CN1882640B - 用电子束交联的聚合物电解质 - Google Patents

用电子束交联的聚合物电解质 Download PDF

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Publication number
CN1882640B
CN1882640B CN2004800336074A CN200480033607A CN1882640B CN 1882640 B CN1882640 B CN 1882640B CN 2004800336074 A CN2004800336074 A CN 2004800336074A CN 200480033607 A CN200480033607 A CN 200480033607A CN 1882640 B CN1882640 B CN 1882640B
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Prior art keywords
fluoropolymer
typically
polymer
group
electron beam
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Expired - Fee Related
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CN2004800336074A
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English (en)
Chinese (zh)
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CN1882640A (zh
Inventor
迈克尔·A·扬德拉希茨
史蒂文·J·汉罗克
景乃勇
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2287—After-treatment
    • C08J5/2293—After-treatment of fluorine-containing membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CN2004800336074A 2003-11-13 2004-10-13 用电子束交联的聚合物电解质 Expired - Fee Related CN1882640B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/712,361 2003-11-13
US10/712,361 US7179847B2 (en) 2003-11-13 2003-11-13 Polymer electrolytes crosslinked by e-beam
PCT/US2004/033807 WO2005052036A1 (en) 2003-11-13 2004-10-13 Polymer electrolytes crosslinked by e-beam

Publications (2)

Publication Number Publication Date
CN1882640A CN1882640A (zh) 2006-12-20
CN1882640B true CN1882640B (zh) 2010-06-09

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Family Applications (1)

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CN2004800336074A Expired - Fee Related CN1882640B (zh) 2003-11-13 2004-10-13 用电子束交联的聚合物电解质

Country Status (8)

Country Link
US (2) US7179847B2 (enExample)
EP (1) EP1689808A1 (enExample)
JP (2) JP5319067B2 (enExample)
KR (1) KR20060117946A (enExample)
CN (1) CN1882640B (enExample)
CA (1) CA2545172A1 (enExample)
TW (1) TW200530285A (enExample)
WO (1) WO2005052036A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7060756B2 (en) * 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
JP4854284B2 (ja) * 2005-12-02 2012-01-18 日東電工株式会社 高分子電解質膜の製造方法
EP2055758A1 (en) * 2007-10-31 2009-05-06 S.A. Imperbel N.V. A bituminous glue.
EP2554580B1 (en) 2008-04-24 2015-01-14 3M Innovative Properties Company Proton conducting materials
WO2010098867A1 (en) * 2009-02-27 2010-09-02 Millipore Corporation Membrane with sulfonic groups for removing protein aggregates
JP5948243B2 (ja) 2009-08-26 2016-07-06 エヴォクア ウォーター テクノロジーズ ピーティーイー リミテッド イオン交換膜
US9893373B2 (en) 2010-05-25 2018-02-13 3M Innovative Properties Company Reinforced electrolyte membrane
SG189895A1 (en) 2010-10-15 2013-06-28 Siemens Industry Inc Anion exchange membranes and process for making
EA023933B1 (ru) 2010-10-15 2016-07-29 ЭВОКУА УОТЕР ТЕКНОЛОДЖИЗ ЭлЭлСи Способ получения катионообменной мембраны
US9353052B2 (en) 2010-12-17 2016-05-31 3M Innovative Properties Company Fluorinated oligomers having pendant bromine-containing moieties
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
WO2014055123A1 (en) 2012-10-04 2014-04-10 Evoqua Water Technologies Llc High-performance anion exchange membranes and methods of making same
US9540261B2 (en) 2012-10-11 2017-01-10 Evoqua Water Technologies Llc Coated ion exchange membranes
CN105980047B (zh) 2013-12-12 2019-01-04 Emd密理博公司 使用含丙烯酰胺的过滤器分离蛋白
KR102771421B1 (ko) 2018-09-25 2025-02-20 에보쿠아 워터 테크놀로지스 엘엘씨 Uv 개시 중합을 통한 이온 교환막
CN116387612B (zh) * 2023-02-13 2023-12-15 北京纯锂新能源科技有限公司 一种聚合物电解质膜、制备方法及金属锂电池

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4602045A (en) * 1980-11-27 1986-07-22 Ici Australia Limited Cation-exchange resins and use as membranes in electrolytic cells
US5330626A (en) * 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
US5466930A (en) * 1994-02-23 1995-11-14 Florida State University Solid scintillators for detecting radioactive ions in solution

Family Cites Families (123)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
GB1184321A (en) 1968-05-15 1970-03-11 Du Pont Electrochemical Cells
US3635926A (en) 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US3784399A (en) 1971-09-08 1974-01-08 Du Pont Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such
US4000356A (en) 1972-06-19 1976-12-28 Dynamit Nobel Aktiengesellschaft Process for the preparation of thermoplastically workable fluoro-olefin polymers
US3853828A (en) 1973-11-21 1974-12-10 Us Army Process for crosslinking fluorocarbon polymers
US4169023A (en) 1974-02-04 1979-09-25 Tokuyama Soda Kabushiki Kaisha Electrolytic diaphragms, and method of electrolysis using the same
US4035565A (en) 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
US4073752A (en) 1975-06-02 1978-02-14 The B. F. Goodrich Company High normality ion exchange membranes containing entrapped electrostatically bulky multicharged ions and method of production
GB1518387A (en) 1975-08-29 1978-07-19 Asahi Glass Co Ltd Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
US4508603A (en) 1976-08-22 1985-04-02 Asahi Glass Company Ltd. Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide
JPS5329291A (en) 1976-09-01 1978-03-18 Toyo Soda Mfg Co Ltd Cation exchange membrane and production of the same
JPS5397988U (enExample) 1977-01-12 1978-08-09
JPS5397988A (en) 1977-02-08 1978-08-26 Toyo Soda Mfg Co Ltd Production of cation exchange membrane
JPS53134088U (enExample) 1977-03-31 1978-10-24
FR2387260A1 (fr) 1977-04-12 1978-11-10 Rhone Poulenc Ind Membranes echangeuses d'ions
JPS53134088A (en) 1977-04-28 1978-11-22 Asahi Glass Co Ltd Production of fluorocopolymer having ion exchange groups and its crosslinked article
US4230549A (en) 1977-05-31 1980-10-28 Rai Research Corporation Separator membranes for electrochemical cells
JPS53149881A (en) * 1977-06-03 1978-12-27 Asahi Glass Co Ltd Strengthened cation exchange resin membrane and production thereof
JPS6026145B2 (ja) 1977-10-04 1985-06-21 旭硝子株式会社 改良された含フツ素陽イオン交換膜
DE2964541D1 (en) 1978-09-05 1983-02-24 Ici Plc Sulphonated polyaryletherketones and process for the manufacture thereof
US4281092A (en) 1978-11-30 1981-07-28 E. I. Du Pont De Nemours And Company Vulcanizable fluorinated copolymers
US4242498A (en) 1979-04-09 1980-12-30 Frosch Robert A Process for the preparation of fluorine containing crosslinked elastomeric polytriazine and product so produced
JPS5672002A (en) 1979-11-16 1981-06-16 Asahi Glass Co Ltd Production of fluorine-containing polymer containing iodine
US4470889A (en) 1980-06-11 1984-09-11 The Dow Chemical Company Electrolytic cell having an improved ion exchange membrane and process for operating
US4330654A (en) 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
DE3023455A1 (de) 1980-06-24 1982-01-14 Hoechst Ag, 6000 Frankfurt Verfahren zur fluorierung von polymeren und perfluorierte ionenaustauscher
US4334082A (en) 1980-09-26 1982-06-08 E. I. Du Pont De Nemours And Company Dialkyl perfluoro-ω-fluoroformyl diesters and monomers and polymers therefrom
US4414159A (en) 1980-09-26 1983-11-08 E. I. Du Pont De Nemours & Co. Vinyl ether monomers and polymers therefrom
US4391844A (en) 1981-06-26 1983-07-05 Diamond Shamrock Corporation Method for making linings and coatings from soluble cross-linkable perfluorocarbon copolymers
US4440917A (en) 1981-12-14 1984-04-03 E. I. Du Pont De Nemours & Company Vinyl ethers monomers and polymers therefrom
US4454247A (en) 1981-12-14 1984-06-12 E. I. Du Pont De Nemours & Company Ion exchange membranes
JPS5952690A (ja) * 1982-05-08 1984-03-27 Mitsubishi Paper Mills Ltd ノ−カ−ボン記録紙用顕色剤シ−ト
JPS60250009A (ja) 1984-05-25 1985-12-10 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体の製造方法
JPH0657723B2 (ja) 1984-07-13 1994-08-03 エルフ アトケム ソシエテ アノニム 新規なイオン性フッ素化ポリマーと、その製造方法
JPH0641494B2 (ja) 1984-08-31 1994-06-01 旭化成工業株式会社 架橋可能な含フツ素共重合体
JPS61164630A (ja) 1985-01-16 1986-07-25 Kinki Kokakoola Botoringu Kk 炭酸水の製造装置
US4686024A (en) 1985-02-01 1987-08-11 The Green Cross Corporation Novel perfluoro chemicals and polyfluorinated compounds and process for production of the same
US4743419A (en) 1985-03-04 1988-05-10 The Dow Chemical Company On-line film fluorination method
US4755567A (en) 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
JPS62288617A (ja) 1986-06-06 1987-12-15 Asahi Glass Co Ltd スルホン酸型官能基を有するパ−フルオロカ−ボン重合体を製造する方法
JPH0637416B2 (ja) 1987-06-26 1994-05-18 徳山曹達株式会社 フルオロジビニルエ−テル化合物及びその製造方法
US5693748A (en) 1989-02-01 1997-12-02 Asahi Kasei Kogyo Kabushiki Kaisha High molecular weight polyimidoylamidine and a polytriazine derived therefrom
JP2750594B2 (ja) 1989-02-01 1998-05-13 旭化成工業株式会社 高分子量ポリイミドイルアミジンとその製造法および用途
US5986012A (en) 1989-04-24 1999-11-16 E. I. Du Pont De Nemours And Company Fluorination of radiation crosslinked perfluoroelastomers
US5260351A (en) 1989-04-24 1993-11-09 E. I. Du Pont De Nemours And Company Radiation curing of perfluoroelastomers
IT1235545B (it) 1989-07-10 1992-09-09 Ausimont Srl Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione
US5852148A (en) 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US6048952A (en) 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
US5264093A (en) * 1992-04-30 1993-11-23 E. I. Du Pont De Nemours And Company Irradiation of cation exchange membranes to increse current efficiency and reduce power consumption
JP3101085B2 (ja) 1992-05-11 2000-10-23 日東電工株式会社 電池用セパレータの製造法
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
JPH08500374A (ja) 1992-07-30 1996-01-16 インペリアル・ケミカル・インダストリーズ・ピーエルシー フッ素化ポリマー
CN1062873C (zh) 1993-10-12 2001-03-07 旭化成工业株式会社 含官能团的全氟化碳共聚物及其制备方法
US5447993A (en) 1994-04-19 1995-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer curing
JP3298321B2 (ja) 1994-08-31 2002-07-02 ダイキン工業株式会社 ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法
USRE37307E1 (en) 1994-11-14 2001-08-07 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US6254978B1 (en) 1994-11-14 2001-07-03 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
USRE37701E1 (en) 1994-11-14 2002-05-14 W. L. Gore & Associates, Inc. Integral composite membrane
JPH08239494A (ja) 1995-03-02 1996-09-17 Mitsubishi Chem Corp ポリオレフィン系陽イオン交換膜の製造法
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5795496A (en) 1995-11-22 1998-08-18 California Institute Of Technology Polymer material for electrolytic membranes in fuel cells
DE19622337C1 (de) 1996-06-04 1998-03-12 Dlr Deutsche Forschungsanstalt Vernetzung von modifizierten Engineering Thermoplasten
US5798417A (en) 1996-10-15 1998-08-25 E. I. Du Pont De Nemours And Company (Fluorovinyl ether)-grafted high-surface-area polyolefins and preparation thereof
US5747546A (en) 1996-12-31 1998-05-05 The Dow Chemical Company Ion-exchange polymers having an expanded microstructure
EP1026152B1 (en) 1997-03-31 2006-07-26 Daikin Industries, Limited Process for producing perfluorovinyl ethersulfonic acid derivatives
CA2266660C (fr) 1997-07-25 2012-07-17 Acep Inc. Composes ioniques perfluorovinyliques, leurs utilisations comme composants de conducteurs ioniques du type polymere, de membranes selectives, de catalyseurs
US6248469B1 (en) 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
JPH11111310A (ja) 1997-09-30 1999-04-23 Aisin Seiki Co Ltd 燃料電池用の固体高分子電解質膜およびその製造方法
DE19854728B4 (de) 1997-11-27 2006-04-27 Aisin Seiki K.K., Kariya Polymerelektrolyt-Brennstoffzelle
US6462228B1 (en) 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
JPH11204121A (ja) * 1998-01-19 1999-07-30 Aisin Seiki Co Ltd 固体高分子電解質型燃料電池
DE69940033D1 (de) 1998-01-30 2009-01-15 Hydro Quebec Verfahren zur Herstellung von vernetzten sulfonierten Polymeren
WO1999045048A1 (en) 1998-03-03 1999-09-10 E.I. Du Pont De Nemours And Company Substantially fluorinated ionomers
JP4150867B2 (ja) 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
US6090895A (en) 1998-05-22 2000-07-18 3M Innovative Properties Co., Crosslinked ion conductive membranes
EP1082389B1 (en) 1998-05-29 2004-03-24 E.I. Du Pont De Nemours And Company Dyeable fluoropolymer fibers
CA2343115A1 (en) 1998-09-15 2000-03-23 National Power Plc Water based grafting
JP2000119420A (ja) 1998-10-19 2000-04-25 Nissan Motor Co Ltd イオン交換膜およびその製造方法
US6385769B1 (en) * 1999-02-03 2002-05-07 International Business Machines Corporation Text based object oriented program code with a visual program builder and parser support for predetermined and not predetermined formats
AU3511000A (en) 1999-03-02 2000-09-21 E.I. Du Pont De Nemours And Company Free radical polymerization method for fluorinated copolymers
JP2000268834A (ja) 1999-03-12 2000-09-29 Mireenu Corporation:Kk プロトン伝導型燃料電池
US6255370B1 (en) 1999-04-29 2001-07-03 Railroad-Solutions, Llc Rail spike retention and tie preservation mixture and method
JP2001029800A (ja) 1999-05-18 2001-02-06 Sumitomo Electric Ind Ltd イオン交換膜、イオン交換膜・電極接合体、及びこれらの製造方法
US6277512B1 (en) 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
JP4539896B2 (ja) 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
CA2384202A1 (en) 1999-10-12 2001-04-19 Millipore Corporation Fluorocarbon polymeric compositions having hydrophilic functional groups and process
US6423784B1 (en) 1999-12-15 2002-07-23 3M Innovative Properties Company Acid functional fluoropolymer membranes and method of manufacture
JP4714957B2 (ja) 1999-12-21 2011-07-06 旭硝子株式会社 固体高分子電解質型燃料電池
JP4352546B2 (ja) 1999-12-22 2009-10-28 ユニマテック株式会社 フルオロエラストマー、その製造方法、架橋性組成物およびその硬化物
US6780935B2 (en) 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
DE10021104A1 (de) 2000-05-02 2001-11-08 Univ Stuttgart Organisch-anorganische Membranen
US6982303B2 (en) 2000-05-19 2006-01-03 Jochen Kerres Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
DE10024576A1 (de) 2000-05-19 2001-11-22 Univ Stuttgart Kovalent und ionisch vernetzte Polymere und Polymermembranen
CA2312194A1 (fr) 2000-06-13 2001-12-13 Mario Boucher Elastomeres reticulables fluores bromosulfones a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
JP2001354641A (ja) 2000-06-13 2001-12-25 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
JP2002003466A (ja) 2000-06-23 2002-01-09 Asahi Glass Co Ltd 新規含フッ素化合物およびその製造方法
IT1318593B1 (it) 2000-06-23 2003-08-27 Ausimont Spa Ionomeri fluorurati.
IT1318669B1 (it) 2000-08-08 2003-08-27 Ausimont Spa Ionomeri fluorurati solfonici.
CA2328433A1 (fr) 2000-12-20 2002-06-20 Hydro-Quebec Elastomeres nitriles fluorosulfones reticulables a faible tg a base de fluorure de vinylidene et ne contenant ni du tetrafluoroethylene ni de groupement siloxane
WO2002062749A1 (fr) 2001-02-01 2002-08-15 Asahi Kasei Kabushiki Kaisha Monomere d'ether perfluorovinylique ayant un groupe sulfonamide
ITMI20010383A1 (it) 2001-02-26 2002-08-26 Ausimont Spa Membrane idrofiliche porose
DE10114243B4 (de) * 2001-03-22 2004-07-29 Heraeus Kulzer Gmbh & Co. Kg Verfahren zur Herstellung einer Prothese sowie Prothesenwerkstoff und dessen Verwendung
JP2002313364A (ja) 2001-04-13 2002-10-25 Hitachi Cable Ltd 燃料電池用電解質膜及びその製造方法並びに燃料電池
US6503378B1 (en) 2001-04-23 2003-01-07 Motorola, Inc. Polymer electrolyte membrane and method of fabrication
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
KR100403754B1 (ko) 2001-06-19 2003-10-30 송민규 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지
CA2352417A1 (fr) 2001-07-05 2003-01-05 Hydro-Quebec Procede de synthese de monomeres fluorosulfones et leur copolymerisation avec des alcenes fluores
DE10209784A1 (de) 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
EP1444748B1 (en) 2001-10-15 2008-08-13 E.I. Du Pont De Nemours And Company Solid polymer membrane for fuel cell with polyvinylamine imbibed therein for reducing methanol permeability
US6727386B2 (en) 2001-10-25 2004-04-27 3M Innovative Properties Company Aromatic imide and aromatic methylidynetrissulfonyl compounds and method of making
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7259208B2 (en) 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
US7074841B2 (en) 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7179847B2 (en) 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4602045A (en) * 1980-11-27 1986-07-22 Ici Australia Limited Cation-exchange resins and use as membranes in electrolytic cells
US5330626A (en) * 1993-02-16 1994-07-19 E. I. Du Pont De Nemours And Company Irradiation of polymeric ion exchange membranes to increase water absorption
US5466930A (en) * 1994-02-23 1995-11-14 Florida State University Solid scintillators for detecting radioactive ions in solution

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
GAB-JIN H ET AL.PREPERATION OF CATION EXCHANGE MEMBRANE AS ASEPARATOR FOR THE AII-VANADIUM REDOX FLOWBATTERY.JOURNAL OF MEMBRANE SCIENCE第120卷 第1期.1996,第120卷(第1期),第55-67页.
GAB-JIN H ET AL.PREPERATION OF CATION EXCHANGE MEMBRANE AS ASEPARATOR FOR THE AII-VANADIUM REDOX FLOWBATTERY.JOURNAL OF MEMBRANE SCIENCE第120卷 第1期.1996,第120卷(第1期),第55-67页. *

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US7179847B2 (en) 2007-02-20
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