JP6001685B2 - 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 - Google Patents
高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 Download PDFInfo
- Publication number
- JP6001685B2 JP6001685B2 JP2014558810A JP2014558810A JP6001685B2 JP 6001685 B2 JP6001685 B2 JP 6001685B2 JP 2014558810 A JP2014558810 A JP 2014558810A JP 2014558810 A JP2014558810 A JP 2014558810A JP 6001685 B2 JP6001685 B2 JP 6001685B2
- Authority
- JP
- Japan
- Prior art keywords
- styrene
- hsbs
- polymer
- block copolymer
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D153/02—Vinyl aromatic monomers and conjugated dienes
- C09D153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/002—Inorganic yarns or filaments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/50—FELT FABRIC
- Y10T442/56—From synthetic organic fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/601—Nonwoven fabric has an elastic quality
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Nonwoven Fabrics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
ブロック状%=100×(ブロック状スチレン単位/全スチレン単位)
ポリマー−Bd−S−(S)n−S−Bd−ポリマー(式中、nはゼロより大きい。)のように表されるものは、ブロック状スチレンと定義される。例えば、上の例においてnが8に等しい場合、ブロック状化指数は80%になるであろう。ブロック状化指数は、約40未満であることが好ましい。10重量パーセントから40重量パーセントのスチレン含有量を有するポリマーの一部については、ブロック状化指数が約10未満であることが好ましい。
高メルトフローhSBSポリマー
hSBS:シクロヘキサン201kgおよびスチレン9.1kgを約50℃の80ガロンのステンレス製反応器に投入した。次に約12重量%のs−ブチルリチウム2428mLを反応器に投入して重合を開始した。スチレン重合が完了するまで約50℃で進行させ、GPC用にサンプルを採取した。このステップにおける分子量は、4.8kg/molであることが明らかになった。さらにスチレン0.38kgを加えて重合させた。このポリマーをGPCで分析したところ、分子量は5.0kg/molであることが判明した。ブタジエンは、約1kg/分の速度で加えた。ブタジエンの段取りを開始して1分未満で、1,2−ジエトキシプロパン198グラムを加え、次いでブタジエンの添加速度を1.5kg/分に上げた。合計36.05kgのブタジエンを加え、温度を約50℃から55℃の間に保ち、重合が完了するまで継続した。このステップの終了時に採取したサンプルは、分子量26.0kg/mol、1H NMRによるビニル含有量は73.7%、ポリスチレン含有量は24.1%であった。次に、メチルトリメトキシシラン114mLを加えることにより、S−Bジブロックポリマーをカップリングさせて、ジブロック鎖の94%がカップリングしたポリマーを生じさせたが、この大部分(82%)は直鎖状であり、残りの部分は主として3本の腕がある放射状の化学種である。メタノール55mlを加えて、停止するようにした。次いでこのポリマーについて、残った0.12meqオレフィン/gの不飽和を、Co/Al触媒(Al:Coは1.7:1(mol/mol)、Coは約22ppm。)を用いて、700psiの水素下、85℃で水素化し、選択的に水素化されたスチレン−ブタジエン−スチレンポリマーを生成した。全ポリマー溶液125kgのうちの約60kgは最初のバッチ投入で加え、残りの部分は、所望の範囲内に反応温度を保つのに必要な速度で加えた。N2/O2混合ガスでスパージしながら、セメントを水性のリン酸に接触させることにより、触媒を酸化および抽出した。さらに、カプリル酸約100mlを加えた。次に、アンモニアでスパージすることによりセメントを中和して脱イオン水を用いて洗浄し、さらにEthanox330(ポリマーベースで0.2重量%)およびIrgafos168(ポリマーベースで0.3重量%)を加えることにより安定化させた。生じた本発明のhSBSポリマーは、220g/10分のメルトフローレートを有していた。
[実施例2]
繊維ガラスマットおよびスクリム
本発明の技術は、製造および健康、安全ならびに環境の面で著しく改善されると共に、繊維ガラスマットおよびスクリムを含む複合材に耐衝撃性および向上した靭性をもたらすと期待される。100g/10分以上のメルトフローレートを有する本発明のhSBSまたはhSBSSは、十分に高い分子量を有するため揮発性がなく、優れた弾性および靭性を示す一方で、高流動特性により、メルトブロー繊維、布または低坪量フィルムとしての応用が可能になる。靭性、弾性があり、高流動のhSBSまたはhSBSSと繊維ガラスマットまたはスクリムとを組み合わせるための異なる工程を少なくとも3つ想定することができる。
1.13.5osy−オンス/平方ヤード(約450g/m2−グラム/平方メートル)チョップド繊維ガラスマットをUS Composites社より購入した。このタイプのマットは一般に、金型、自動車およびボートの建造用途に用いられる。このマットは、十分な靭性を持たせるために通常24osyの樹脂を必要とする。
hSBSフィルムを、Killion製フィルム押出機にて温度設定を300−330−360−370°Fに、ダイの設定を370°Fにして押出した。
低粘度被覆
低粘度ポリマー(上述のhSBSおよびhSBSS)は、VOC(揮発性有機炭素)の規制を満たさなければならない用途において重要である。hSBSは高メルトフローレート(低粘度)を有し、これを他の低粘度ポリマーと比較した。4種類のVOC除外溶媒のみ、即ち酢酸メチル、p−クロロベンゾトリフルオリド、酢酸t−ブチルおよびアセトンをhSBSと共に検討できることが明らかになった。非VOC規制が許容される分野においては、低粘度ポリマーに適合する任意の非除外溶媒(除外されていない有機溶媒)を用いてもよい。例示的な非除外溶媒には、Aromatic 100(軽質芳香族ナフサ)、Aromatic 200(重質芳香族ナフサ)、キシレン、トルエンなどがある。溶媒(除外、非除外、またはこれらの混合物)のブレンドおよび本発明のhSBSまたはhSBSSのスチレン系ブロックコポリマーを少なくとも40重量%含む被覆は、450グラム/リットル未満、好ましくは350グラム/リットル未満、より好ましくは250グラム/リットル未満のVOC含有量を有する。
キシレンおよびVOC除外溶媒のp−クロロベンゾトリフルオリド(PCBTF)を含む溶媒ブレンドの溶液粘度を測定した。溶液は、G1643およびhSBSポリマーを用いて、固形分15、20および25重量%で作った。結果はセンチポアズ(cps)で測定した(表3参照)。G1643と比べてhSBSが最も低い粘度を有していた。粘度は、溶液中においてPCBTFがキシレンを置き換えるにつれて上昇する。
白色のエラストマー屋根被覆には、VOCが250g/リットルを超えてはならないなど、さらに厳しい要件がある。白色のエラストマー屋根被覆を配合してG1643およびhSBSポリマーの溶液粘度を比較した。配合は、VOC250グラム/リットルを満たすことを目標とし、全ての原料の濃度を重量%で一覧にした。粘度の低減は、塗工坪量および被覆の乾燥時間に対して著しい効果がある。hSBSは、G1643よりも特性が適しており、粘度が低い被覆の配合が得られた(表4参照)。エラストマーの屋根被覆に関する要件は、ASTM D6083に記載されている。粘度の要件は、ASTM D562のメソッドA、手順Aに従った測定で、85から141cpsである。
接着性配合物
既に述べた通り、APOベースの接着性配合物は低コストおよび低性能である。しかし、これらは吹付が可能で、幅広い物品に適用できる。APO接着性配合物の性能は、本発明のhSBSとブレンドすることにより、少なくとも中位の性能にまで改良することができる。100g/10分未満のメルトフローレートを備えるSEBSポリマーに基づく、従来のSEBSベースの配合を含む中位の性能を持つ多くのポリマーとは異なり、この配合物は依然として吹付が可能である。接着性配合物は、感圧接着材、ホットメルト接着剤、建築用接着剤、弾性接着剤などにおいて有用である。概してこれらの配合には、本発明のスチレン系ブロックコポリマー、ポリ−アルファ−オレフィン樹脂、粘着付与樹脂、および鉱油、酸化防止剤などの任意選択の原料が含まれる。通常、これらの組成物には、上記組成物の約30から約80重量%だけ存在するポリ−アルファ−オレフィン、上記組成物の約10から約35重量%だけ存在するスチレン系ブロックコポリマーhSBSおよび/またはhSBSS、ならびに上記組成物の約20から約60重量%だけ存在する上記粘着付与樹脂が含まれる。
標準的な剥離、粘着、凝集および粘度試験を、これらの配合物に対し、感圧テープ評議会(Pressure Sensitive Tape Council)(PSTC)による感圧テープに関する試験法マニュアル(Test method manual for Pressure Sensitive Tapes)、感圧材料に関する標準FINAT試験法(standard FINAT test method for Pressure sensitive materials)、感圧接着テープに関するAFERA試験法(AFERA test methods for Pressure Sensitive Adhesive Tapes)および関連するASTM法に記載の通り実施した。適用における配合物の機能を明らかにするために、異なる試験表面を用いた。即ち、FINATにより推奨されているクロムめっきしたステンレス鋼板(No.304「ss」)およびクラフト紙である。
本発明における接着剤組成物の調製工程には特定の制限は課されない。従って、ロール、バンバリーミキサーまたはDalton社ニーダーを利用する機械的な混合工程、撹拌機、高剪断Z翼ミキサー、一軸または二軸スクリュー押出機を備えた溶融ケトルを用いることにより加熱および混合が行われることを特徴とするホットメルト工程、コンパウンド成分が適した溶媒に注入され、撹拌されることによって、感圧接着組成物の均質な溶液を得ることができる溶媒工程など、任意の工程を用いてもよい。
身体衛生用途向けフィルムおよび不織布の実施例。
スラッシュおよび回転成形の実施例
本発明のポリマーhSBSをベースとする化合物は、スラッシュ成形工程および回転成形工程のように剪断が小さい工程で用いられるとき、改善された溶融特性を示す。スラッシュ成形および回転成形化合物の典型的な配合は、表10で参照することができる。
Claims (4)
- 身体衛生構造物接着剤、弾性付着接着剤またはホットメルト接着剤として使用するための非感圧接着組成物であって、ポリ−アルファ−オレフィン、スチレン系ブロックコポリマーおよび粘着付与樹脂のブレンドを含み、前記スチレン系ブロックコポリマーは、230℃および2.16kgの質量で100g/10分を超えるメルトフローレートを有し、前記スチレン系ブロックコポリマーが、選択的に水素化されたスチレン−ジエン−スチレンまたは選択的に水素化された制御分布スチレン−ジエン/スチレン−スチレンであり、ジエンが、ブタジエン、イソプレン、またはこれらの混合物である、非感圧接着組成物。
- 前記ポリ−アルファ−オレフィンは、前記組成物の30から80重量%存在し、前記スチレン系ブロックコポリマーは、前記組成物の10から35重量%存在し、および前記粘着付与樹脂は、前記組成物の20から60重量%存在する、請求項1に記載の接着組成物。
- 前記ポリ−アルファ−オレフィンは非晶質である、請求項1に記載の接着組成物。
- 請求項1に記載の接着組成物であって、前記スチレン系ブロックコポリマーは、SDSまたは(SD)nXの構造を有する、選択的に水素化された直鎖状またはカップリングされたブロックコポリマーであり、それぞれ、式中、Sはスチレン、Dはジエンまたはジエン/スチレンであり、式中、n=2または3;およびXはカップリング剤残基である、接着組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/404,150 US20130225020A1 (en) | 2012-02-24 | 2012-02-24 | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
US13/404,150 | 2012-02-24 | ||
PCT/US2013/027009 WO2013148024A1 (en) | 2012-02-24 | 2013-02-21 | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016004995A Division JP6321055B2 (ja) | 2012-02-24 | 2016-01-14 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015513584A JP2015513584A (ja) | 2015-05-14 |
JP6001685B2 true JP6001685B2 (ja) | 2016-10-05 |
Family
ID=49003345
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014558810A Active JP6001685B2 (ja) | 2012-02-24 | 2013-02-21 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2016004995A Active JP6321055B2 (ja) | 2012-02-24 | 2016-01-14 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2017156467A Active JP6702917B2 (ja) | 2012-02-24 | 2017-08-14 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016004995A Active JP6321055B2 (ja) | 2012-02-24 | 2016-01-14 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2017156467A Active JP6702917B2 (ja) | 2012-02-24 | 2017-08-14 | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
Country Status (8)
Country | Link |
---|---|
US (5) | US20130225020A1 (ja) |
EP (2) | EP2817371B1 (ja) |
JP (3) | JP6001685B2 (ja) |
KR (1) | KR101680441B1 (ja) |
CN (2) | CN104379667B (ja) |
BR (1) | BR112014020022A8 (ja) |
TW (2) | TWI561602B (ja) |
WO (1) | WO2013148024A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016128622A (ja) * | 2012-02-24 | 2016-07-14 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2016530355A (ja) * | 2013-07-12 | 2016-09-29 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよびその用途 |
US11015046B2 (en) | 2017-07-31 | 2021-05-25 | Kuraray Co., Ltd. | Thermoplastic resin composition, hot melt adhesive, automobile member, and hygienic material member |
Families Citing this family (78)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140141233A1 (en) * | 2012-07-03 | 2014-05-22 | Peterson Chemical Technology, Inc. | Surface Infusion of Flexible Cellular Foams With Novel Liquid Gel Mixture |
US10022889B2 (en) | 2013-03-14 | 2018-07-17 | Stratasys, Inc. | Ceramic support structure |
EP3521012A1 (en) | 2013-09-18 | 2019-08-07 | Firestone Building Products Co., LLC | Peel and stick roofing membranes with cured pressure-sensitive adhesives |
JP6154725B2 (ja) * | 2013-10-24 | 2017-06-28 | ヘンケルジャパン株式会社 | ホットメルト接着剤 |
US10843401B2 (en) | 2013-11-01 | 2020-11-24 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
WO2015081001A1 (en) | 2013-11-26 | 2015-06-04 | Kraton Polymers U.S. Llc | Laser sintering powder, laser sintering article, and a method of making a laser sintering article |
TWI506043B (zh) * | 2013-12-31 | 2015-11-01 | Chi Mei Corp | 異戊二烯-乙烯基芳香烴共聚物及其合成方法 |
CA2941239C (en) | 2014-03-07 | 2022-12-06 | Firestone Building Products Co., LLC | Roofing membranes with pre-applied, cured, pressure-sensitive seam adhesives |
US9394472B2 (en) * | 2014-03-27 | 2016-07-19 | Kraton Polymers U.S. Llc | Low fluid loss drilling fluid compositions comprising diblock copolymers |
JP6212427B2 (ja) * | 2014-03-31 | 2017-10-11 | 株式会社クラレ | エラストマー含有繊維形状複合体基材およびその成形体 |
AU2015256412B2 (en) | 2014-05-05 | 2018-10-25 | Horton, Inc. | Composite fan |
JP6707529B2 (ja) | 2014-09-09 | 2020-06-10 | エイチ.ビー.フラー カンパニー | 弾性ホットメルト接着剤組成物及びそれと共に製造される弾性複合材料 |
US20160101209A1 (en) * | 2014-10-09 | 2016-04-14 | Donn DuBois | Adhesive compositions with amorphous polyolefins |
WO2016060070A1 (ja) * | 2014-10-15 | 2016-04-21 | 日本ゼオン株式会社 | ブロック共重合体水素化物、およびそれからなる延伸フィルム |
AT516548B1 (de) * | 2014-12-04 | 2017-08-15 | Stefanski Claus | Thermoplastisches Gussmaterial |
US10100216B2 (en) | 2014-12-15 | 2018-10-16 | Ppg Industries Ohio, Inc. | Coating compositions, coatings and methods for sound and vibration damping and water resistance |
US9546296B2 (en) | 2014-12-15 | 2017-01-17 | Ppg Industries Ohio, Inc. | Coating compositions, coatings and methods for sound and vibration damping and water resistance |
US10150896B2 (en) * | 2014-12-19 | 2018-12-11 | Tredegar Film Products Corporation | Surface protection film |
US9982098B2 (en) * | 2015-01-29 | 2018-05-29 | Rextac Llc | Performance APAO hot melt adhesives containing high melt flow rate hydrogenated styrene block copolymers |
US10457805B2 (en) | 2015-02-11 | 2019-10-29 | Polyone Corporation | Damping thermoplastic elastomers |
WO2016130627A1 (en) | 2015-02-11 | 2016-08-18 | Polyone Corporation | Damping thermoplastic elastomers |
US10329417B2 (en) | 2015-02-11 | 2019-06-25 | Polyone Corporation | Sound damping thermoplastic elastomer articles |
EP3256526B1 (en) | 2015-02-11 | 2020-05-27 | PolyOne Corporation | Damping thermoplastic elastomer articles with low compression set |
ES2645887T3 (es) * | 2015-02-12 | 2017-12-11 | Dynasol Elastómeros S.A. | Composición de copolímero segmentado con propiedades mejoradas |
WO2016149375A1 (en) * | 2015-03-16 | 2016-09-22 | H.B. Fuller Company | Low application temperature hot melt adhesive composition |
EP3271438B1 (en) * | 2015-03-16 | 2022-12-21 | H.B. Fuller Company | An elastic adhesive composition and an elastic composite made with the same |
CN106147559A (zh) * | 2015-04-01 | 2016-11-23 | 3M创新有限公司 | 聚苯醚化合物作为底涂的方法及其应用、用聚苯醚化合物作为底涂的感压胶膜及其制造方法 |
JPWO2016163409A1 (ja) * | 2015-04-09 | 2018-02-01 | 日本ゼオン株式会社 | 樹脂組成物及びその利用 |
US10053609B2 (en) | 2015-06-12 | 2018-08-21 | Kraton Polymers U.S. Llc | Styrenic block copolymers as thermally-activated viscosifiers for oilfield applications |
CN107849326B (zh) | 2015-06-12 | 2021-04-02 | 科腾聚合物美国有限责任公司 | 用于电缆填充应用的热活化的凝胶 |
CN104910573B (zh) * | 2015-06-26 | 2017-08-15 | 台橡(上海)实业有限公司 | 一种热塑性弹性体医用薄膜材料 |
KR101721635B1 (ko) * | 2015-07-20 | 2017-03-30 | 공요찬 | 스피커 엣지 및 스피커 |
CN105153625A (zh) * | 2015-08-31 | 2015-12-16 | 苏州莱特复合材料有限公司 | 用于运动器材的复合材料及其制备方法 |
TWI617613B (zh) | 2015-09-08 | 2018-03-11 | 科騰聚合物美國有限責任公司 | 共聚酯/控制分佈苯乙烯嵌段共聚物摻合物以及其製造及使用方法 |
KR102546315B1 (ko) * | 2015-09-25 | 2023-06-21 | 삼성전자주식회사 | 리튬전지용 전극 복합분리막 어셈블리 및 이를 포함한 리튬전지 |
WO2017143167A1 (en) | 2016-02-19 | 2017-08-24 | Teknor Apex Company | Fiber forming compositions, fibers and methods for production |
US12006692B2 (en) | 2016-03-25 | 2024-06-11 | Holcim Technology Ltd | Fully-adhered roof system adhered and seamed with a common adhesive |
US20200299965A1 (en) | 2016-03-25 | 2020-09-24 | Firestone Building Products Company, Llc | Fully-adhered roof system adhered and seamed with a common adhesive |
JP2019506973A (ja) | 2016-03-28 | 2019-03-14 | キンバリー クラーク ワールドワイド インコーポレイテッド | 弾性ストランドを貼り付ける方法 |
CN105885733B (zh) * | 2016-05-06 | 2018-05-08 | 广州易嘉粘合剂有限公司 | 一种聚烯烃类热熔胶的制备方法及所制备的聚烯烃类热熔胶 |
EP3317350B1 (en) | 2016-05-27 | 2019-01-09 | SABIC Global Technologies B.V. | Poly(phenylene ether) composition and article |
WO2018005862A1 (en) | 2016-06-30 | 2018-01-04 | Kraton Polymers U.S. Llc | Improved performance high vinyl block copolymer compositions and uses thereof |
MY186706A (en) * | 2016-07-13 | 2021-08-11 | Toyo Boseki | Net-like structure |
US10814593B2 (en) | 2016-07-25 | 2020-10-27 | Avient Corporation | Super-vibration damping thermoplastic elastomer blends and articles made therewith |
JP6992470B2 (ja) | 2016-12-14 | 2022-01-13 | Mcppイノベーション合同会社 | 溶融押出成形用熱可塑性エラストマー組成物、押出成形体及び医療用チューブ |
CA2989709C (en) | 2016-12-21 | 2020-06-09 | Saint-Gobain Adfors Canada, Ltd. | A fiber mat, method of making the fiber mat, and bituminous roofing product |
WO2018151190A1 (ja) * | 2017-02-17 | 2018-08-23 | 積水フーラー株式会社 | ホットメルト接着剤及び伸縮性積層体 |
EP3677645A4 (en) * | 2017-08-31 | 2021-06-02 | Zeon Corporation | MULTI-BLOCK COPOLYMER COMPOSITION OBTAINED BY MODIFICATION TREATMENT, AND FILM |
JP6907090B2 (ja) * | 2017-10-12 | 2021-07-21 | 株式会社イノアックコーポレーション | ホットメルト接着剤組成物 |
CN107698860B (zh) * | 2017-10-30 | 2020-09-08 | 美瑞新材料股份有限公司 | 一种鞋底用高回弹组合物发泡材料及其制备方法 |
CN107674625A (zh) * | 2017-10-30 | 2018-02-09 | 江苏双双高新科技有限公司 | 电子元器件一体成型用胶黏剂及其制备方法 |
CN109810454B (zh) * | 2017-11-22 | 2022-07-08 | 中国石油化工股份有限公司 | 一种免充气轮胎胶料、制备及其应用 |
US11332881B2 (en) | 2018-01-05 | 2022-05-17 | Certainteed Llc | Fiber mat, method of making the fiber mat, and bituminous roofing product |
US10920064B2 (en) | 2018-03-23 | 2021-02-16 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
US11279821B2 (en) | 2018-03-23 | 2022-03-22 | Kraton Polymers Llc | Ultrahigh melt flow styrenic block copolymers |
EP3578384B1 (de) * | 2018-06-05 | 2021-10-20 | Akzenta Paneele + Profile GmbH | Trägermaterial auf basis einer kunststoffzusammensetzung und einer feststoffzusammensetzung auf mineralbasis für dekorierte wand- oder bodenpaneele |
EP3814441B1 (en) * | 2018-06-27 | 2023-11-22 | 3M Innovative Properties Company | Adhesive compositions, assemblies, and methods thereof |
CN109017163A (zh) * | 2018-08-14 | 2018-12-18 | 项晓村 | 一种主动防御轮胎及其生产方法 |
JP2020041141A (ja) * | 2018-09-10 | 2020-03-19 | クレイトン・ポリマーズ・リサーチ・ベー・フェー | ゴム組成物及びその製造方法 |
WO2020088454A1 (zh) | 2018-10-30 | 2020-05-07 | 中国石油化工股份有限公司 | 氢化苯乙烯/共轭二烯烃共聚物及其发泡材料和应用 |
US11732161B2 (en) | 2018-12-18 | 2023-08-22 | Tredegar Surface Protection, Llc | Masking film for protecting sensitive substrates |
CN109897423A (zh) * | 2019-02-20 | 2019-06-18 | 安徽吉川科技有限公司 | 一种空腔防腐材料及其制作方法 |
JP2020183525A (ja) * | 2019-05-03 | 2020-11-12 | クレイトン・ポリマーズ・リサーチ・ベー・フェー | ブロックコポリマー組成物、それから作製されたプリプレグ及び積層体 |
US20200354282A1 (en) * | 2019-05-10 | 2020-11-12 | Owens Corning Intellectual Capital, Llc | Coated roofing materials |
US11613619B2 (en) | 2019-05-29 | 2023-03-28 | Kraton Corporation | Molding compositions and foam molded articles made thereof |
CN110452521A (zh) * | 2019-07-08 | 2019-11-15 | 上海凯牟达新材料科技有限公司 | 热塑性聚氨酯组合物及其制备压敏胶膜的方法 |
CN112239511B (zh) | 2019-07-16 | 2023-07-18 | 旭化成株式会社 | 氢化嵌段共聚物、氢化嵌段共聚物组合物以及成型体 |
CN110437862B (zh) * | 2019-09-04 | 2021-06-08 | 北京旭阳科技有限公司 | 一种中间相沥青焦的制备方法、中间相沥青焦、负极材料及锂电池 |
CN110776764A (zh) * | 2019-09-16 | 2020-02-11 | 山东光韵智能科技有限公司 | 一种高吸音高音阻耐磨内墙面隔音涂料及其制造方法 |
WO2021062432A1 (en) * | 2019-09-23 | 2021-04-01 | The Procter & Gamble Company | Sap immobilizing material based on styrenic block copolymers |
WO2021108160A1 (en) * | 2019-11-25 | 2021-06-03 | Exxonmobil Chemical Patents Inc. | Hot melt pressure-sensitive adhesives and processes for making same |
WO2021178669A1 (en) * | 2020-03-06 | 2021-09-10 | Tredegar Surface Protection, Llc | Carrier film for semiconductor wafer processing |
CN116157470A (zh) * | 2020-07-30 | 2023-05-23 | 株式会社Lg化学 | 热塑性树脂组合物 |
CN112266735B (zh) * | 2020-11-03 | 2022-08-23 | 浙江精华科技有限公司 | 一种一次性无纺布防护服胶带用胶及其制备方法 |
JP2022104079A (ja) | 2020-12-28 | 2022-07-08 | 日本光電工業株式会社 | ガス計測用アダプタ |
CN113896833B (zh) * | 2021-11-11 | 2023-06-20 | 中国科学院长春应用化学研究所 | 一种酮类化合物改性丁二烯-异戊二烯共聚物橡胶及其制备方法和硫化橡胶 |
WO2023249093A1 (ja) * | 2022-06-23 | 2023-12-28 | 株式会社クラレ | 改善された油保持性を有するコポリマーの製造方法 |
WO2024091938A1 (en) * | 2022-10-24 | 2024-05-02 | Ac Products Inc. | Transferable maskants suitable for chemical processing |
Family Cites Families (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US27145A (en) | 1860-02-14 | Mortising-machine | ||
CA716645A (en) | 1965-08-24 | Shell Oil Company | Block polymers and process for preparing them | |
US3595942A (en) | 1968-12-24 | 1971-07-27 | Shell Oil Co | Partially hydrogenated block copolymers |
USRE27145E (en) | 1969-05-20 | 1971-06-22 | Side-chain | |
US3634549A (en) | 1969-08-04 | 1972-01-11 | Shell Oil Co | Conjugated diene block copolymers having a random copolymer elastomeric block and their hydrogenated counterparts |
US3670054A (en) | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
US3700748A (en) | 1970-05-22 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
US3686366A (en) | 1970-07-22 | 1972-08-22 | Shell Oil Co | Hydrohalogenated selectively hydrogenated block copolymers |
US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
US3753938A (en) * | 1972-04-18 | 1973-08-21 | Edwards R Montague | Thermoplastic sheet material |
US4039593A (en) | 1973-05-18 | 1977-08-02 | Lithium Corporation Of America | Preparation of hydroxy-terminated conjugated diene polymers |
US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
US4444953A (en) | 1981-11-12 | 1984-04-24 | Shell Oil Company | Assymetric block copolymers and corresponding adhesive formulations |
US4391949A (en) | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
US4578429A (en) | 1984-08-31 | 1986-03-25 | Shell Oil Company | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
US5371141A (en) | 1985-07-31 | 1994-12-06 | Shell Oil Company | High impact resistant blends of thermoplastic polyamides and modified block copolymers |
JPS6241213A (ja) | 1985-08-16 | 1987-02-23 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | 変性ブロツクコポリマ−、該コポリマ−を含有する耐衝撃性組成物、及び該コポリマ−の製造法 |
US4882384A (en) | 1988-02-01 | 1989-11-21 | Shell Oil Company | Modified block copolymers |
US4970265A (en) | 1989-03-27 | 1990-11-13 | Shell Oil Company | Functionalized polymers and process for modifying unsaturated polymers |
GB9112419D0 (en) | 1991-06-10 | 1991-07-31 | Shell Int Research | Process for polymer preparation |
DE69404125T2 (de) * | 1993-01-08 | 1998-01-22 | Dow Chemical Co | Folien mit hoher festigkeit aus blockcopolymerlatices |
ITMI940871A1 (it) * | 1994-05-05 | 1995-11-05 | M & G Ricerche Spa | Resine poliammidiche con migliorate proprieta' reologiche |
TR199600222A2 (tr) | 1995-03-24 | 1996-10-21 | Shell Int Research | Döner kaliplama ve benzeri islemlerde kullanima uygun,monovinil aromatik blok kopolimer iceren bilesimler ve bunlardan türetilen mikrogranüller ve tozlar. |
TW373000B (en) * | 1996-08-16 | 1999-11-01 | Shell Int Research | Bituminous composition |
US6391981B1 (en) | 1999-04-23 | 2002-05-21 | Kraton Polymers Us Llc | Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls |
US6657000B1 (en) | 1999-06-25 | 2003-12-02 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive (III) |
US6503620B1 (en) | 1999-10-29 | 2003-01-07 | Avery Dennison Corporation | Multilayer composite PSA constructions |
WO2001034719A1 (en) | 1999-11-05 | 2001-05-17 | H.B. Fuller Licensing & Financing, Inc. | Hot melt adhesives and method of use thereof in bookbinding at low application temperature |
US6664309B2 (en) * | 2000-12-07 | 2003-12-16 | Bostik Findley, Inc. | Antimicrobial hot melt adhesive |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US7141621B2 (en) | 2002-02-07 | 2006-11-28 | Kraton Polymers U.S. Llc | Gels from controlled distribution block copolymers |
EP1498458B1 (en) * | 2002-04-24 | 2012-03-28 | Asahi Kasei Chemicals Corporation | Asphalt composition |
JP4606693B2 (ja) * | 2002-11-22 | 2011-01-05 | ソニー株式会社 | 光ディスク、記録装置、再生装置、記録方法、再生方法 |
JP2005025586A (ja) | 2003-07-04 | 2005-01-27 | Hitachi Ltd | 旅行情報提供サービス方法、旅行情報提供サービスシステム、情報提供サービス会社の情報管理サーバおよび旅行情報提供サービス用プログラム |
US20050119403A1 (en) * | 2003-12-01 | 2005-06-02 | St. Clair David J. | Solvent based, elastomeric coatings with lower VOC |
TWI242632B (en) | 2003-12-17 | 2005-11-01 | Univ Nat Taipei Technology | Electro-hydro-dynamic condensing device |
CA2554134C (en) * | 2004-01-23 | 2012-09-11 | Blanco Gmbh + Co Kg | Casting mass, in particular, for the production of kitchen sinks, molded sanitary articles, kitchen worktops or the like |
WO2005092936A2 (en) * | 2004-03-03 | 2005-10-06 | Kraton Polymers Research B.V. | Block copolymers having high flow and high elasticity |
KR100788123B1 (ko) * | 2004-03-03 | 2007-12-21 | 크레이튼 폴리머즈 리서치 비.브이. | 흐름성 및 탄성이 높은 블록 공중합체를 함유하는 중합체조성물 |
JP2005255856A (ja) * | 2004-03-11 | 2005-09-22 | Jsr Corp | 水添ジエン系共重合体及びその製造方法 |
US8182456B2 (en) * | 2004-03-29 | 2012-05-22 | The Procter & Gamble Company | Disposable absorbent articles with components having both plastic and elastic properties |
US7348376B2 (en) * | 2004-04-13 | 2008-03-25 | Kraton Polymers U.S. Llc | Adhesive composition |
US8071681B2 (en) * | 2004-08-13 | 2011-12-06 | Exxonmobil Chemical Patents Inc. | Polymeric compositions including their uses and methods of production |
JP2006152525A (ja) * | 2004-11-08 | 2006-06-15 | Chisso Corp | バインダー不織布及びそれを用いた積層物 |
JP2006342329A (ja) * | 2005-05-09 | 2006-12-21 | Sanyo Chem Ind Ltd | 難接着基材用ホットメルト接着剤 |
TWI326691B (en) | 2005-07-22 | 2010-07-01 | Kraton Polymers Res Bv | Sulfonated block copolymers, method for making same, and various uses for such block copolymers |
US7695812B2 (en) * | 2005-09-16 | 2010-04-13 | Dow Global Technologies, Inc. | Fibers made from copolymers of ethylene/α-olefins |
US20070066753A1 (en) * | 2005-09-16 | 2007-03-22 | Ehrlich Martin L | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers |
US7737206B2 (en) | 2005-11-18 | 2010-06-15 | Exxonmobil Chemical Patents Inc. | Polyolefin composition with high filler loading capacity |
JP2007154364A (ja) * | 2005-12-06 | 2007-06-21 | Toho Tenax Co Ltd | ゴム補強用コード及び繊維強化ゴム材料 |
EP1991518A2 (en) * | 2006-01-20 | 2008-11-19 | Archer-Daniels-Midland Company | Levulinic acid ester derivatives as reactive plasticizers and coalescent solvents |
US20090050266A1 (en) * | 2007-08-21 | 2009-02-26 | Kang Yang | Crosslinked polymeric materials as filler and spacers in adhesives |
US20090096130A1 (en) * | 2007-09-28 | 2009-04-16 | Advanced Composites, Inc. | Thermoplastic polyolefin material with high surface gloss |
JP2011500895A (ja) * | 2007-10-09 | 2011-01-06 | クレイトン ポリマーズ ユー.エス. エルエルシー | 特定のブロックコポリマーから調製される最終使用用途 |
BRPI0820134A2 (pt) * | 2007-12-21 | 2015-05-12 | Kraton Polymers Us Llc | Películas elastoméricas macias |
US7994075B1 (en) * | 2008-02-26 | 2011-08-09 | Honeywell International, Inc. | Low weight and high durability soft body armor composite using topical wax coatings |
US7928156B2 (en) | 2008-06-27 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | Nanocomposite comprising exfoliated nanoclay-styrenic concentrate and methods of preparation |
US20100056721A1 (en) * | 2008-09-03 | 2010-03-04 | Kathryn Wright | Articles prepared from certain hydrogenated block copolymers |
DE102009027447A1 (de) * | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
CN102428143B (zh) | 2010-01-29 | 2015-05-20 | 美国科通聚合物有限公司 | 用于冷凝模塑的热熔性组合物 |
US8324309B2 (en) * | 2010-04-27 | 2012-12-04 | Kraton Polymers Us Llc | High melt flow block copolymers for non-woven adhesives |
CN102116151B (zh) * | 2011-02-24 | 2012-10-03 | 三一重型装备有限公司 | 一种连续采煤机及其截割减速器 |
US20130225020A1 (en) * | 2012-02-24 | 2013-08-29 | Kraton Polymers Us Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
-
2012
- 2012-02-24 US US13/404,150 patent/US20130225020A1/en not_active Abandoned
-
2013
- 2013-01-16 TW TW102101683A patent/TWI561602B/zh active
- 2013-01-16 TW TW104132881A patent/TWI595061B/zh active
- 2013-02-21 EP EP13769284.4A patent/EP2817371B1/en active Active
- 2013-02-21 WO PCT/US2013/027009 patent/WO2013148024A1/en active Application Filing
- 2013-02-21 EP EP18172919.5A patent/EP3381953B1/en active Active
- 2013-02-21 CN CN201380010772.7A patent/CN104379667B/zh active Active
- 2013-02-21 JP JP2014558810A patent/JP6001685B2/ja active Active
- 2013-02-21 BR BR112014020022A patent/BR112014020022A8/pt not_active Application Discontinuation
- 2013-02-21 CN CN201611230886.4A patent/CN107057260B/zh active Active
- 2013-03-15 KR KR1020147026808A patent/KR101680441B1/ko active IP Right Grant
-
2014
- 2014-08-27 US US14/469,695 patent/US9243163B2/en active Active
- 2014-08-27 US US14/469,716 patent/US9359523B2/en active Active
- 2014-08-27 US US14/469,732 patent/US9249335B2/en active Active
-
2015
- 2015-12-17 US US14/972,188 patent/US9637660B2/en active Active
-
2016
- 2016-01-14 JP JP2016004995A patent/JP6321055B2/ja active Active
-
2017
- 2017-08-14 JP JP2017156467A patent/JP6702917B2/ja active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016128622A (ja) * | 2012-02-24 | 2016-07-14 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2018035490A (ja) * | 2012-02-24 | 2018-03-08 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 |
JP2016530355A (ja) * | 2013-07-12 | 2016-09-29 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよびその用途 |
US11015046B2 (en) | 2017-07-31 | 2021-05-25 | Kuraray Co., Ltd. | Thermoplastic resin composition, hot melt adhesive, automobile member, and hygienic material member |
Also Published As
Publication number | Publication date |
---|---|
TW201339268A (zh) | 2013-10-01 |
EP2817371A1 (en) | 2014-12-31 |
CN104379667A (zh) | 2015-02-25 |
TWI595061B (zh) | 2017-08-11 |
KR20150012237A (ko) | 2015-02-03 |
BR112014020022A8 (pt) | 2017-07-11 |
CN107057260A (zh) | 2017-08-18 |
EP2817371A4 (en) | 2016-04-13 |
JP2016128622A (ja) | 2016-07-14 |
US20130225020A1 (en) | 2013-08-29 |
US9359523B2 (en) | 2016-06-07 |
JP2015513584A (ja) | 2015-05-14 |
CN107057260B (zh) | 2020-03-06 |
JP6702917B2 (ja) | 2020-06-03 |
EP2817371B1 (en) | 2018-07-18 |
US20140364532A1 (en) | 2014-12-11 |
US20160102164A1 (en) | 2016-04-14 |
US20140364555A1 (en) | 2014-12-11 |
EP3381953A1 (en) | 2018-10-03 |
JP2018035490A (ja) | 2018-03-08 |
US9637660B2 (en) | 2017-05-02 |
US9243163B2 (en) | 2016-01-26 |
KR101680441B1 (ko) | 2016-11-28 |
EP3381953B1 (en) | 2020-04-01 |
JP6321055B2 (ja) | 2018-05-09 |
CN104379667B (zh) | 2017-02-22 |
US9249335B2 (en) | 2016-02-02 |
BR112014020022A2 (ja) | 2017-06-20 |
WO2013148024A1 (en) | 2013-10-03 |
TW201602279A (zh) | 2016-01-16 |
TWI561602B (en) | 2016-12-11 |
US20140371377A1 (en) | 2014-12-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6321055B2 (ja) | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよび用途 | |
JP6600346B2 (ja) | 高流動水素化スチレン−ブタジエン−スチレンブロックコポリマーおよびその用途 | |
US20030181584A1 (en) | Elastomeric articles prepared from controlled distribution block copolymers | |
JP6488006B2 (ja) | 非晶質ポリオレフィンを有する接着剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150909 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150929 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20151225 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160114 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160209 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20160502 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160715 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160809 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160901 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6001685 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |