JP2021521308A - 熱可塑性樹脂組成物 - Google Patents
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- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 58
- 239000011342 resin composition Substances 0.000 title claims abstract description 57
- 239000000178 monomer Substances 0.000 claims abstract description 133
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 86
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 66
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 57
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 48
- 229920001577 copolymer Polymers 0.000 claims abstract description 48
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 31
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 150000003440 styrenes Chemical class 0.000 claims abstract description 11
- 239000007771 core particle Substances 0.000 claims abstract description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 14
- 229920000800 acrylic rubber Polymers 0.000 claims description 6
- HOYUQSOBHNSRER-UHFFFAOYSA-N ethenyl cyanate Chemical compound C=COC#N HOYUQSOBHNSRER-UHFFFAOYSA-N 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 10
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 7
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 6
- 238000004040 coloring Methods 0.000 description 5
- 229920006037 cross link polymer Polymers 0.000 description 4
- -1 ethylhexyl Chemical group 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920006243 acrylic copolymer Polymers 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000007810 chemical reaction solvent Substances 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/08—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of nitriles
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- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/16—Homopolymers or copolymers of alkyl-substituted styrenes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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Abstract
Description
本発明は、2018年10月31日付で出願された韓国特許出願第10−2018−0132192号及び2019年10月28日付で出願された韓国特許出願第10−2019−0134501号に基づく優先権の利益を主張し、当該韓国特許出願の文献に開示されている全ての内容を本明細書の一部として含む。
グラフト率(%):グラフトされた単量体の重量(g)/架橋重合体の重量(g)×100
グラフトされた単量体の重量(g):グラフト共重合体1gをアセトン30gに溶解させて遠心分離した後の不溶性物質(gel)の重量
架橋重合体の重量(g):グラフト共重合体粉末中、理論上投入されたC4からC10のアルキル(メタ)アクリレート系単量体の重量
本発明の一実施形態に係る熱可塑性樹脂組成物は、1)C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む第1のグラフト共重合体と、2)C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む第2のグラフト共重合体と、3)C1からC3のアルキル置換スチレン系単量体、ビニルシアン系単量体及びC1からC3のアルキル(メタ)アクリレート系単量体を含む単量体混合物の共重合物である第1のスチレン系共重合体と、を含んでなり、前記第1のグラフト共重合体と第2のグラフト共重合体はコアの平均粒径が互いに異なる。
第1のグラフト共重合体は、C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む。
第2のグラフト共重合体は、C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む。
第1のスチレン系共重合体は、C1からC3のアルキル置換スチレン系単量体、ビニルシアン系単量体及びC1からC3のアルキル(メタ)アクリレート系単量体を含む単量体混合物の共重合物である。
第2のスチレン系共重合体は、芳香族ビニル系単量体及びビニルシアン系単量体を含む単量体混合物の共重合物であってよい。
(メタ)アクリル系重合体は、C1からC3のアルキル(メタ)アクリレート系単量体単位を含むことができる。
α−メチルスチレン60重量%、アクリロニトリル30重量%及びメチルメタクリレート10重量%を含む単量体混合物95重量部と、反応溶媒としてトルエン5重量部と、開始剤として1,1−ビス(t−ブチルペルオキシ)シクロヘキサン0.075重量部及びポリエーテルポリ−t−ブチルペルオキシカーボネート0.195重量部とを添加して重合溶液を製造した。前記重合溶液を110℃の温度条件の反応器に連続的に投入して重合反応を行った。製造された重合生成物を脱揮発槽に移送させ、235℃の温度及び20.6torrの圧力下で未反応単量体と反応溶媒を回収及び除去してペレット状の耐熱性スチレン系樹脂を製造した。
下記実施例及び比較例で用いられた成分の仕様は、次の通りである。
(C−1)耐熱SAN共重合体:LG化学社製の200UH(α−メチルスチレン及びアクリロニトリルの共重合物)を用いた。
(D−1)ポリ(メチルメタクリレート):LG PMMA社製のIH830を用いた。
実施例及び比較例の熱可塑性樹脂組成物を押出混錬機(シリンダーの温度:240℃)に投入し、押出してペレットを製造し、下記に記載の方法で物性を評価してその結果を[表1]に記載した。
実験例1で製造したペレットを射出して試験片を製造し、下記に記載の方法で評価してその結果を下記[表1]に記載した。
◎:耐候性テストの後、試験片の色感の変化なし。
○:耐候性テストの後、試験片の色感が若干変化。
△:耐候性テストの後、試験片の色感が大きく変化。
Claims (10)
- C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む第1のグラフト共重合体と、
C4からC10のアルキル(メタ)アクリレート系単量体単位、芳香族ビニル系単量体単位及びビニルシアン系単量体単位を含む第2のグラフト共重合体と、
C1からC3のアルキル置換スチレン系単量体、ビニルシアン系単量体及びC1からC3のアルキル(メタ)アクリレート系単量体を含む単量体混合物の共重合物である第1のスチレン系共重合体と、を含んでなり、
前記第1のグラフト共重合体と第2のグラフト共重合体は、コアの平均粒径が互いに異なる、熱可塑性樹脂組成物。 - 前記単量体混合物は、
前記C1からC3のアルキル置換スチレン系単量体50から75重量%と、
前記ビニルシアン系単量体15から40重量%と、
前記C1からC3のアルキル(メタ)アクリレート系単量体1から20重量%と、を含む、請求項1に記載の熱可塑性樹脂組成物。 - 前記第1のグラフト共重合体は、コアの平均粒径が350から600nmである、請求項1又は2に記載の熱可塑性樹脂組成物。
- 前記第2のグラフト共重合体は、コアの平均粒径が30から200nmである、請求項1〜3のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記第1のグラフト共重合体及び第2のグラフト共重合体は、それぞれアクリロニトリル−スチレン−アルキルアクリレート共重合体である、請求項1〜4のいずれか一項に記載の熱可塑性樹脂組成物。
- 前記第1のグラフト共重合体1から20重量%と、
前記第2のグラフト共重合体20から45重量%と、
前記第1のスチレン系共重合体40から70重量%と、を含む、請求項1〜5のいずれか一項に記載の熱可塑性樹脂組成物。 - 第2のスチレン系共重合体をさらに含み、
前記第2のスチレン系共重合体は、芳香族ビニル系単量体及びビニルシアン系単量体を含む単量体混合物の共重合物である、請求項1〜6のいずれか一項に記載の熱可塑性樹脂組成物。 - 前記第2のスチレン系共重合体を1から20重量%で含む、請求項7に記載の熱可塑性樹脂組成物。
- (メタ)アクリル系重合体をさらに含み、
前記(メタ)アクリル系重合体は、C1からC3のアルキル(メタ)アクリレート系単量体単位を含む、請求項1から請求項8のいずれか一項に記載の熱可塑性樹脂組成物。 - 前記(メタ)アクリル系重合体を1から10重量%で含む、請求項9に記載の熱可塑性樹脂組成物。
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2023503073A (ja) * | 2020-09-15 | 2023-01-26 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物、その製造方法及びそれから製造された成形品 |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP4001360A4 (en) * | 2020-06-26 | 2023-06-28 | LG Chem, Ltd. | Thermoplastic resin composition and molded article comprising same |
JP7342252B2 (ja) * | 2020-06-26 | 2023-09-11 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物及びそれを含む成形品 |
CN116406385A (zh) * | 2021-10-12 | 2023-07-07 | 株式会社Lg化学 | 聚合物的制备方法 |
KR20240016797A (ko) * | 2022-07-29 | 2024-02-06 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이로부터 제조되는 성형품 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001253990A (ja) * | 2000-03-13 | 2001-09-18 | Kanegafuchi Chem Ind Co Ltd | 車両灯具成形用樹脂組成物及びそれを用いた車両用灯具 |
JP2002338777A (ja) * | 2001-05-18 | 2002-11-27 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物およびこれを用いた多層押出シート |
JP2006241283A (ja) * | 2005-03-02 | 2006-09-14 | Nippon A & L Kk | 熱可塑性樹脂組成物およびそれからなる樹脂成形品。 |
US20150005435A1 (en) * | 2013-06-28 | 2015-01-01 | Cheil Industries Inc. | Thermoplastic Resin Composition and Molded Article Using the Same |
KR20170090765A (ko) * | 2016-01-29 | 2017-08-08 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5915145B2 (ja) * | 1979-02-23 | 1984-04-07 | 東レ株式会社 | 耐衝撃性熱可塑性樹脂組成物 |
JPS60208352A (ja) * | 1984-04-03 | 1985-10-19 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物 |
JP2941485B2 (ja) | 1991-05-10 | 1999-08-25 | 呉羽化学工業株式会社 | 熱可塑性樹脂組成物 |
JP3278183B2 (ja) * | 1991-10-16 | 2002-04-30 | 鐘淵化学工業株式会社 | 難燃樹脂組成物 |
JP3558373B2 (ja) * | 1994-07-11 | 2004-08-25 | テクノポリマー株式会社 | 熱可塑性樹脂組成物 |
WO1996015190A1 (fr) * | 1994-11-11 | 1996-05-23 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Composition de resine thermoplastique et garnitures pour l'industrie automobile |
US20030236350A1 (en) * | 2002-06-21 | 2003-12-25 | General Electric Company | Impact-modified compositions |
US8969476B2 (en) * | 2002-06-21 | 2015-03-03 | Sabic Global Technologies B.V. | Impact-modified compositions |
ATE338782T1 (de) * | 2003-05-09 | 2006-09-15 | Gen Electric | Schlagzäh modifizierte zusammensetzungen und verfahren |
US20040225034A1 (en) | 2003-05-09 | 2004-11-11 | General Electric Company | Impact-modified compositions and method |
KR100509868B1 (ko) * | 2003-06-09 | 2005-08-22 | 주식회사 엘지화학 | 내후성 및 외관특성이 우수한 열가소성 수지 조성물 |
KR100626956B1 (ko) | 2004-08-17 | 2006-09-20 | 주식회사 엘지화학 | 그라프트 공중합체 조성물 및 이를 이용한 열가소성 수지조성물 |
KR101151062B1 (ko) | 2006-10-18 | 2012-06-01 | 주식회사 엘지화학 | 내열성 및 가공성이 우수한 알파메틸스티렌 -아크릴로니트릴 - 메틸메타크릴레이트 공중합 수지 및 그제조방법 |
US20080242779A1 (en) * | 2007-04-02 | 2008-10-02 | Satish Kumar Gaggar | Resinous compositions and articles made therefrom |
US8318851B2 (en) * | 2007-10-16 | 2012-11-27 | Sabic Innovative Plastics Ip B.V. | Weatherable resinous compositions |
US20100160190A1 (en) | 2008-12-19 | 2010-06-24 | Kuvshinnikova Olga I | Weatherable colored resinous composition and method |
KR101466152B1 (ko) | 2010-12-24 | 2014-11-27 | 제일모직 주식회사 | 아크릴계 수지 조성물 및 이를 이용한 성형품 |
KR101531613B1 (ko) * | 2011-11-24 | 2015-06-25 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101486564B1 (ko) | 2012-07-04 | 2015-01-26 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101425754B1 (ko) | 2012-08-27 | 2014-08-05 | 주식회사 엘지화학 | 아크릴로니트릴―아크릴레이트―스티렌 그라프트 공중합체 및 이를 포함하는 열가소성 수지 조성물 |
KR101654722B1 (ko) * | 2012-12-28 | 2016-09-13 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 포함한 성형품 |
KR20140086729A (ko) | 2012-12-28 | 2014-07-08 | 제일모직주식회사 | 투명 열가소성 수지 조성물 및 이를 이용한 성형품 |
WO2014104485A1 (ko) | 2012-12-28 | 2014-07-03 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 포함한 성형품 |
KR101681212B1 (ko) * | 2013-09-03 | 2016-11-30 | 롯데첨단소재(주) | 열가소성 수지 조성물을 이용한 자동차용 성형품 |
KR20150114239A (ko) * | 2014-04-01 | 2015-10-12 | 제일모직주식회사 | 내열성 및 착색성이 향상된 열가소성 수지 조성물 |
KR101719034B1 (ko) * | 2014-08-29 | 2017-03-22 | 롯데첨단소재(주) | 열가소성 수지 조성물 |
KR101905939B1 (ko) | 2015-08-31 | 2018-10-08 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 이의 제조방법 |
KR101816428B1 (ko) * | 2016-08-04 | 2018-01-08 | 현대자동차주식회사 | 내후성 및 내열성이 우수한 저광택 asa계 수지 조성물 |
KR102056742B1 (ko) * | 2016-11-04 | 2019-12-18 | 주식회사 엘지화학 | 내후성이 우수한 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품 |
KR102197799B1 (ko) * | 2016-12-28 | 2021-01-04 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 사출 성형품 |
-
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- 2019-10-29 EP EP19878064.5A patent/EP3875534B1/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001253990A (ja) * | 2000-03-13 | 2001-09-18 | Kanegafuchi Chem Ind Co Ltd | 車両灯具成形用樹脂組成物及びそれを用いた車両用灯具 |
JP2002338777A (ja) * | 2001-05-18 | 2002-11-27 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物およびこれを用いた多層押出シート |
JP2006241283A (ja) * | 2005-03-02 | 2006-09-14 | Nippon A & L Kk | 熱可塑性樹脂組成物およびそれからなる樹脂成形品。 |
US20150005435A1 (en) * | 2013-06-28 | 2015-01-01 | Cheil Industries Inc. | Thermoplastic Resin Composition and Molded Article Using the Same |
KR20170090765A (ko) * | 2016-01-29 | 2017-08-08 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2023503073A (ja) * | 2020-09-15 | 2023-01-26 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物、その製造方法及びそれから製造された成形品 |
JP7455973B2 (ja) | 2020-09-15 | 2024-03-26 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物、その製造方法及びそれから製造された成形品 |
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US11608401B2 (en) | 2023-03-21 |
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