JP6859926B2 - 固体電解質、その製造方法、ガスセンサ - Google Patents
固体電解質、その製造方法、ガスセンサ Download PDFInfo
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- JP6859926B2 JP6859926B2 JP2017213346A JP2017213346A JP6859926B2 JP 6859926 B2 JP6859926 B2 JP 6859926B2 JP 2017213346 A JP2017213346 A JP 2017213346A JP 2017213346 A JP2017213346 A JP 2017213346A JP 6859926 B2 JP6859926 B2 JP 6859926B2
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- solid electrolyte
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- concentration
- phase particles
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- 239000007784 solid electrolyte Substances 0.000 title claims description 166
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 239000002245 particle Substances 0.000 claims description 339
- 239000000843 powder Substances 0.000 claims description 73
- 239000000463 material Substances 0.000 claims description 65
- 239000003381 stabilizer Substances 0.000 claims description 64
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 62
- 239000002994 raw material Substances 0.000 claims description 57
- 239000013078 crystal Substances 0.000 claims description 38
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 claims description 35
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 22
- 229910052596 spinel Inorganic materials 0.000 claims description 21
- 239000011029 spinel Substances 0.000 claims description 21
- 238000010304 firing Methods 0.000 claims description 20
- 238000000465 moulding Methods 0.000 claims description 16
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 11
- 239000007789 gas Substances 0.000 description 107
- 238000005259 measurement Methods 0.000 description 45
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- 238000001514 detection method Methods 0.000 description 19
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- 238000000550 scanning electron microscopy energy dispersive X-ray spectroscopy Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
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- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910020068 MgAl Inorganic materials 0.000 description 2
- 241000968352 Scandia <hydrozoan> Species 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
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- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000007561 laser diffraction method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- HJGMWXTVGKLUAQ-UHFFFAOYSA-N oxygen(2-);scandium(3+) Chemical compound [O-2].[O-2].[O-2].[Sc+3].[Sc+3] HJGMWXTVGKLUAQ-UHFFFAOYSA-N 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000013001 point bending Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 238000000790 scattering method Methods 0.000 description 2
- 239000011163 secondary particle Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009429 electrical wiring Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62695—Granulation or pelletising
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
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- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
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- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/78—Grain sizes and shapes, product microstructures, e.g. acicular grains, equiaxed grains, platelet-structures
- C04B2235/786—Micrometer sized grains, i.e. from 1 to 100 micron
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Molecular Biology (AREA)
- Thermal Sciences (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Conductive Materials (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017213346A JP6859926B2 (ja) | 2017-11-03 | 2017-11-03 | 固体電解質、その製造方法、ガスセンサ |
| PCT/JP2018/038082 WO2019087736A1 (ja) | 2017-11-03 | 2018-10-12 | 固体電解質、その製造方法、ガスセンサ |
| CN201880071066.6A CN111372905B (zh) | 2017-11-03 | 2018-10-12 | 固体电解质、其制造方法、气体传感器 |
| DE112018005236.2T DE112018005236B4 (de) | 2017-11-03 | 2018-10-12 | Festelektrolyt, dessen Herstellungsverfahren und Gassensor |
| US16/864,256 US11656196B2 (en) | 2017-11-03 | 2020-05-01 | Solid electrolyte, manufacturing method thereof, and gas sensor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017213346A JP6859926B2 (ja) | 2017-11-03 | 2017-11-03 | 固体電解質、その製造方法、ガスセンサ |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019085285A JP2019085285A (ja) | 2019-06-06 |
| JP2019085285A5 JP2019085285A5 (enExample) | 2020-02-06 |
| JP6859926B2 true JP6859926B2 (ja) | 2021-04-14 |
Family
ID=66332478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017213346A Active JP6859926B2 (ja) | 2017-11-03 | 2017-11-03 | 固体電解質、その製造方法、ガスセンサ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US11656196B2 (enExample) |
| JP (1) | JP6859926B2 (enExample) |
| CN (1) | CN111372905B (enExample) |
| DE (1) | DE112018005236B4 (enExample) |
| WO (1) | WO2019087736A1 (enExample) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7272250B2 (ja) | 2019-12-04 | 2023-05-12 | 株式会社デンソー | ガスセンサおよびガスセンサ用粉末 |
| JP7593493B2 (ja) * | 2021-06-01 | 2024-12-03 | 株式会社デンソー | 固体電解質およびガスセンサ |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6013464B2 (ja) * | 1978-04-10 | 1985-04-08 | 株式会社デンソー | 酸素濃度センサ−用固体電解質体 |
| JPS5546130A (en) * | 1978-09-29 | 1980-03-31 | Hitachi Ltd | Oxygen sensor |
| JPS5642909A (en) | 1979-09-18 | 1981-04-21 | Ngk Insulators Ltd | Solid electrolyte |
| JPS60155568A (ja) * | 1984-01-25 | 1985-08-15 | 東レ株式会社 | 部分安定化ジルコニア焼結体 |
| JPH0788251B2 (ja) | 1985-11-06 | 1995-09-27 | 株式会社日立製作所 | ジルコニア焼結体 |
| JP2616772B2 (ja) * | 1987-05-22 | 1997-06-04 | 株式会社デンソー | プロトン導電性セラミックスの製造方法 |
| JPH04357165A (ja) * | 1991-05-29 | 1992-12-10 | Ngk Insulators Ltd | ジルコニア磁器およびこれを用いた電気化学的素子 |
| JP3475548B2 (ja) * | 1994-04-19 | 2003-12-08 | 株式会社デンソー | 層状セラミックス体、並びに酸素センサ及びその製法 |
| JPH09124365A (ja) | 1995-09-01 | 1997-05-13 | Denso Corp | 酸素センサ素子 |
| JP3959762B2 (ja) * | 1996-11-12 | 2007-08-15 | 東ソー株式会社 | 固体電解質用ジルコニア微粉末及びその製造方法 |
| JP2000202406A (ja) | 1999-01-19 | 2000-07-25 | Sanyo Electric Co Ltd | 有機物処理装置 |
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| KR102196575B1 (ko) * | 2013-03-11 | 2020-12-30 | 쿠라레 노리타케 덴탈 가부시키가이샤 | 지르코니아 소결체, 그리고 지르코니아의 조성물 및 가소체 |
| AT17516U1 (de) * | 2014-06-23 | 2022-06-15 | Tosoh Corp | Gefärbter lichtdurchlässiger zirkonoxidsinterkörper und -pulver, und anwendung davon |
| JP6405969B2 (ja) * | 2014-12-10 | 2018-10-17 | 株式会社デンソー | 固体電解質体及びガスセンサ |
| JP6717766B2 (ja) | 2017-02-23 | 2020-07-01 | サンコール株式会社 | アクチュエータ付き長下肢装具 |
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2017
- 2017-11-03 JP JP2017213346A patent/JP6859926B2/ja active Active
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2018
- 2018-10-12 CN CN201880071066.6A patent/CN111372905B/zh active Active
- 2018-10-12 WO PCT/JP2018/038082 patent/WO2019087736A1/ja not_active Ceased
- 2018-10-12 DE DE112018005236.2T patent/DE112018005236B4/de active Active
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2020
- 2020-05-01 US US16/864,256 patent/US11656196B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| DE112018005236T5 (de) | 2020-06-18 |
| CN111372905B (zh) | 2022-07-29 |
| JP2019085285A (ja) | 2019-06-06 |
| DE112018005236B4 (de) | 2024-11-07 |
| US20200256822A1 (en) | 2020-08-13 |
| US11656196B2 (en) | 2023-05-23 |
| CN111372905A (zh) | 2020-07-03 |
| WO2019087736A1 (ja) | 2019-05-09 |
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