JP5848645B2 - リチウムイオン二次電池 - Google Patents
リチウムイオン二次電池 Download PDFInfo
- Publication number
- JP5848645B2 JP5848645B2 JP2012062934A JP2012062934A JP5848645B2 JP 5848645 B2 JP5848645 B2 JP 5848645B2 JP 2012062934 A JP2012062934 A JP 2012062934A JP 2012062934 A JP2012062934 A JP 2012062934A JP 5848645 B2 JP5848645 B2 JP 5848645B2
- Authority
- JP
- Japan
- Prior art keywords
- lithium
- positive electrode
- secondary battery
- ion secondary
- containing composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 109
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 109
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 122
- 229910052744 lithium Inorganic materials 0.000 claims description 122
- 239000002131 composite material Substances 0.000 claims description 99
- 229910021389 graphene Inorganic materials 0.000 claims description 78
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 77
- 239000007774 positive electrode material Substances 0.000 claims description 55
- 239000003792 electrolyte Substances 0.000 claims description 31
- 239000013078 crystal Substances 0.000 claims description 30
- 239000011230 binding agent Substances 0.000 claims description 25
- 229910013275 LiMPO Inorganic materials 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 66
- 238000000034 method Methods 0.000 description 30
- 239000002002 slurry Substances 0.000 description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- 238000012545 processing Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 239000007773 negative electrode material Substances 0.000 description 10
- 239000010450 olivine Substances 0.000 description 10
- 229910052609 olivine Inorganic materials 0.000 description 10
- 239000011888 foil Substances 0.000 description 9
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910052723 transition metal Inorganic materials 0.000 description 9
- 150000003624 transition metals Chemical class 0.000 description 9
- -1 LiMnPO 4 Inorganic materials 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- 239000007784 solid electrolyte Substances 0.000 description 8
- 239000002482 conductive additive Substances 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 239000011572 manganese Substances 0.000 description 7
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229910013716 LiNi Inorganic materials 0.000 description 3
- 239000003929 acidic solution Substances 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
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- 238000000576 coating method Methods 0.000 description 3
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- 229910052751 metal Inorganic materials 0.000 description 3
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- 239000010935 stainless steel Substances 0.000 description 3
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- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910011281 LiCoPO 4 Inorganic materials 0.000 description 2
- 229910013086 LiNiPO Inorganic materials 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
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- 239000000203 mixture Substances 0.000 description 2
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- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MMUHJUKUIJGDJI-UHFFFAOYSA-N [O].[P].[Fe] Chemical compound [O].[P].[Fe] MMUHJUKUIJGDJI-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 230000008859 change Effects 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- 150000001993 dienes Chemical class 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
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- 150000004676 glycans Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- QOSATHPSBFQAML-UHFFFAOYSA-N hydrogen peroxide;hydrate Chemical compound O.OO QOSATHPSBFQAML-UHFFFAOYSA-N 0.000 description 1
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- 239000011229 interlayer Substances 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
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- 239000010936 titanium Substances 0.000 description 1
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- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/043—Processes of manufacture in general involving compressing or compaction
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- H01—ELECTRIC ELEMENTS
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10340561B2 (en) | 2013-11-19 | 2019-07-02 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| US10689769B2 (en) | 2015-05-13 | 2020-06-23 | Aqua Metals Inc. | Electrodeposited lead composition, methods of production, and uses |
| US10793957B2 (en) | 2015-05-13 | 2020-10-06 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
| US11028460B2 (en) | 2015-05-13 | 2021-06-08 | Aqua Metals Inc. | Systems and methods for recovery of lead from lead acid batteries |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8945498B2 (en) * | 2011-03-18 | 2015-02-03 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing lithium-containing composite oxide |
| JP6025284B2 (ja) | 2011-08-19 | 2016-11-16 | 株式会社半導体エネルギー研究所 | 蓄電装置用の電極及び蓄電装置 |
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| US20140023920A1 (en) | 2012-07-20 | 2014-01-23 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery |
| JP6207923B2 (ja) | 2012-08-27 | 2017-10-04 | 株式会社半導体エネルギー研究所 | 二次電池用正極の製造方法 |
| JP6153802B2 (ja) * | 2012-11-30 | 2017-06-28 | 日本碍子株式会社 | 蓄電素子 |
| KR20150107777A (ko) | 2013-01-11 | 2015-09-23 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 전자 디바이스 충전 방법 |
| US9787126B2 (en) | 2013-02-08 | 2017-10-10 | Semiconductor Energy Laboratory Co., Ltd. | Driving method of electrochemical device |
| KR101736975B1 (ko) * | 2013-07-08 | 2017-05-18 | 삼성전자주식회사 | 다층 그래핀막, 다층 그래핀막을 전극으로 사용하는 에너지 저장 장치 및 다층 그래핀막과 에너지 저장 장치의 제조방법 |
| US20150016022A1 (en) | 2013-07-08 | 2015-01-15 | Samsung Corning Precision Materials Co., Ltd. | Multi-layered graphene films, energy storage devices using multi-layered graphene films as electrodes, and methods of manufacturing multi-layered graphene films and energy storage devices |
| KR102172024B1 (ko) * | 2013-07-16 | 2020-10-30 | 삼성에스디아이 주식회사 | 집전체 구조 및 이를 채용한 전극과 리튬 전지 |
| US9496582B1 (en) * | 2014-03-24 | 2016-11-15 | Amazon Technologies, Inc. | Flexible battery |
| KR20240132127A (ko) * | 2014-05-09 | 2024-09-02 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 이온 이차 전지 및 전자 장치 |
| WO2016178117A1 (en) | 2015-05-06 | 2016-11-10 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery and electronic device |
| US10686207B2 (en) | 2015-07-03 | 2020-06-16 | Semiconductor Energy Laboratory Co., Ltd. | Lithium-ion storage battery and electronic device |
| CN105098193A (zh) * | 2015-09-24 | 2015-11-25 | 宁德时代新能源科技有限公司 | 正极片以及包括该正极片的锂离子电池 |
| CN108140812B (zh) * | 2015-10-14 | 2022-02-01 | 西北大学 | 石墨烯涂层金属氧化物尖晶石阴极及其制备方法 |
| JP6917161B2 (ja) * | 2016-03-03 | 2021-08-11 | 株式会社半導体エネルギー研究所 | リチウムイオン二次電池用の正極活物質、二次電池、電池制御ユニットおよび電子機器 |
| US11276849B2 (en) * | 2016-05-12 | 2022-03-15 | ELIIY Power Co., Ltd | Positive electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery |
| US10680242B2 (en) * | 2016-05-18 | 2020-06-09 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing positive electrode active material, and lithium ion battery |
| WO2017203747A1 (ja) * | 2016-05-26 | 2017-11-30 | 株式会社村田製作所 | リチウムイオン二次電池 |
| CN116544521A (zh) | 2016-07-05 | 2023-08-04 | 株式会社半导体能源研究所 | 锂离子二次电池的制造方法 |
| US12308421B2 (en) | 2016-09-12 | 2025-05-20 | Semiconductor Energy Laboratory Co., Ltd. | Electrode and power storage device comprising graphene compound |
| CN116454360A (zh) | 2016-10-12 | 2023-07-18 | 株式会社半导体能源研究所 | 正极活性物质粒子以及正极活性物质粒子的制造方法 |
| JP6686966B2 (ja) | 2017-05-17 | 2020-04-22 | 株式会社デンソー | 回転式アクチュエータ |
| CN108075164A (zh) * | 2016-11-09 | 2018-05-25 | 林逸樵 | 二次电池及其制作方法 |
| JP7097690B2 (ja) * | 2016-12-02 | 2022-07-08 | 株式会社半導体エネルギー研究所 | 電極および蓄電池 |
| WO2018120147A1 (zh) * | 2016-12-30 | 2018-07-05 | 北京旭碳新材料科技有限公司 | 一种制备锂离子电池用石墨烯/三元材料复合物的方法及其产品 |
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| KR20210007149A (ko) * | 2019-07-10 | 2021-01-20 | 현대자동차주식회사 | 전고체 전지용 복합 음극 |
| CN115832176B (zh) * | 2021-10-28 | 2025-02-18 | 宁德时代新能源科技股份有限公司 | 正极极片及其设计方法、二次电池、电池模块、电池包及用电装置 |
| WO2025099550A1 (ja) * | 2023-11-10 | 2025-05-15 | 株式会社半導体エネルギー研究所 | 二次電池およびその作製方法 |
| CN119890233B (zh) * | 2025-01-06 | 2025-11-18 | 合肥国轩高科动力能源有限公司 | 磷酸铁锂正极片及其制备方法和锂离子电池 |
Family Cites Families (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5910382A (en) | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
| US6514640B1 (en) | 1996-04-23 | 2003-02-04 | Board Of Regents, The University Of Texas System | Cathode materials for secondary (rechargeable) lithium batteries |
| JPH1125983A (ja) | 1997-07-04 | 1999-01-29 | Japan Storage Battery Co Ltd | リチウム電池用活物質 |
| JP4482987B2 (ja) * | 1999-12-07 | 2010-06-16 | 株式会社豊田中央研究所 | リチウム二次電池正極活物質用リチウム遷移金属複合酸化物およびその製造方法 |
| US6913855B2 (en) | 2002-07-22 | 2005-07-05 | Valence Technology, Inc. | Method of synthesizing electrochemically active materials from a slurry of precursors |
| JP4058680B2 (ja) | 2002-08-13 | 2008-03-12 | ソニー株式会社 | 正極活物質の製造方法及び非水電解質二次電池の製造方法 |
| JP3632686B2 (ja) | 2002-08-27 | 2005-03-23 | ソニー株式会社 | 正極活物質及び非水電解質二次電池 |
| JP4201619B2 (ja) * | 2003-02-26 | 2008-12-24 | 三洋電機株式会社 | 非水電解質二次電池、及びそれに使用する電極の製造方法 |
| JP2006004739A (ja) * | 2004-06-17 | 2006-01-05 | Toyota Motor Corp | リチウム二次電池と該電池に備えられる正極及びその製造方法 |
| FR2873854A1 (fr) | 2004-07-30 | 2006-02-03 | Commissariat Energie Atomique | Procede de fabrication d'une electrode lithiee, electrode lithiee susceptible d'etre obtenue par ce procede et ses utilisations |
| JP4923397B2 (ja) | 2004-09-06 | 2012-04-25 | 日産自動車株式会社 | 非水電解質リチウムイオン二次電池用正極材料およびその製造方法 |
| US7842432B2 (en) | 2004-12-09 | 2010-11-30 | Nanosys, Inc. | Nanowire structures comprising carbon |
| US8278011B2 (en) | 2004-12-09 | 2012-10-02 | Nanosys, Inc. | Nanostructured catalyst supports |
| EP1829141B1 (en) | 2004-12-09 | 2013-05-29 | Nanosys, Inc. | Nanowire-based membrane electrode assemblies for fuel cells |
| US7939218B2 (en) | 2004-12-09 | 2011-05-10 | Nanosys, Inc. | Nanowire structures comprising carbon |
| JP4273422B2 (ja) | 2005-03-09 | 2009-06-03 | ソニー株式会社 | 正極材料および電池 |
| JP2006252945A (ja) | 2005-03-10 | 2006-09-21 | Sony Corp | 非水電解質二次電池用の電極及びその製造方法、並びに非水電解質二次電池 |
| JP3850427B2 (ja) | 2005-03-22 | 2006-11-29 | 株式会社物産ナノテク研究所 | 炭素繊維結合体およびこれを用いた複合材料 |
| DE102005015613A1 (de) | 2005-04-05 | 2006-10-12 | Süd-Chemie AG | Kristallines Ionenleitendes Nanomaterial und Verfahren zu seiner Herstellung |
| KR100790844B1 (ko) * | 2005-06-01 | 2008-01-02 | 강원대학교산학협력단 | 박막 전지 및 그 제조 방법 |
| JP2007035358A (ja) * | 2005-07-25 | 2007-02-08 | Toyota Central Res & Dev Lab Inc | 正極活物質及びその製造方法、並びにリチウムイオン二次電池 |
| JP5159048B2 (ja) | 2005-09-08 | 2013-03-06 | 三洋電機株式会社 | 非水電解質二次電池 |
| CN101563801B (zh) | 2005-11-21 | 2013-03-27 | 纳米系统公司 | 含碳的纳米线结构体 |
| EP1989747B1 (en) | 2006-02-14 | 2017-04-12 | Dow Global Technologies LLC | Lithium manganese phosphate positive material for lithium secondary battery |
| KR100873273B1 (ko) | 2006-02-17 | 2008-12-11 | 주식회사 엘지화학 | 리튬-금속 복합산화물의 제조방법 |
| JP4767798B2 (ja) | 2006-09-05 | 2011-09-07 | 住友大阪セメント株式会社 | 電極材料の製造方法、リチウムの回収方法、正極材料及び電極並びに電池 |
| US20090197174A1 (en) | 2006-12-22 | 2009-08-06 | Umicore | Synthesis of Electroactive Crystalline Nanometric LiMnPO4 Powder |
| EP2103570A3 (en) | 2006-12-22 | 2011-12-21 | Umicore | Synthesis of electroactive crystalline nanometric LiMnPO4 powder |
| CN101682029A (zh) | 2007-01-25 | 2010-03-24 | 麻省理工学院 | 锂氧化物颗粒上的氧化物涂层 |
| JP4289406B2 (ja) | 2007-02-19 | 2009-07-01 | トヨタ自動車株式会社 | 電極活物質およびその製造方法 |
| US8231998B2 (en) | 2007-03-30 | 2012-07-31 | The Regents Of The University Of Michigan | Deposited microarchitectured battery and manufacturing method |
| JP4317571B2 (ja) | 2007-04-27 | 2009-08-19 | Tdk株式会社 | 活物質、電極、電池、及び活物質の製造方法 |
| US7745047B2 (en) | 2007-11-05 | 2010-06-29 | Nanotek Instruments, Inc. | Nano graphene platelet-base composite anode compositions for lithium ion batteries |
| JP5470700B2 (ja) | 2007-12-10 | 2014-04-16 | 住友大阪セメント株式会社 | 電極材料およびその製造方法、並びに、電極および電池 |
| JP5377946B2 (ja) | 2007-12-25 | 2013-12-25 | 花王株式会社 | リチウム電池正極用複合材料 |
| US8426064B2 (en) | 2007-12-25 | 2013-04-23 | Kao Corporation | Composite material for positive electrode of lithium battery |
| US8236446B2 (en) * | 2008-03-26 | 2012-08-07 | Ada Technologies, Inc. | High performance batteries with carbon nanomaterials and ionic liquids |
| EP2276698A1 (en) | 2008-04-14 | 2011-01-26 | Dow Global Technologies Inc. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| TW200951066A (en) | 2008-04-17 | 2009-12-16 | Basf Se | Process for the preparation of crystalline lithium-, iron-and phosphate-comprising materials |
| WO2009134707A2 (en) * | 2008-04-27 | 2009-11-05 | Board Of Regents, The University Of Texas System | Ultracapacitors and methods of making and using |
| US8257867B2 (en) * | 2008-07-28 | 2012-09-04 | Battelle Memorial Institute | Nanocomposite of graphene and metal oxide materials |
| EP2472656A3 (en) * | 2008-08-15 | 2013-02-20 | Massachusetts Institute of Technology | Layer-by-layer assemblies of carbon-based nanostructures and their applications in energy storage and generation devices |
| JP5098954B2 (ja) | 2008-10-28 | 2012-12-12 | 日本ゼオン株式会社 | 電気化学素子用電極の製造方法および電気化学素子 |
| JP5381024B2 (ja) | 2008-11-06 | 2014-01-08 | 株式会社Gsユアサ | リチウム二次電池用正極及びリチウム二次電池 |
| US8580432B2 (en) | 2008-12-04 | 2013-11-12 | Nanotek Instruments, Inc. | Nano graphene reinforced nanocomposite particles for lithium battery electrodes |
| EP2369666B1 (en) | 2008-12-24 | 2018-09-12 | NGK Insulators, Ltd. | Plate-shaped particles for positive electrode material of lithium secondary batteries, lithium secondary battery positive electrode active material films, manufacturing method therefor, lithium secondary battery positive electrode active material manufacturing method, and lithium secondary batteries |
| US20130045424A1 (en) | 2008-12-24 | 2013-02-21 | Ngk Insulators, Ltd. | Plate-like particle for cathode active material for lithium secondary battery, cathode active material film for lithium secondary battery, methods for manufacturing the particle and film, method for manufacturing cathode active material for lithium secondary battery, and lithium secondary battery |
| WO2010074302A1 (ja) | 2008-12-24 | 2010-07-01 | 日本碍子株式会社 | リチウム二次電池の正極活物質用の板状粒子、及び同物質膜、並びにリチウム二次電池 |
| EP2369660A4 (en) | 2008-12-24 | 2013-11-20 | Ngk Insulators Ltd | PLATE-LIKE PARTICLES FOR POSITIVE ELECTRODE ACTIVE MATERIAL OF LITHIUM SECONDARY BATTERIES, FILMS THEREOF, AND LITHIUM SECONDARY BATTERIES |
| EP2369663A1 (en) | 2008-12-24 | 2011-09-28 | NGK Insulators, Ltd. | Plate-shaped particles for positive electrode active material of lithium secondary batteries, films of said material as well as lithium secondary batteries |
| EP2369664B1 (en) | 2008-12-24 | 2015-02-25 | NGK Insulators, Ltd. | Plate-shaped particles for positive electrode active material of lithium secondary batteries, lithium secondary battery positive electrode active material films, manufacturing method therefor, lithium secondary battery positive electrode active material manufacturing method and lithium secondary batteries |
| CN102171865A (zh) | 2008-12-24 | 2011-08-31 | 日本碍子株式会社 | 锂二次电池的正极活性物质用的板状粒子以及锂二次电池 |
| WO2010074313A1 (ja) | 2008-12-24 | 2010-07-01 | 日本碍子株式会社 | リチウム二次電池の正極活物質用の板状粒子、及び同物質膜、並びにリチウム二次電池 |
| US9093693B2 (en) | 2009-01-13 | 2015-07-28 | Samsung Electronics Co., Ltd. | Process for producing nano graphene reinforced composite particles for lithium battery electrodes |
| EP2383820B1 (en) | 2009-01-15 | 2014-03-26 | GS Yuasa International Ltd. | Positive electrode active material for lithium secondary battery, and lithium secondary battery |
| EP2389662A1 (en) | 2009-01-23 | 2011-11-30 | Koninklijke Philips Electronics N.V. | Cardiac image processing and analysis |
| TW201029918A (en) | 2009-02-12 | 2010-08-16 | Enerage Inc | Method for synthesizing lithium phosphate compound having olivine crystal structure |
| EP2228855B1 (en) | 2009-03-12 | 2014-02-26 | Belenos Clean Power Holding AG | Open porous electrically conductive nanocomposite material |
| JP5381192B2 (ja) * | 2009-03-16 | 2014-01-08 | Tdk株式会社 | リチウムイオン二次電池用活物質の製造方法 |
| JP2010232091A (ja) * | 2009-03-27 | 2010-10-14 | Sumitomo Osaka Cement Co Ltd | リチウムイオン電池用正極活物質の製造方法とリチウムイオン電池用正極活物質及びリチウムイオン電池用電極並びにリチウムイオン電池 |
| WO2010129417A1 (en) | 2009-05-04 | 2010-11-11 | Meecotech, Inc. | Electrode active composite materials and methods of making thereof |
| US20140370380A9 (en) | 2009-05-07 | 2014-12-18 | Yi Cui | Core-shell high capacity nanowires for battery electrodes |
| EP3865454A3 (en) * | 2009-05-26 | 2021-11-24 | Belenos Clean Power Holding AG | Stable dispersions of single and multiple graphene layers in solution |
| EP2448044B1 (en) | 2009-06-24 | 2019-02-27 | GS Yuasa International Ltd. | Positive electrode active material for lithium secondary battery, and lithium secondary battery |
| EP2287946A1 (en) * | 2009-07-22 | 2011-02-23 | Belenos Clean Power Holding AG | New electrode materials, in particular for rechargeable lithium ion batteries |
| KR101748406B1 (ko) * | 2009-08-07 | 2017-06-16 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 |
| US8835046B2 (en) * | 2009-08-10 | 2014-09-16 | Battelle Memorial Institute | Self assembled multi-layer nanocomposite of graphene and metal oxide materials |
| KR101635835B1 (ko) * | 2009-08-11 | 2016-07-05 | 한국세라믹기술원 | 그래핀 산화물의 코팅방법 |
| KR101740692B1 (ko) * | 2009-09-30 | 2017-05-26 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 축전 장치용 전극의 제작 방법 및 축전 장치의 제작 방법 |
| JP2011076820A (ja) | 2009-09-30 | 2011-04-14 | Hitachi Vehicle Energy Ltd | リチウム二次電池及びリチウム二次電池用正極 |
| WO2011057074A2 (en) | 2009-11-06 | 2011-05-12 | Northwestern University | Electrode material comprising graphene-composite materials in a graphite network |
| US9431649B2 (en) | 2009-11-23 | 2016-08-30 | Uchicago Argonne, Llc | Coated electroactive materials |
| US8652687B2 (en) | 2009-12-24 | 2014-02-18 | Nanotek Instruments, Inc. | Conductive graphene polymer binder for electrochemical cell electrodes |
| JP5149920B2 (ja) | 2010-02-05 | 2013-02-20 | トヨタ自動車株式会社 | リチウム二次電池用電極の製造方法 |
| WO2012047316A1 (en) * | 2010-05-21 | 2012-04-12 | Ada Technologies, Inc. | High performance carbon nano-tube composites for electrochemical energy storage devices |
| DE112011102750T5 (de) | 2010-08-19 | 2013-07-04 | Semiconductor Energy Laboratory Co., Ltd. | Elektrisches Gerät |
| EP2445049B1 (en) | 2010-10-22 | 2018-06-20 | Belenos Clean Power Holding AG | Electrode (anode and cathode) performance enhancement by composite formation with graphene oxide |
| KR101924989B1 (ko) | 2011-01-07 | 2018-12-04 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 축전 장치의 제작 방법 |
| US9236197B2 (en) * | 2011-02-18 | 2016-01-12 | The Board Of Trustees Of The Leland Stanford Junior University | Graphene hybrid materials, apparatuses, systems and methods |
| CN102148371A (zh) * | 2011-03-03 | 2011-08-10 | 上海大学 | 三明治结构的石墨烯/磷酸铁锂复合材料及其制备方法 |
| US8945498B2 (en) | 2011-03-18 | 2015-02-03 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing lithium-containing composite oxide |
| US9577261B2 (en) | 2011-03-18 | 2017-02-21 | Semiconductor Energy Laboratory Co., Ltd. | Lithium ion secondary battery and method for manufacturing the same |
| CN102201604A (zh) * | 2011-04-22 | 2011-09-28 | 华南师范大学 | 一种电容电池电芯及其制作方法 |
| JP6057893B2 (ja) | 2011-04-28 | 2017-01-11 | 昭和電工株式会社 | リチウム二次電池用正極材料及びその製造方法 |
| US9249524B2 (en) | 2011-08-31 | 2016-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
| CN102315450A (zh) | 2011-08-31 | 2012-01-11 | 合肥国轩高科动力能源有限公司 | 一种离子掺杂高性能磷酸铁锂的水热合成制备法 |
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| US10665907B2 (en) | 2013-11-19 | 2020-05-26 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| US10689769B2 (en) | 2015-05-13 | 2020-06-23 | Aqua Metals Inc. | Electrodeposited lead composition, methods of production, and uses |
| US10793957B2 (en) | 2015-05-13 | 2020-10-06 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
| US11028460B2 (en) | 2015-05-13 | 2021-06-08 | Aqua Metals Inc. | Systems and methods for recovery of lead from lead acid batteries |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140027166A (ko) | 2014-03-06 |
| WO2012132307A9 (en) | 2013-04-25 |
| DE112012002563T5 (de) | 2014-03-20 |
| KR20190025046A (ko) | 2019-03-08 |
| JP6092989B2 (ja) | 2017-03-08 |
| CN105742570A (zh) | 2016-07-06 |
| JP2016028404A (ja) | 2016-02-25 |
| KR102131859B1 (ko) | 2020-07-08 |
| US20190165370A1 (en) | 2019-05-30 |
| DE112012002563B4 (de) | 2021-10-07 |
| US20120244430A1 (en) | 2012-09-27 |
| US11101460B2 (en) | 2021-08-24 |
| JP2017098270A (ja) | 2017-06-01 |
| KR101954780B1 (ko) | 2019-03-06 |
| US20150263343A1 (en) | 2015-09-17 |
| CN103443971A (zh) | 2013-12-11 |
| JP6377786B2 (ja) | 2018-08-22 |
| US10205160B2 (en) | 2019-02-12 |
| US9059478B2 (en) | 2015-06-16 |
| CN103443971B (zh) | 2016-06-08 |
| KR20200083678A (ko) | 2020-07-08 |
| JP2012216515A (ja) | 2012-11-08 |
| WO2012132307A1 (en) | 2012-10-04 |
| KR102250080B1 (ko) | 2021-05-07 |
| CN105742570B (zh) | 2021-05-07 |
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