JP4538573B2 - ハイパーブランチポリマーの製造方法 - Google Patents

ハイパーブランチポリマーの製造方法 Download PDF

Info

Publication number
JP4538573B2
JP4538573B2 JP2000506251A JP2000506251A JP4538573B2 JP 4538573 B2 JP4538573 B2 JP 4538573B2 JP 2000506251 A JP2000506251 A JP 2000506251A JP 2000506251 A JP2000506251 A JP 2000506251A JP 4538573 B2 JP4538573 B2 JP 4538573B2
Authority
JP
Japan
Prior art keywords
monomer
reactor
methacrylate
monomer mixture
dimethacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2000506251A
Other languages
English (en)
Japanese (ja)
Other versions
JP2001512752A (ja
JP2001512752A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html
Inventor
キャンベル，ジェー．，デヴィッド
テイマー，ファウド
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of JP2001512752A publication Critical patent/JP2001512752A/ja
Publication of JP2001512752A5 publication Critical patent/JP2001512752A5/ja
Application granted granted Critical
Publication of JP4538573B2 publication Critical patent/JP4538573B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/02—Polymerisation in bulk
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B01J2219/0006—Temperature measurement of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compounds Of Unknown Constitution (AREA)
JP2000506251A 1997-08-05 1998-08-04 ハイパーブランチポリマーの製造方法 Expired - Lifetime JP4538573B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/906,140 1997-08-05
US08/906,140 US5986020A (en) 1997-08-05 1997-08-05 Process for producing hyperbranched polymers
PCT/US1998/016199 WO1999007754A1 (en) 1997-08-05 1998-08-04 Process for producing hyperbranched polymers

Publications (3)

Publication Number Publication Date
JP2001512752A JP2001512752A (ja) 2001-08-28
JP2001512752A5 JP2001512752A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2008-10-30
JP4538573B2 true JP4538573B2 (ja) 2010-09-08

Family

ID=25421991

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000506251A Expired - Lifetime JP4538573B2 (ja) 1997-08-05 1998-08-04 ハイパーブランチポリマーの製造方法

Country Status (12)

Country Link
US (4) US5986020A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP1001998B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP4538573B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR100551187B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1294163C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AT (1) ATE227312T1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU747995B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2295654C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69809247T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (2) MXPA00001295A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW505661B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1999007754A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5986020A (en) * 1997-08-05 1999-11-16 Campbell; J. David Process for producing hyperbranched polymers
CZ302849B6 (cs) * 1998-03-12 2011-12-14 Lucite International Uk Limited Zpusob prípravy rozpustného rozvetveného polymeru, tento polymer, náterová kompozice obsahující tento polymer, lisovaný polymerní výrobek obsahující tento polymer a použití tohoto polymeru
US6806301B2 (en) * 1998-11-30 2004-10-19 Flint Ink Corporation Lithographic printing inks
US6140392A (en) * 1998-11-30 2000-10-31 Flint Ink Corporation Printing inks
US6638995B1 (en) * 1998-11-30 2003-10-28 Flint Ink Corporation Printing inks
FR2791990A1 (fr) * 1999-04-06 2000-10-13 Oreal Composition cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation notamment en capillaire
FR2791986A1 (fr) 1999-04-06 2000-10-13 Oreal Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation
US6946525B2 (en) 1999-04-06 2005-09-20 L'oreal S.A. Composition comprising polymers having a star structure, the polymers, and their use
FR2791988A1 (fr) * 1999-04-06 2000-10-13 Oreal Composition notamment cosmetique ou pharmaceutique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation
FR2791987A1 (fr) 1999-04-06 2000-10-13 Oreal Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation
FR2791989A1 (fr) 1999-04-06 2000-10-13 Oreal Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation
AU6089600A (en) * 1999-07-14 2001-02-05 Johnson Polymer, Inc. Process for the continuous production of gel free polymers, and powder and liquid coating applications containing gel free polymers
ATE315052T1 (de) 1999-07-14 2006-02-15 Johnson Polymer Inc Verfahren zur kontinuierlichen herstellung von epoxy - (meth)acryl - styrolpolymeren und ihre verwendung in beschichtungsmassen
US6605680B1 (en) 2000-04-07 2003-08-12 Eastman Chemical Resins, Inc. Low color, aromatic modified C5 hydrocarbon resins
DE10035119A1 (de) 2000-07-19 2002-01-31 Basf Ag Teilverzweigte Polymere
US20020020669A1 (en) * 2000-07-28 2002-02-21 Kim Yung K. Silicone derivatized macromolecules
EP1367080A1 (en) 2002-05-29 2003-12-03 Hycail B.V. Hyperbranched poly(hydroxycarboxylic acid) polymers
AU2003204606A1 (en) * 2002-06-14 2004-01-15 Rohm And Haas Company Water-based adhesives
US6840175B2 (en) 2002-11-20 2005-01-11 Flint Ink Corporation Lithographic printing method using a single fluid ink
JP3999746B2 (ja) * 2003-05-19 2007-10-31 ローム アンド ハース カンパニー ポリマーナノ粒子の高固形分調製方法
US20050080209A1 (en) * 2003-10-08 2005-04-14 Blankenship Robert Mitchell Continuous production of crosslinked polymer nanoparticles
US6982309B2 (en) * 2003-12-19 2006-01-03 Fina Technology, Inc. Synthesis of branched styrenic copolymers with p-t-butylstyrene
ATE547442T1 (de) 2004-04-02 2012-03-15 Nexttec Gmbh Verfahren zur herstellung eines verbundsorptionsmaterials für die chromatographische trennung von biopolymeren
US7504466B2 (en) * 2004-11-04 2009-03-17 Rohm And Haas Company High solids preparation of crosslinked polymer particles
DE602006007947D1 (de) * 2005-01-25 2009-09-03 Lg Chemical Ltd Thermisch härtbare harzzusammensetzung mit verlängerter lagerungsstabilität und guten hafteigenschaften
US8192695B2 (en) * 2005-05-04 2012-06-05 Fina Technology, Inc. Reactor apparatus having reduced back mixing
US7511101B2 (en) * 2005-05-13 2009-03-31 Fina Technology, Inc. Plug flow reactor and polymers prepared therewith
TWI379849B (en) * 2005-09-20 2012-12-21 Eternal Chemical Co Ltd Radiation-curable alkoxy silanized hyperbranched polyester acrylates and preparation thereof
US8163443B2 (en) * 2006-03-09 2012-04-24 Nippon Steel Chemical Co., Ltd. Photosensitive resin composition for volume phase hologram recording and optical information recording medium using the same
US8231973B2 (en) * 2006-06-13 2012-07-31 3M Innovative Properties Company Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film
US7615283B2 (en) * 2006-06-13 2009-11-10 3M Innovative Properties Company Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film
US10435639B2 (en) 2006-09-05 2019-10-08 Cerion, Llc Fuel additive containing lattice engineered cerium dioxide nanoparticles
WO2008030813A1 (en) * 2006-09-05 2008-03-13 Cerion Technology, Inc. Method of conditioning an internal combustion engine
US8883865B2 (en) 2006-09-05 2014-11-11 Cerion Technology, Inc. Cerium-containing nanoparticles
WO2008124265A2 (en) * 2007-04-09 2008-10-16 Dow Global Technologies, Inc. Capped polyester polyol lubricant composition
US8221574B2 (en) 2007-04-26 2012-07-17 Csd, Llc Top coating for indoor and outdoor temporary removable graphics and system and method for making, applying and removing such graphics
US20080268140A1 (en) 2007-04-26 2008-10-30 Csd, Inc. Temporary removable solvent based protective coating
KR20110005682A (ko) * 2008-01-30 2011-01-18 제론 코포레이션 줄기 세포 유래 심근세포 배양용 합성 표면
CN101939362A (zh) * 2008-01-30 2011-01-05 杰龙公司 用于培养干细胞衍生的少突胶质细胞前体细胞的合成表面
WO2009149225A2 (en) * 2008-06-06 2009-12-10 Avery Dennison Corporation Temporary outdoor graphic film
US7919640B2 (en) * 2008-12-30 2011-04-05 Fina Technology, Inc. Synthesis with metal methacrylates as comonomers
US20100168357A1 (en) * 2008-12-30 2010-07-01 Fina Technology, Inc. Branched Ionomers with Metal Methacrylates as Comonomers
US7919641B2 (en) * 2008-12-30 2011-04-05 Fina Technology, Inc. Synthesis of styrene-soluble ionic comonomer
KR20110122122A (ko) * 2009-01-12 2011-11-09 바스프 에스이 고탄성 연질 폴리우레탄 폼
CN102549033A (zh) 2009-09-30 2012-07-04 巴斯夫欧洲公司 烷氧基化聚合物
JP5658607B2 (ja) * 2010-03-31 2015-01-28 新日鉄住金化学株式会社 多分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物
TWI507425B (zh) * 2010-06-14 2015-11-11 Nippon Steel & Sumikin Chem Co An ultraviolet-curing resin composition for use in an ink-jet printing method, and an optical element
SG11201400246SA (en) * 2011-08-30 2014-03-28 Chevron Phillips Chemical Co Hyperbranched polymers and methods of making and using same
JP5858705B2 (ja) * 2011-09-26 2016-02-10 新日鉄住金化学株式会社 高分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物
JP5913919B2 (ja) * 2011-11-09 2016-04-27 新日鉄住金化学株式会社 高分岐型ゴム変性スチレン系樹脂組成物及びシート
JP5913917B2 (ja) * 2011-11-09 2016-04-27 新日鉄住金化学株式会社 高分岐型発泡用スチレン系樹脂組成物
JP5913918B2 (ja) * 2011-11-09 2016-04-27 新日鉄住金化学株式会社 高分岐型板状押出発泡体用スチレン系樹脂組成物
JP5930667B2 (ja) * 2011-11-09 2016-06-08 新日鉄住金化学株式会社 高分岐型フィルム用スチレン系樹脂組成物及びスチレン系樹脂フィルム
JP5930668B2 (ja) * 2011-11-09 2016-06-08 新日鉄住金化学株式会社 インジェクションブロー成形品の製造方法
JP5930666B2 (ja) * 2011-11-09 2016-06-08 新日鉄住金化学株式会社 高分岐型二軸延伸シート用スチレン系樹脂組成物及び二軸延伸シート
CN102807631A (zh) * 2012-08-15 2012-12-05 罗吉尔 管道式连续聚合反应法
WO2014197421A1 (en) 2013-06-05 2014-12-11 Biotime, Inc. Compositions and methods for induced tissue regeneration in mammalian species
US10143661B2 (en) 2013-10-17 2018-12-04 Cerion, Llc Malic acid stabilized nanoceria particles
US11078462B2 (en) 2014-02-18 2021-08-03 ReCyte Therapeutics, Inc. Perivascular stromal cells from primate pluripotent stem cells
US10240127B2 (en) 2014-07-03 2019-03-26 ReCyte Therapeutics, Inc. Exosomes from clonal progenitor cells
TW201710411A (zh) * 2015-06-09 2017-03-16 P2I有限公司 塗層
CA3202332A1 (en) 2015-12-07 2017-06-15 Agex Therapeutics, Inc. Methods for the re-derivation of diverse pluripotent stem cell-derived brown fat cells
US9869018B2 (en) * 2016-04-26 2018-01-16 Taiwan Semiconductor Manufacturing Co., Ltd. Solid precursor delivery method using liquid solvent for thin film deposition
CN106065053A (zh) * 2016-06-13 2016-11-02 江苏大学 一种超支化聚二乙烯基苯多臂共聚物的合成方法
KR102406946B1 (ko) * 2020-07-16 2022-06-10 한국화학연구원 항균 하이퍼브랜치드 고분자 및 이를 이용한 항균 구형 활성탄
CN112574428B (zh) * 2020-12-16 2022-04-12 济南大学 一种超支化型含氟硅耐高温脱模剂及其应用
CN114426675B (zh) * 2021-12-17 2023-04-07 湖北康创科技有限公司 一种超支化阳离子聚合物乳液及其在污泥脱水上的应用
CN114539642A (zh) * 2022-01-18 2022-05-27 宁波伏龙同步带有限公司 一种机器人用的高性能双面齿覆带及其制备方法
CN115466358B (zh) * 2022-09-30 2024-12-10 中南民族大学 一种无溶剂水溶性氯化聚丙烯的制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE571473A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1957-12-17
DE2936235C2 (de) * 1978-09-09 1984-08-09 Asahi Kasei Kogyo K.K., Osaka Monovinylbenzol-Polyvinylbenzol-Copolymerisat, Verfahren zur Herstellung und dessen Verwendung
DE3026831A1 (de) * 1980-07-16 1982-02-18 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von copolymerisaten auf basis von monovinylaromaten und ethylenisch ungesaettigten carbonsaeuren und deren verwendung von oberflaechenverguetungsmittel
EP0068024B2 (en) * 1981-01-09 1996-02-07 S.C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
US4414370A (en) * 1981-01-09 1983-11-08 S. C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
US5631329A (en) * 1990-08-27 1997-05-20 Dendritech, Inc. Process for producing hyper-comb-branched polymers
SE9103077D0 (sv) * 1991-10-22 1991-10-22 Neste Oy Omaettad etensampolymer och saett foer framstaellning daerav
DE4306384A1 (de) * 1993-03-02 1994-09-08 Basf Ag Chlorfreie, nicht-trocknende Isobuten-Dien-Copolymere
JPH09502212A (ja) * 1993-09-01 1997-03-04 モービル・オイル・コーポレイション 非共役ジエンからの新しい閉環重合ポリマー
US5484866A (en) * 1993-11-09 1996-01-16 Mobil Oil Corporation Concentrates of a highly branched polymer and functional fluids prepared therefrom
FR2714384B1 (fr) * 1993-12-29 1996-02-02 Atochem Elf Sa Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal.
US5414062A (en) * 1994-03-10 1995-05-09 Rohm And Haas Company Method for reduction of aqueous phase polymer formation in suspension polymerization
US5508366A (en) * 1994-10-18 1996-04-16 S. C. Johnson & Son, Inc. Continuous production of reduced gel content hydroxylated addition polymers
US5587441A (en) * 1994-11-08 1996-12-24 Cornell Research Foundation, Inc. Hyperbranched polymers from AB monomers
US5767211A (en) * 1996-05-02 1998-06-16 E. I. Du Pont De Nemours And Company Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst
US5986020A (en) * 1997-08-05 1999-11-16 Campbell; J. David Process for producing hyperbranched polymers

Also Published As

Publication number Publication date
JP2001512752A (ja) 2001-08-28
EP1001998B1 (en) 2002-11-06
WO1999007754A1 (en) 1999-02-18
KR20010022585A (ko) 2001-03-26
EP1001998A1 (en) 2000-05-24
CA2295654A1 (en) 1999-02-18
US5986020A (en) 1999-11-16
MXPA03007260A (es) 2005-09-08
MXPA00001295A (es) 2000-10-31
CA2295654C (en) 2006-05-16
US6265511B1 (en) 2001-07-24
CN1294163C (zh) 2007-01-10
US6627720B2 (en) 2003-09-30
DE69809247D1 (de) 2002-12-12
KR100551187B1 (ko) 2006-02-13
US20040048987A1 (en) 2004-03-11
TW505661B (en) 2002-10-11
CN1265680A (zh) 2000-09-06
MX217863B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2003-12-01
ATE227312T1 (de) 2002-11-15
AU747995B2 (en) 2002-05-30
US20010039316A1 (en) 2001-11-08
AU8767498A (en) 1999-03-01
DE69809247T2 (de) 2003-07-24

Similar Documents

Publication Publication Date Title
JP4538573B2 (ja) ハイパーブランチポリマーの製造方法
JP3628518B2 (ja) メタクリル系重合体およびその製造方法
EP0307238B2 (en) Production of styrene resins by continuous bulk polymerization
KR20030092043A (ko) 물질의 조합 라이브러리 제조를 위한 연속 공정
JPH0912638A (ja) 重合体の連続的製造方法およびこのための装置
WO2008027764A1 (en) Continuous process polymerization of (meth)acrylate copolymers
EP1572750A1 (en) Continuous process for the production of controlled architecture materials under high solids loading conditions
KR20010022584A (ko) 마크로머의 제조 방법
Xiang et al. Tailoring polymer molecular weight distribution and multimodality in RAFT polymerization using tube reactor with recycle
Awad et al. Influence of HMTA ligand in MMA AGET ATRP emulsion polymerization
US6774198B2 (en) Partially branched polymers
JP4676687B2 (ja) （メタ）アクリル系重合体の製造方法
US5473031A (en) Branched polystyrene production by free radical bulk polymerization
JP3506323B2 (ja) 共重合体の製造方法
EP4041785B1 (en) Optical grade moulding compositions having increased thermal stability
Delassus et al. Incorporation of benzocyclobutene into polystyrene allowing postpolymerizer chain extension/branching
JPH10152505A (ja) スチレン−メチルメタクリレート系重合体の製造方法
Nising High-temperature radical polymerization of methyl methacrylate in a continuous pilot scale process
Samdhian Free Radical Polymerization of Acrylic Acid at High Monomer Concentration in a Continuous Flow Reactor
CN117597370A (zh) 制备乙烯基芳香族聚合物的方法

Legal Events

Date Code Title Description
A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20041015

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20041227

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050531

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050531

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080602

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080902

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20080902

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090302

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20090602

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20090611

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090701

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090902

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090909

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20100122

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100125

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100125

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100218

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130702

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term