JP6333791B2 - 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 - Google Patents
樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 Download PDFInfo
- Publication number
- JP6333791B2 JP6333791B2 JP2015212316A JP2015212316A JP6333791B2 JP 6333791 B2 JP6333791 B2 JP 6333791B2 JP 2015212316 A JP2015212316 A JP 2015212316A JP 2015212316 A JP2015212316 A JP 2015212316A JP 6333791 B2 JP6333791 B2 JP 6333791B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- prepreg
- component
- printed wiring
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011342 resin composition Substances 0.000 title claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 41
- 229920005989 resin Polymers 0.000 claims description 41
- 239000011347 resin Substances 0.000 claims description 41
- 229920001296 polysiloxane Polymers 0.000 claims description 35
- -1 maleimide compound Chemical class 0.000 claims description 30
- 125000000962 organic group Chemical group 0.000 claims description 24
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
- 125000003700 epoxy group Chemical group 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate group Chemical group [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims description 12
- 239000011256 inorganic filler Substances 0.000 claims description 12
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 8
- 125000003277 amino group Chemical group 0.000 claims description 7
- 229920001187 thermosetting polymer Polymers 0.000 claims description 7
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 125000005641 methacryl group Chemical group 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- 125000001033 ether group Chemical group 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 description 60
- 239000003822 epoxy resin Substances 0.000 description 31
- 229920000647 polyepoxide Polymers 0.000 description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 16
- 239000011521 glass Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 239000011889 copper foil Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229910000679 solder Inorganic materials 0.000 description 8
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920003986 novolac Polymers 0.000 description 6
- 239000002966 varnish Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 4
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 239000005062 Polybutadiene Substances 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 238000010030 laminating Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 150000003949 imides Chemical class 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920003192 poly(bis maleimide) Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GUIACFHOZIQGKX-UHFFFAOYSA-N 1-[4-[4-(2,5-dioxopyrrol-1-yl)phenyl]sulfonylphenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=C(S(=O)(=O)C=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=C1 GUIACFHOZIQGKX-UHFFFAOYSA-N 0.000 description 2
- XAZPKEBWNIUCKF-UHFFFAOYSA-N 1-[4-[4-[2-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]propan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C)(C)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O XAZPKEBWNIUCKF-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical compound NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 description 2
- 229940018563 3-aminophenol Drugs 0.000 description 2
- ZORMWTDEFZLFJA-UHFFFAOYSA-N 3-aminophenol;4-aminophenol Chemical compound NC1=CC=C(O)C=C1.NC1=CC=CC(O)=C1 ZORMWTDEFZLFJA-UHFFFAOYSA-N 0.000 description 2
- PDCMTKJRBAZZHL-UHFFFAOYSA-N 5-aminobenzene-1,3-diol Chemical compound NC1=CC(O)=CC(O)=C1 PDCMTKJRBAZZHL-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- ATHHXGZTWNVVOU-UHFFFAOYSA-N N-methylformamide Chemical compound CNC=O ATHHXGZTWNVVOU-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229960004050 aminobenzoic acid Drugs 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012766 organic filler Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920001955 polyphenylene ether Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000000930 thermomechanical effect Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- PUKLCKVOVCZYKF-UHFFFAOYSA-N 1-[2-(2,5-dioxopyrrol-1-yl)ethyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1CCN1C(=O)C=CC1=O PUKLCKVOVCZYKF-UHFFFAOYSA-N 0.000 description 1
- IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 description 1
- LTGTVRSJQNJRCS-UHFFFAOYSA-N 1-[3-[1-[3-(2,5-dioxopyrrol-1-yl)phenoxy]-4-phenylcyclohexa-2,4-dien-1-yl]oxyphenyl]pyrrole-2,5-dione Chemical group O=C1C=CC(=O)N1C1=CC=CC(OC2(C=CC(=CC2)C=2C=CC=CC=2)OC=2C=C(C=CC=2)N2C(C=CC2=O)=O)=C1 LTGTVRSJQNJRCS-UHFFFAOYSA-N 0.000 description 1
- MBNMVPPPCZKPIJ-UHFFFAOYSA-N 1-[3-[3-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=C(OC=3C=C(C=CC=3)N3C(C=CC3=O)=O)C=CC=2)=C1 MBNMVPPPCZKPIJ-UHFFFAOYSA-N 0.000 description 1
- XUYYHEMUYJTNNL-UHFFFAOYSA-N 1-[3-[4-[1-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]ethyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=C(C=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C)C(C=C1)=CC=C1OC(C=1)=CC=CC=1N1C(=O)C=CC1=O XUYYHEMUYJTNNL-UHFFFAOYSA-N 0.000 description 1
- FKHUSFNOGXJJRH-UHFFFAOYSA-N 1-[3-[4-[2-[4-[2-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]propan-2-yl]phenyl]propan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(C(C)(C)C=2C=CC(OC=3C=C(C=CC=3)N3C(C=CC3=O)=O)=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OC(C=1)=CC=CC=1N1C(=O)C=CC1=O FKHUSFNOGXJJRH-UHFFFAOYSA-N 0.000 description 1
- BYXJCAQAONKDLQ-UHFFFAOYSA-N 1-[3-[4-[2-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=C(C=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C(F)(F)F)(C(F)(F)F)C(C=C1)=CC=C1OC(C=1)=CC=CC=1N1C(=O)C=CC1=O BYXJCAQAONKDLQ-UHFFFAOYSA-N 0.000 description 1
- OYQKHVOHNOPHCU-UHFFFAOYSA-N 1-[3-[4-[2-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]ethyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(CCC=3C=CC(OC=4C=C(C=CC=4)N4C(C=CC4=O)=O)=CC=3)=CC=2)=C1 OYQKHVOHNOPHCU-UHFFFAOYSA-N 0.000 description 1
- JAZKPFCQIJDBSX-UHFFFAOYSA-N 1-[3-[4-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]benzoyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=C(C=CC=2)N2C(C=CC2=O)=O)C=CC=1C(=O)C(C=C1)=CC=C1OC(C=1)=CC=CC=1N1C(=O)C=CC1=O JAZKPFCQIJDBSX-UHFFFAOYSA-N 0.000 description 1
- BKEACNYLDYJTTP-UHFFFAOYSA-N 1-[3-[4-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenoxy]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(OC=3C=CC(OC=4C=C(C=CC=4)N4C(C=CC4=O)=O)=CC=3)=CC=2)=C1 BKEACNYLDYJTTP-UHFFFAOYSA-N 0.000 description 1
- DWJYMIWBPJIVFF-UHFFFAOYSA-N 1-[3-[4-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfanylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(SC=3C=CC(OC=4C=C(C=CC=4)N4C(C=CC4=O)=O)=CC=3)=CC=2)=C1 DWJYMIWBPJIVFF-UHFFFAOYSA-N 0.000 description 1
- PYEMBNRNLTZWBY-UHFFFAOYSA-N 1-[3-[4-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfinylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(=CC=2)S(=O)C=2C=CC(OC=3C=C(C=CC=3)N3C(C=CC3=O)=O)=CC=2)=C1 PYEMBNRNLTZWBY-UHFFFAOYSA-N 0.000 description 1
- HRPHBJSWDLCUDG-UHFFFAOYSA-N 1-[3-[4-[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfonylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(=CC=2)S(=O)(=O)C=2C=CC(OC=3C=C(C=CC=3)N3C(C=CC3=O)=O)=CC=2)=C1 HRPHBJSWDLCUDG-UHFFFAOYSA-N 0.000 description 1
- IZTXRIJQXAMBOE-UHFFFAOYSA-N 1-[3-[4-[[4-[3-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]methyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(OC=2C=CC(CC=3C=CC(OC=4C=C(C=CC=4)N4C(C=CC4=O)=O)=CC=3)=CC=2)=C1 IZTXRIJQXAMBOE-UHFFFAOYSA-N 0.000 description 1
- AQGZJQNZNONGKY-UHFFFAOYSA-N 1-[4-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=C(N2C(C=CC2=O)=O)C=C1 AQGZJQNZNONGKY-UHFFFAOYSA-N 0.000 description 1
- KGARIUYNSFEPKD-UHFFFAOYSA-N 1-[4-[1-[4-(2,5-dioxopyrrol-1-yl)phenoxy]-4-phenylcyclohexa-2,4-dien-1-yl]oxyphenyl]pyrrole-2,5-dione Chemical group O=C1C=CC(=O)N1C(C=C1)=CC=C1OC1(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC(C=2C=CC=CC=2)=CC1 KGARIUYNSFEPKD-UHFFFAOYSA-N 0.000 description 1
- UGJHILWNNSROJV-UHFFFAOYSA-N 1-[4-[3-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC1=CC=CC(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)=C1 UGJHILWNNSROJV-UHFFFAOYSA-N 0.000 description 1
- ORQOWEDKMXGKDJ-UHFFFAOYSA-N 1-[4-[4-(2,5-dioxopyrrol-1-yl)benzoyl]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(N2C(C=CC2=O)=O)C=CC=1C(=O)C(C=C1)=CC=C1N1C(=O)C=CC1=O ORQOWEDKMXGKDJ-UHFFFAOYSA-N 0.000 description 1
- XOJRVZIYCCJCRD-UHFFFAOYSA-N 1-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC1=CC=C(N2C(C=CC2=O)=O)C=C1 XOJRVZIYCCJCRD-UHFFFAOYSA-N 0.000 description 1
- VZBQHKQTICAEPG-UHFFFAOYSA-N 1-[4-[4-[1-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]ethyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O VZBQHKQTICAEPG-UHFFFAOYSA-N 0.000 description 1
- XGCQISUCYGFJFQ-UHFFFAOYSA-N 1-[4-[4-[2-[4-[2-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]propan-2-yl]phenyl]propan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(C(C)(C)C=2C=CC(OC=3C=CC(=CC=3)N3C(C=CC3=O)=O)=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O XGCQISUCYGFJFQ-UHFFFAOYSA-N 0.000 description 1
- PYTZZNUKESXWLN-UHFFFAOYSA-N 1-[4-[4-[2-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C(F)(F)F)(C(F)(F)F)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O PYTZZNUKESXWLN-UHFFFAOYSA-N 0.000 description 1
- FUIYMUCYALFQRH-UHFFFAOYSA-N 1-[4-[4-[2-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]butan-2-yl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC=1C(C)(CC)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O FUIYMUCYALFQRH-UHFFFAOYSA-N 0.000 description 1
- UARUPSPWUIRUTJ-UHFFFAOYSA-N 1-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenyl]cyclohexyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=C(C2CCC(CC2)C=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=C1 UARUPSPWUIRUTJ-UHFFFAOYSA-N 0.000 description 1
- MWVPSAKHPCVPHF-UHFFFAOYSA-N 1-[4-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]benzoyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound C=1C=C(OC=2C=CC(=CC=2)N2C(C=CC2=O)=O)C=CC=1C(=O)C(C=C1)=CC=C1OC(C=C1)=CC=C1N1C(=O)C=CC1=O MWVPSAKHPCVPHF-UHFFFAOYSA-N 0.000 description 1
- LZNGBBXVZZYWMT-UHFFFAOYSA-N 1-[4-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenoxy]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC(C=C1)=CC=C1OC(C=C1)=CC=C1OC1=CC=C(N2C(C=CC2=O)=O)C=C1 LZNGBBXVZZYWMT-UHFFFAOYSA-N 0.000 description 1
- ZEEJBKCPBGYONQ-UHFFFAOYSA-N 1-[4-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfanylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC(C=C1)=CC=C1SC(C=C1)=CC=C1OC1=CC=C(N2C(C=CC2=O)=O)C=C1 ZEEJBKCPBGYONQ-UHFFFAOYSA-N 0.000 description 1
- QZNBDHWYUPJSIT-UHFFFAOYSA-N 1-[4-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfinylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC1=CC=C(S(=O)C=2C=CC(OC=3C=CC(=CC=3)N3C(C=CC3=O)=O)=CC=2)C=C1 QZNBDHWYUPJSIT-UHFFFAOYSA-N 0.000 description 1
- NJMJISMIDHAPSG-UHFFFAOYSA-N 1-[4-[4-[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]sulfonylphenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC1=CC=C(S(=O)(=O)C=2C=CC(OC=3C=CC(=CC=3)N3C(C=CC3=O)=O)=CC=2)C=C1 NJMJISMIDHAPSG-UHFFFAOYSA-N 0.000 description 1
- OBPBQKFGLIVSKR-UHFFFAOYSA-N 1-[4-[4-[[4-[4-(2,5-dioxopyrrol-1-yl)phenoxy]phenyl]methyl]phenoxy]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1OC(C=C1)=CC=C1CC(C=C1)=CC=C1OC1=CC=C(N2C(C=CC2=O)=O)C=C1 OBPBQKFGLIVSKR-UHFFFAOYSA-N 0.000 description 1
- DRIJMZWXZMSZKJ-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)-3-methylphenyl]methyl]-2-methylphenyl]pyrrole-2,5-dione Chemical compound C=1C=C(N2C(C=CC2=O)=O)C(C)=CC=1CC(C=C1C)=CC=C1N1C(=O)C=CC1=O DRIJMZWXZMSZKJ-UHFFFAOYSA-N 0.000 description 1
- LIRFWAADGFIXIJ-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)cyclohexyl]methyl]cyclohexyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCC(CC2CCC(CC2)N2C(C=CC2=O)=O)CC1 LIRFWAADGFIXIJ-UHFFFAOYSA-N 0.000 description 1
- MPLHZTWRCINWPX-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]disulfanyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1SSC1=CC=C(N2C(C=CC2=O)=O)C=C1 MPLHZTWRCINWPX-UHFFFAOYSA-N 0.000 description 1
- JZHXUFCBZBJDGE-UHFFFAOYSA-N 1-[[4-[(2,5-dioxopyrrol-1-yl)methyl]cyclohexyl]methyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1CC1CCC(CN2C(C=CC2=O)=O)CC1 JZHXUFCBZBJDGE-UHFFFAOYSA-N 0.000 description 1
- XFRPTDABLAIJMY-UHFFFAOYSA-N 1-[[4-[(2,5-dioxopyrrol-1-yl)methyl]phenyl]methyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1CC(C=C1)=CC=C1CN1C(=O)C=CC1=O XFRPTDABLAIJMY-UHFFFAOYSA-N 0.000 description 1
- SEULWJSKCVACTH-UHFFFAOYSA-N 1-phenylimidazole Chemical compound C1=NC=CN1C1=CC=CC=C1 SEULWJSKCVACTH-UHFFFAOYSA-N 0.000 description 1
- LABVVLMFRIFJRX-UHFFFAOYSA-N 2-[4-[2-[4-(2-aminophenoxy)phenyl]propan-2-yl]phenoxy]aniline Chemical compound C=1C=C(OC=2C(=CC=CC=2)N)C=CC=1C(C)(C)C(C=C1)=CC=C1OC1=CC=CC=C1N LABVVLMFRIFJRX-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 1
- KBZFDRWPMZESDI-UHFFFAOYSA-N 5-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=CC(C(O)=O)=CC(C(O)=O)=C1 KBZFDRWPMZESDI-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- NOHQTLHHNIKWBA-UHFFFAOYSA-N [SiH4].NC(=O)N Chemical compound [SiH4].NC(=O)N NOHQTLHHNIKWBA-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000012772 electrical insulation material Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 150000003384 small molecules Chemical group 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 125000006839 xylylene group Chemical group 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/092—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08L79/085—Unsaturated polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0366—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/546—Flexural strength; Flexion stiffness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
- C08J2479/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
- C08J2479/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2479/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3445—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0137—Materials
- H05K2201/0154—Polyimide
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0137—Materials
- H05K2201/0162—Silicon containing polymer, e.g. silicone
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/06—Thermal details
- H05K2201/068—Thermal details wherein the coefficient of thermal expansion is important
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Laminated Bodies (AREA)
Description
すなわち、一般的に、エポキシ樹脂の場合180℃以下の温度で硬化可能であるが、ポリビスマレイミド樹脂を積層する場合は220℃以上の高温でかつ長時間の処理が必要である。また、変性イミド樹脂組成物は耐湿性や接着性が改良されるものの(例えば、特許文献2参照)、メチルエチルケトン等の汎用性溶剤への可溶性確保のため水酸基とエポキシ基を含有する低分子化合物で変性するので、得られる変性イミド樹脂の耐熱性がポリビスマレイミド樹脂と比較すると大幅に劣る。
1.(a)1分子構造中に少なくとも2個のN−置換マレイミド基を有するマレイミド化合物と、(b)1分子構造中に少なくとも1個の反応性の有機基を有するシリコーン化合物を含有することを特徴とする樹脂組成物。
2.さらに、(c)熱硬化性樹脂を含有する上記1に記載の樹脂組成物。
3.さらに、(d)下記一般式(I)で表される酸性置換基を有するアミン化合物を含有する上記1又は2に記載の樹脂組成物。
4.(b)成分が、下記一般式(II)で表される構造を含むシリコーン化合物である上記1〜3のいずれかに記載の樹脂組成物。
5(b)成分の反応性有機基が、エポキシ基、アミノ基、水酸基、メタクリル基、メルカプト基、カルボキシル基、アルコキシ基から選ばれる少なくとも1種である上記1〜4のいずれかに記載の樹脂組成物。
6.(b)成分が、1分子構造中に少なくとも2個の反応性有機基を有するシリコーン化合物である上記1〜5のいずれかに記載の樹脂組成物。
7.(b)成分が両末端に反応性有機基を有するシリコーン化合物である上記1〜5のいずれかに記載の樹脂組成物。
8.(b)成分が、どちらか一方の末端に反応性有機基を有するシリコーン化合物である上記1〜5のいずれかに記載の樹脂組成物。
9.(b)成分が側鎖に反応性有機基を有するシリコーン化合物である上記1〜5のいずれかに記載の樹脂組成物。
10.(b)成分が、側鎖及び、少なくとも一方の末端に反応性の有機基を有するシリコーン化合物である上記1〜5のいずれかに記載の樹脂組成物。
11.(c)成分が、分子構造中にエポキシ基および/またはシアネート基を有する熱硬化性樹脂である上記1〜10いずれかに記載の樹脂組成物。
12.さらに、下記一般式(III)又は(IV)で表される(e)硬化促進剤を含有する上記1〜11のいずれかに記載の樹脂組成物。
13.さらに、(f)無機充填材を含有する上記1〜12のいずれかに記載の樹脂組成物。
14.上記1〜13いずれかに記載の樹脂組成物を用いたプリプレグ。
15.上記14のプリプレグを用いて積層成形して得られた積層板。
16.上記15の積層板を用いて製造されたプリント配線板。
分子構造中にエポキシ基を有するシリコーン化合物は、市販品を用いることができ、例えば、両末端にエポキシ基を有する「X−22−163」(官能基当量200)、「KF−105」(官能基当量490)、「X−22−163A」(官能基当量1000)、「X−22−163B」(官能基当量1750)、「X−22−163C」(官能基当量2700)、両末端に脂環式エポキシ基を有する「X−22−169AS」(官能基当量500)、「X−22−169B」(官能基当量1700)、一方の末端にエポキシ基を有する「X−22−1730X」(官能基当量4500)、側鎖及び両末端にエポキシ基を有する「X−22−9002」(官能基当量5000)、側鎖にエポキシ基を有する「X−22−343」(官能基当量525)、「KF−101」(官能基当量350)、「KF−1001」(官能基当量3500)、「X−22−2000」(官能基当量620)、「X−22−4741」(官能基当量2500)、「KF−1002」(官能基当量4300)、側鎖に脂環式エポキシ基を有する「X−22−2046」(官能基当量600)、「KF−102」(官能基当量3600、以上、信越化学工業(株)製)が挙げられ、これらは単独で、または2種類以上を混合して、さらには各種エポキシ樹脂と混合して使用することができる。
これらの分子構造中にエポキシ基を有するシリコーン化合物の中で、耐熱性の点から「X−22−163A」、「X−22−163B」、「X−22−343」、「X−22−9002」、「KF−101」が好ましく、「X−22−163A」、「X−22−163B」がより好ましく、低熱膨張率の点から「X−22−163B」が特に好ましい。
これらの分子構造中にアミノ基を有するシリコーン化合物の中で低吸水率の点からX−22−161A、X−22−161B、KF−8012、KF−8008、X−22−1660B−3、BY−16−853Bが好ましく、低熱膨張性の点からX−22−161A、X−22−161B、KF−8012が特に好ましい。
その中でもイミダゾール類及びその誘導体が耐熱性や難燃性、銅箔接着性等の点から好ましく、更に下記一般式(III)で表されるイソシアネート樹脂や、下記一般式(IV)で表されるイミダゾール基がエポキシ樹脂によって置換された化合物によって置換された化合物が、200℃以下での比較的低温での硬化成形性とワニスやプリプレグの経日安定性に優れるためより好ましく、具体的には下記式(V)又は式(VI)で表される化合物が少量の配合使用でよく、また商業的にも安価であることから特に好ましい。
熱可塑性樹脂の例としては、ポリテトラフルオロエチレン、ポリエチレン、ポリプロピレン、ポリスチレン、ポリフェニレンエーテル樹脂、フェノキシ樹脂、ポリカーボネート樹脂、ポリエステル樹脂、ポリアミド樹脂、ポリイミド樹脂、キシレン樹脂、石油樹脂及びシリコーン樹脂が挙げられる。
エラストマーの例としては、ポリブタジエン、ポリアクリロニトリル、エポキシ変性ポリブタジエン、無水マレイン酸変性ポリブタジエン、フェノール変性ポリブタジエン及びカルボキシ変性ポリアクリロニトリルが挙げられる。
有機充填材の例としては、シリコーンパウダー、テトラフルオロエチレン、ポリエチレン、ポリプロピレン、ポリスチレン、並びにポリフェニレンエーテル等の有機物粉末が挙げられる。
本発明の樹脂組成物はプレプリグを製造する際にワニスとして用いられる。ワニスに用いられる溶剤には前記の反応に用いられるものと同様の溶剤が用いられる。ワニスは固形分濃度として50〜75質量%として使用することが好ましい。
本発明のプリプレグは、本発明の樹脂組成物を、基材に含浸又は塗工し、加熱等により半硬化(Bステージ化)して製造することができる。ここで用いられる基材としては、各種の電気絶縁材料用積層板に用いられている周知のものが使用できる。その材質の例としては、Eガラス、Dガラス、Sガラス及びQガラス等の無機物繊維、ポリイミド、ポリエステル及びポリテトラフルオロエチレン等の有機繊維、並びにそれらの混合物が挙げられる。
積層板を製造する際の成形条件は、例えば、電気絶縁材料用積層板及び多層板の手法が適用でき、例えば多段プレス、多段真空プレス、連続成形機、オートクレーブ成形機等を使用し、温度100〜250℃、圧力0.2〜10MPa、加熱時間0.1〜5時間の範囲で成形することができる。また、本発明のプリプレグと内層用配線板とを組合せ、積層成形して、積層板を製造することもできる。
なお、各実施例および比較例で得られた銅張積層板を用いて、ガラス転移温度、熱膨張率、はんだ耐熱性、そり特性について以下の方法で測定・評価した。
銅張積層板を銅エッチング液に浸漬することにより銅箔を取り除いた5mm角の評価基板を作製し、TMA試験装置(デュポン社製、TMA2940)を用いて圧縮法で熱機械分析をおこなった。評価基板を前記装置にZ方向に装着後、荷重5g、昇温速度10℃/分の測定条件にて連続して2回測定した。2回目の測定における熱膨張曲線の異なる接線の交点で示されるTgを求め、耐熱性を評価した。
(2)熱膨張率の測定
銅張積層板を銅エッチング液に浸漬することにより銅箔を取り除いた5mm角の評価基板を作製し、TMA試験装置(デュポン社製、TMA2940)を用いて圧縮法で熱機械分析をおこなった。評価基板を前記装置にX方向に装着後、荷重5g、昇温速度10℃/分の測定条件にて連続して2回測定した。2回目の測定における30℃から100℃の平均熱膨張率を算出し、これを熱膨張率の値とした。
5cm角の銅張積層板を作製し、温度288℃のはんだ浴に、評価基板を1分間浮かべた後、外観を観察することによりはんだ耐熱性を評価した。
(4)そり量の評価
AKROMETRIX社製サーモレイPS200シャドーモアレ分析を用いて、基板の反り量を評価した。基板のサンプルサイズは40mm×40mmとし、測定エリアは36mm×36mmとした。室温から260℃まで加熱し、その後50℃まで冷却した時のそり量を測定した。
以下に示す(a)〜(d)成分と、(e)硬化促進剤、(f)無機充填材、及び希釈溶剤にメチルエチルケトンを使用して、第1表〜第5表に示した配合割合(質量部)で混合して樹脂分65質量%の均一なワニスを得た。
次に、上記ワニスを厚さ0.1mmのEガラスクロスに含浸塗工し、160℃で10分加熱乾燥して樹脂含有量50質量%のプリプレグを得た。
このプリプレグを4枚重ね、18μmの電解銅箔を上下に配置し、圧力2.5MPa、温度230℃で90分間プレスを行って、銅張積層板を得た。
得られた銅張積層板の測定・評価結果を第1表〜第5表に示す。
ビス(4−マレイミドフェニル)メタン
3,3−ジメチル−5,5−ジエチル−4,4−ジフェニルメタンビスマレイミド
(b)シリコーン化合物
X−22−161A(信越化学工業(株)製、両末端アミノ変性、官能基当量800)
X−22−161B(信越化学工業(株)製、両末端アミノ変性、官能基当量1500)
KF−8012(信越化学工業(株)製、両末端アミノ変性、官能基当量2200)
KF−864(信越化学工業(株)製、片末端アミノ変性、官能基当量3800)
X−22−163B(信越化学工業(株)製、両末端エポキシ変性、官能基当量1750)
KF−6002(信越化学工業(株)製、両末端水酸基変性、官能基当量1600)
X−22−1821(信越化学工業(株)製、両末端フェノール性水酸基変性、官能基当量(1470)
X−22−164A(信越化学工業(株)製、両末端メタクリル変性、官能基当量860)
X−22−167B(信越化学工業(株)製、両末端メルカプト変性、官能基当量1670)
X−22−162C(信越化学工業(株)製、両末端カルボキシル変性、官能基当量2300)
FZ−3704(東レ・ダウコーニング(株)製、側鎖アルコキシ変性、官能基当量150)
(c)熱硬化性樹脂
ビフェニルアラルキル型エポキシ樹脂(日本化薬(株)製NC−3000)
ビスフェノールA型シアネート樹脂(ロンザジャパン(株)製B10)
(d)アミン化合物
m−アミノフェノール
p−アミノフェノール
(e)硬化促進剤:
G−8009L(ヘキサメチレンジイソシアネート樹脂と2−エチル−4−メチルイミダゾールの付加反応物:前記の式(V)で表される化合物)
(f)無機充填材:溶融シリカ((株)アドマテックス製SO−C2)
その他の化合物
ジアミノジフェニルメタン(比較例)
2,2−ビス[4−(アミノフェノキシ)フェニル]プロパン(比較例)
Claims (12)
- (a)1分子構造中に少なくとも2個のN−置換マレイミド基を有するマレイミド化合物と、(b)1分子構造中に少なくとも1個の反応性の有機基を有するシリコーン化合物と、(c)熱硬化性樹脂(前記(a)成分を除く)と、(d)下記一般式(I)で表される酸性置換基を有するアミン化合物とを含有する樹脂組成物を用いたプリント配線板用プリプレグであり、
前記(b)成分の含有量が、前記(a)成分100質量部に対して、1〜100質量部であり、
前記(c)成分の含有量が、前記(a)成分100質量部に対して、10〜200質量部であり、
前記(b)成分が下記一般式(II)で表される構造を含むシリコーン化合物である、プリント配線板用プリプレグ。
(式中、R 1 は複数ある場合は各々独立に、酸性置換基である水酸基、カルボキシル基又はスルホン酸基、R 2 は複数ある場合は各々独立に水素原子、炭素数1〜5の脂肪族炭化水素基又はハロゲン原子を示し、xは1〜5の整数、yは0〜4の整数で、x+y=5である。)
[式中、R3、R4はそれぞれ独立にアルキル基、フェニル基又は置換フェニル基を示し、nは9〜100の整数である。] - 前記(c)成分が、分子構造中にエポキシ基および/またはシアネート基を有する熱硬化性樹脂である、請求項1に記載のプリント配線板用プリプレグ。
- 前記(b)成分の反応性の有機基が、エポキシ基、アミノ基、水酸基、メタクリル基、メルカプト基、カルボキシル基、アルコキシ基から選ばれる少なくとも1種である、請求項1又は2に記載のプリント配線板用プリプレグ。
- 前記(b)成分が、1分子構造中に少なくとも2個の反応性の有機基を有するシリコーン化合物である、請求項1〜3のいずれか一項に記載のプリント配線板用プリプレグ。
- 前記(b)成分が、両末端に反応性の有機基を有するシリコーン化合物である、請求項1〜3のいずれか一項に記載のプリント配線板用プリプレグ。
- 前記(b)成分が、どちらか一方の末端に反応性の有機基を有する、シリコーン化合物である、請求項1〜3のいずれか一項に記載のプリント配線板用プリプレグ。
- 前記(b)成分が、側鎖に反応性の有機基を有するシリコーン化合物である、請求項1〜3のいずれか一項に記載のプリント配線板用プリプレグ。
- 前記(b)成分が、側鎖及び、少なくとも一方の末端に反応性の有機基を有するシリコーン化合物である、請求項1〜3のいずれか一項に記載のプリント配線板用プリプレグ。
- 前記樹脂組成物が下記一般式(III)又は(IV)で表される(e)硬化促進剤を含有する、請求項1〜8のいずれか一項に記載のプリント配線板用プリプレグ。
(式中、R6、R7、R8、R9はそれぞれ独立に、水素原子、炭素数1〜5の脂肪族炭化水素基、又はフェニル基を示し、Dはアルキレン基又は芳香族炭化水素基である。)
(式中、R6、R7、R8、R9は各々独立に水素原子、又は炭素数1〜5の脂肪族炭化水素基、フェニル基を示し、Bは単結合、又はアルキレン基、アルキリデン基、エーテル基、スルフォニル基のいずれかである。) - 前記樹脂組成物が(f)無機充填材を含有する、請求項1〜9のいずれか一項に記載のプリント配線板用プリプレグ。
- 請求項1〜10のいずれか一項に記載のプリント配線板用プリプレグを用いて積層成形して得られた積層板。
- 請求項11に記載の積層板を用いて製造されたプリント配線板。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015212316A JP6333791B2 (ja) | 2011-01-18 | 2015-10-28 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011008312 | 2011-01-18 | ||
JP2011008312 | 2011-01-18 | ||
JP2015212316A JP6333791B2 (ja) | 2011-01-18 | 2015-10-28 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012553739A Division JP5831462B2 (ja) | 2011-01-18 | 2012-01-17 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016028164A JP2016028164A (ja) | 2016-02-25 |
JP6333791B2 true JP6333791B2 (ja) | 2018-05-30 |
Family
ID=46515755
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012553739A Active JP5831462B2 (ja) | 2011-01-18 | 2012-01-17 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2015212316A Active JP6333791B2 (ja) | 2011-01-18 | 2015-10-28 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2015212313A Active JP6270797B2 (ja) | 2011-01-18 | 2015-10-28 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2016246740A Active JP6241536B2 (ja) | 2011-01-18 | 2016-12-20 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2017216687A Active JP6969843B2 (ja) | 2011-01-18 | 2017-11-09 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012553739A Active JP5831462B2 (ja) | 2011-01-18 | 2012-01-17 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015212313A Active JP6270797B2 (ja) | 2011-01-18 | 2015-10-28 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2016246740A Active JP6241536B2 (ja) | 2011-01-18 | 2016-12-20 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
JP2017216687A Active JP6969843B2 (ja) | 2011-01-18 | 2017-11-09 | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2666825A1 (ja) |
JP (5) | JP5831462B2 (ja) |
KR (2) | KR101832869B1 (ja) |
CN (5) | CN105504809A (ja) |
TW (3) | TWI602843B (ja) |
WO (1) | WO2012099132A1 (ja) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101832869B1 (ko) * | 2011-01-18 | 2018-04-13 | 히타치가세이가부시끼가이샤 | 수지 조성물 및 이것을 이용한 프리프레그, 적층판, 인쇄 배선판 |
JP6314830B2 (ja) | 2012-10-19 | 2018-04-25 | 三菱瓦斯化学株式会社 | 樹脂組成物、プリプレグ、積層板、及びプリント配線板 |
JP6107050B2 (ja) * | 2012-10-26 | 2017-04-05 | 日立化成株式会社 | 熱硬化性樹脂組成物、プリプレグ、積層板及びプリント配線板 |
JP6357762B2 (ja) * | 2012-11-28 | 2018-07-18 | 日立化成株式会社 | 変性シロキサン化合物、熱硬化性樹脂組成物、プリプレグ、樹脂付きフィルム、積層板、多層プリント配線板及び半導体パッケージ |
JP6167850B2 (ja) * | 2013-10-29 | 2017-07-26 | 日立化成株式会社 | 熱硬化性樹脂組成物、これを用いたプリプレグ、樹脂付フィルム、積層板、プリント配線板及び半導体パッケージ |
JP6229439B2 (ja) * | 2013-11-05 | 2017-11-15 | 住友ベークライト株式会社 | 金属張積層板、プリント配線基板、および半導体装置 |
JP6476599B2 (ja) * | 2014-06-09 | 2019-03-06 | 日立化成株式会社 | 熱硬化性樹脂組成物、並びにこれを用いたプリプレグ、積層板及びプリント配線板 |
JP2015232066A (ja) * | 2014-06-09 | 2015-12-24 | 日立化成株式会社 | 熱硬化性樹脂組成物、これを用いたプリプレグ、積層板及びプリント配線板 |
JP6596811B2 (ja) * | 2014-07-25 | 2019-10-30 | 日立化成株式会社 | 熱硬化性樹脂組成物、これを用いるプリプレグ、樹脂付フィルム、積層板、多層プリント配線板及び半導体パッケージ |
JP6428082B2 (ja) * | 2014-09-16 | 2018-11-28 | 日立化成株式会社 | 熱硬化性樹脂組成物、プリプレグ、積層板及びプリント配線板 |
JP2016079317A (ja) * | 2014-10-20 | 2016-05-16 | 日立化成株式会社 | 熱硬化性樹脂組成物、並びにこれを用いたプリプレグ、積層板及びプリント配線板 |
JP2018531317A (ja) * | 2015-08-08 | 2018-10-25 | デジグナー モレキュールズ インク. | 陰イオン性硬化可能な組成物 |
JP6785422B2 (ja) * | 2015-12-22 | 2020-11-18 | 昭和電工マテリアルズ株式会社 | 熱硬化性樹脂組成物、プリプレグ、樹脂付きフィルム、積層板、多層プリント配線板及び半導体パッケージ |
JP6686433B2 (ja) * | 2015-12-28 | 2020-04-22 | 日立化成株式会社 | アンダーフィル用樹脂組成物、電子部品装置及び電子部品装置の製造方法 |
CN113845772A (zh) * | 2016-05-02 | 2021-12-28 | 三菱瓦斯化学株式会社 | 树脂组合物、预浸料、树脂片、层叠树脂片、层叠板、覆金属箔层叠板和印刷电路板 |
CN109312140B (zh) * | 2016-05-31 | 2022-03-29 | 三菱瓦斯化学株式会社 | 树脂组合物、层叠体、带有树脂组合物层的半导体晶圆、带有树脂组合物层的半导体搭载用基板和半导体装置 |
WO2018016405A1 (ja) * | 2016-07-19 | 2018-01-25 | セントラル硝子株式会社 | 硬化性樹脂組成物およびその硬化物、並びにこれらを用いた半導体装置 |
JP2018016796A (ja) * | 2016-07-19 | 2018-02-01 | セントラル硝子株式会社 | 硬化性樹脂組成物およびその硬化物、並びにこれらを用いた半導体装置 |
CN110662793B (zh) | 2017-03-28 | 2022-05-10 | 昭和电工材料株式会社 | 无芯基板用预浸渍体、无芯基板和半导体封装体 |
JP6597721B2 (ja) * | 2017-06-28 | 2019-10-30 | 日立化成株式会社 | 熱硬化性樹脂組成物、これを用いたプリプレグ、樹脂付フィルム、積層板、プリント配線板及び半導体パッケージ |
JP6988204B2 (ja) * | 2017-06-29 | 2022-01-05 | 昭和電工マテリアルズ株式会社 | 熱硬化性樹脂組成物、プリプレグ、積層板、プリント配線板及び高速通信対応モジュール |
CN109054381B (zh) * | 2018-07-06 | 2020-09-11 | 苏州生益科技有限公司 | 改性马来酰亚胺树脂组合物及其制备的半固化片和层压板 |
JP7024672B2 (ja) * | 2018-09-12 | 2022-02-24 | 信越化学工業株式会社 | 熱硬化性樹脂組成物、熱硬化性樹脂フィルム及び半導体装置 |
US11963297B2 (en) * | 2019-01-11 | 2024-04-16 | Daikin Industries, Ltd. | Fluororesin composition, fluororesin sheet, laminate and substrate for circuits |
JP7365574B2 (ja) * | 2019-07-29 | 2023-10-20 | 三菱瓦斯化学株式会社 | マレイミド化合物及びその製造方法、アミド酸化合物及びその製造方法、樹脂組成物、硬化物、樹脂シート、プリプレグ、金属箔張積層板、プリント配線板、封止用材料、繊維強化複合材料、接着剤、並びに半導体装置 |
CN114230793B (zh) * | 2021-12-30 | 2024-03-29 | 苏州生益科技有限公司 | 改性双马来酰亚胺预聚物及制备方法、应用 |
CN116410596A (zh) * | 2021-12-31 | 2023-07-11 | 广东生益科技股份有限公司 | 一种树脂组合物及其应用 |
CN118240374A (zh) * | 2022-12-23 | 2024-06-25 | 广东生益科技股份有限公司 | 一种树脂组合物及其应用 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847154A (en) * | 1987-05-29 | 1989-07-11 | Basf Corporation | Thermosetting resin systems containing secondary amine-terminated siloxane modifiers |
JPH03221526A (ja) * | 1990-01-26 | 1991-09-30 | Hitachi Chem Co Ltd | マレイミド樹脂硬化物の製造方法 |
JPH05186661A (ja) * | 1991-10-24 | 1993-07-27 | Nippon Soda Co Ltd | 硬化性樹脂組成物 |
JP2740990B2 (ja) | 1991-11-26 | 1998-04-15 | 株式会社日立製作所 | 低熱膨張性加圧成形用樹脂組成物 |
JPH06122765A (ja) * | 1992-09-02 | 1994-05-06 | Mitsubishi Kasei Corp | 半導体封止用樹脂組成物 |
JPH06145380A (ja) * | 1992-11-13 | 1994-05-24 | Nec Corp | プリプレグ及び銅張積層板 |
JP3372982B2 (ja) | 1993-03-12 | 2003-02-04 | 三井化学株式会社 | 熱硬化性樹脂組成物並びにそれを用いたプリプレグおよび積層板 |
JPH11124487A (ja) * | 1997-10-22 | 1999-05-11 | Mitsubishi Gas Chem Co Inc | シアン酸エステル−マレイミド液状樹脂組成物及び半導体封止装置 |
JP4140115B2 (ja) * | 1999-02-16 | 2008-08-27 | 東亞合成株式会社 | 硬化性組成物 |
JP2000323804A (ja) * | 1999-05-07 | 2000-11-24 | Toagosei Co Ltd | プリント配線板用銅張り積層板 |
JP2002121520A (ja) * | 2000-10-05 | 2002-04-26 | Saehan Ind Inc | 電子部品接着テープ |
JP4957166B2 (ja) * | 2005-10-14 | 2012-06-20 | 三菱瓦斯化学株式会社 | プリプレグ並びに銅張積層板 |
JP5176068B2 (ja) * | 2006-10-24 | 2013-04-03 | 日立化成株式会社 | 導体張積層板、印刷配線板及び多層配線板 |
JP2008095014A (ja) * | 2006-10-13 | 2008-04-24 | Tomoegawa Paper Co Ltd | Qfn用熱硬化型樹脂組成物および接着シート |
JP5417799B2 (ja) * | 2008-10-30 | 2014-02-19 | 日立化成株式会社 | 熱硬化性樹脂組成物、及びこれを用いたプリプレグ,積層板 |
JP5149823B2 (ja) * | 2009-01-27 | 2013-02-20 | 京セラケミカル株式会社 | 耐熱性樹脂組成物及びそれを用いた成形品 |
US20120077401A1 (en) * | 2009-03-27 | 2012-03-29 | Tomohiko Kotake | Resin composition for production of clad layer, resin film for production of clad layer utilizing the resin composition, and optical waveguide and optical module each utilizing the resin composition or the resin film |
JP5149917B2 (ja) * | 2009-03-27 | 2013-02-20 | 日立化成工業株式会社 | 熱硬化性樹脂組成物、並びにこれを用いたプリプレグ、積層板及び多層プリント配線板 |
JP5589292B2 (ja) * | 2009-03-27 | 2014-09-17 | 日立化成株式会社 | 熱硬化性絶縁樹脂組成物、並びにこれを用いた支持体付絶縁フィルム、プリプレグ、積層板及び多層プリント配線板 |
KR101832869B1 (ko) * | 2011-01-18 | 2018-04-13 | 히타치가세이가부시끼가이샤 | 수지 조성물 및 이것을 이용한 프리프레그, 적층판, 인쇄 배선판 |
JP6122765B2 (ja) * | 2013-11-01 | 2017-04-26 | 日立建機株式会社 | 作業機械 |
-
2012
- 2012-01-17 KR KR1020137018827A patent/KR101832869B1/ko active IP Right Grant
- 2012-01-17 EP EP12736878.5A patent/EP2666825A1/en not_active Withdrawn
- 2012-01-17 CN CN201610011778.1A patent/CN105504809A/zh active Pending
- 2012-01-17 KR KR1020187004994A patent/KR102127581B1/ko active IP Right Grant
- 2012-01-17 CN CN2012800056862A patent/CN103328577A/zh active Pending
- 2012-01-17 CN CN201610012258.2A patent/CN105602197B/zh active Active
- 2012-01-17 WO PCT/JP2012/050876 patent/WO2012099132A1/ja active Application Filing
- 2012-01-17 CN CN201610012257.8A patent/CN105462253A/zh active Pending
- 2012-01-17 CN CN201610011769.2A patent/CN105647118B/zh active Active
- 2012-01-17 JP JP2012553739A patent/JP5831462B2/ja active Active
- 2012-01-18 TW TW105110764A patent/TWI602843B/zh active
- 2012-01-18 TW TW101102043A patent/TWI541263B/zh active
- 2012-01-18 TW TW104137207A patent/TWI576365B/zh active
-
2015
- 2015-10-28 JP JP2015212316A patent/JP6333791B2/ja active Active
- 2015-10-28 JP JP2015212313A patent/JP6270797B2/ja active Active
-
2016
- 2016-12-20 JP JP2016246740A patent/JP6241536B2/ja active Active
-
2017
- 2017-11-09 JP JP2017216687A patent/JP6969843B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
EP2666825A1 (en) | 2013-11-27 |
KR101832869B1 (ko) | 2018-04-13 |
JP2016028164A (ja) | 2016-02-25 |
JP2017106019A (ja) | 2017-06-15 |
CN105602197B (zh) | 2020-11-20 |
TW201249885A (en) | 2012-12-16 |
CN105647118B (zh) | 2020-06-26 |
TWI602843B (zh) | 2017-10-21 |
KR20180023022A (ko) | 2018-03-06 |
WO2012099132A1 (ja) | 2012-07-26 |
JP6969843B2 (ja) | 2021-11-24 |
CN105647118A (zh) | 2016-06-08 |
TWI541263B (zh) | 2016-07-11 |
CN103328577A (zh) | 2013-09-25 |
CN105504809A (zh) | 2016-04-20 |
CN105462253A (zh) | 2016-04-06 |
JP6270797B2 (ja) | 2018-01-31 |
KR102127581B1 (ko) | 2020-06-26 |
JPWO2012099132A1 (ja) | 2014-06-30 |
TW201629118A (zh) | 2016-08-16 |
TW201605921A (zh) | 2016-02-16 |
TWI576365B (zh) | 2017-04-01 |
JP2016028163A (ja) | 2016-02-25 |
JP6241536B2 (ja) | 2017-12-06 |
JP2018028105A (ja) | 2018-02-22 |
KR20140006826A (ko) | 2014-01-16 |
JP5831462B2 (ja) | 2015-12-09 |
CN105602197A (zh) | 2016-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6241536B2 (ja) | 樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 | |
JP6160675B2 (ja) | 樹脂組成物、これを用いたプリプレグ、積層板及びプリント配線板 | |
JP6330892B2 (ja) | マレイミド樹脂組成物、その硬化物、プリプレグ、積層板及び多層プリント配線板 | |
CN106973490B (zh) | 硅氧烷化合物用于印刷布线板的用途 | |
US8735733B2 (en) | Resin composition, prepreg laminate obtained with the same and printed-wiring board | |
JP5895342B2 (ja) | 熱硬化性樹脂組成物及びこれを用いたプリプレグ、積層板並びにプリント配線板 | |
JP6259557B2 (ja) | 熱硬化性樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 | |
JP6107050B2 (ja) | 熱硬化性樹脂組成物、プリプレグ、積層板及びプリント配線板 | |
JP5987965B2 (ja) | 熱硬化性樹脂組成物及びこれを用いたプリプレグ、積層板並びにプリント配線板 | |
JP2017071794A (ja) | 熱硬化性樹脂組成物、及びこれを用いたプリプレグ、積層板、プリント配線板 | |
JP2015224289A (ja) | 熱硬化性樹脂組成物、プリプレグ、樹脂付フィルム、積層板、多層プリント配線板及び半導体パッケージ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20151126 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160628 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160826 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20161108 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20170307 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180226 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180425 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6333791 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |