JP5319067B2 - Ｅ−ビームにより架橋されたポリマー電解質 - Google Patents

Ｅ−ビームにより架橋されたポリマー電解質 Download PDF

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Publication number
JP5319067B2
JP5319067B2 JP2006539505A JP2006539505A JP5319067B2 JP 5319067 B2 JP5319067 B2 JP 5319067B2 JP 2006539505 A JP2006539505 A JP 2006539505A JP 2006539505 A JP2006539505 A JP 2006539505A JP 5319067 B2 JP5319067 B2 JP 5319067B2
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typically
polymer
mrad
membrane
fluoropolymer
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Expired - Fee Related
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JP2006539505A
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Japanese (ja)
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JP2007514012A (ja
JP2007514012A5 (enExample
Inventor
エー． ヤンドラシッツ，マイケル
ジェイ． ハムロック，スティーブン
ジン，ナイヨン
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C08J5/2293—After-treatment of fluorine-containing membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2006539505A 2003-11-13 2004-10-13 Ｅ−ビームにより架橋されたポリマー電解質 Expired - Fee Related JP5319067B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/712,361 2003-11-13
US10/712,361 US7179847B2 (en) 2003-11-13 2003-11-13 Polymer electrolytes crosslinked by e-beam
PCT/US2004/033807 WO2005052036A1 (en) 2003-11-13 2004-10-13 Polymer electrolytes crosslinked by e-beam

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2012118371A Division JP2012180529A (ja) 2003-11-13 2012-05-24 一体多層式のイオン交換複合膜

Publications (3)

Publication Number Publication Date
JP2007514012A JP2007514012A (ja) 2007-05-31
JP2007514012A5 JP2007514012A5 (enExample) 2007-11-29
JP5319067B2 true JP5319067B2 (ja) 2013-10-16

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JP2006539505A Expired - Fee Related JP5319067B2 (ja) 2003-11-13 2004-10-13 Ｅ−ビームにより架橋されたポリマー電解質
JP2012118371A Withdrawn JP2012180529A (ja) 2003-11-13 2012-05-24 一体多層式のイオン交換複合膜

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JP2012118371A Withdrawn JP2012180529A (ja) 2003-11-13 2012-05-24 一体多層式のイオン交換複合膜

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US (2) US7179847B2 (enExample)
EP (1) EP1689808A1 (enExample)
JP (2) JP5319067B2 (enExample)
KR (1) KR20060117946A (enExample)
CN (1) CN1882640B (enExample)
CA (1) CA2545172A1 (enExample)
TW (1) TW200530285A (enExample)
WO (1) WO2005052036A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
JP4854284B2 (ja) * 2005-12-02 2012-01-18 日東電工株式会社 高分子電解質膜の製造方法
EP2055758A1 (en) * 2007-10-31 2009-05-06 S.A. Imperbel N.V. A bituminous glue.
US20090269644A1 (en) 2008-04-24 2009-10-29 3M Innovative Properties Company Proton conducting materials
CN104801204B (zh) * 2009-02-27 2019-01-01 Emd密理博公司 用于除去蛋白质聚集体的具有磺酸基团的膜
IN2012DN01816A (enExample) * 2009-08-26 2015-06-05 Siemens Pte Ltd
EP2577787B1 (en) 2010-05-25 2016-10-05 3M Innovative Properties Company Reinforced electrolyte membrane
EP2627436B1 (en) 2010-10-15 2018-01-17 Evoqua Water Technologies LLC Process for making a monomer solution for making cation exchange membranes
EP3626341B1 (en) 2010-10-15 2021-06-09 Evoqua Water Technologies LLC Anion exchange membranes and process for making
EP2652049A4 (en) * 2010-12-17 2016-01-13 3M Innovative Properties Co FLUORINATED OLIGOMERS HAVING FRACTIONS CONTAINING PENDING BROMINE
US9711816B2 (en) 2011-08-04 2017-07-18 3M Innovative Properties Company Low equivalent weight polymers
WO2014055123A1 (en) 2012-10-04 2014-04-10 Evoqua Water Technologies Llc High-performance anion exchange membranes and methods of making same
ES2816948T3 (es) 2012-10-11 2021-04-06 Evoqua Water Tech Llc Membranas de intercambio iónico revestidas
WO2015088677A1 (en) 2013-12-12 2015-06-18 Emd Millipore Corporation Protein separations using an acrylamide containing filter
US12163001B2 (en) 2018-09-25 2024-12-10 Evoqua Water Technologies Llc Ion exchange membrane through UV initiation polymerization
CN116387612B (zh) * 2023-02-13 2023-12-15 北京纯锂新能源科技有限公司 一种聚合物电解质膜、制备方法及金属锂电池

Family Cites Families (126)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
GB1184321A (en) 1968-05-15 1970-03-11 Du Pont Electrochemical Cells
US3635926A (en) 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US3784399A (en) 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US4000356A (en) 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US3853828A (en) 1973-11-21 1974-12-10 Us Army Process for crosslinking fluorocarbon polymers
US4169023A (en) 1974-02-04 1979-09-25 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4073752A (en) 1975-06-02 1978-02-14 The B. F. Goodrich Company High normality ion exchange membranes containing entrapped electrostatically bulky multicharged ions and method of production
GB1518387A (en) 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
US4508603A (en) 1976-08-22 1985-04-02 Asahi Glass Company Ltd. Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5329291A (en) 1976-09-01 1978-03-18 Toyo Soda Mfg Co Ltd Cation exchange membrane and production of the same
JPS5397988U (enExample) 1977-01-12 1978-08-09
JPS5397988A (en) 1977-02-08 1978-08-26 Toyo Soda Mfg Co Ltd Production of cation exchange membrane
JPS53134088U (enExample) 1977-03-31 1978-10-24
FR2387260A1 (fr) 1977-04-12 1978-11-10 Rhone Poulenc Ind Membranes echangeuses d'ions
JPS53134088A (en) 1977-04-28 1978-11-22 Asahi Glass Co Ltd Production of fluorocopolymer having ion exchange groups and its crosslinked article
US4230549A (en) 1977-05-31 1980-10-28 Rai Research Corporation Separator membranes for electrochemical cells
JPS53149881A (en) * 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
JPS6026145B2 (ja) 1977-10-04 1985-06-21 旭硝子株式会社 改良された含フツ素陽イオン交換膜
EP0029633B1 (en) 1978-09-05 1983-10-05 Imperial Chemical Industries Plc Polyarylethersulphone copolymers
US4281092A (en) 1978-11-30 1981-07-28 E. I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
US4242498A (en) 1979-04-09 1980-12-30 Frosch Robert A Process for the preparation of fluorine containing crosslinked elastomeric polytriazine and product so produced
JPS5672002A (en) 1979-11-16 1981-06-16 Asahi Glass Co Ltd Production of fluorine-containing polymer containing iodine
US4470889A (en) 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
US4330654A (en) 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
DE3023455A1 (de) 1980-06-24 1982-01-14 Hoechst Ag, 6000 Frankfurt Verfahren zur fluorierung von polymeren und perfluorierte ionenaustauscher
US4334082A (en) 1980-09-26 1982-06-08 E. I. Du Pont De Nemours And Company Dialkyl perfluoro-ω-fluoroformyl diesters and monomers and polymers therefrom
US4414159A (en) 1980-09-26 1983-11-08 E. I. Du Pont De Nemours & Co. Vinyl ether monomers and polymers therefrom
ZA818207B (en) * 1980-11-27 1982-10-27 Ici Australia Ltd Permselective membranes
US4391844A (en) 1981-06-26 1983-07-05 Diamond Shamrock Corporation Method for making linings and coatings from soluble cross-linkable perfluorocarbon copolymers
US4454247A (en) 1981-12-14 1984-06-12 E. I. Du Pont De Nemours & Company Ion exchange membranes
US4440917A (en) 1981-12-14 1984-04-03 E. I. Du Pont De Nemours & Company Vinyl ethers monomers and polymers therefrom
JPS5952690A (ja) * 1982-05-08 1984-03-27 Mitsubishi Paper Mills Ltd ノ−カ−ボン記録紙用顕色剤シ−ト
JPS60250009A (ja) 1984-05-25 1985-12-10 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体の製造方法
DE3568050D1 (en) 1984-07-13 1989-03-09 Atochem New ionic fluorinated polymer, preparation process thereof and electrolysis membranes formed from said polymer
JPH0641494B2 (ja) 1984-08-31 1994-06-01 旭化成工業株式会社 架橋可能な含フツ素共重合体
JPS61164630A (ja) 1985-01-16 1986-07-25 Kinki Kokakoola Botoringu Kk 炭酸水の製造装置
US4686024A (en) 1985-02-01 1987-08-11 The Green Cross Corporation Novel perfluoro chemicals and polyfluorinated compounds and process for production of the same
US4743419A (en) 1985-03-04 1988-05-10 The Dow Chemical Company On-line film fluorination method
US4755567A (en) 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
JPS62288617A (ja) 1986-06-06 1987-12-15 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体を製造する方法
JPH0637416B2 (ja) 1987-06-26 1994-05-18 徳山曹達株式会社 フルオロジビニルエ−テル化合物及びその製造方法
US5693748A (en) 1989-02-01 1997-12-02 Asahi Kasei Kogyo Kabushiki Kaisha High molecular weight polyimidoylamidine and a polytriazine derived therefrom
JP2750594B2 (ja) 1989-02-01 1998-05-13 旭化成工業株式会社 高分子量ポリイミドイルアミジンとその製造法および用途
US5260351A (en) 1989-04-24 1993-11-09 E. I. Du Pont De Nemours And Company Radiation curing of perfluoroelastomers
US5986012A (en) 1989-04-24 1999-11-16 E. I. Du Pont De Nemours And Company Fluorination of radiation crosslinked perfluoroelastomers
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
US5852148A (en) 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US6048952A (en) 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
US5264093A (en) * 1992-04-30 1993-11-23 E. I. Du Pont De Nemours And Company Irradiation of cation exchange membranes to increse current efficiency and reduce power consumption
JP3101085B2 (ja) 1992-05-11 2000-10-23 日東電工株式会社 電池用セパレータの製造法
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
WO1994003503A2 (en) 1992-07-30 1994-02-17 Imperial Chemical Industries Plc Fluorinated polymers
US5330626A (en) * 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
US5608022A (en) 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
US5466930A (en) * 1994-02-23 1995-11-14 Florida State University Solid scintillators for detecting radioactive ions in solution
US5447993A (en) 1994-04-19 1995-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer curing
JP3298321B2 (ja) 1994-08-31 2002-07-02 ダイキン工業株式会社 ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法
US6254978B1 (en) 1994-11-14 2001-07-03 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
USRE37701E1 (en) 1994-11-14 2002-05-14 W. L. Gore & Associates, Inc. Integral composite membrane
USRE37307E1 (en) 1994-11-14 2001-08-07 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
JPH08239494A (ja) 1995-03-02 1996-09-17 Mitsubishi Chem Corp ポリオレフィン系陽イオン交換膜の製造法
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5795496A (en) 1995-11-22 1998-08-18 California Institute Of Technology Polymer material for electrolytic membranes in fuel cells
DE19622337C1 (de) 1996-06-04 1998-03-12 Dlr Deutsche Forschungsanstalt Vernetzung von modifizierten Engineering Thermoplasten
US5798417A (en) 1996-10-15 1998-08-25 E. I. Du Pont De Nemours And Company (Fluorovinyl ether)-grafted high-surface-area polyolefins and preparation thereof
US5747546A (en) 1996-12-31 1998-05-05 The Dow Chemical Company Ion-exchange polymers having an expanded microstructure
WO1998043952A1 (en) 1997-03-31 1998-10-08 Daikin Industries, Ltd. Process for producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
EP0968196B1 (fr) 1997-07-25 2004-10-27 Acep Inc. Composes ioniques perfluorovinyliques et leur utilisation dans des materiaux conducteurs
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
JPH11111310A (ja) 1997-09-30 1999-04-23 Aisin Seiki Co Ltd 燃料電池用の固体高分子電解質膜およびその製造方法
DE19854728B4 (de) 1997-11-27 2006-04-27 Aisin Seiki K.K., Kariya Polymerelektrolyt-Brennstoffzelle
US6462228B1 (en) 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
JPH11204121A (ja) * 1998-01-19 1999-07-30 Aisin Seiki Co Ltd 固体高分子電解質型燃料電池
DE69940033D1 (de) 1998-01-30 2009-01-15 Hydro Quebec Verfahren zur Herstellung von vernetzten sulfonierten Polymeren
DE69904919T2 (de) 1998-03-03 2003-11-13 E.I. Du Pont De Nemours And Co., Wilmington Im wesentlichen fluorierte ionomere
JP4150867B2 (ja) 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
US6090895A (en) 1998-05-22 2000-07-18 3M Innovative Properties Co., Crosslinked ion conductive membranes
BR9911197A (pt) 1998-05-29 2001-02-06 Du Pont Mistura compreendendo um primeiro copolìmero e um segundo copolìmero, fibra, termopolìmero, terpolìmero e processo de produção de um artigo moldado
IL141879A0 (en) 1998-09-15 2002-03-10 Regenesys Tech Ltd A process for the preparation of a monomer-grafted cross-linked polymer
JP2000119420A (ja) 1998-10-19 2000-04-25 Nissan Motor Co Ltd イオン交換膜およびその製造方法
US6385769B1 (en) * 1999-02-03 2002-05-07 International Business Machines Corporation Text based object oriented program code with a visual program builder and parser support for predetermined and not predetermined formats
JP2002538235A (ja) 1999-03-02 2002-11-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ素化コポリマーのフリーラジカル重合方法
JP2000268834A (ja) 1999-03-12 2000-09-29 Mireenu Corporation:Kk プロトン伝導型燃料電池
US6255370B1 (en) 1999-04-29 2001-07-03 Railroad-Solutions, Llc Rail spike retention and tie preservation mixture and method
JP2001029800A (ja) 1999-05-18 2001-02-06 Sumitomo Electric Ind Ltd イオン交換膜、イオン交換膜・電極接合体、及びこれらの製造方法
US6277512B1 (en) 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
JP4539896B2 (ja) 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
CN1233668C (zh) 1999-10-12 2005-12-28 迈克里斯公司 具有亲水官能团的氟烃聚合物及方法
US6423784B1 (en) 1999-12-15 2002-07-23 3M Innovative Properties Company Acid functional fluoropolymer membranes and method of manufacture
JP4714957B2 (ja) 1999-12-21 2011-07-06 旭硝子株式会社 固体高分子電解質型燃料電池
JP4352546B2 (ja) 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
US6780935B2 (en) 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
DE10021104A1 (de) 2000-05-02 2001-11-08 Univ Stuttgart Organisch-anorganische Membranen
DE10024576A1 (de) 2000-05-19 2001-11-22 Univ Stuttgart Kovalent und ionisch vernetzte Polymere und Polymermembranen
US6982303B2 (en) 2000-05-19 2006-01-03 Jochen Kerres Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
JP2001354641A (ja) 2000-06-13 2001-12-25 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
CA2312194A1 (fr) 2000-06-13 2001-12-13 Mario Boucher Elastomeres reticulables fluores bromosulfones a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
JP2002003466A (ja) 2000-06-23 2002-01-09 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
IT1318593B1 (it) 2000-06-23 2003-08-27 Ausimont Spa Ionomeri fluorurati.
IT1318669B1 (it) 2000-08-08 2003-08-27 Ausimont Spa Ionomeri fluorurati solfonici.
CA2328433A1 (fr) 2000-12-20 2002-06-20 Hydro-Quebec Elastomeres nitriles fluorosulfones reticulables a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
WO2002062749A1 (fr) 2001-02-01 2002-08-15 Asahi Kasei Kabushiki Kaisha Monomere d'ether perfluorovinylique ayant un groupe sulfonamide
ITMI20010383A1 (it) 2001-02-26 2002-08-26 Ausimont Spa Membrane idrofiliche porose
DE10114243B4 (de) * 2001-03-22 2004-07-29 Heraeus Kulzer Gmbh & Co. Kg Verfahren zur Herstellung einer Prothese sowie Prothesenwerkstoff und dessen Verwendung
JP2002313364A (ja) 2001-04-13 2002-10-25 Hitachi Cable Ltd 燃料電池用電解質膜及びその製造方法並びに燃料電池
US6503378B1 (en) 2001-04-23 2003-01-07 Motorola, Inc. Polymer electrolyte membrane and method of fabrication
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
KR100403754B1 (ko) 2001-06-19 2003-10-30 송민규 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지
CA2352417A1 (fr) 2001-07-05 2003-01-05 Hydro-Quebec Procede de synthese de monomeres fluorosulfones et leur copolymerisation avec des alcenes fluores
DE10209784A1 (de) 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
CN1571808A (zh) 2001-10-15 2005-01-26 纳幕尔杜邦公司 通过原位聚合制备的用于燃料电池的固体聚合物薄膜
US6727386B2 (en) 2001-10-25 2004-04-27 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination

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CN1882640A (zh) 2006-12-20
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WO2005052036A1 (en) 2005-06-09
US7179847B2 (en) 2007-02-20
CA2545172A1 (en) 2005-06-09
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EP1689808A1 (en) 2006-08-16
TW200530285A (en) 2005-09-16
US20050107488A1 (en) 2005-05-19
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US20070142563A1 (en) 2007-06-21

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