JP2017501527A - 導電フィルム - Google Patents
導電フィルム Download PDFInfo
- Publication number
- JP2017501527A JP2017501527A JP2016517002A JP2016517002A JP2017501527A JP 2017501527 A JP2017501527 A JP 2017501527A JP 2016517002 A JP2016517002 A JP 2016517002A JP 2016517002 A JP2016517002 A JP 2016517002A JP 2017501527 A JP2017501527 A JP 2017501527A
- Authority
- JP
- Japan
- Prior art keywords
- conductive film
- resin
- metal layer
- film according
- stress relaxation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012360 testing method Methods 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims description 75
- 239000002184 metal Substances 0.000 claims description 75
- 229920005989 resin Polymers 0.000 claims description 74
- 239000011347 resin Substances 0.000 claims description 74
- 239000003822 epoxy resin Substances 0.000 claims description 40
- 229920000647 polyepoxide Polymers 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 36
- 230000008569 process Effects 0.000 claims description 20
- 229920001187 thermosetting polymer Polymers 0.000 claims description 13
- 230000001788 irregular Effects 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 238000004364 calculation method Methods 0.000 claims description 9
- 239000000758 substrate Substances 0.000 claims description 9
- 238000002834 transmittance Methods 0.000 claims description 9
- 238000005259 measurement Methods 0.000 claims description 7
- 239000010931 gold Substances 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 15
- 239000012789 electroconductive film Substances 0.000 claims 1
- 239000011342 resin composition Substances 0.000 description 32
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- 125000004122 cyclic group Chemical group 0.000 description 22
- 239000003795 chemical substances by application Substances 0.000 description 21
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- 125000000524 functional group Chemical group 0.000 description 11
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- 230000000052 comparative effect Effects 0.000 description 10
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- 238000001035 drying Methods 0.000 description 6
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 5
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- 229920000858 Cyclodextrin Polymers 0.000 description 4
- UENWRTRMUIOCKN-UHFFFAOYSA-N benzyl thiol Chemical class SCC1=CC=CC=C1 UENWRTRMUIOCKN-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920003986 novolac Polymers 0.000 description 4
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- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
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- 238000012937 correction Methods 0.000 description 3
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- TUPXQRMDEWSUSH-UHFFFAOYSA-N 1-phenyl-9h-fluoren-2-ol Chemical compound OC1=CC=C2C3=CC=CC=C3CC2=C1C1=CC=CC=C1 TUPXQRMDEWSUSH-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
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- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- LUFPJJNWMYZRQE-UHFFFAOYSA-N benzylsulfanylmethylbenzene Chemical class C=1C=CC=CC=1CSCC1=CC=CC=C1 LUFPJJNWMYZRQE-UHFFFAOYSA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical group O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
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- KMOUUZVZFBCRAM-UHFFFAOYSA-N 1,2,3,6-tetrahydrophthalic anhydride Chemical compound C1C=CCC2C(=O)OC(=O)C21 KMOUUZVZFBCRAM-UHFFFAOYSA-N 0.000 description 1
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- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- MODAACUAXYPNJH-UHFFFAOYSA-N 1-(methoxymethyl)-4-[4-(methoxymethyl)phenyl]benzene Chemical group C1=CC(COC)=CC=C1C1=CC=C(COC)C=C1 MODAACUAXYPNJH-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本実施形態で用いられる伸張−復元試験では、フィルム片(厚み:50μm、サンプル形状:ダンベル6号(測定部位幅:4mm、平行部分長さ:25mm))を用いて、ISO3384に準拠した引張−圧縮試験機(例えば、島津製作所製のオートグラフ(型式:AGS-X))を用いて、下記条件で伸張行程を行った後に復元行程を行い、下記算出方法によって応力緩和率R及び残留歪み率αを計算する。
試験片をつかみ具に取り付けたときに発生するたわみを除去するために、たわみ補正を0.05N以下の力で行う。
試験速度:25mm/min、0〜25%伸張まで
温度条件:23℃
伸張・保持条件:25%伸張で、保持時間5分
試験速度:0.1mm/min、引張力が0±0.05Nになるまで
温度条件:23℃
20%≦R≦95%かつ
0%≦α≦3%
(熱硬化性樹脂)
・ポリロタキサン:(アドバンス・ソフトマテリアルズ社製「A1000」、PEGを軸分子、α−シクロデキストリンを環状分子とし、反応基としてOH基を有する)
・エポキシ樹脂(三菱化学製「JER1003」、メチル基が7〜8個、2官能、分子量1300)
・エポキシ樹脂(DIC製「EXA−4816」、分子量824、メチル基多数、2官能)
・エポキシ樹脂(新日鉄住友金属化学製「YP50」、分子量60000〜80000、メチル基多数、2官能)
・エチレンオキサイド付加型ヒドロキシフェニルフルオレン型エポキシ樹脂(大阪ガスケミカル製「EG−280」)
・プロピレンオキサイド付加型ビスフェノールA型エポキシ樹脂(ADEKA製「EP−4003S」)
(硬化剤)
・多官能フェノール系硬化剤(日本化薬(株)製「GPH−103」、ビフェニルアラルキル型フェノール)
・イミダゾール系硬化促進剤(四国化成製「2E4MZ」、2エチル4メチルイミダゾール)
・ポリイソシアネート(ポリイソシアネート、DIC製「DN950」)
・カチオン硬化剤(三新化学製「SI−150」、六フッ化アンチモンスルホニウム塩)
(樹脂基材比較例)
・PETフィルム(東洋紡社製「A4300」)
下記表1に示す配合組成(質量部)で、固形分濃度が40質量%となるように、溶剤(メチルエチルケトン)に添加して、各成分を均一に混合し、樹脂基材1〜5用の樹脂組成物を調製した。
(実施例1〜9、比較例1〜3、5、7、9、11)
それぞれ表2および3に示す樹脂基材又はフィルム上に、ドライフィルムレジストをラミネートし、ドット網パターン、ジグザグ網パターン、ランダム網パターンのマスクを用いて露光、現像により各網パターンレジスト層を形成した。網パターンレジスト層付き樹脂フィルムをマグネトロンスパッタ法により金(Au)を10nm、銀(Ag)を10nm、ITOを100nmの膜厚になるように蒸着し、苛性ソーダ水溶液でレジストを剥離し、網パターン金属層付き樹脂フィルムを得た。
PETフィルム上にドライフィルムレジストをラミネートし、ランダム網パターンのマスクを用いて露光、現像により各網パターンレジスト層を形成した。網パターンレジスト層付きPETフィルムをマグネトロンスパッタ法によりAgを10nmの膜厚になるように蒸着し、苛性ソーダ水溶液でレジストを剥離し、網パターン金属層付きPETフィルムを得た。網パターン金属層付きPETフィルムを電着レジスト水溶液(エレコートPI(シミズ社製))中で金属層にレジスト樹脂を電着した。電着済みの網パターン金属層付きPETフィルム面に樹脂基材5の樹脂組成物を塗布し、100℃にて10分乾燥し溶媒を除去した後、170℃で60分間加熱硬化させ、電着済み網パターン金属層付きPETフィルム上に厚み50μmとなる樹脂フィルムを得た。
それぞれの樹脂フィルム上にマグネトロンスパッタ法によりAgを10nm、ITOを100nmの膜厚になるように蒸着し、金属層付き樹脂フィルムを得た。
本実施例で用いられる伸張−復元試験では、上記実施例および比較例のサンプルを用いて、下記条件で伸張行程を行った後に復元行程を行い、下記算出方法によって応力緩和率R及び残留歪み率αを計算した。
試験片をつかみ具に取り付けたときに発生するたわみを除去するために、たわみ補正を0.05N以下の力で行った。
試験速度:25mm/min、0〜25%伸張まで
温度条件:23℃
伸張・保持条件:25%伸張で、保持時間5分
試験速度:0.1mm/min、引張力が0±0.05Nになるまで
温度条件:23℃
応力緩和率算出方法:伸張行程終了時の引張力の測定を行い、これを初期引張力FA0とした。その後、上述の伸張・保持条件で歪量を保持し5分後に引張力を測定した。これをFA(t10)とする。応力緩和率Rは下記式によって計算した。
上記実施例および比較例のサンプルを用いて、ISO3384に準拠した引張−圧縮試験機で、下記条件で伸張行程を行い、伸張終了時の引張力の測定を行って、これを初期引張力FB0とした。その後、30分後に引張力FB(t30)を測定した。
試験片をつかみ具に取り付けたときに発生するたわみを除去するために、たわみ補正を行う。たわみ補正は、0.05N以下の力で行った。
試験速度:25mm/min、50%伸張まで
温度条件:23℃
伸張・保持条件:50%伸張で、保持時間30分
得られた各導電フィルムを、ISO3195に準拠した試験機で表面抵抗値を測定した。結果を表2および3に示す。
得られた各導電フィルムを、ISO2556に準拠した試験機で全光線透過率を測定した。結果を表2および3に示す。
得られた各導電フィルムを、長さ6cm、幅5mmの寸法で切り出し、フィルム延伸機につかみ具間距離が4cmとなるようにセットした。そして、フィルムの伸張前と伸張率25%の伸張時、さらにつかみ具を戻しフィルムが元の位置へ復元したところで、それぞれ抵抗計(日置電機社製RM3548)を用いて端子間距離が3cmとなる位置で抵抗値を測定した。伸縮前の抵抗値からの抵抗増加量を100分率で示した結果を表2および3に示す。
比較例1〜3では、従来の熱可塑フィルムで、導電フィルム用の可とう性基材として実績のあるPETフィルム(A4300)を樹脂基材とし、本発明の実施例として使われる網パターン金属層形成手法を用いてそれぞれ導電フィルムを作成し、実施例との比較を行った。
Claims (13)
- 弾性変形可能な樹脂基材上に、規則的なメッシュ構造もしくは不規則的なランダムメッシュ構造を有する金属層を形成した導電フィルムであって、
以下の伸張−復元試験により測定される応力緩和率Rおよび残留歪みαが、以下の式を満たすことを特徴とする、導電フィルム。
20%≦R≦95%かつ
0%≦α≦3%
〔伸張−復元試験〕
フィルム片(厚み:50μm、サンプル形状:ダンベル6号(測定部位幅:4mm、平行部分長さ:25mm))を用いて、ISO3384に準拠した引張−圧縮試験機で、下記条件で伸張行程を行った後に復元行程を行い、下記算出方法によって応力緩和率R及び残留歪み率αを計算する。
伸張行程条件:
試験片をつかみ具に取り付けたときに発生するたわみを除去するために、たわみ
補正を0.05N以下の力で行う。
試験速度:25mm/min、0〜25%伸張まで
温度条件:23℃
伸張・保持条件:25%伸張で、保持時間5分
復元行程条件:
試験速度:0.1mm/min、引張力が0±0.05Nになるまで
温度条件:23℃
応力緩和率算出方法:伸張行程終了時の引張力の測定を行い、これを初期引張力FA0とする。その後、上述の伸張・保持条件で歪量を保持し5分後に引張力を測定する。これをFA(t5)とする。応力緩和率Rは下記式によって計算する。
- 前記樹脂基材が少なくとも熱硬化性樹脂を含有する、請求項1記載の導電フィルム。
- 前記熱硬化性樹脂がエポキシ樹脂である、請求項2記載の導電フィルム。
- 前記金属層が、金、銀、銅、アルミ、又はそれらの金属の組合せのうち少なくとも一つを含有する、請求項1〜3のいずれかに記載の導電フィルム。
- 前記金属層において、金属で被覆される面積が5〜80%である、請求項1〜4のいずれかに記載の導電フィルム。
- 前記金属層の厚みが10μm以下かつ最小線幅が0.1μm以上である、請求項1〜5のいずれかに記載の導電フィルム。
- 前記金属層の一部もしくは全体が、弾性変形可能な前記樹脂基材に埋め込まれている、請求項1〜6のいずれかに記載の導電フィルム。
- 前記金属層と前記樹脂基材層との間に、前記樹脂基材層の樹脂とは異なる組成の樹脂層を有する、請求項1〜7のいずれかに記載の導電フィルム。
- 全光線透過率が70%以上である、請求項1〜8のいずれかに記載の導電フィルム。
- 請求項1〜9のいずれかに記載の導電フィルムの金属層を、部分的に除去することによりパターニングしている、導電フィルム。
- 請求項1〜10に記載の導電フィルムを用いるディスプレイ。
- 請求項1〜10に記載の導電フィルムを用いるタッチセンサ。
- 請求項1〜10に記載の導電フィルムを用いる太陽電池。
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