMBF-UHFFFAOYSA-N scentenal Chemical compound C12CC(C=O)CC2C2CC(OC)C1C2 UOGMZEGKCNHMBF-UHFFFAOYSA-N 0.000 claims 3
- AZOCECCLWFDTAP-RKDXNWHRSA-N (+)-dihydrocarvone Chemical compound C[C@@H]1CC[C@@H](C(C)=C)CC1=O AZOCECCLWFDTAP-RKDXNWHRSA-N 0.000 claims 2
- MDFQXBNVOAKNAY-BBBLOLIVSA-N (+)-sabinol Chemical compound C([C@@H](O)C1=C)[C@@]2(C(C)C)[C@@H]1C2 MDFQXBNVOAKNAY-BBBLOLIVSA-N 0.000 claims 2
- QMAYBMKBYCGXDH-SOUVJXGZSA-N (-)-alpha-amorphene Chemical compound C1CC(C)=C[C@@H]2[C@H](C(C)C)CC=C(C)[C@@H]21 QMAYBMKBYCGXDH-SOUVJXGZSA-N 0.000 claims 2
- NFLGAXVYCFJBMK-IUCAKERBSA-N (-)-isomenthone Chemical compound CC(C)[C@@H]1CC[C@H](C)CC1=O NFLGAXVYCFJBMK-IUCAKERBSA-N 0.000 claims 2
- QILMAYXCYBTEDM-HNQUOIGGSA-N (10e)-1-oxacycloheptadec-10-en-2-one Chemical compound O=C1CCCCCCC\C=C\CCCCCCO1 QILMAYXCYBTEDM-HNQUOIGGSA-N 0.000 claims 2
- MJBVGUVEKHRPDM-HWKANZROSA-N (11e)-1-oxacycloheptadec-11-en-2-one Chemical compound O=C1CCCCCCCC\C=C\CCCCCO1 MJBVGUVEKHRPDM-HWKANZROSA-N 0.000 claims 2
- AGZBJJSLDGWKSU-CSKARUKUSA-N (13e)-1-oxacyclohexadec-13-en-2-one Chemical compound O=C1CCCCCCCCCC\C=C\CCO1 AGZBJJSLDGWKSU-CSKARUKUSA-N 0.000 claims 2
- FAMPSKZZVDUYOS-PGPZXUPKSA-N (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene Chemical compound C\C1=C\CC(C)(C)\C=C\C\C(C)=C/CC1 FAMPSKZZVDUYOS-PGPZXUPKSA-N 0.000 claims 2
- CRDAMVZIKSXKFV-YFVJMOTDSA-N (2-trans,6-trans)-farnesol Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CO CRDAMVZIKSXKFV-YFVJMOTDSA-N 0.000 claims 2
- JPVSSFXLONAFGV-KYFFJNGRSA-N (2R)-2-[(1R,4S)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl]propanoic acid Chemical compound C[C@H](C1C[C@@H]2CC[C@]1(C2(C)C)C)C(=O)O JPVSSFXLONAFGV-KYFFJNGRSA-N 0.000 claims 2
- LJOISVFAMDWVFA-DRZSPHRISA-N (2s,5s,6s)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol Chemical compound O1[C@@H](C)CC[C@@]21[C@](O)(C)CCCC2(C)C LJOISVFAMDWVFA-DRZSPHRISA-N 0.000 claims 2
- YPZUZOLGGMJZJO-RRCSTGOVSA-N (3ar,5ar,9ar,9br)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1h-benzo[e][1]benzofuran Chemical compound CC([C@H]1CC2)(C)CCC[C@@]1(C)[C@@H]1[C@]2(C)OCC1 YPZUZOLGGMJZJO-RRCSTGOVSA-N 0.000 claims 2
- DBWSGRFEGVADLQ-ZHACJKMWSA-N (3e)-trideca-3,12-dienenitrile Chemical compound C=CCCCCCCC\C=C\CC#N DBWSGRFEGVADLQ-ZHACJKMWSA-N 0.000 claims 2
- QVEOSYKPYFNQAZ-XYOKQWHBSA-N (4e)-4,8-dimethyldeca-4,9-dienal Chemical compound C=CC(C)CC\C=C(/C)CCC=O QVEOSYKPYFNQAZ-XYOKQWHBSA-N 0.000 claims 2
- PAZWFUGWOAQBJJ-SWZPTJTJSA-N (4e,8e)-4,8,12-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene Chemical compound C1C\C(C)=C\CCC(/C)=C/CCC2(C)OC21 PAZWFUGWOAQBJJ-SWZPTJTJSA-N 0.000 claims 2
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 claims 2
- KRLBLPBPZSSIGH-CSKARUKUSA-N (6e)-3,7-dimethylnona-1,6-dien-3-ol Chemical compound CC\C(C)=C\CCC(C)(O)C=C KRLBLPBPZSSIGH-CSKARUKUSA-N 0.000 claims 2
- 239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 claims 2
- PANBRUWVURLWGY-MDZDMXLPSA-N (E)-2-undecenal Chemical compound CCCCCCCC\C=C\C=O PANBRUWVURLWGY-MDZDMXLPSA-N 0.000 claims 2
- LDUYDLGCMTVIIO-VOTSOKGWSA-N (e)-1-(1-methoxypropoxy)hex-3-ene Chemical compound CC\C=C\CCOC(CC)OC LDUYDLGCMTVIIO-VOTSOKGWSA-N 0.000 claims 2
- QZFSNJAQFWEXEA-MDZDMXLPSA-N (e)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol Chemical compound CC(O)C(C)(C)\C=C\C1CC=C(C)C1(C)C QZFSNJAQFWEXEA-MDZDMXLPSA-N 0.000 claims 2
- IXLLBXDECOMIBP-ALCCZGGFSA-N (z)-1-(2,2-dimethyl-6-methylidenecyclohexyl)but-2-en-1-one Chemical compound C\C=C/C(=O)C1C(=C)CCCC1(C)C IXLLBXDECOMIBP-ALCCZGGFSA-N 0.000 claims 2
- SSNZFFBDIMUILS-KHPPLWFESA-N (z)-dodec-2-enal Chemical compound CCCCCCCCC\C=C/C=O SSNZFFBDIMUILS-KHPPLWFESA-N 0.000 claims 2
- HETFMJQWNWIBPN-KTKRTIGZSA-N (z)-undec-2-enenitrile Chemical compound CCCCCCCC\C=C/C#N HETFMJQWNWIBPN-KTKRTIGZSA-N 0.000 claims 2
- ZCMKNGQFIXAHLP-UHFFFAOYSA-N 1,1,2,3,3-pentamethyl-2h-indene Chemical compound C1=CC=C2C(C)(C)C(C)C(C)(C)C2=C1 ZCMKNGQFIXAHLP-UHFFFAOYSA-N 0.000 claims 2
- BZOOCKAFKVYAOZ-UHFFFAOYSA-N 1,1-Dimethoxyoctane Chemical compound CCCCCCCC(OC)OC BZOOCKAFKVYAOZ-UHFFFAOYSA-N 0.000 claims 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims 2
- ABADUMLIAZCWJD-UHFFFAOYSA-N 1,3-dioxole Chemical compound C1OC=CO1 ABADUMLIAZCWJD-UHFFFAOYSA-N 0.000 claims 2
- GJJSUPSPZIZYPM-UHFFFAOYSA-N 1,4-dioxacyclohexadecane-5,16-dione Chemical compound O=C1CCCCCCCCCCC(=O)OCCO1 GJJSUPSPZIZYPM-UHFFFAOYSA-N 0.000 claims 2
- BVDMQAQCEBGIJR-UHFFFAOYSA-N 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol Chemical compound CCCC(O)CCC1C(C)CCCC1(C)C BVDMQAQCEBGIJR-UHFFFAOYSA-N 0.000 claims 2
- FXCYGAGBPZQRJE-ZHACJKMWSA-N 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one Chemical compound CC1=CCCC(C)(C)C1\C=C\C(=O)CCC=C FXCYGAGBPZQRJE-ZHACJKMWSA-N 0.000 claims 2
- KUZMAEUMYSXKOU-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one Chemical compound CCC(=O)CCC1C(C)=CCCC1(C)C KUZMAEUMYSXKOU-UHFFFAOYSA-N 0.000 claims 2
- OHYNEUHOSWPWLZ-UHFFFAOYSA-N 1-(3,3-dimethylcyclohexyl)pent-4-en-1-one Chemical compound CC1(C)CCCC(C(=O)CCC=C)C1 OHYNEUHOSWPWLZ-UHFFFAOYSA-N 0.000 claims 2
- XVULBTBTFGYVRC-UHFFFAOYSA-N 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyl-decahydronaphthalen-2-ol Chemical compound CC1(C)CCCC2(C)C(CCC(O)(C)C=C)C(C)(O)CCC21 XVULBTBTFGYVRC-UHFFFAOYSA-N 0.000 claims 2
- NEHPIUGJDUWSRR-UHFFFAOYSA-N 1-(4-propan-2-ylcyclohexyl)ethanol Chemical compound CC(C)C1CCC(C(C)O)CC1 NEHPIUGJDUWSRR-UHFFFAOYSA-N 0.000 claims 2
- OEVIJAZJVZDBQL-UHFFFAOYSA-N 1-(5,5-dimethylcyclohexen-1-yl)pent-4-en-1-one Chemical compound CC1(C)CCC=C(C(=O)CCC=C)C1 OEVIJAZJVZDBQL-UHFFFAOYSA-N 0.000 claims 2
- QWAUHUKNKGMBBD-XFIKWOAQSA-N 1-[(2e,5z,9z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl]ethanone Chemical compound CC(=O)C1CC\C(C)=C/CC\C(C)=C/C\C=C1/C QWAUHUKNKGMBBD-XFIKWOAQSA-N 0.000 claims 2
- CNANHJLQJZEVPS-UHFFFAOYSA-N 1-ethoxyethoxycyclododecane Chemical compound CCOC(C)OC1CCCCCCCCCCC1 CNANHJLQJZEVPS-UHFFFAOYSA-N 0.000 claims 2
- XDFCZUMLNOYOCH-UHFFFAOYSA-N 1-hydroxydecan-3-one Chemical compound CCCCCCCC(=O)CCO XDFCZUMLNOYOCH-UHFFFAOYSA-N 0.000 claims 2
- WCOYPFBMFKXWBM-UHFFFAOYSA-N 1-methyl-2-phenoxybenzene Chemical compound CC1=CC=CC=C1OC1=CC=CC=C1 WCOYPFBMFKXWBM-UHFFFAOYSA-N 0.000 claims 2
- VUIWFNRBSGUSIN-UHFFFAOYSA-N 1-methyl-4-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)=CCCC1=CCC(C)(C=O)CC1 VUIWFNRBSGUSIN-UHFFFAOYSA-N 0.000 claims 2
- RTIYSHLNESDZSF-UHFFFAOYSA-N 1-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)-7-oxabicyclo[3.2.1]octane Chemical compound CC1(C)C(C)=CCC1C1(CCC2)CC2(C)OC1 RTIYSHLNESDZSF-UHFFFAOYSA-N 0.000 claims 2
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 claims 2
- QQLMXACDDRGTPU-UHFFFAOYSA-N 10-Isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene Chemical compound CC(C)C1CCC(C)=CC11C=CC(C)O1 QQLMXACDDRGTPU-UHFFFAOYSA-N 0.000 claims 2
- NUSRNVWNTPMBJA-UHFFFAOYSA-N 13-methyl-1-oxacyclopentadec-10-en-2-one Chemical compound CC1CCOC(=O)CCCCCCCC=CC1 NUSRNVWNTPMBJA-UHFFFAOYSA-N 0.000 claims 2
- LOKPJYNMYCVCRM-UHFFFAOYSA-N 16-Hexadecanolide Chemical compound O=C1CCCCCCCCCCCCCCCO1 LOKPJYNMYCVCRM-UHFFFAOYSA-N 0.000 claims 2
- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 claims 2
- QFQQCCDAGARSEN-UHFFFAOYSA-N 2,2,6,6,7,8,8-heptamethyl-4,5,7,8b-tetrahydro-3ah-cyclopenta[g][1,3]benzodioxole Chemical compound CC1(C)C(C)C(C)(C)C2=C1C1OC(C)(C)OC1CC2 QFQQCCDAGARSEN-UHFFFAOYSA-N 0.000 claims 2
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Description
適した悪臭低減物質の限定されないセットが下の表に記載される。使い易さのために、表1〜3の各々の物質には数字の識別子が割り当られ、それは「番号」と示される各表の列に見出される。表4は表1の部分集合であり、表5は表2の部分集合であり、表6は表3の部分集合である。そこで、表4、5及び6に関して、各表はそれぞれ表1〜3に見出されるのと同じ識別子を使用する。
米国ニュージャージー州プレインズボロ所在のフィルメニッヒ社;米国ニューヨーク州ニューヨーク所在のインターナショナル・フレーバー・アンド・フレグランス社;米国ニュージャージー州テターボロ所在のタカサゴ社;米国ニュージャージー州テターボロ所在のSymrise社;米国カリフォルニア州カールスバッド所在のシグマ−アルドリッチ/SAFC社;及び米国コネチカット州ダンベリー所在のBedoukian Research社。
好適な送達系、送達系を製造する方法、及びそのような送達系の使用法の非限定例が、米国特許出願公開第2007/0275866(A1)号に開示されている。このような送達系としては、以下が挙げられる。
マトリックス系:芳香剤をポリマーマトリックス又は粒子中に溶解又は分散させる。例えば、香料は、1)製品に配合する前にポリマー中に分散させるか、又は2)製品の配合中又は配合後にポリマーとは別に添加してよい。ポリマーからの香料の拡散は、所望の表面(部位)に付着又は塗布されたポリマー性マトリックス系から香料を放出させるか、あるいはその放出速度を増加させるうえで一般的な誘因であるが、香料の放出を制御する他の多くの誘因が知られている。ポリマー粒子、フィルム、溶液などの内部又は上部への吸収及び/又は吸着はこの技術の態様である。有機材料(例えば、ラテックス)からなるナノ又はマイクロ粒子がその例である。好適な粒子としては、限定するものではないが、ポリアセタール、ポリアクリレート、ポリアクリル酸、ポリアクリロニトリル、ポリアミド、ポリアリールエーテルケトン、ポリブタジエン、ポリブチレン、ポリブチレンテレフタレート、ポリクロロプレン、ポリエチレン、ポリエチレンテレフタラート、ポリシクロヘキシレンジメチレンテレフタレート、ポリカーボネート、ポリクロロプレン、ポリヒドロキシアルカノエート、ポリケトン、ポリエステル、ポリエーテルイミド、ポリエーテルスルホン、ポリエチレンクロリネート、ポリイミド、ポリイソプレン、ポリ乳酸、ポリメチルペンテン、ポリフェニレンオキシド、ポリフェニレンスルフィド、ポリフタルアミド、ポリプロピレン、ポリスチレン、ポリスルホン、ポリ酢酸ビニル、ポリ塩化ビニル、並びにアクリロニトリル−ブタジエン、酢酸セルロース、エチレン−酢酸ビニル、エチレンビニルアルコール、スチレン−ブタジエン、酢酸ビニル−エチレン、及びこれらの混合物等に基づくポリマー又はコポリマー等の広範な材料が挙げられる。
が開示される。
a)有益剤の総重量に基づいて、約0.1〜約50%の悪臭低減組成物を含む、ポリマー支援型送達(PAD)系、
b)有益剤の総重量に基づいて、約0.1〜約75%の悪臭低減組成物を含む、分子支援型送達(MAD)系。
c)有益剤の総重量に基づいて、約0.1〜約20%の悪臭低減組成物を含む、シクロデキストリン(CD)系。
d)有益剤の総重量に基づいて、約0.1〜約80%の悪臭低減組成物を含む、デンプン封入アコード(SEA)系。
e)有益剤の総重量に基づいて、約0.1〜約30%の悪臭低減組成物を含む、ゼオライト&無機担体(ZIC)系。
661、663、668、671、673、674、675、676、677、678、679、680、681、682、683、684、686、691、692、693、694、696、697、698、700、702、704、706、707、708、709、710、711、712、713、714、715、716、717、718、719、720、721、722、723、724、725、726、727、730、731、733、735、736、738、741、742、746、748、750、752、754、757、758、763、764、766、767、768、769、770、771、772、774、775、776、778、781、782、786、788、791、792、800、802、803、804、805、806、807、814、821、824、826、827、828、829、831、833、834、837、839、840、849、850、852、856、864、865、866、868、869、870、871、872、873、876、877、878、879、881、884、885、886、890、892、893、894、897、905、908、912、913、914、916、919、920、922、923、924、925、926、927、928、929、930、933、937、939、941、942、943、945、946、947、948、950、951、953、954、955、959、962、965、967、969、973、974、976、978、980、982、985、988、993、998、1000、1003、1006、1007、1008、1009、1010、1012、1016、1020、1021、1022、1023、1024、1025、1026、1027、1028、1029、1031、1032、1033、1035、1036、1037、1038、1042、1043、1045、1046、1047、1053、1057、1059、1060、1062、1063、1064、1065、1066、1067、1070、1072、1073、1075、1077、1078、1082、1083、1085、1089、1090、1091、1093、1095、1097、1099、1102、1104、1105、1107、1111、1113、1116、1117、1120、1121、1125、1126、1129、1131、1135、1136、1137、1138、1139、1140、1142、1143、1144、1145、1146、1147、1148、1149、表2の物質2、23、141、185、227、230、246、248、343、359、565、631、659、674、678、679、715、758、1028、1097及びそれらの混合物からなる群から選択され、より好ましくは前記悪臭低減物質は、表4の物質7、14、39、48、183、199、206、212、215、229、260、261、281、329、335、353、360、441、484、487、488、501、566、567、569、570、573、574、603、616、621、624、627、632、663、680、684、694、696、708、712、714、726、750、764、775、776、788、804、872、919、927、933、978、1007、1022、1024、1027、1029、1035、1038、1060、1089、1107、1129、1131、1136、1137、1140、1142、1143、1144、1145、1148、1149、表5の物質248及びそれらの混合物からなる群から選択され、最も好ましくは前記悪臭低減物質は、表4の物質261、680、788、1129、1148、1149及びそれらの混合物からなる群から選択される。
、631、632、633、635、636、638、639、644、650、653、658、659、660、661、663、671、673、674、675、676、677、678、679、680、681、683、684、686、691、692、693、694、696、697、698、700、702、704、706、707、708、709、710、711、712、713、714、715、716、717、718、719、720、721、722、723、724、725、726、727、731、741、742、746、748、750、752、754、757、758、763、766、768、769、771、774、775、776、778、781、782、786、788、791、800、802、803、804、806、807、814、821、826、827、828、831、833、849、850、852、866、868、870、871、872、873、876、877、878、879、881、884、885、886、890、892、893、894、897、905、908、912、913、914、916、919、920、922、923、924、925、926、927、930、933、937、939、941、942、943、945、946、947、948、950、951、953、954、959、962、965、967、973、974、976、978、980、982、985、988、998、1000、1003、1006、1007、1008、1009、1010、1012、1016、1020、1022、1023、1024、1025、1026、1027、1028、1029、1031、1032、1033、1035、1036、1037、1038、1043、1045、1046、1047、1053、1057、1059、1060、1062、1063、1065、1075、1083、1085、1089、1090、1091、1093、1095、1097、1099、1102、1104、1105、1107、1111、1116、1117、1120、1121、1125、1126、1129、1131、1135、1136、1137、1139、1140、1142、1143、1144、1145、1146、1147、1148、1149;表2の物質2、23、141、185、227、230、246、248、343、359、565、631、659、674、678、679、715、758、1028、1097、及びそれらの混合物からなる群から選択され、最も好ましくは前記悪臭低減物質は、表4の物質7、14、39、48、183、199、206、212、215、229、260、261、281、329、335、353、360、441、484、487、488、501、566、567、569、570、573、574、603、616、621、624、627、632、663、680、684、694、696、708、712、714、726、750、775、776、788、804、872、919、927、933、978、1007、1022、1024、1027、1029、1035、1038、1060、1089、1107、1129、1131、1136、1137、1140、1142、1143、1144、1145、1148、1149、表5の物質248及びそれらの混合物からなる群から選択される。これらは、香料マイクロカプセル中で安定であり、漏れない材料であるので、堆積して利用可能となり悪臭を中和する。
従って、送達系の近くの基質又は送達系と接触している基質上で、より良好に悪臭の知覚を遮断することができる。
a)前記部位を所望により洗浄、すすぎ、及び/又は乾燥する工程、
b)前記部位を請求項1〜12に記載の送達系及び/又は請求項13に記載の消費者向け製品と接触させる工程;及び
c)前記部位を所望により洗浄、すすぎ、及び/又は乾燥する工程を含む前記方法
が開示される。
一態様では、以下の工程を含むプロセス:
a.)溶液の総重量に基づいて、約20%〜約90%、約40%〜約80%、又はさらに約60%〜約80%の水を含んでよく、第1の乳化剤及び第1の樹脂からなる第1の溶液であって、前記第1の乳化剤と前記第1の樹脂の比が、約0.1:0〜約10:0、約0.1:1〜約10:1、約0.5:1〜約3:1、又はさらに約0.8:1〜約1.1:1である溶液を調製する工程;
b.)溶液の総重量に基づいて、約20%〜約95%の水を含んでよく、第2の乳化剤及び第2の樹脂からなる第2の溶液であって、前記第2の乳化剤と前記第2の樹脂の比が、約0:1〜約3:1、約0.04:1〜約0.2:1、又はさらに約0.05:1〜約0.15:1である溶液を調製する工程;
c.)本明細書に開示される香料を含み得るコア材料及び前記第1の溶液を合して、第1の組成物を形成する工程;
d.)前記第1の組成物を乳化させる工程;
e.)前記第1の組成物及び前記第2の溶液を合して第2の組成物を形成し、所望により任意の加工助剤及び前記第2の組成物を合する工程であって、前記第1の組成物及び前記第2の溶液は、任意の順序で合してよいが、一態様では、前記第2の溶液が前記第1の組成物に添加されるか、又は前記第2の溶液及び前記第1の組成物が同時に合される工程;
f.)前記第2の組成物を、少なくとも15分、少なくとも1時間又はさらに約4時間〜約100時間、約25℃〜約100℃、約45℃〜約90℃の温度、又はさらに約50℃〜約80℃の熱で混合し、所望により任意の加工助剤を前記第2の組成物に合する工程;
g.)所望により任意の捕捉材料、構造化剤、及び/又は抗凝集剤を前記第2の組成物と工程f.)中又はその後に合する工程であって、そのような材料が任意の順序で合されてよいが、一態様では、捕捉材料が最初に合され、次に任意の構造化剤、その後抗凝集剤が合される工程;及び
h.)所望により前記第2の組成物を噴霧乾燥する工程
が開示される。
一態様では、本明細書で開示されている香料送達系及び/又は香料の任意の態様を含むことができる組成物が開示される。
一態様では、本明細書に開示される香料送達系は、ホルムアルデヒド捕捉剤と組み合わされてよい。一態様では、そのような香料送達系は、本発明の封入体を含んでよい。好適なホルムアルデヒド捕捉剤としては、亜硫酸水素ナトリウム、尿素、エチレン尿素、システイン、システアミン、リシン、グリシン、セリン、カルノシン、ヒスチジン、グルタチオン、3,4−ジアミノ安息香酸、アラントイン、グリコウリル、アントラニル酸、アントラニル酸メチル、4−アミノ安息香酸メチル、エチルアセトアセテート、アセトアセトアミド、マロンアミド、アスコルビン酸、1,3−ジヒドロキシアセトン二量体、ビウレット、オキサミド、ベンゾグアナミン、ピログルタミン酸、ピロガロール、没食子酸メチル、没食子酸エチル、没食子酸プロピル、トリエタノールアミン、スクシンアミド、チアベンダゾール、ベンゾトリアゾール、トリアゾール、インドリン、スルファニル酸、オキサミド、ソルビトール、グルコース、セルロース、ポリ(ビニルアルコール)、部分的に加水分解されたポリ(ビニルホルムアミド)、ポリ(ビニルアミン)、ポリ(エチレンイミン)、ポリ(オキシアルキレンアミン)、ポリ(ビニルアルコール)−コ−ポリ(ビニルアミン)、ポリ(4−アミノスチレン)、ポリ(L−リシン)、キトサン、ヘキサンジオール、エチレンジアミン−N,N’−ビスアセトアセトアミド、N−(2−エチルヘキシル)アセトアセトアミド、2−ベンゾイルアセトアセトアミド、N−(3−フェニルプロピル)アセトアセトアミド、リリアール(登録商標)、ヘリオナール、メロナール、トリプラール(登録商標)、5,5−ジメチル−1,3−シクロヘキサンジオン、2,4−ジメチル−3−シクロヘキセンカルボキシアルデヒド、2,2−ジメチル−1,3−ジオキサン−4,6−ジオン、2−ペンタノン、ジブチルアミン、トリエチレンテトラミン、水酸化アンモニウム、ベンジルアミン、ヒドロキシシトロネロール、シクロヘキサノン、2−ブタノン、ペンタンジオン、デヒドロ酢酸、又はこれらの混合物からなる群から選択される物質が挙げられる。これらのホルムアルデヒド捕捉剤は、米国ミズーリ州セントルイス所在のシグマ/アルドリッチ/フルカ又は米国ペンシルバニア州ウォリントン所在のポリサイエンス社から入手することができる。
本発明の各消費者向け製品実施形態に必須ではないが、以下に例示される補助剤の非限定的なリストは、本消費者向け製品での使用に好適であり、例えば、性能を補助若しくは向上させるために、洗浄される基材の処理のために、又は香料、着色剤、染料などを用いる場合のように組成物の審美性を変化させるために、望ましくは本発明の所定の実施形態に組み込まれてもよい。これらの追加成分の正確な性質及びそれを組み込む濃度は、組成物の物理形態及び使用される作業の性質に依存する。そのような補助剤は、本明細書で前に開示した香料及び/又は香料送達系に加えられる。好適な補助剤物質としては、界面活性剤、ビルダー、キレート剤、染料移行防止剤、分散剤、酵素、及び酵素安定剤、触媒材料、漂白活性化剤、ポリマー分散剤、粘土質除去/再付着防止剤、増白剤、発泡抑制剤、染料、追加の香料及び香料送達系、構造弾性化剤、増粘剤/構造化剤、布地柔軟剤、担体、ヒドロトロープ、加工助剤及び/又は顔料が挙げられるが、これらに限定されない。
界面活性剤−本発明による組成物は、界面活性剤又は界面活性剤系を含んでよく、この界面活性剤は、非イオン性及び/又はアニオン性及び/又はカチオン性界面活性剤、及び/又は両性及び/又は双性及び/又は半極性非イオン性界面活性剤から選択され得る。界面活性剤は、典型的に、洗浄組成物の約0.1重量%から、約1重量%から、又は更には約5重量%から、洗浄組成物の約99.9重量%まで、約80重量%まで、約35重量%まで、又は更には約30重量%までの濃度で存在する。
本発明の液体組成物はレオロジー改質剤を含んでよい。レオロジー改質剤は、非ポリマー結晶性のヒドロキシ官能性材料であり、組成物の水性液体マトリクスに剪断減粘特性を付与する、ポリマーレオロジー変性剤からなる群から選択されてよい。一態様では、かかるレオロジー変性剤は、水性液体組成物に、20秒−1の剪断速度及び21℃にて、1〜7000mPa.sの高剪断粘度、及び、低剪断(21℃において剪断速度0.5秒−1)にて1000mPa.s超又は更には1000mPa.s〜200,000mPa.sの粘度を付与する。一態様では、洗浄及びトリートメント組成物のために、かかるレオロジー変性剤は、水性液体組成物に、約20秒−1及び21℃において50〜3000mPa.sの高剪断粘度、及び、低剪断(21℃において0.5秒−1の剪断速度)において1000mPa.s超又は更には1000mPa.s〜200,000mPa.sの粘度を付与する。本発明による粘度は、プレート直径40mm及び間隙サイズ500μmを有する平板鋼スピンドルを使用する、TA instruments製のAR2000レオメーターを使用して測定される。20秒−1の高剪断粘度及び0.5秒−1の低剪断粘度は、21℃で3分の時間内の0.1秒−1から25秒−1までの対数剪断速度掃引から得ることができる。結晶性ヒドロキシ官能性材料は、マトリックス内で現場で結晶化されると組成物のマトリックスの全体にわたって糸様構造系を形成するレオロジー改質剤である。高分子レオロジー変性剤は、好ましくはポリアクリレート、高分子ゴム、その他の非ゴム多糖類、及びこれらの高分子材料の組み合わせから選択される。
本発明の消費者向け製品の実施形態は、任意の好適な形態に配合され、配合者によって選択される任意のプロセスによって調製され得、その非限定例は、米国特許第5,879,584号に記載されている:それは参照により本明細書に組み込まれる。
本明細書に開示されている封入体を含有する消費者向け製品などの組成物は、部位、とりわけ表面又は布地を洗浄及び処理するために使用することができる。一般に、この部位の少なくとも一部を、無希釈形態で、又は液体(例えば洗浄液)で希釈して、本出願人の組成物の実施形態と接触させた後、所望によりその部位を洗浄及び/又はすすぎ洗いしてもよい。一態様では、ある部位が所望により洗浄され及び/又はすすがれ、本発明による封入体に又は上記封入体を含む組成物に接触され、次に所望により洗浄され及び/又はすすがれる。本発明の目的に関して、洗浄は、こすり洗い及び機械的撹拌を含むが、これらに限定されない。部位は、例えば、布地、通常の消費者使用条件で洗濯又は処理できる布地といった、殆どのどんな材料も含み得る。開示される組成物を含み得る液体は、約3〜約11.5のpHを有していてよい。このような組成物は、典型的に、溶液中約500ppm〜約15,000ppmの濃度で使用される。洗浄溶媒が水であるとき、水温は、一般に約5℃〜約90℃であり、部位が布地を含むとき、水の布地に対する比は、典型的に、約1:1〜約30:1である。
悪臭低減物質は、GC−MS及び/又はNMRを含む分析法によって、限定されるものではないが消費者向け製品などの最終製品を含む混合物から分離され、同定されることができる。
粒度は、カリフォルニア州サンタバーバラ所在のParticle Sizing Systems製Accusizer 780Aを用いて測定する。計測器はDuke粒度基準を用いて0から300μまで較正する。粒度評価のためのサンプルは、約1gの乳濁液(乳濁液の体積加重平均粒度を求める場合)、又は1gのカプセルスラリー(最終カプセルの体積加重平均粒度を求める場合)を約5gの脱イオン水に希釈し、約1gのこの溶液を約25gの水にさらに希釈することによって準備する。
飽和蒸気圧(VP)値は、試験される香料混合物中の各々のPRMについて算定される。個々のPRMのVPは、Advanced Chemistry Development Inc.(ACD/Labs)(カナダ、トロント)より入手可能なVP計算モデル、14.02版(Linux)を用いて計算され、トルの単位で表示される25℃でのVP値が得られる。ACD/Labsの蒸気圧モデルは、ACD/Labsモデルスイートの一部である。
オクタノール/水分配係数のlog値(logP)は、試験される香料混合物中の各々のPRMについて算定される。個々のPRMのlogPは、Advanced Chemistry Development Inc.(ACD/Labs)(カナダ、トロント)より入手可能なConsensus logP計算モデル、バージョン14.02(Linux)を用いて計算され、単位のないlogP値が得られる。ACD/LabsのConsensus logP計算モデルは、ACD/Labsモデルスイートの一部である。
本明細書に記載される算定値試験方法に含まれる計算を実行するために、必要とされる開始情報には、その香料の一部として、試験される香料中の各々のPRMの識別値(identity)、重量パーセント、及びモルパーセントが含まれ、香料組成物中の全てのPRMが計算に含められる。その上に、本明細書に記載される分子記述子の生成のための試験方法に従って求められるように、それらのPRMの各々についての分子構造、及び様々な演算によって導かれた分子記述子の値も必要とされる。
1)1又はそれ以上の香料成分の分子構造を、SDFファイルとも呼ばれるMACCS構造データファイル、又はSMILESファイルの形態で集める。
2)winMolconnプログラムのバージョン1.0.1.3を使用し、適切なコンピュータで実行し、上記のSDF又はSMILESファイルを入力として使用して、プログラムから利用可能な分子記述子の完全なコンプリメントを算定する。
a.winMolconnの出力は、ASCIIテキストファイルの形態であり、一般的にスペースで区切られ、入力ファイルの各々の構造について最初のカラムに構造識別子を含み、残りのカラムにそれぞれの分子記述子を含む。
3)表計算ソフトウェアプログラム又は何らかの他の適切な技法を用いてテキストファイルを構文解析してカラムにする。分子記述子ラベルは得られる表の1行目に見出される。
4)分子記述子ラベルによって特定され、各々のモデルに必要な入力に対応する、記述子カラムを検出して抜き出す。
a.winMolconn分子記述子ラベルは大文字と小文字が区別されることに注意。
1.)上記方法によって求められる分子記述子値を次の4つの式に入力する:
a)MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)
b)MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)
c)MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).
d)MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)
式a)は、悪臭トランス−3−メチル−2−ヘキセン酸(カルボン酸 系の悪臭)を低減する物質の有効性に関する
式b)は、悪臭トリメチルアミン(アミン系の悪臭)を低減する物質の有効性に関する
式c)は、悪臭3−メルカプト−3−メチルヘキサン−1−オール(チオール系の悪臭)を低減する物質の有効性に関する
式d)は、悪臭スカトール(インドール系の悪臭)を低減する物質の有効性に関する
2.)本願の目的において、物質のMORVは、式1.)a)〜1.)d)から得られる最大MORV値である。
3.)上の式1.)a)〜1.)d)から得られる全てのMORV値が0.5よりも大きい場合、対象物質はユニバーサルMORVを有する。
本発明の消費者向け製品での使用に好適なブロッカー材料は、悪臭を低減し、その一方で芳香剤の知覚を妨げないその能力で選択される。材料選択は、臭気強度をランク付けするために2つの基準スケールから2つの指数を試験サンプル材料に割り当てることによって行われる。2つの基準スケールは、芳香剤忠実度指数(FFI)のスケール及びブロッカー指数(BI)のスケールである。FFIは、別の芳香剤と組み合わせた場合に干渉を引き起こし得る、知覚できる臭気を付与する試験サンプル材料の能力をランク付け、BIは、試験サンプル材料の悪臭の知覚を低減する能力をランク付ける。FFI基準スケール及びBI基準スケールによって試験サンプルに指数を割り当てるための方法は下に記載される。
FFI基準スケールでFFIを試験サンプルに割り当てるための方法の最初の段階は、FFI基準見本を作成することである。スケール用の見本は、清浄な布地見本を既知量の既知濃度のエチルバニリン溶液で処理することによって作成される。この試験のための布地見本は、PC50/50として注文されるEMC製の白色ポリコットン編地(10センチメートル×10センチメートル(4インチ×4インチ))見本である。供給者は見本を最初に色抜きするよう指示され、色抜きは芳香剤を含まない洗剤で2回洗浄し、3回すすぐことを必要とする。
50%/50% EtOH/水を希釈液として次の濃度:25ppm、120ppm及び1000ppmで用いてエチルバニリンの3つの溶液を作成する。この3つの溶液の各々の13μLを清浄な見本の中央にピペットで移して、見本の中央に直径約1cmの溶液を得る。これは、見本の上にピペットで移した溶液の濃度に基づく、3つの異なる臭気レベルをもつ3つの見本の感覚の尺度となる。排気フード内で30分間乾燥させた後、見本をアルミ箔で包んで処理した見本への臭気混入を防ぐ。正常な未処理の見本もFFIスケールでの臭気強度基準の最も低いアンカーポイントとして含める。FFI基準スケール見本は、0.5〜12時間以内に使用され、12時間後に廃棄されるべきである。見本は、評点者が1以上の試験サンプルを評価し、表7に示されるように芳香剤忠実度指数(FFI)を割り当てる際のスケールアンカーポイントとして使用される。
清浄な見本を13μLの既知濃度の試験サンプル材料で処理し、その結果清浄な見本上に約1cmの溶液を得る。基準見本のように、試験サンプル材料見本を排気フード内で30分間乾燥させた後、アルミ箔で包んで汚染を防ぐ。試験物質見本及びFFI基準見本は互いに2時間以内に作成されなければならない。試験物質見本は0.5〜12時間以内に使用され、12時間後に廃棄されなければならない。
少なくとも2名のパフューマー/熟練評点者を使用してFFI評点を試験サンプルに割り当てる。パフューマー/熟練評点者は、試験サンプル見本を彼らの鼻から2.5センチメートル(1インチ)に保持し、鼻を試験サンプルがピペットで布地に移された区域の中心の上方に置くことによってその見本の匂いを嗅ぎ、その後FFI基準スケールアンカー見本を対照として用いて試験サンプルにFFI評点を割り当てる。試験サンプル見本は、表9に示されるFFIスケールの数字又は数字間のFFI評点が割り当てられる。試験サンプル物質に3よりも大きい評点がつけられる場合には、その試験物質はブロッカー物質ではないか、又は、物質の濃度を下げて再評価して低い濃度で悪臭ブロッカー官能性があるかどうか判断する必要がある。
BI基準スケールでBIを試験サンプル物質に割り当てるための方法の最初の段階は、BI基準見本を作成することである。スケール用の見本は、清浄な布地見本を既知濃度の既知量の既知容積のイソ吉相酸溶液で処理することによって作成される。この試験のための布地見本は、PC50/50として注文されるEMC製の白色ポリコットン編地(10センチメートル×10センチメートル(4インチ×4インチ))見本である。供給者は見本を最初に色抜きするよう指示され、色抜きは芳香剤を含まない洗剤で2回洗浄し、3回すすぐことを必要とする。
50%/50% EtOH/水を希釈液として用いて1つの0.08%イソ吉草酸の溶液を作成する。BIスケールは、悪臭を適用しない清浄な見本を1つ含む。その他の3つの見本は各々、異なる容積の0.08%イソ吉草酸が適用される。ピペットで2μLの0.08%イソ吉相酸溶液を1つの清浄な見本に移し、5μLの0.08%イソ吉相酸溶液を次の見本に移し、20μLのイソ吉草酸を最後の清浄な見本に移した。これらの溶液はピペットで見本の中央に移される。これは、見本の上にピペットで移した0.08%イソ吉相酸溶液の容積に基づく、3つの異なる臭気レベルをもつ3つの見本の感覚の尺度となる。排気フード内で30分間乾燥させた後、見本をアルミ箔で包んで処理した見本への臭気混入を防ぐ。正常な未処理の見本もBIスケールでの悪臭強度基準の最も低いアンカーポイントとして含める。BI基準スケール見本は、0.5〜12時間以内に使用され、12時間後に廃棄されるべきである。見本は、評点者が1以上の試験サンプルを評価し、表12に示されるようにブロッカー指数(BI)を割り当てる際のスケールアンカーポイントとして使用される。
Biを評価するために、試験物質を悪臭のある見本に適用して試験物質がどのようにうまく悪臭をブロックするかを判定する。悪臭のある見本は、イソ吉草酸の0.08%溶液20μLで清浄な見本を処理することによって作成される。イソ吉草酸で処理した悪臭のある見本を排気フード内で30分間乾燥させる。悪臭のある見本を乾燥させた後、1ppm〜100ppmの間の既知濃度の試験物質溶液を、ピペットで悪臭のある見本の上に移す。イソ吉相酸溶液が塗布されて直径約1cmのスポットを作っている場所の真上に試験物質溶液を適用する。BI基準見本のように、イソ吉草酸+試験物質見本を排気フード内で30分間乾燥させ、その後アルミ箔で包んで汚染を防ぐ。イソ吉草酸+試験物質見本及びBI基準見本は互いに2時間以内に作成されなければならない。イソ吉草酸+試験物質見本は、基準見本のように1〜12時間の間に使用されなければならない。BIを判定するために、約1〜約100ppmの間のいくつかの試験物質の濃度を評価することが必要な場合がある。
少なくとも2名のパフューマー/熟練評点者を使用してBIを試験サンプルに割り当てる。熟練評点者は、イソ吉草酸+試験物質見本を鼻から2.5センチメートル(1インチ)に保持し、鼻を試験サンプルがピペットで布地に移された区域の中心の上方に置くことによってその見本の匂いを嗅ぎ、その後BI基準スケールの見本の臭気強度に対してその臭気強度を順位づけることによってイソ吉草酸+試験物質見本にBIを割り当てる。試験サンプル見本には、表中のBIの数字又は数字間のBIが割り当てられる。イソ吉草酸+試験物質見本の臭気がBI基準スケールの3よりも大きい場合、これはその物質がブロッカー材料ではないか、又は、試験物質の濃度を下げてそのブロッカー官能性を達成する必要があることを示す。
下記は、悪臭制御化合物が低い濃度で改良された悪臭制御を与える、好ましい挙動のいくつかの限定されない例である。これらの限定されないデータは悪臭がマスクされずにブロックされている点において、さらなる納得できるデータを提供する。
下の例は、ある悪臭制御化合物が高い濃度で臭気ブロッキングを示すことができなかった(BI>2.5)とはいえ、それを低い濃度で再試験してそれが合格するかどうか判定するべきであることを示す。
本発明では、ブレンドによってより強力な悪臭低減が可能である。なぜなら、ブレンドは嗅覚によって検知されるようになるまでに、製品組成物の高い%で有用であるためである。下記は、悪臭低減化合物の限定されない例である。
25グラムのブチルアクリレート−アクリル酸コポリマー乳化剤(Colloid C351、固形分25%、pKa4.5〜4.7(米国ジョージア州ケネソー所在のKemira Chemicals,Inc.))を脱イオン水200グラムに溶解させ、混合する。溶液のpHを、水酸化ナトリウム溶液pH4.0に調整する。8グラムの部分メチル化メチロールメラミン樹脂(Cymel 385、固形分80%(米国ニュージャージー州ウエストパターソン所在のCytec Industries))を乳化剤溶液に添加する。表1又は表2による香油200グラムを、前の混合物に機械的撹拌下で添加し、温度を50℃に上昇させる。安定な乳剤が得られるまで高速で混合した後、第2の溶液及び4グラムの硫酸ナトリウム塩をこの乳剤に加える。この第2の溶液は、10グラムのブチルアクリレート−アクリル酸コポリマー乳化剤(Colloid C351、固形分25%、pKa4.5〜4.7、Kemira)、120グラムの蒸留水、pHを4.8に調整するための水酸化ナトリウム溶液、25グラムの部分メチル化メチロールメラミン樹脂(Cymel 385、固形分80%、Cytec)を含有する。この混合物を70℃に加熱し、連続的に撹拌しながら一晩維持して、カプセル封入プロセスを完了させる。23グラムのアセトアセトアミド(シグマ−アルドリッチ(米国ミズーリ州セントルイス))を懸濁液に添加する。780型Accusizerによって分析したときに30μmの平均カプセルサイズを得る。
本発明の利益を実証するために、本出願人は以下の液体洗剤マトリックスAを調製した。
本明細書に開示されるポリマーコーティングした香料マイクロカプセルを含有する布地コンディショナーの非限定的実施例を以下の表にまとめる。
bメチルビス(タローアミドエチル)2−ヒドロキシエチルアンモニウムメチルサルフェート。
c脂肪酸とメチルジエタノールアミンのモル比1.5:1の反応生成物、塩化メチルで四級化され、N,N−ビス(ステアロイル−オキシ−エチル)N,N−ジメチルアンモニウムクロライド及びN−(ステアロイル−オキシ−エチル)N,−ヒドロキシエチルN,Nジメチルアンモニウムクロライドの1:1モル混合物となる。
dNational Starchから商標名CATO(登録商標)で入手可能なカチオン性高アミローストウモロコシデンプン。
fBASF製のRheovis DCE
gWacker製SE39。
hジエチレントリアミン五酢酸
iローム・アンド・ハース社から入手可能なKATHON(登録商標)CG。「PPM」は、「百万分の一」。
jグルタルアルデヒド(Gluteraldehyde)
kDC2310の商標名でダウ・コーニング社(Dow Corning Corp.)から入手可能なシリコーン消泡剤。
†残部
以下は、液体組成物がPVAフィルム内に封入される単位用量の実施例である。本実施例で使用される好ましいフィルムは、厚さ76μmのMonosol M8630である。
そのような香料を含む香料及び/又はマイクロカプセルを含む自由流動粒子製品が下に記載される。下の表はまた、遊離しているか又はマイクロカプセル中の香料も含む組合せ、あるいは悪臭低減物質及び/又は組成物を含む上述の組合せとこれらの組合せも例示する。この表はまた、本質的に「無香料」の製品を提供するために芳香剤をほとんど又は全く含まない、遊離しているか又はマイクロカプセル中の悪臭低減物質及び/又は組成物だけを有する組成物、ならびにその組合せも例示する。
(2)粘土
(3)尿素
(4)多糖、大部分がデンプン、未加工デンプン、デンプン誘導体、酸加工デンプン及びκカラゲナン
(5)ゼオライト
(6)デンプン/ゼオライト−SEA
(7)金属酸化物−非限定例−TiO2、ZnO、MnO
(8)金属触媒
(9)乳白剤
Claims (8)
- 送達系の総重量に基づいて、合計0.00025%〜30%の、1又はそれ以上の悪臭低減物質を含む有益剤を含む送達系であって、
前記悪臭低減物質が、
1,3,4,6,7,8α−ヘキサヒドロ−1,1,5,5−テトラメチル−2H−2,4α−メタノフタレン−8(5H)−オンのみからなり、または、
前記悪臭低減物質が、
1,3,4,6,7,8α−ヘキサヒドロ−1,1,5,5−テトラメチル−2H−2,4α−メタノフタレン−8(5H)−オンを必須成分として含むとともに、
3−(3,3−ジメチル−2,3−ジヒドロ−1H−インデン−5−イル)プロパナール、
2,2,6,6,7,8,8−ヘプタメチルデカヒドロ−2H−インデノ[4,5−b]フラン、
5−シクロヘキサデセノン、
1−((3R,3aR,7R,8aS)−3,6,8,8−テトラメチル−2,3,4,7,8,8a−ヘキサヒドロ−1H−3a,7−メタノアズレン−5−イル)エタン−1−オン、および
4,5−エポキシ−4,11,11−トリメチル−8−メチレンビシクロ(7.2.0)ウンデカン
からなる群から選択される、1又はそれ以上を含み、
前記送達系が、有益剤の総重量に基づいて、0.1〜50%の悪臭低減物質を含む、ポリマー支援型送達(PAD)系であり、
前記ポリマー支援型送達(PAD)系がポリマー支援型送達(PAD)リザーバ系を含み、
前記ポリマー支援型送達(PAD)リザーバ系が、シェル材料及びコア材料を含む香料送達粒子であり、前記シェル材料が前記コア材料を取り囲み、前記コア材料が前記悪臭低減物質を含み、前記シェルがメラミンホルムアルデヒド又は架橋メラミンホルムアルデヒドを含む、送達系。 - 前記シェルが、多糖、カチオン修飾デンプン及びカチオン修飾グアー、ポリシロキサン、ポリハロゲン化ジメチルジアリルアンモニウム、ポリ塩化ジメチルジアリルアンモニウムとビニルピロリドンのコポリマー、アクリルアミド、イミダゾール、ハロゲン化イミダゾリニウム及びハロゲン化イミダゾリウム、並びにポリビニルアミン及びそのN−ビニルホルムアミドとのコポリマーからなる群から選択される水溶性カチオンポリマーによってコーティングされている、請求項1に記載のポリマー支援型送達(PAD)リザーバ系。
- 前記シェルをコーティングする前記コーティングが、カチオン性ポリマー及びアニオン性ポリマーを含む、請求項2に記載のポリマー支援型送達(PAD)リザーバ系。
- a)前記カチオン性ポリマーがヒドロキシルエチルセルロースを含み;前記アニオン性ポリマーがカルボキシルメチルセルロースを含む、請求項3に記載のポリマー支援型送達(PAD)リザーバ系。
- 前記コアが、
2−エチルヘキシル(Z)−3−(4−メトキシフェニル)アクリレート;2,4−ジメチル−2−(5,5,8,8−テトラメチル−5,6,7,8−テトラヒドロナフタレン−2−イル)−1,3−ジオキソラン;1,1−ジメトキシノン−2−イン;2−(p−トリル)プロパン−2−オール;3−メトキシ−7,7−ジメチル−10−メチレンビシクロ[4.3.1]デカン;メトキシシクロドデカン;1,1−ジメトキシシクロドデカン;(Z)−トリデカ−2−エンニトリル;(2−ヒドロキシ−4−メトキシフェニル)(フェニル)メタノン;2,4a,5,8a−テトラメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−イルホルメート;4−メチル−1−オキサスピロ[5.5]ウンデカン−4−オール;1,8−ジオキサシクロヘプタデカン−9−オン;4−(tert−ペンチル)シクロヘキサン−1−オン;2−メトキシ−1,1’−ビフェニル;3a,5,6,7,8,8b−ヘキサヒドロ−2,2,6,6,7,8,8−ヘプタメチル−4H−インデノ(4,5−d)−1,3−ジオキソール;7−イソプロピル−8,8−ジメチル−6,10−ジオキサスピロ[4.5]デカン;オクチルフラン−2−カルボキシラート;酢酸オクチル;2−ヘプチル−4−メチル−1,3−ジオキソラン;1,1−ジメトキシオクタン;2−メチル−6−メチレンオクタ−7−エン−2−オール;2−メチル−6−メチレンオクタ−7−エン−2−イルアセテート;テトラデカナール;4−メトキシ−6−プロパ−2−エニル−1,3−ベンゾジオキソール;テトラデカンニトリル;2,2,6,8−テトラメチル−1,2,3,4,4a,5,8,8a−オクタヒドロナフタレン−1−オール;(E)−2,6−ジメチルオクタ−5,7−ジエン−2−オール;(E)−2,7−ジメチルオクタ−1,5,7−トリエン−3−オール;2−((1S,5R)−6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−イル)エチルアセテート;(4R,4aS,6R)−4,4a−ジメチル−6−(プロパ−1−エン−2−イル)−4,4a,5,6,7,8−ヘキサヒドロナフタレン−2(3H)−オン;ノナン−1−オール;2−メチル−14−テトラデカ−9−エノリド;N−エチル−2−イソプロピル−5−メチルシクロヘキサン−1−カルボキサミド;(E)−3,7,11−トリメチルドデカ−1,6,10−トリエン−3−オール;1−エチル−3−メトキシトリシクロ[2.2.1.02,6]ヘプタン;メチル(E)−ノン−2−エノアート;10−イソプロピル−2,7−ジメチル−1−オキサスピロ[4.5]デカ−3,6−ジエン;2−(2−(4−メチルシクロヘキサ−3−エン−1−イル)プロピル)シクロペンタン−1−オン;6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−カルバルデヒド;(E)−4−(2,2,3,6−テトラメチルシクロヘキシル)−ブタ−3−エン−2−オン;(4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−イル)メチルアセテート;2−(tert−ブチル)−4,5,6−トリメチル−1,3−フェニレンジニトリット;1,7−ジオキサシクロヘプタデカン−8−オン;1−(4−(tert−ブチル)−2,6−ジメチル−3,5−ジニトロフェニル)エタン−1−オン;1−(tert−ブチル)−2−メトキシ−4−メチル−3,5−ジニトロベンゼン;3−メチルシクロペンタデカン−1−オン;(E)−3−メチルシクロペンタデカ−4−エン−1−オン;1−(4−イソプロピルシクロヘキシル)エタン−1−オール;(E)−デカ−5−エン酸;2−メチルデカナール;6,6−ジメトキシ−2,5,5−トリメチルヘキサ−2−エン;ステアリン酸メチル;1,1−ジメトキシ−2−メチルウンデカン;ウンデカン−2−オン;2−メチルウンデカナール;メチルテトラデカノアート;メチル(9Z,12Z)−オクタデカ−9,12−ジエノアート;1−ヒドロキシデカン−3−オン;パルミチン酸メチル;メチル2−((1R,2R)−3−オキソ−2−((Z)−ペンタ−2−エン−1−イル)シクロペンチル)アセテート;メチル2−(3−オキソ−2−ペンチルシクロペンチル)アセテート;1−メチル−2−フェノキシベンゼン;メチル2,6,6−トリメチルシクロヘキサ−2−エン−1−カルボキシラート;7−メトキシ−3,7−ジメチルオクタナール;7−イソプロピル−10−メチル−1,5−ジオキサスピロ[5.5]ウンデカン−3−オール;オクタヒドロ−1H−4,7−メタノインデン−1−カルバルデヒド;3−(3−(tert−ブチル)フェニル)−2−メチルプロパナール;(E)−4−(4,8−ジメチルノナ−3,7−ジエン−1−イル)ピリジン;(E)−トリデカ−3,12−ジエンニトリル;2,2−ジメチル−3−(m−トリル)プロパン−1−オール;2,4−ジメチル−4,4a,5,9b−テトラヒドロインデノ[1,2−d][1,3]ジオキシン;8−イソプロピル−6−メチルビシクロ[2.2.2]オクタ−5−エン−2−カルバルデヒド;4−(4−ヒドロキシ−4−メチルペンチル)シクロヘキサ−3−エン−1−カルバルデヒド;(S)−1−メチル−4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン;3,7−ジメチルオクタ−1,6−ジエン−3−イルオクタノエート;3,7−ジメチルオクタ−1,6−ジエン−3−イルイソブチラート;3,7−ジメチルオクタ−1,6−ジエン−3−イルベンゾエート;3,7−ジメチルオクタ−1,6−ジエン−3−イル2−アミノベンゾエート;2−(5−メチル−5−ビニルテトラヒドロフラン−2−イル)プロパン−2−オール;6−メチル−2−(オキシラン−2−イル)ヘプタ−5−エン−2−オール;(2Z,6E)−3,7−ジメチルノナ−2,6−ジエンニトリル;3−(4−メチルシクロヘキサ−3−エン−1−イル)ブタナール;(2,5−ジメチル−1,3−ジヒドロインデン−2−イル)メタノール;3−(4−(tert−ブチル)フェニル)−2−メチルプロパナール;(E)−1−(1−メトキシプロポキシ)ヘキサ−3−エン;(E)−1−(1−エトキシエトキシ)ヘキサ−3−エン;(1S,5R)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサ−2−エン−1−オール;ドデカン−1−オール;ドデシルアセテート;ドデカン酸;5−ヘキシル−5−メチルジヒドロフラン−2(3H)−オン;ドデカナール;3,6−ジメチルヘキサヒドロベンゾフラン−2(3H)−オン;4−(1−エトキシビニル)−3,3,5,5−テトラメチルシクロヘキサン−1−オン;((3S,3aR,6R,8aS)−7,7−ジメチル−8−メチレンオクタヒドロ−1H−3a,6−メタノアズレン−3−イル)メタノール5−(sec−ブチル)−2−(2,4−ジメチルシクロヘキサ−3−エン−1−イル)−5−メチル−1,3−ジオキサン;(1−メチル−2−((1,2,2−トリメチルビシクロ[3.1.0]ヘキサン−3−イル)メチル)シクロプロピル)メタノール;2−プロピルヘプタンニトリル;2−ヘキシルシクロペンタン−1−オン;2,6,9,10−テトラメチル−1−オキサスピロ(4.5)デカ−3,6−ジエン;(1R,2S,5R)−5−メチル−2−(プロパ−1−エン−2−イル)シクロヘキサン−1−オール;パルミチン酸イソプロピル;イソプロピルテトラデカノアート;イソプロピルドデカノアート;4,9−ジメトキシ−7H−フロ[3,2−g]クロメン−7−オン;(E)−シクロヘキサデカ−8−エン−1−オン;(2S,5S)−2−イソプロピル−5−メチルシクロヘキサン−1−オン;2−ヘキシルシクロペンタ−2−エン−1−オン;(2S,5S)−2−イソプロピル−5−メチルシクロヘキサン−1−オン;4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−カルバルデヒド;(Z)−1−(ベンジルオキシ)−2−メトキシ−4−(プロパ−1−エン−1−イル)ベンゼン;1−((2S,3S)−2,3,8,8−テトラメチル−1,2,3,4,5,6,7,8−オクタヒドロナフタレン−2−イル)エタン−1−オン;2,5,6−トリメチルシクロヘキサ−3−エン−1−カルバルデヒド;6−(sec−ブチル)キノリン;2−(シクロヘキシルオキシ)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン;(1R,2R,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルプロピオネート;(1S,2S,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルイソブチラート;4−((2R)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イル)シクロヘキサン−1−オール;(1R,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;2−(4−イソプロピルシクロヘキサ−1,4−ジエン−1−イル)エチルホルメート;イソペンチル(E)−ウンデカ−6−エノアート;イソペンチルドデカノアート;(E)−オキサシクロヘプタデカ−10−エン−2−オン;(E)−8−(1H−インドール−1−イル)−2,6−ジメチルオクタ−7−エン−2−オール;8,8−ジ(1H−インドール−1−イル)−2,6−ジメチルオクタン−2−オール;4,4a,5,9b−テトラヒドロインデノ[1,2−d][1,3]ジオキシン;3,7−ジメチルオクタン−1,7−ジオール;2−シクロドデシルプロパン−1−オール;3−メチル−5−フェニルペンタンニトリル;(1,1−ジメトキシプロパン−2−イル)ベンゼン;2,3−ジヒドロ−3,3−ジメチル−1H−インデン−5−プロパナール;3−(3,3−ジメチル−2,3−ジヒドロ−1H−インデン−5−イル)プロパナール;オクタン酸ヘキシル;ヘキサン酸ヘキシル;(Z)−2−ベンジリデンオクタナール;安息香酸ヘキシル;(Z)−ヘキサ−1−エン−1−イル(Z)−2−メチル−ブタ−2−エノアート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イルパルミテート;オキサシクロヘプタデカン−2−オン;2−ブチル−4,4,6−トリメチル−1,3−ジオキサン;エチル(1R,2R,3R,4R)−3−イソプロピルビシクロ[2.2.1]ヘプタ−5−エン−2−カルボキシラート;3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルアセテート;2−(1−(3,3−ジメチルシクロヘキシル)エトキシ)−2−メチルプロピルプロピオネート;5−(ジエトキシメチル)ベンゾ[d][1,3]ジオキソール;3−(ベンゾ[d][1,3]ジオキソール−5−イル)−2−メチルプロパナール;(E)−オキサシクロヘキサデカ−13−エン−2−オン;6−ブチル−2,4−ジメチル−3,6−ジヒドロ−2H−ピラン;2−((3S,5R,8S)−3,8−ジメチル−1,2,3,4,5,6,7,8−オクタヒドロアズレン−5−イル)プロパン−2−オール;1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ペンタン−3−オン;エチル2−エチル−6,6−ジメチルシクロヘキサ−2−エン−1−カルボキシラート;(1Z,5Z)−1,5−ジメチル−8−(プロパン−2−イリデン)シクロデカ−1,5−ジエン;(1E,6E)−8−イソプロピル−1−メチル−5−メチレンシクロデカ−1,6−ジエン;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イル2−フェニルアセテート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イル2−フェニルアセテート;(6E,10E)−3,7,11,15−テトラメチルヘキサデカ−1,6,10,14−テトラエン−3−オール;(E)−2−(3,7−ジメチルオクタ−2,6−ジエン−1−イル)シクロペンタン−1−オン;5−ヘプチルジヒドロフラン−2(3H)−オン;1−メチル−4−(プロパン−2−イリデン)シクロヘキシルアセテート;1−メチル−4−(プロパン−2−イリデン)シクロヘキサン−1−オール;
(1R,4aR,8aS)−1−イソプロピル−7−メチル−4−メチレン−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;(Z)−4−(2,2−ジメチル−6−メチレンシクロヘキシル)−ブタ−3−エン−2−オン;(4aS,9aR)−3,5,5,9−テトラメチル−2,4a,5,6,7,9a−ヘキサヒドロ−1H−ベンゾ[7]アヌレン;(1R,3aR,4R,7R)−1,4−ジメチル−7−(プロパ−1−エン−2−イル)−1,2,3,3a,4,5,6,7−オクタヒドロアズレン;2−((2R,4aR)−4a,8−ジメチル−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン−2−イル)プロパン−2−オール;5−オクチルジヒドロフラン−2(3H)−オン;(Z)−1−(2,2−ジメチル−6−メチレンシクロヘキシル)−ブタ−2−エン−1−オン;5−ヘキシルジヒドロフラン−2(3H)−オン;(1R,4aS,8aS)−1−イソプロピル−7−メチル−4−メチレン−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;1−(3,3−ジメチルシクロヘキシル)ペンタ−4−エン−1−オン;4,6,6,7,8,8−ヘキサメチル−1,3,4,6,7,8−ヘキサヒドロシクロペンタ[g]イソクロメン;フラン−2−イルメチルオクタノエート;フラン−2−イルメチルヘキサノエート;フラン−2−イルメチルヘプタノエート;2−メチルデカンニトリル;8,8−ジメチル−3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルプロピオネート;エチル(3aR,4S,7R,7aR)−オクタヒドロ−3aH−4,7−メタノインデン−3a−カルボキシラート;ジエチルシクロヘキサン−1,4−ジカルボキシラート;(6−イソプロピル−9−メチル−1,4−ジオキサスピロ[4.5]デカン−2−イル)メタノール;2−イソブチル−4−メチルテトラヒドロ−2H−ピラン−4−オール;ウンデカ−10−エンニトリル;(Z)−6−エチリデンオクタヒドロ−2H−5,8−メタノクロメン−2−オン;3−(2−エチルフェニル)−2,2−ジメチルプロパナール;(E)−4,8−ジメチルデカ−4,9−ジエナール;(E)−4−((3aR,4R,7R,7aR)−1,3a,4,6,7,7a−ヘキサヒドロ−5H−4,7−メタノインデン−5−イリデン)−3−メチルブタン−2−オール;8,8−ジメチル−3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルアセテート;3−(4−エチルフェニル)−2,2−ジメチルプロパンニトリル;2−ヘプチルシクロペンタン−1−オン;1−エトキシエトキシシクロドデカン;3−シクロヘキセン−1−カルボン酸、2,6,6−トリメチル−、メチルエステル;(2E,6E)−3,7,11−トリメチルドデカ−2,6,10−トリエン−1−イルアセテート;(2E,6E)−3,7,11−トリメチルドデカ−2,6,10−トリエン−1−オール;オキサシクロヘキサデカン−2−オン;(E)−シクロペンタデカ−4−エン−1−オン;1−シクロペンタデカ−4−エン−1−オン;2−メトキシ−4−(4−メチレンテトラヒドロ−2H−ピラン−2−イル)フェノール;4−アリル−2−メトキシフェニルアセテート;エチル3−メチル−3−フェニルオキシラン−2−カルボキシラート;1,4−ジオキサシクロヘプタデカン−5,17−ジオン;エチルウンデカ−10−エノアート;パルミチン酸エチル;ノナン酸エチル;エチルテトラデカノアート;(E)−3,7−ジメチルノナ−1,6−ジエン−3−オール;ドデカン酸メチル;デカン酸エチル;エチル6,6−ジメチル−2−メチレンシクロヘキサ−3−エン−1−カルボキシラート;エチル3−フェニルオキシラン−2−カルボキシラート;6−エチル−2,10,10−トリメチル−1−オキサスピロ[4.5]デカ−3,6−ジエン;2−((1R,3S,4S)−4−メチル−3−(プロパ−1−エン−2−イル)−4−ビニルシクロヘキシル)プロパン−2−オール;(2−(1−エトキシエトキシ)エチル)ベンゼン;(E)−3−メチル−5−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ペンタ−4−エン−2−オール;(2R,3S,4R)−2,3,4,5−テトラヒドロキシペンタナール;(E)−4−((3aS,7aS)−オクタヒドロ−5H−4,7−メタノインデン−5−イリデン)ブタナール;1,1−ジメトキシドデカン;(R)−1−メチル−4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン;7,9−ジメチルスピロ[5.5]ウンデカン−3−オン;2−メチル−1−フェニルプロパン−2−イルブチラート;2,6−ジメチルオクタ−7−エン−4−オン;オクタヒドロ−1H−4,7−メタノインデン−5−イルアセテート;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキシルアセテート;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサン−1−オール;3,7−ジメチルオクタ−6−エン−3−オール;メチル2−ヘキシル−3−オキソシクロペンタン−1−カルボキシラート;1,2−ジフェニルエタン;6−ヘキシルテトラヒドロ−2H−ピラン−2−オン;(3R,4R)−1−イソプロピル−4−メチル−3−(プロパ−1−エン−2−イル)−4−ビニルシクロヘキサ−1−エン;(3S,3aS,5R)−3,8−ジメチル−5−(プロパ−1−エン−2−イル)−1,2,3,3a,4,5,6,7−オクタヒドロアズレン;6−ヘプチルテトラヒドロ−2H−ピラン−2−オン;6−ヘキシルテトラヒドロ−2H−ピラン−2−オン;6−ペンチルテトラヒドロ−2H−ピラン−2−オン;(1S,8aR)−4,7−ジメチル−1−(プロパン−2−イル)−1,2,3,5,6,8a−ヘキサヒドロナフタレン;(Z)−1−((1R,2S)−2,6,6−トリメチルシクロヘキサ−3−エン−1−イル)−ブタ−2−エン−1−オン;((1S,8aS)−1−イソプロピル−4,7−ジメチル−1,2,3,5,6,8a−ヘキサヒドロナフタレン;3,7,7−トリメチルビシクロ[4.1.0]ヘプタ−3−エン;デカ−9−エン−1−オール;デシルプロピオネート;1,1−ジエトキシデカン;1−シクロヘキシルエチル(E)−ブタ−2−エノアート;3−(4−イソプロピルフェニル)−2−メチルプロパナール;シクロテトラデカン;シクロペンタデカノン;シクロヘキシル2−ヒドロキシベンゾエート;3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルブチラート;1,4−ジオキサシクロヘキサデカン−5,16−ジオン;8,8−ジメチル−1,2,3,4,5,6,7,8−オクタヒドロナフタレン−2−カルバルデヒド;3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−5−イルイソブチラート;(5R,6R)−3,6−ジメチル−5−(プロパ−1−エン−2−イル)−6−ビニル−4,5,6,7−テトラヒドロベンゾフラン;(4−イソプロピルフェニル)メタノール;2−(3−フェニルプロピル)ピリジン;ドデカンニトリル;(E)−シクロヘプタデカ−9−エン−1−オン;3−(4−メチルシクロヘキサ−3−エン−1−イル)−ブタ−3−エン−1−イルアセテート;3−(4−メチルシクロヘキサ−3−エン−1−イル)ブタン−1−オール;(E)−3−メチル−5−フェニルペンタ−2−エンニトリル;(E)−2−(2,6−ジメチルヘプタ−1,5−ジエン−1−イル)−4−メチル−1,3−ジオキソラン;(E)−1,1−ジメトキシ−3,7−ジメチルオクタ−2,6−ジエン;(E)−1,1−ジエトキシ−3,7−ジメチルオクタ−2,6−ジエン;(1R,4R,6S)−1−メチル−4−(プロパ−1−エン−2−イル)−7−オキサビシクロ[4.1.0]ヘプタン;(E)−オキサシクロヘプタデカ−11−エン−2−オン;(1R,5R)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサ−2−エン−1−オール;(E)−ヘキサ−3−エン−1−イル(E)−ヘキサ−3−エノアート;(Z)−ヘキサ−3−エン−1−イル2−ヒドロキシベンゾエート;(Z)−ヘキサ−3−エン−1−イルベンゾエート;(Z)−ヘキサ−3−エン−1−イル2−メチルブタノエート;プロピオン酸シンナミル;イソ酪酸シンナミル;ケイ皮酸シンナミル;ヘキサデカン−1−オール;(E)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ヘプタ−1,6−ジエン−3−オン;2−メチル−4−(2,6,6−トリメチルシクロヘキサ−1−エン−1−イル)ブタナール;(3aR,5aR,9aR,9bR)−3a,6,6,9a−テトラメチルドデカヒドロナフト[2,1−b]フラン;1,6−ジオキサシクロヘプタデカン−7−オン;1−(6−(tert−ブチル)−1,1−ジメチル−2,3−ジヒドロ−1H−インデン−4−イル)エタン−1−オン;3R,3aR,6S,7S,8aS)−6−メトキシ−3,6,8,8−テトラメチルオクタヒドロ−1H−3a,7−メタノアズレン;(3R,3aS,6R,7R,8aS)−3,6,8,8−テトラメチルオクタヒドロ−1H−3a,7−メタノアズレン−3−イルホルメート;(3R,3aS,6R,7R,8aS)−3,6,8,8−テトラメチルオクタヒドロ−1H−3a,7−メタノアズレン−6−イルアセテート;(4Z,8Z)−1,5,9−トリメチル−13−オキサビシクロ[10.1.0]トリデカ−4,8−ジエン;(3R,3aS,6R,7R,8aS)−3,6,8,8−テトラメチルオクタヒドロ−1H−3a,7−メタノアズレン−6−オール;5−メチル−1−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−6−オキサビシクロ[3.2.1]オクタン;5−メチル−1−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−6−オキサビシクロ[3.2.1]オクタン;1,1,2,3,3−ペンタメチル−1,2,3,5,6,7−ヘキサヒドロ−4H−インデン−4−オン;(Z)−4,11,11−トリメチル−8−メチレンビシクロ[7.2.0]ウンデカ−3−エン−5−イルアセテート;(1S,2S,5R,8S)−4,4,8−トリメチルトリシクロ[6.3.1.02,5]ドデカン−1−オール;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサ−2−エン−1−イルアセテート;デカン酸;3−(4−メトキシフェニル)−2−メチルプロパナール;1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2,3−ジオン;2,2−ジメチル−3−メチレンビシクロ[2.2.1]ヘプタン;エチル2−メチル−4−オキソ−6−ペンチルシクロヘキサ−2−エン−1−カルボキシラート;2,6−ジ−tert−ブチル−4−メチルフェノール;ステアリン酸ブチル;1−ブタ−キシ−1−オキソプロパン−2−イルブチラート;ブチルウンデカ−10−エノアート;2−メチル−4−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ブタン−1−オール;3−(4−(tert−ブチル)フェニル)プロパナール;(1S,2S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルイソブチラート;1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;2−エトキシ−2,6,6−トリメチル−9−メチレンビシクロ[3.3.1]ノナン;(エトキシメトキシ)シクロドデカン;(E)−1−メチル−4−(6−メチルヘプト−5−エン−2−イリデン)シクロヘキサ−1−エン;3,3,6,7−テトラメチルオクタヒドロ−2H−クロメン;(5R,10R)−6,10−ジメチル−2−(プロパン−2−イリデン)スピロ[4.5]デカ−6−エン−8−オン;1−メチル−4−(プロパ−1−エン−2−イル)シクロヘキシルアセテート;1−メチル−4−(プロパ−1−エン−2−イル)シクロヘキサン−1−オール;(2Z,6E)−2,6−ジメチル−10−メチレンドデカ−2,6,11−トリエナール;
(R)−3−メチレン−6−((S)−6−メチルヘプト−5−エン−2−イル)シクロヘキサ−1−エン;(4aR,7R,8aS)−4a−メチル−1−メチレン−7−(プロパ−1−エン−2−イル)デカヒドロナフタレン;(Z)−2−メチル−5−((1S,2R,4R)−2−メチル−3−メチレンビシクロ[2.2.1]ヘプタン−2−イル)ペンタ−2−エン−1−オール;6,6−ジメチル−2−メチレンビシクロ[3.1.1]ヘプタン;2−エトキシナフタレン;(1S,4R,7R)−1,4,9,9−テトラメチル−1,2,3,4,5,6,7,8−オクタヒドロ−4,7−メタノアズレン;(1aS,5aR,9aR)−1a,5,5,7−テトラメチル−1a,2,3,4,5,5a,8,9−オクタヒドロベンゾ[1,7]シクロヘプタ[1,2−b]オキシレン;(R)−3,5,5,9−テトラメチル−2,4a,5,6,7,8−ヘキサヒドロ−1H−ベンゾ[7]アヌレン;(1S,4S)−1,4−ジメチル−7−(プロパン−2−イリデン)−1,2,3,4,5,6,7,8−オクタヒドロアズレン;(2,2−ジメトキシエチル)ベンゼン;(E)−7,11−ジメチル−3−メチレンドデカ−1,6,10−トリエン;(1R,2S,6S,7S,8S)−8−イソプロピル−1−メチル−3−メチレントリシクロ[4.4.0.02,7]デカン;(3R,3aS,7S,8aS)−3,8,8−トリメチル−6−メチレンオクタヒドロ−1H−3a,7−メタノアズレン;(1R,9S,Z)−4,11,11−トリメチル−8−メチレンビシクロ[7.2.0]ウンデカ−4−エン;(S)−4−メチル−1−((S)−6−メチルヘプト−5−エン−2−イル)シクロヘキサ−3−エン−1−オール;(Z)−4−(2,2,6−トリメチル−7−オキサビシクロ[4.1.0]ヘプタン−1−イル)−ブタ−3−エン−2−オン;4−メトキシ−7H−フロ[3,2−g]クロメン−7−オン;2−メチル−4−フェニルブタン−2−オール;ドデカン酸ベンジル;ケイ皮酸ベンジル;安息香酸ベンジル;7−イソペンチル−2H−ベンゾ[b][1,4]ジオキセピン−3(4H)−オン;2’−イソプロピル−1,7,7−トリメチルスピロ[ビシクロ[2.2.1]ヘプタン−2,4’−[1,3]ジオキサン]/A;4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−カルボニトリル;メチル(E)−2−((7−ヒドロキシ−3,7−ジメチルオクチリデン)アミノ)ベンゾエート;4−メトキシベンジル2−フェニルアセテート;ペンチル(Z)−3−フェニルアクリレート;(3aR,5aS,9aS,9bR)−3a,6,6,9a−テトラメチルドデカヒドロナフト[2,1−b]フラン;(4aR,5R,7aS,9R)−2,2,5,8,8,9a−ヘキサメチルオクタヒドロ−4H−4a,9−メタノアズレノ[5,6−d][1,3]ジオキソール;2,5,5−トリメチル−1,2,3,4,5,6,7,8−オクタヒドロナフタレン−2−オール;2,5,5−トリメチル−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン−2−オール;1−((2−(tert−ブチル)シクロヘキシル)オキシ)ブタン−2−オール;(3S,5aR,7aS,11aS,11bR)−3,8,8,11a−テトラメチルドデカヒドロ−5H−3,5a−エポキシナフト[2,1−c]オキセピン;2,2,6,6,7,8,8−ヘプタメチルデカヒドロ−2H−インデノ[4,5−b]フラン;2,2,7,7,8,9,9−ヘプタメチルデカヒドロインデノ[4,3a−b]フラン;2−(sec−ブチル)−1−ビニルシクロヘキシルアセテート;(1S,4R,5R)−1−イソプロピル−4−メチルビシクロ[3.1.0]ヘキサン−3−オン;(4R,4aS)−4,4a−ジメチル−6−(プロパン−2−イリデン)−4,4a,5,6,7,8−ヘキサヒドロナフタレン−2(3H)−オン;2−(4−メチルシクロヘキサ−3−エン−1−イル)プロパン−2−イルプロピオネート;(2Z,6E,9E)−2,6,10−トリメチルドデカ−2,6,9,11−テトラエナール;(2R,4aR,8aR)−4a,8−ジメチル−2−(プロパ−1−エン−2−イル)−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;1,7−ジメチル−7−(4−メチルペンタ−3−エン−1−イル)トリシクロ[2.2.1.02,6]ヘプタン;(E)−5−(2,3−ジメチルトリシクロ[2.2.1.02,6]ヘプタン−3−イル)−2−メチルペンタ−2−エン−1−オール;(1R,3aS,7S,8aR)−1,4,9,9−テトラメチル−2,3,6,7,8,8a−ヘキサヒドロ−1H−3a,7−メタノアズレン;1−(5,5−ジメチルシクロヘキサ−1−エン−1−イル)ペンタ−4−エン−1−オン;(1S,4aS,8aR)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;(R,Z)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ペンタ−1−エン−3−オン;1−メチル−4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン;(Z)−4−(2,5,6,6−テトラメチルシクロヘキサ−2−エン−1−イル)−ブタ−3−エン−2−オン;(1Z,4E,8Z)−2,6,6,9−テトラメチルシクロウンデカ−1,4,8−トリエン;(4aR,8S,9aS)−3,5,5,8−テトラメチル−9−メチレン−2,4a,5,6,7,8,9,9a−オクタヒドロ−1H−ベンゾ[7]アヌレン;(1aR,4R,4aR,7bS)−1,1,4,7−テトラメチル−1a,2,3,4,4a,5,6,7b−オクタヒドロ−1H−シクロプロパ[e]アズレン;1,4−ジメチル−7−(プロパ−1−エン−2−イル)−1,2,3,4,5,6,7,8−オクタヒドロアズレン;(3E,6E)−3,7,11−トリトリメチルドデカ−1,3,6,10−テトラエン;7,7−ジメチル−2−メチレンビシクロ[2.2.1]ヘプタン;2−((2R,4aR,8aR)−4a,8−ジメチル−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン−2−イル)プロパン−2−オール;(R)−1−メチル−4−(6−メチルヘプト−5−エン−2−イル)ベンゼン;(3aR,3bR,4S,7R,7aS)−4−イソプロピル−7−メチル−3a,3b,4,5,6,7−ヘキサヒドロ−1H−シクロペンタ[1,3]シクロプロパ[1,2]ベンゼン;(1aS,2aR,3R,5aS,7R,7aR)−3,6,6,7a−テトラメチルオクタヒドロ−2H−2a,7−メタノアズレノ[5,6−b]オキシレン;(1R,4S,4aR,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;1S,4aR,8aR)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;(R)−2−((R)−4−メチルシクロヘキサ−3−エン−1−イル)ヘキサ−5−エン−2−オール;(Z)−1−メチル−4−(6−メチルヘプトa−2,5−ジエン−2−イル)シクロヘキサ−1−エン;2,6−ジメチル−6−(4−メチルペンタ−3−エン−1−イル)ビシクロ[3.1.1]ヘプタ−2−エン;(E)−2−ベンジリデンヘプタン−1−オール;(E)−2−ベンジリデンヘプチルアセテート;(Z)−(2−(ジエトキシメチル)ヘプタ−1−エン−1−イル)ベンゼン;(E)−2−ベンジリデンヘプタナール;(1S,4aR,8aS)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;(3R,5aS,9aR)−2,2,5a,9−テトラメチル−3,4,5,5a,6,7−ヘキサヒドロ−2H−3,9a−メタノベンゾ[b]オキセピン;1−メチル−4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−カルバルデヒド;3−メチル−1−フェニルペンタン−3−オール;2,6,10−トリメチルウンデカナール;α−4−ジメチルベンゼンプロパナール;アリル3−シクロヘキシルプロパノエート;アリル2−(イソペンチルオキシ)アセテート;(1aR,4aS,7R,7aR,7bS)−1,1,7−トリメチル−4−メチレンデカヒドロ−1H−シクロプロパ[e]アズレン;(E)−ウンデカ−9−エナール;メチル(E)−2−(((3,5−ジメチルシクロヘキサ−3−エン−1−イル)メチレン)アミノ)ベンゾエート;2,6,10−トリメチルウンデカ−9−エナール;(7,7,8,8−テトラメチルオクタヒドロ−2,3b−メタノシクロペンタ[1,3]シクロプロパ[1,2]ベンゼン−4−イル)メチルアセテート;ノニルアセテート;(2−(1−プロポキシエトキシ)エチル)ベンゼン;((1−(2−メトキシエトキシ)エトキシ)メチル)ベンゼン;(Z)−2−(4−メチルベンジリデン)ヘプタナール;(Z)−オキサシクロヘプタデカ−8−エン−2−オン;(2S,4aR,8aR)−4a,8−ジメチル−2−(プロパ−1−エン−2−イル)−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;2−((2S,4aR,8aR)−4a,8−ジメチル−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン−2−イル)プロパン−2−オール;1−(3,5,5,6,8,8−ヘキサメチル−5,6,7,8−テトラヒドロナフタレン−2−イル)エタン−1−オン;6−イソプロピルキノリン;3−(6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−イル)プロパナール;6,10,14−トリメチルペンタデカン−2−オン;2−メチル−5−(プロパ−1−エン−2−イル)−2−ビニルテトラヒドロフラン;(E)−シクロヘキサデカ−5−エン−1−オン;1−イソプロピル−4−メチルシクロヘキサ−3−エン−1−オール;1−イソプロピル−4−メチルシクロヘキサ−3−エン−1−オール;3,6−ジメチル−4,5,6,7−テトラヒドロベンゾフラン;4−(4−メトキシフェニル)ブタン−2−オン;(1aR,2S,4aS)−2,4a,8,8−テトラメチルオクタヒドロシクロプロパ[d]ナフタレン−3(1H)−オン;(Z)−ドデカ−2−エナール;3−メチル−5−フェニルペンタナール;(E)−ヘキサ−3−エン−1−イル3−メチルブタノエート;3,6−ジメチルオクタン−3−イルアセテート;3−(4−イソプロピルフェニル)プロパナール;(Z)−ウンデカ−2−エンニトリル;(E)−ウンデカ−2−エナール;フェネチルブチラート;(Z)−3−(フラン−2−イル)−2−フェニルアクリルアルデヒド;2−イソブチルキノリン;(E)−2−ヘキシリデンシクロペンタン−1−オン;2−ヘプチルテトラヒドロフラン;2,6−ジメチルオクタナール;デカン−1−オール;ウンデカ−10−エン−1−オール;ウンデカ−10−エナール;2−((2R,4aS)−4a,8−ジメチル−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン−2−イル)プロパン−2−オール;1−イソプロピル−4−メチル−7−チアビシクロ[2.2.1]ヘプタン;(3E,5Z)−ウンデカ−1,3,5−トリエン;3,7−ジメチルオクタ−6−エン−3−オール;1,3,3−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;1,1,2,3,3−ペンタメチル−2,3−ジヒドロ−1H−インデン;(Z)−6,10−ジメチルウンデカ−5,9−ジエン−2−イルアセテート;(Z)−ドデカ−3−エナール;(S)−5−ヘプチルジヒドロフラン−2(3H)−オン;(R)−5−ヘプチルジヒドロフラン−2(3H)−オン;(E)−6,10−ジメチルウンデカ−5,9−ジエン−2−イルアセテート;(Z)−3−メチル−5−フェニルペンタ−2−エンニトリル;(2S,5S,6S)−2,6,10,10−テトラメチル−1−オキサスピロ[4.5]デカン−6−オール;
(2E)−3−メチル−5−フェニル−2−ペンテンニトリル;
(1S,2S,5S)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサン−1−オール;(2S,5R)−2−イソプロピル−5−メチルシクロヘキサン−1−オン;(R,E)−2−メチル−4−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−ブタ−2−エン−1−オール;2−(8−イソプロピル−6−メチルビシクロ[2.2.2]オクタ−5−エン−2−イル)−1,3−ジオキソラン;(E)−4−(2,2−ジメチル−6−メチレンシクロヘキシル)−3−メチル−ブタ−3−エン−2−オン;3−(3−イソプロピルフェニル)ブタナール;3−(1−エトキシエトキシ)−3,7−ジメチルオクタ−1,6−ジエン;3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルプロピオネート;2−((3S,3aS,5R)−3,8−ジメチル−1,2,3,3a,4,5,6,7−オクタヒドロアズレン−5−イル)プロパン−2−オール;ベンジル2−フェニルアセテート;2−ヒドロキシ−1,2−ジフェニルエタン−1−オン;(E)−1,2,4−トリメトキシ−5−(プロパ−1−エン−1−イル)ベンゼン;3−(6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−イル)−2,2−ジメチルプロパナール;2−メチル−5−(6−メチルヘプト−5−エン−2−イル)ビシクロ[3.1.0]ヘキサ−2−エン;1−(1,1,2,3,3,6−ヘキサメチル−2,3−ジヒドロ−1H−インデン−5−イル)エタン−1−オン;(E)−トリデカ−2−エナール;(1R,4S,4aS,6R,8aS)−4,8a,9,9−テトラメチルオクタヒドロ−1,6−メタノナフタレン−1(2H)−オール;p−トリルイソブチラート;p−トリルフェニルアセテート;5−ヘキシル−4−メチルジヒドロフラン−2(3H)−オン;エチル(2Z,4E)−デカ−2,4−ジエノアート;2,4−ジメチル−6−フェニル−3,6−ジヒドロ−2H−ピラン;2−シクロヘキシリンデン−2−フェニルアセトニトリル;4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−カルバルデヒド;(4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−イル)メチルアセテート;(4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−イル)メタノール;(2−イソプロポキシエチル)ベンゼン;2−シクロヘキシルヘプタ−1,6−ジエン−3−オン;(2−(シクロヘキシルオキシ)エチル)ベンゼン;フェネチル2−メチルブタノエート;フェネチル2−フェニルアセテート;3−メチル−5−フェニルペンタン−1−オール;安息香酸フェニル;安息香酸フェネチル;2−(6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−イル)アセトアルデヒド;6,6−ジメチル−2−メチレンビシクロ[3.1.1]ヘプタン−3−オール;4−(ベンゾ[d][1,3]ジオキソール−5−イル)ブタン−2−オン;3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルピバレート;(4aR,8aS)−7−メチルオクタヒドロ−1,4−メタノナフタレン−6(2H)−オン;4−イソプロピル−1−メチルシクロヘキサ−3−エン−1−オール;(E)−3,3−ジメチル−5−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ペンタ−4−エン−2−オール;1−メチル−4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−カルバルデヒド;p−トリル2−フェニルアセテート;エチル2,4,7−デカトリエノアート;2−ベンジル−4,4,6−トリメチル−1,3−ジオキサン;2,4−ジメチル−4−フェニルテトラヒドロフラン;(2R,4a’R,8a’R)−3,7’−ジメチル−3’,4’,4a’,5’,8’,8a’−ヘキサヒドロ−1’H−スピロ[オキシラン−2,2’−[1,4]メタノナフタレン];(Z)−6−エチリデンオクタヒドロ−2H−5,8−メタノクロメン;2−((S)−1−((S)−3,3−ジメチルシクロヘキシル)エトキシ)−2−オキソエチルプロピオネート;メチル2,2−ジメチル−6−メチレンシクロヘキサン−1−カルボキシラート;2−メチル−5−フェニルペンタン−1−オール;4−メチル−2−フェニル−3,6−ジヒドロ−2H−ピラン;(1S,3R,5S)−1−イソプロピル−4−メチレンビシクロ[3.1.0]ヘキサン−3−オール;2,2,7,9−テトラメチルスピロ(5.5)ウンデカ−8−エン−1−オン;3−メチル−5−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ペンタン−2−オール;(Z)−2−エチル−4−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−ブタ−2−エン−1−オール;(E)−2−メチル−4−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−ブタ−2−エン−1−オール;5−メトキシオクタヒドロ−1H−4,7−メタノインデン−2−カルバルデヒド;5−メトキシオクタヒドロ−1H−4,7−メタノインデン−2−カルバルデヒド;1−(3−ヒドロキシ−3−メチルペンタ−4−エン−1−イル)−2,5,5,8a−テトラメチルデカヒドロナフタレン−2−オール;(4aR,6aS,10aS,10bR)−3,4a,7,7,10a−ペンタメチル−4a,5,6,6a,7,8,9,10,10a,10b−デカヒドロ−1H−ベンゾ[f]クロメン;(4aR,8aR)−4a,8−ジメチル−2−(プロパン−2−イリデン)−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;2−(1−(3,3−ジメチルシクロヘキシル)エトキシ)−2−メチルプロピルシクロプロパンカルボキシラート;3−(4−イソブチルフェニル)−2−メチルプロパナール;(1aR,4aR,7S,7aR,7bR)−1,1,7−トリメチル−4−メチレンデカヒドロ−1H−シクロプロパ[e]アズレン−7−オール;(1R,3R,6R)−2’,2’,3,7,7−ペンタメチルスピロ[ビシクロ[4.1.0]ヘプタン−2,5’−[1,3]ジオキサン];2−メチル−1,5−ジオキサスピロ[5.5]ウンデカン;1−(スピロ[4.5]デカ−7−エン−7−イル)ペンタ−4−エン−1−オン;2−(ヘプタン−3−イル)−1,3−ジオキソラン;(Z)−ドデカ−4−エナール;(1S,4S,4aR,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;(1S,4S,4aR,8aS)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;3−メチル−2−ペンチルシクロペンタン−1−オン;2,6,10,10−テトラメチル−1−オキサスピロ[4.5]デカ−6−エン;2−(2−メルカプトプロパン−2−イル)−5−メチルシクロヘキサン−1−オン;(1aR,4aS)−2,4a,8,8−テトラメチル−1,1a,4,4a,5,6,7,8−オクタヒドロシクロプロパ[d]ナフタレン;1−イソプロピル−2−メトキシ−4−メチルベンゼン;1−(2,2,6−トリメチルシクロヘキシル)ヘキサン−3−オール;(2E,6E)−3,7,11−トリメチルドデカ−2,6,10−トリエン−1−オール;(Z)−オキサシクロヘプタデカ−8−エン−2−オン;メチル2−((1S,2S)−3−オキソ−2−ペンチルシクロペンチル)アセテート;7−(1,1−ジメチルエチル)−2H−1,5−ベンゾジオキセピン−3(4H)−オン;(1R−(1α,3α,4aα))−2,3,4,4a,5,6−ヘキサヒドロ−2,2−ジメチル−1,3−メタノナフタレン−7(1H)−オン;トリデカン−1−オール;トリエチル2−ヒドロキシプロパン−1,2,3−トリカルボキシラート;メチル2−((1−ヒドロキシ−3−フェニルブチル)アミノ)ベンゾエート;1−((2E,5Z,9Z)−2,6,10−トリメチルシクロドデカ−2,5,9−トリエン−1−イル)エタン−1−オン;デカヒドロ−2,6,6,7,8,8−ヘキサメチル−2h−インデノ(4,5−b)フラン;13−メチルオキサシクロペンタデカ−10−エン−2−オン;ウンデカナール;(E)−4−メチルデカ−3−エン−5−オール;(3R,4aS,5R)−4a,5−ジメチル−3−(プロパ−1−エン−2−イル)−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン;2−((2R,8R,8aS)−8,8a−ジメチル−1,2,3,4,6,7,8,8a−オクタヒドロナフタレン−2−イル)プロパン−2−オール;4−ホルミル−2−メトキシフェニルイソブチラート;(Z)−2−メチル−4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタ−2−エナール;メチル2,4−ジヒドロキシ−3,6−ジメチルベンゾエート;1−メトキシ−3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン;メチル(Z)−2−((3−(4−(tert−ブチル)フェニル)−2−メチルプロピリデン)アミノ)ベンゾエート;(Z)−ヘキサ−3−エン−1−イルイソブチラート;2,4,6−トリメチル−4−フェニル−1,3−ジオキサン;1−((3R,3aR,7R,8aS)−3,6,8,8−テトラメチル−2,3,4,7,8,8a−ヘキサヒドロ−1H−3a,7−メタノアズレン−5−イル)エタン−1−オン;メチル(Z)−2−(((2,4−ジメチルシクロヘキサ−3−エン−1−イル)メチレン)アミノ)ベンゾエート;4,8−ジメチル−2−(プロパン−2−イリデン)−1,2,3,3a,4,5,6,8a−オクタヒドロアズレン−6−オール;4,8−ジメチル−2−(プロパン−2−イリデン)−1,2,3,3a,4,5,6,8a−オクタヒドロアズレン−6−イルアセテート;デカヒドロ−3H−スピロ[フラン−2,5’−[4,7]メタノインデン];(Z)−シクロオクタ−4−エン−1−イルメチルカーボネート;(1aR,4S,4aS,7R,7aS,7bS)−1,1,4,7−テトラメチルデカヒドロ−1H−シクロプロパ[e]アズレン−4−オール;3,5,5,6,7,8,8−ヘプタメチル−5,6,7,8−テトラヒドロナフタレン−2−カルボニトリル;(1S,2S,3S,5R)−2,6,6−トリメチルスピロ[ビシクロ[3.1.1]ヘプタン−3,1’−シクロヘキサン]−2’−エン−4’−オン;1’,1’,5’,5’−テトラメチルヘキサヒドロ−2’H,5’H−スピロ[[1,3]ジオキソラン−2,8’−[2,4a]メタノナフタレン];(2’S,4a’S,8a’S)−1’,1’,5’,5’−テトラメチルヘキサヒドロ−2’H,5’H−スピロ[[1,3]ジオキソラン−2,8’−[2,4a]メタノナフタレン];4−(4−ヒドロキシ−3−メトキシフェニル)ブタン−2−オン;(1R,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,7,8,8a−ヘキサヒドロナフタレン;4,5−エポキシ−4,11,11−トリメチル−8−メチレンビシクロ(7.2.0)ウンデカン;1,3,4,6,7,8α−ヘキサヒドロ−1,1,5,5−テトラメチル−2H−2,4α−メタノフタレン−8(5H)−オン;2,4−ジメチル−2−(5,5,8,8−テトラメチル−5,6,7,8−テトラヒドロナフタレン−2−イル)−1,3−ジオキソラン;3a,5,6,7,8,8b−ヘキサヒドロ−2,2,6,6,7,8,8−ヘプタメチル−4H−インデノ(4,5−d)−1,3−ジオキソール;2,4−ジメチル−4,4a,5,9b−テトラヒドロインデノ[1,2−d][1,3]ジオキシン;(1−メチル−2−((1,2,2−トリメチルビシクロ[3.1.0]ヘキサン−3−イル)メチル)シクロプロピル)メタノール;2−(シクロヘキシルオキシ)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン;4−((2R)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イル)シクロヘキサン−1−オール;
8,8−ジ(1H−インドール−1−イル)−2,6−ジメチルオクタン−2−オール;(7,7,8,8−テトラメチルオクタヒドロ−2,3b−メタノシクロペンタ[1,3]シクロプロパ[1,2]ベンゼン−4−イル)メタノール;8,8−ジメチル−3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン−6−イルプロピオネート;(E)−4−((3aR,4R,7R,7aR)−1,3a,4,6,7,7a−ヘキサヒドロ−5H−4,7−メタノインデン−5−イリデン)−3−メチルブタン−2−オール;3R,3aR,6S,7S,8aS)−6−メトキシ−3,6,8,8−テトラメチルオクタヒドロ−1H−3a,7−メタノアズレン;(1R,2S,6S,7S,8S)−8−イソプロピル−1−メチル−3−メチレントリシクロ[4.4.0.02,7]デカン;2’−イソプロピル−1,7,7−トリメチルスピロ[ビシクロ[2.2.1]ヘプタン−2,4’−[1,3]ジオキサン];(4aR,5R,7aS,9R)−2,2,5,8,8,9a−ヘキサメチルオクタヒドロ−4H−4a,9−メタノアズレノ[5,6−d][1,3]ジオキソール;(3S,5aR,7aS,11aS,11bR)−3,8,8,11a−テトラメチルドデカヒドロ−5H−3,5a−エポキシナフト[2,1−c]オキセピン;2,2,6,6,7,8,8−ヘプタメチルデカヒドロ−2H−インデノ[4,5−b]フラン;(1aS,2aR,3R,5aS,7R,7aR)−3,6,6,7a−テトラメチルオクタヒドロ−2H−2a,7−メタノアズレノ[5,6−b]オキシレン;(7,7,8,8−テトラメチルオクタヒドロ−2,3b−メタノシクロペンタ[1,3]シクロプロパ[1,2]ベンゼン−4−イル)メチルアセテート;1−(3−ヒドロキシ−3−メチルペンタ−4−エン−1−イル)−2,5,5,8a−テトラメチルデカヒドロナフタレン−2−オール;デカヒドロ−2,6,6,7,8,8−ヘキサメチル−2h−インデノ(4,5−b)フラン;2−エチルヘキシル(Z)−3−(4−メトキシフェニル)アクリレート;メトキシシクロドデカン;1−エトキシ−4−(tert−ペンチル)シクロヘキサン;(2−ヒドロキシ−4−メトキシフェニル)(フェニル)メタノン;(3Z)−1−(2−ブテン−1−イルオキシ)−3−ヘキセン;4−(2−メトキシプロパン−2−イル)−1−メチルシクロヘキサ−1−エン;4−(tert−ペンチル)シクロヘキサン−1−オン;3−メトキシ−3,7−ジメチルオクタ−1,6−ジエン;7−イソプロピル−8,8−ジメチル−6,10−ジオキサスピロ[4.5]デカン;3,7−ジメチルオクタナール;1,1−ジメトキシオクタン;2−メチル−6−メチレンオクタ−7−エン−2−オール;4−メトキシ−6−プロパ−2−エニル−1,3−ベンゾジオキソール;テトラデカンニトリル;(E)−2,7−ジメチルオクタ−1,5,7−トリエン−3−オール;3,3−ジメチル5(2,2,3−トリメチル−3−シクロペンテン−1イル)−4−ペンテン−2−オール;ヘキシル2−ヒドロキシベンゾエート;ヘキシル(Z)−ブタ−2−エノアート;(Z)−3,7−ジメチルオクタ−2,6−ジエン−1−イルホルメート;1−エチル−3−メトキシトリシクロ[2.2.1.02,6]ヘプタン;10−イソプロピル−2,7−ジメチル−1−オキサスピロ[4.5]デカ−3,6−ジエン;6,6−ジメチルビシクロ[3.1.1]ヘプタ−2−エン−2−カルバルデヒド;(E)−4−(2,2,3,6−テトラメチルシクロヘキシル)−ブタ−3−エン−2−オン;(Z)−1−(2,6,6−トリメチルシクロヘキサ−1−エン−1−イル)ペンタ−1−エン−3−オン;(E)−2,2−ジメチル−3−(3−メチルペンタ−2,4−ジエン−1−イル)オキシラン;3−メチルシクロペンタデカン−1−オン;(E)−3,7−ジメチルオクタ−4,6−ジエン−3−オール;1−(4−イソプロピルシクロヘキシル)エタン−1−オール;(E)−デカ−5−エン酸;1−フェニルエチルプロピオネート;ステアリン酸メチル;メチル(9Z,12Z)−オクタデカ−9,12−ジエノアート;1−ヒドロキシデカン−3−オン;パルミチン酸メチル;メチル(Z)−3,7−ジメチルオクタ−2,6−ジエノアート;1−メチル−2−フェノキシベンゼン;6−メトキシ−2,6−ジメチルヘプタナール;7−メトキシ−3,7−ジメチルオクタナール;((1s,4s)−4−イソプロピルシクロヘキシル)メタノール;3−(3−(tert−ブチル)フェニル)−2−メチルプロパナール;(E)−4−(4,8−ジメチルノナ−3,7−ジエン−1−イル)ピリジン;(E)−トリデカ−3,12−ジエンニトリル;2,2−ジメチル−3−(m−トリル)プロパン−1−オール;8−イソプロピル−6−メチルビシクロ[2.2.2]オクタ−5−エン−2−カルバルデヒド;4−(4−ヒドロキシ−4−メチルペンチル)シクロヘキサ−3−エン−1−カルバルデヒド;3,7−ジメチルオクタ−1,6−ジエン−3−イルプロピオネート;3,7−ジメチルオクタ−1,6−ジエン−3−イルオクタノエート;3,7−ジメチルオクタ−1,6−ジエン−3−イルホルメート;3,7−ジメチルオクタ−1,6−ジエン−3−イルブチラート;3,7−ジメチルオクタ−1,6−ジエン−3−イルベンゾエート;3,7−ジメチルオクタ−1,6−ジエン−3−イル2−アミノベンゾエート;3,7−ジメチルオクタ−1,6−ジエン−3−イルアセテート;3,7−ジメチルオクタ−1,6−ジエン−3−オール;3−(4−メチルシクロヘキサ−3−エン−1−イル)ブタナール;3−(4−(tert−ブチル)フェニル)−2−メチルプロパナール;(E)−1−(1−メトキシプロポキシ)ヘキサ−3−エン;2−メチル−5−(1−メチルエテニル)−2−シクロヘキセノン;ドデカナール;2,2−ジメチル−5−フェニルヘキサンニトリル;2−ヘキシルシクロペンタン−1−オン;(Z)−4−(6,6−ジメチルシクロヘキサ−2−エン−1−イル)−3−メチル−ブタ−3−エン−2−オン;2,6,9,10−テトラメチル−1−オキサスピロ(4.5)デカ−3,6−ジエン;パルミチン酸イソプロピル;イソプロピルドデカノアート;イソプロピル2−メチルブタノエート;4−メチルペンタ−4−エン−2−イルイソブチラート;7−メチルオクチルアセテート;4−(4−メチルペンタ−3−エン−1−イル)シクロヘキサ−3−エン−1−カルバルデヒド;(Z)−2−メトキシ−4−(プロパ−1−エン−1−イル)フェニルアセテート;(1R,2R,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルプロピオネート;(1R,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−オール;2−(4−イソプロピルシクロヘキサ−1,4−ジエン−1−イル)エチルホルメート;イソペンチル(E)−ウンデカ−6−エノアート;イソペンチルオクタノエート;イソペンチルドデカノアート;イソペンチルイソブチラート;(E)−オキサシクロヘプタデカ−10−エン−2−オン;8,8−ジ(1H−インドール−1−イル)−2,6−ジメチルオクタン−2−オール;2−シクロドデシルプロパン−1−オール;(1,1−ジメトキシプロパン−2−イル)ベンゼン;酪酸ヘキシル;ヘキシル2−メチルブタノエート;ヘキシルフラン−2−カルボキシラート;オキサシクロヘプタデカン−2−オン;2−(1−(3,3−ジメチルシクロヘキシル)エトキシ)−2−メチルプロピルプロピオネート5−(ジエトキシメチル)ベンゾ[d][1,3]ジオキソール;3−(ベンゾ[d][1,3]ジオキソール−5−イル)−2−メチルプロパナール;(E)−オキサシクロヘキサデカ−13−エン−2−オン;6−ブチル−2,4−ジメチル−3,6−ジヒドロ−2H−ピラン;2−((3S,5R,8S)−3,8−ジメチル−1,2,3,4,5,6,7,8−オクタヒドロアズレン−5−イル)プロパン−2−オール;1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ペンタン−3−オン;(1Z,5Z)−1,5−ジメチル−8−(プロパン−2−イリデン)シクロデカ−1,5−ジエン;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イル2−フェニルアセテート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イル2−フェニルアセテート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イルホルメート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イルオクタノエート;(E)−3,7−ジメチルオクタ−2,6−ジエン−1−イルベンゾエート;N,2−ジメチル−N−フェニルブタンアミド;1−イソプロピル−4−メチルシクロヘキサ−1,4−ジエン;
(1R,4aR,8aS)−1−イソプロピル−7−メチル−4−メチレン−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;(4aS,9aR)−3,5,5,9−テトラメチル−2,4a,5,6,7,9a−ヘキサヒドロ−1H−ベンゾ[7]アヌレン;(Z)−1−(2,2−ジメチル−6−メチレンシクロヘキシル)−ブタ−2−エン−1−オン;(1R,4aS,8aS)−1−イソプロピル−7−メチル−4−メチレン−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;1−(3,3−ジメチルシクロヘキシル)ペンタ−4−エン−1−オン;フラン−2−イルメチルオクタノエート;フラン−2−イルメチルヘキサノエート;フラン−2−イルメチルヘプタノエート;エチル(3aR,4S,7R,7aR)−オクタヒドロ−3aH−4,7−メタノインデン−3a−カルボキシラート;3−(2−エチルフェニル)−2,2−ジメチルプロパナール;2−(tert−ブチル)シクロヘキシルエチルカーボネート;3−(2−エチルフェニル)−2,2−ジメチルプロパナール;(E)−4,8−ジメチルデカ−4,9−ジエナール;3−(4−エチルフェニル)−2,2−ジメチルプロパンニトリル;2−ヘプチルシクロペンタン−1−オン;1−エトキシエトキシシクロドデカン;1,3,3−トリメチルビシクロ[2.2.1]ヘプタン−2−オール;オキサシクロヘキサデカン−2−オン;(E)−シクロペンタデカ−4−エン−1−オン;1−シクロペンタデカ−4−エン−1−オン;4−アリル−2−メトキシフェニルアセテート;1,3,3−トリメチル−2−オキサビシクロ[2,2,2]オクタン;エチル3−メチル−3−フェニルオキシラン−2−カルボキシラート;1,4−ジオキサシクロヘプタデカン−5,17−ジオン;2−エトキシ−4−ホルミルフェニルアセテート;エチルウンデカ−10−エノアート;パルミチン酸エチル;オクタン酸エチル;エチルテトラデカノアート;(E)−3,7−ジメチルノナ−1,6−ジエン−3−オール;エチル3−フェニルオキシラン−2−カルボキシラート;エチル2−シクロヘキシルプロパノエート;6−エチル−2,10,10−トリメチル−1−オキサスピロ[4.5]デカ−3,6−ジエン;(2R,3S,4R)−2,3,4,5−テトラヒドロキシペンタナール;(E)−4−((3aS,7aS)−オクタヒドロ−5H−4,7−メタノインデン−5−イリデン)ブタナール;(2R,5R)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサン−1−オン;4−メチル−2−フェニルテトラヒドロ−2H−ピラン;2−メチル−1−フェニルプロパン−2−イルブチラート;2,6−ジメチルオクタ−7−エン−2−オール;3−メチル−2−ペンチルシクロペンタ−2−エン−1−オン;3,3,5−トリメチルシクロヘキサン−1−オン;2−メトキシ−4−プロピルフェノール;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサン−1−オン;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキシルアセテート;2−(4−メチルシクロヘキシル)プロパン−2−イルアセテート;
4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ブタン−2−オン;(オキシビス(メチレン))ジベンゼン;フタル酸ジブチル;1,2−ジフェニルエタン;(3R,4R)−1−イソプロピル−4−メチル−3−(プロパ−1−エン−2−イル)−4−ビニルシクロヘキサ−1−エン;(1S,8aR)−4,7−ジメチル−1−(プロパン−2−イル)−1,2,3,5,6,8a−ヘキサヒドロナフタレン;((1S,8aS)−1−イソプロピル−4,7−ジメチル−1,2,3,5,6,8a−ヘキサヒドロナフタレン;デシル2−アミノベンゾエート;メチル(1s,4s)−1,4−ジメチルシクロヘキサン−1−カルボキシラート;3−(4−イソプロピルフェニル)−2−メチルプロパナール;シクロテトラデカン;シクロペンタデカノン;2−シクロヘキシルエチルアセテート;シクロヘキシル2−ヒドロキシベンゾエート;1,4−ジオキサシクロヘキサデカン−5,16−ジオン;(4−イソプロピルフェニル)メタノール;4−シクロヘキシル−2−メチルブタン−2−オール;2−(3−フェニルプロピル)ピリジン;3−(4−メチルシクロヘキサ−3−エン−1−イル)−ブタ−3−エン−1−イルアセテート;3−(4−メチルシクロヘキサ−3−エン−1−イル)ブタン−1−オール;2−ベンジル−2−メチルブタ−3−エンニトリル;3,7−ジメチルオクタ−6−エン−1−イル2−フェニルアセテート;3,7−ジメチルオクタ−6−エン−1−イルホルメート;3,7−ジメチルオクタ−6−エン−1−イルベンゾエート;3,7−ジメチルオクタ−6−エン−1−オール;3,7−ジメチルオクタ−6−エナール;(1R,2S,5R)−2,6,6−トリメチルビシクロ[3.1.1]ヘプタン;(Z)−3−メチル−2−(ペンタ−2−エン−1−イル)シクロペンタ−2−エン−1−オン;(E)−オキサシクロヘプタデカ−11−エン−2−オン;(Z)−ヘキサ−3−エン−1−イルペンタノエート;(E)−ヘキサ−3−エン−1−イル(E)−2−メチル−ブタ−2−エノアート;(Z)−ヘキサ−3−エン−1−イル2−ヒドロキシベンゾエート;(Z)−ヘキサ−3−エン−1−イルブチラート;(Z)−ヘキサ−3−エン−1−イルベンゾエート;(Z)−ヘキサ−3−エン−1−イル2−メチルブタノエート;イソ酪酸シンナミル;4−クロロ−3,5−ジメチルフェノール;ヘキサデカン−1−オール;(E)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ヘプタ−1,6−ジエン−3−オン;2−メチル−4−(2,6,6−トリメチルシクロヘキサ−1−エン−1−イル)ブタナール;(3aR,5aR,9aR,9bR)−3a,6,6,9a−テトラメチルドデカヒドロナフト[2,1−b]フラン;(4Z,8Z)−1,5,9−トリメチル−13−オキサビシクロ[10.1.0]トリデカ−4,8−ジエン;5−メチル−1−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)−6−オキサビシクロ[3.2.1]オクタン;1,1,2,3,3−ペンタメチル−1,2,3,5,6,7−ヘキサヒドロ−4H−インデン−4−オン;5−イソプロピル−2−メチルフェノール;2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサ−2−エン−1−オン;2−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)アセトニトリル;1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−オン;2,2−ジメチル−3−メチレンビシクロ[2.2.1]ヘプタン;2,6−ジ−tert−ブチル−4−メチルフェノール;ステアリン酸ブチル;ブチルウンデカ−10−エノアート;2−メチル−4−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ブタン−1−オール;(E)−2−メチル−4−(2,6,6−トリメチルシクロヘキサ−1−エン−1−イル)−ブタ−2−エナール;1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;(1S,2R,4S)−1,7,7−トリメチルビシクロ[2.2.1]ヘプタン−2−オール;3,3,6,7−テトラメチルオクタヒドロ−2H−クロメン;6,6−ジメチルスピロ[ビシクロ[3.1.1]ヘプタン−2,2’−オキシラン];3−イソプロピル−6−メチレンシクロヘキサ−1−エン;2−エトキシナフタレン;(R)−3,5,5,9−テトラメチル−2,4a,5,6,7,8−ヘキサヒドロ−1H−ベンゾ[7]アヌレン;(1S,4S)−1,4−ジメチル−7−(プロパン−2−イリデン)−1,2,3,4,5,6,7,8−オクタヒドロアズレン;(1R,9S,Z)−4,11,11−トリメチル−8−メチレンビシクロ[7.2.0]ウンデカ−4−エン;(Z)−4−(2,2,6−トリメチル−7−オキサビシクロ[4.1.0]ヘプタン−1−イル)−ブタ−3−エン−2−オン;4−メトキシ−7H−フロ[3,2−g]クロメン−7−オン;ベンジル2−ヒドロキシベンゾエート;ドデカン酸ベンジル;ベンジル3−メチルブタノエート;ベンジルイソブチラート;ケイ皮酸ベンジル;酪酸ベンジル;安息香酸ベンジル;1−(3,3−ジメチルシクロヘキシル)エチルホルメート;ペンチルベンゾエート;(3aR,5aS,9aS,9bR)−3a,6,6,9a−テトラメチルドデカヒドロナフト[2,1−b]フラン;2,5,5−トリメチル−1,2,3,4,5,6,7,8−オクタヒドロナフタレン−2−オール;2,5,5−トリメチル−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン−2−オール;2−(sec−ブチル)−1−ビニルシクロヘキシルアセテート;(1S,4R,5R)−1−イソプロピル−4−メチルビシクロ[3.1.0]ヘキサン−3−オン;2−(4−メチルシクロヘキサ−3−エン−1−イル)プロパン−2−イルプロピオネート;2−(4−メチルシクロヘキサ−3−エン−1−イル)プロパン−2−イルアセテート;1,7−ジメチル−7−(4−メチルペンタ−3−エン−1−イル)トリシクロ[2.2.1.02,6]ヘプタン;1−(5,5−ジメチルシクロヘキサ−1−エン−1−イル)ペンタ−4−エン−1−オン;(1S,4aS,8aR)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;(R,Z)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)ペンタ−1−エン−3−オン;(Z)−3−メチル−4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタ−3−エン−2−オン;(Z)−4−(2,5,6,6−テトラメチルシクロヘキサ−2−エン−1−イル)−ブタ−3−エン−2−オン;(1Z,4E,8Z)−2,6,6,9−テトラメチルシクロウンデカ−1,4,8−トリエン;(4aR,8S,9aS)−3,5,5,8−テトラメチル−9−メチレン−2,4a,5,6,7,8,9,9a−オクタヒドロ−1H−ベンゾ[7]アヌレン;(1R,4S,4aR,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;1S,4aR,8aR)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;(R)−2−((R)−4−メチルシクロヘキサ−3−エン−1−イル)ヘキサ−5−エン−2−オール;(E)−2−ベンジリデンヘプチルアセテート;(1S,4aR,8aS)−1−イソプロピル−4,7−ジメチル−1,2,4a,5,6,8a−ヘキサヒドロナフタレン;4−メトキシ−2,5−ジメチルフラン−3(2H)−オン;α−4−ジメチルベンゼンプロパナール;アリルヘプタノエート;アリル3−シクロヘキシルプロパノエート;N−エチル−N−(m−トリル)プロピオンアミド;2,6,10−トリメチルウンデカ−9−エナール;(Z)−2−(4−メチルベンジリデン)ヘプタナール;(Z)−オキサシクロヘプタデカ−8−エン−2−オン;6,8−ジメチルノナン−2−オール;6,10,14−トリメチルペンタデカン−2−オン;5−メチル−5−フェニルヘキサン−3−オン;4−(4−メトキシフェニル)ブタン−2−オン;(Z)−ドデカ−2−エナール;3−メチル−5−フェニルペンタナール;3,7−ジメチル−2−メチレンオクタ−6−エナール;3,7−ジメチルオクタン−1−オール;(Z)−ウンデカ−2−エンニトリル;(E)−ウンデカ−2−エナール;(Z)−3−(フラン−2−イル)−2−フェニルアクリルアルデヒド;フェネチルプロピオネート;(2S,4S)−2−ヘプチル−2,4−ジメチル−1,3−ジオキソラン;2−イソプロピル−N,2,3−トリメチルブタンアミド;(E)−2−イソプロピル−5−メチルヘキサ−2−エナール;2−イソプロピル−4−メチルチアゾール;(E)−2−ヘキシリデンシクロペンタン−1−オン;1−イソプロピル−4−メチル−7−オキサビシクロ[2.2.1]ヘプタン;1,3,3−トリメチルビシクロ[2.2.1]ヘプタン−2−イルアセテート;1,1,2,3,3−ペンタメチル−2,3−ジヒドロ−1H−インデン;(Z)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタ−2−エン−1−オン;(Z)−6,10−ジメチルウンデカ−5,9−ジエン−2−イルアセテート;(1S,5S)−4,6,6−トリメチルビシクロ[3.1.1]ヘプタ−3−エン−2−オン;(R)−3,7−ジメチルオクタ−1,6−ジエン−3−オール;3,7−ジメチルオクタ−6−エナール;(E)−6,10−ジメチルウンデカ−5,9−ジエン−2−イルアセテート;(R)−3,7−ジメチルオクタ−6−エナール;(2S,5S,6S)−2,6,10,10−テトラメチル−1−オキサスピロ[4.5]デカン−6−オール;3,7−ジメチルオクタ−6−エン−1−オール;3,7−ジメチルオクタ−6−エン−1−オール;(1R,5R)−2,6,6−トリメチルビシクロ[3.1.1]ヘプタ−2−エン;(S)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサ−2−エン−1−オン;(1S,5S)−2,6,6−トリメチルビシクロ[3.1.1]ヘプタ−2−エン;ヘキシル(Z)−2−メチル−ブタ−2−エノアート;2−(8−イソプロピル−6−メチルビシクロ[2.2.2]オクタ−5−エン−2−イル)−1,3−ジオキソラン;3−(3−イソプロピルフェニル)ブタナール;アリル2−(シクロヘキシルオキシ)アセテート;2−((3S,3aS,5R)−3,8−ジメチル−1,2,3,3a,4,5,6,7−オクタヒドロアズレン−5−イル)プロパン−2−オール;1,5−ジメチルビシクロ[3.2.1]オクタン−8−オンオキシム;ベンジル2−フェニルアセテート;2−ヒドロキシ−1,2−ジフェニルエタン−1−オン;(E)−トリデカ−2−エナール;p−トリルイソブチラート;p−トリルフェニルアセテート;p−シメン;5−ヘキシル−4−メチルジヒドロフラン−2(3H)−オン;2−シクロヘキシリンデン−2−フェニルアセトニトリル;4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−カルバルデヒド;(4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−イル)メチルアセテート;(4−(プロパ−1−エン−2−イル)シクロヘキサ−1−エン−1−イル)メタノール;(2−(シクロヘキシルオキシ)エチル)ベンゼン;フェネチル2−メチルブタノエート;フェネチルイソブチラート;フェネチル2−フェニルアセテート;フェネチル(Z)−2−メチル−ブタ−2−エノアート;安息香酸フェニル;安息香酸フェネチル;フェニルエチルメタクリレート;1,2−ジメチル−3−(プロパ−1−エン−2−イル)シクロペンタン−1−オール;(2Z,5Z)−5,6,7−トリメチルオクタ−2,5−ジエン−4−オン;2−(4−(tert−ブチル)フェニル)アセトアルデヒド;4−(tert−ペンチル)シクロヘキサン−1−オール;p−トリル2−フェニルアセテート;
エチル2,4,7−デカトリエノアート;2,6,6−トリメチルビシクロ[3.1.1]ヘプタ−2−エン;2−ベンジル−4,4,6−トリメチル−1,3−ジオキサン;3,7−ジメチルオクタ−7−エン−1−オール;エチル(2,3,6−トリメチルシクロヘキシル)カーボネート;(Z)−6−エチリデンオクタヒドロ−2H−5,8−メタノクロメン;2−((S)−1−((S)−3,3−ジメチルシクロヘキシル)エトキシ)−2−オキソエチルプロピオネート;メチル2,2−ジメチル−6−メチレンシクロヘキサン−1−カルボキシラート;1−(3,3−ジメチルシクロヘキシル)エチルアセテート;(S)−3,7−ジメチルオクタ−1,6−ジエン−3−オール;1−イソプロピル−4−メチレンビシクロ[3.1.0]ヘキサン;5−イソプロピル−2−メチルビシクロ[3.1.0]ヘキサン−2−オール;(1S,3R,5S)−1−イソプロピル−4−メチレンビシクロ[3.1.0]ヘキサン−3−オール;3−メチル−5−(2,2,3−トリメチルシクロペンタ−3−エン−1−イル)ペンタン−2−オール;5−メトキシオクタヒドロ−1H−4,7−メタノインデン−2−カルバルデヒド;プロピル(S)−2−(tert−ペンチルオキシ)プロパノエート;(4aR,8aR)−4a,8−ジメチル−2−(プロパン−2−イリデン)−1,2,3,4,4a,5,6,8a−オクタヒドロナフタレン;2−(1−(3,3−ジメチルシクロヘキシル)エトキシ)−2−メチルプロピルシクロプロパンカルボキシラート;(1R,3R,6R)−2’,2’,3,7,7−ペンタメチルスピロ[ビシクロ[4.1.0]ヘプタン−2,5’−[1,3]ジオキサン];(Z)−5−メチルヘプタン−3−オンオキシム;(1S,4S,4aR,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;(1S,4S,4aR,8aS)−4−イソプロピル−1,6−ジメチル−1,2,3,4,4a,7,8,8a−オクタヒドロナフタレン−1−オール;3,7−ジメチルオクタナール;4−(2,2,6−トリメチルシクロヘキシル)ブタン−2−オール;3−メチル−2−ペンチルシクロペンタン−1−オン;3,7−ジメチルオクタン−3−オール;3,7−ジメチルオクタン−3−イルアセテート;2,6,10,10−テトラメチル−1−オキサスピロ[4.5]デカ−6−エン;エチル(1R,6S)−2,2,6−トリメチルシクロヘキサン−1−カルボキシラート;2−イソプロピル−5−メチルフェノール;1−イソプロピル−2−メトキシ−4−メチルベンゼン;1−(2,2,6−トリメチルシクロヘキシル)ヘキサン−3−オール;(1R,2S)−2−(tert−ブチル)シクロヘキサン−1−オール;(Z)−1−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタ−2−エン−1−オン;(Z)−オキサシクロヘプタデカ−8−エン−2−オン;(2R,5R)−2−メチル−5−(プロパ−1−エン−2−イル)シクロヘキサン−1−オン;2,2,2−トリクロロ−1−フェニルエチルアセテート;トリエチル2−ヒドロキシプロパン−1,2,3−トリカルボキシラート;メチル2−((1−ヒドロキシ−3−フェニルブチル)アミノ)ベンゾエート;1−((2E,5Z,9Z)−2,6,10−トリメチルシクロドデカ−2,5,9−トリエン−1−イル)エタン−1−オン;2−メルカプト−2−メチルペンタン−1−オール;13−メチルオキサシクロペンタデカ−10−エン−2−オン;ウンデカナール;(E)−4−メチルデカ−3−エン−5−オール;(3R,4aS,5R)−4a,5−ジメチル−3−(プロパ−1−エン−2−イル)−1,2,3,4,4a,5,6,7−オクタヒドロナフタレン;4−ホルミル−2−メトキシフェニルイソブチラート;2,2,5−トリメチル−5−ペンチルシクロペンタン−1−オン;(Z)−2−メチル−4−(2,6,6−トリメチルシクロヘキサ−2−エン−1−イル)−ブタ−2−エナール;(1R,5R)−4,6,6−トリメチルビシクロ[3.1.1]ヘプタ−3−エン−2−オン;1−メトキシ−3a,4,5,6,7,7a−ヘキサヒドロ−1H−4,7−メタノインデン;2−(tert−ブチル)シクロヘキサン−1−オール;シス−(4−tert−ブチルシクロヘキシル)アセテート;4−(tert−ブチル)シクロヘキシルアセテート;4−メチル−4−フェニルペンタン−2−イルアセテート;4,8−ジメチル−2−(プロパン−2−イリデン)−1,2,3,3a,4,5,6,8a−オクタヒドロアズレン−6−オール;(Z)−シクロオクタ−4−エン−1−イルメチルカーボネート;4−(4−ヒドロキシ−3−メトキシフェニル)ブタン−2−オン;(1R,8aR)−4−イソプロピル−1,6−ジメチル−1,2,3,7,8,8a−ヘキサヒドロナフタレン及びそれらの混合物からなる群から選択される悪臭低減物質を含む、請求項1〜4のいずれかに記載の送達系。 - 前記コアが1Pa(0.01トル)よりも大きい蒸気圧を有する1以上の悪臭低減物質を含む、請求項1〜3のいずれかに記載の送達系。
- 請求項1〜6のいずれか1項に記載の送達系を含む消費者向け製品。
- ある部位を処理又は洗浄する方法であって、前記方法が、
a)前記部位を所望により洗浄、すすぎ、又は乾燥する工程、
b)前記部位を請求項1〜6のいずれか1項に記載の送達系と接触させる工程;及び
c)前記部位を所望により洗浄、すすぎ、又は乾燥する工程を含む、方法。
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CN107001995A (zh) | 2014-09-26 | 2017-08-01 | 宝洁公司 | 包含恶臭减少组合物的清洁和/或处理组合物 |
WO2018100411A1 (fr) | 2016-11-30 | 2018-06-07 | Arcelormittal | Dispositif de connexion électrique d'installation photovoltaïque |
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