JP2014515044A5 - - Google Patents
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- Publication number
- JP2014515044A5 JP2014515044A5 JP2014500241A JP2014500241A JP2014515044A5 JP 2014515044 A5 JP2014515044 A5 JP 2014515044A5 JP 2014500241 A JP2014500241 A JP 2014500241A JP 2014500241 A JP2014500241 A JP 2014500241A JP 2014515044 A5 JP2014515044 A5 JP 2014515044A5
- Authority
- JP
- Japan
- Prior art keywords
- phosphorus
- polyol
- flame retardant
- containing flame
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 50
- 229910052698 phosphorus Inorganic materials 0.000 claims description 50
- 239000011574 phosphorus Substances 0.000 claims description 50
- 229920005862 polyol Polymers 0.000 claims description 45
- 150000003077 polyols Chemical class 0.000 claims description 45
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 38
- 239000003063 flame retardant Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- -1 alkylene radical Chemical class 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 150000001412 amines Chemical group 0.000 claims description 6
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000004971 nitroalkyl group Chemical group 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- VZMUCIBBVMLEKC-UHFFFAOYSA-N 2-chloro-5,5-dimethyl-1,3,2$l^{5}-dioxaphosphinane 2-oxide Chemical compound CC1(C)COP(Cl)(=O)OC1 VZMUCIBBVMLEKC-UHFFFAOYSA-N 0.000 claims description 2
- RAOZVFGTRXLBTA-UHFFFAOYSA-N 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphinane Chemical compound CC1(C)COP(Cl)OC1 RAOZVFGTRXLBTA-UHFFFAOYSA-N 0.000 claims description 2
- TXHWYSOQHNMOOU-UHFFFAOYSA-N chloro(diethoxy)phosphane Chemical compound CCOP(Cl)OCC TXHWYSOQHNMOOU-UHFFFAOYSA-N 0.000 claims description 2
- LGTLXDJOAJDFLR-UHFFFAOYSA-N diethyl chlorophosphate Chemical compound CCOP(Cl)(=O)OCC LGTLXDJOAJDFLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000006353 oxyethylene group Chemical group 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 2
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical group COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001414 amino alcohols Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNPCT/CN2011/072072 | 2011-03-23 | ||
| PCT/CN2011/072072 WO2012126179A1 (en) | 2011-03-23 | 2011-03-23 | Phosphorous-containing flame retardants for polyurethane foams |
| PCT/CN2012/072802 WO2012126380A1 (en) | 2011-03-23 | 2012-03-22 | Phosphorous-containing flame retardants for polyurethane foams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014515044A JP2014515044A (ja) | 2014-06-26 |
| JP2014515044A5 true JP2014515044A5 (enExample) | 2016-03-24 |
Family
ID=46878610
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500227A Pending JP2014508841A (ja) | 2011-03-23 | 2011-03-23 | ポリウレタンフォームのためのリン含有難燃剤 |
| JP2014500241A Pending JP2014515044A (ja) | 2011-03-23 | 2012-03-22 | ポリウレタンフォーム用リン含有難燃剤 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014500227A Pending JP2014508841A (ja) | 2011-03-23 | 2011-03-23 | ポリウレタンフォームのためのリン含有難燃剤 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20140018509A1 (enExample) |
| EP (2) | EP2688898A4 (enExample) |
| JP (2) | JP2014508841A (enExample) |
| CN (1) | CN103534263B (enExample) |
| AU (2) | AU2011362906A1 (enExample) |
| BR (2) | BR112013022385A2 (enExample) |
| CA (2) | CA2830446A1 (enExample) |
| MX (2) | MX2013010824A (enExample) |
| RU (2) | RU2013147165A (enExample) |
| WO (2) | WO2012126179A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013022385A2 (pt) * | 2011-03-23 | 2016-12-06 | Dow Global Technologies Llc | retardante de chama contendo fósforo, método para preparar um retardante de chama contendo fósforo e produto de poliuretano |
| CN103443186A (zh) * | 2011-03-23 | 2013-12-11 | 陶氏环球技术有限责任公司 | 用于聚氨酯泡沫体的含磷阻燃剂 |
| CN104245771B (zh) | 2011-12-27 | 2017-03-22 | 陶氏环球技术有限责任公司 | 磷系加聚/聚氨酯‑脲多元醇 |
| CN105121449B (zh) * | 2013-04-16 | 2017-10-20 | 巴斯夫欧洲公司 | 含磷阻燃剂 |
| US9840579B2 (en) | 2013-09-13 | 2017-12-12 | Dow Global Technologies Llc | Thixotropic polyol compositions containing dispersed urethane-modified polyisocyanurates |
| CN103641971B (zh) * | 2013-12-16 | 2015-09-09 | 上海华峰超纤材料股份有限公司 | 含氨基甲酸酯结构的磷氮系阻燃剂及其制备方法 |
| CN108473658B (zh) * | 2016-01-18 | 2022-08-26 | 巴斯夫欧洲公司 | 制备多孔材料的方法 |
| EP3532522B1 (en) | 2016-10-25 | 2025-12-03 | Elé Corporation | Low-viscosity phosphate polyols |
| US10421910B2 (en) | 2017-08-16 | 2019-09-24 | International Business Machines Corporation | Sorbitol, glucaric acid, and gluconic acid based flame-retardants |
| US11059723B2 (en) * | 2018-07-18 | 2021-07-13 | International Business Machines Corporation | Renewable flame-retardant compounds derived from muconic acid |
| TW202020037A (zh) | 2018-08-29 | 2020-06-01 | 美商陶氏全球科技有限責任公司 | 用於改良剛性－韌性平衡之聚矽氧增強之乙烯／α－烯烴互聚物 |
| CN113549222B (zh) * | 2021-08-04 | 2022-05-13 | 中国科学技术大学 | 一种基于磷硅氮协效阻燃的超支化阻燃剂及其制备方法和应用 |
| JP2024542453A (ja) * | 2021-11-25 | 2024-11-15 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタン組成物およびこれを用いて調製される表面欠陥の少ない粘弾性ポリウレタンフォーム |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3294873A (en) * | 1961-09-12 | 1966-12-27 | Fmc Corp | Phosphorylated polyether polyols |
| NL129043C (enExample) | 1964-08-14 | |||
| US3382236A (en) * | 1965-07-23 | 1968-05-07 | Weston Chemical Corp | Oxypropylated sucrose phosphites |
| US3369059A (en) * | 1965-07-27 | 1968-02-13 | Weston Chemical Corp | Monomeric polyphosphites with ether linkages |
| JPS4820535B1 (enExample) * | 1969-06-09 | 1973-06-21 | ||
| US3725510A (en) * | 1970-02-05 | 1973-04-03 | Borg Warner | Phosphite-phosphates |
| US3758646A (en) | 1970-07-16 | 1973-09-11 | Borg Warner | Halogen containing phosphorus monools |
| JPS4923241Y1 (enExample) | 1970-09-07 | 1974-06-22 | ||
| JPS492560B1 (enExample) * | 1970-12-28 | 1974-01-21 | ||
| US3839504A (en) | 1971-08-04 | 1974-10-01 | Uniroyal Inc | Reaction of phosphorus trihalides with pentaerythritol and polymeric phosphite products thereof |
| JPS5035537B2 (enExample) * | 1972-06-26 | 1975-11-17 | ||
| JPS5037192B2 (enExample) * | 1972-06-26 | 1975-12-01 | ||
| FR2271229B1 (enExample) * | 1974-05-13 | 1978-01-27 | Poudres & Explosifs Ste Nale | |
| US4049617A (en) * | 1976-01-19 | 1977-09-20 | Velsicol Chemical Corporation | Reactive flame retardants |
| US4070336A (en) * | 1976-09-03 | 1978-01-24 | Monsanto Company | Hydrogen phosphonates and polymer compositions containing them as flame retardants |
| JPS5552314A (en) * | 1978-10-13 | 1980-04-16 | Takeda Chem Ind Ltd | Manufacture of flame-retardant urethane-modified isocyanurate foam |
| US4394491A (en) | 1980-10-08 | 1983-07-19 | The Dow Chemical Company | Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate |
| JPS58108224A (ja) * | 1981-12-21 | 1983-06-28 | Hitachi Chem Co Ltd | アルキド樹脂の製造法 |
| JPS58126896A (ja) * | 1982-01-23 | 1983-07-28 | Ajinomoto Co Inc | アラニルプロリン誘導体およびこれを含有する降圧剤 |
| AT387577B (de) * | 1984-09-26 | 1989-02-10 | Eszakmagyar Vegyimuevek | Verfahren zur herstellung von n-alkyl/en/-n-/o,o- disubstituierten thiophosphoryl/-n'n'disubstituierten-glycinamiden und diese verbindungen enthaltende akarizide, insektizide und fungizide mittel |
| DE3504646A1 (de) * | 1985-02-12 | 1986-08-14 | Basf Ag, 6700 Ludwigshafen | Halogenfreie, selbstverloeschende thermoplastische formmasse |
| US4855345A (en) * | 1986-06-19 | 1989-08-08 | Ciba-Geigy Corporation | Stabilizers for organic polymers |
| US4885327A (en) * | 1987-11-18 | 1989-12-05 | Southwest Research Institute | Swelled polymeric decontamination composition |
| DE3811005A1 (de) * | 1988-03-31 | 1989-10-19 | Bayer Ag | Thionophosphor(phosphon)saeureamidester |
| DE3919195A1 (de) * | 1989-06-13 | 1990-12-20 | Bayer Ag | (di) (thio)phosphor(phosphon)saeure (amid)ester |
| EP0514332B1 (de) * | 1991-05-16 | 1996-04-17 | Ciba-Geigy Ag | Bisphosphite |
| JPH06345788A (ja) * | 1993-06-14 | 1994-12-20 | Nippon Alkyl Alum Kk | 不斉触媒及びそれを用いた光学活性第２級アルコールの製造方法 |
| JP3077786B2 (ja) * | 1993-12-03 | 2000-08-14 | 大八化学工業株式会社 | ポリウレタン用難燃剤 |
| DE4342621A1 (de) * | 1993-12-14 | 1995-06-22 | Bayer Ag | Phosphorsäure-Derivate |
| DE4342973A1 (de) * | 1993-12-16 | 1995-06-22 | Hoechst Ag | Flammwidrige Polyurethane |
| CN1043896C (zh) * | 1993-12-31 | 1999-06-30 | 清华大学 | 胺类在水体系中直接磷酰化合成氨基磷酸盐及其混合物的方法 |
| US5556894A (en) | 1994-11-04 | 1996-09-17 | Basf Corporation | Flame resistant rigid polyurethane foams containing phosphorus and a halogen |
| US5698664A (en) * | 1995-04-26 | 1997-12-16 | The Penn State Research Foundation | Synthesis of polyphosphazenes with controlled molecular weight and polydispersity |
| JPH0923241A (ja) | 1995-07-05 | 1997-01-21 | Fujitsu Ltd | 非同期型データの通信制御方法 |
| US5969015A (en) | 1996-09-25 | 1999-10-19 | Witco Vinyl Additives Gmbh | Monomeric and oligomeric bisphosphites as stabilisers for polyvinyl chloride |
| CN1148402C (zh) * | 1998-12-18 | 2004-05-05 | 陶氏化学公司 | 含有层离石墨的聚氨酯基泡沫及其制备方法 |
| US6211259B1 (en) | 1999-02-01 | 2001-04-03 | Aristech Acrylics Llc | Low volatile reinforcing system |
| GB0108061D0 (en) * | 2001-03-30 | 2001-05-23 | Baxenden Chem | Low monomer one component foam |
| WO2004041897A1 (ja) * | 2002-11-06 | 2004-05-21 | Daihachi Chemical Industry Co., Ltd. | 難燃性軟質ポリウレタン発泡体用組成物 |
| KR100690185B1 (ko) * | 2003-08-14 | 2007-03-08 | 제일모직주식회사 | 난연성 고무강화 폴리스티렌 수지 조성물 |
| WO2005082916A1 (en) * | 2004-02-26 | 2005-09-09 | Bayer Cropscience S.A. | 5-phosphorylaminopyrazole derivatives and their use as pesticides |
| WO2008067026A2 (en) * | 2006-09-29 | 2008-06-05 | Michigan Technological University | Purification of synthetic oligomers |
| US20100063169A1 (en) | 2007-01-04 | 2010-03-11 | Jeffrey Stowell | Phosphoramide ester flame retardant and resins containing same |
| CN101463086B (zh) * | 2009-01-09 | 2012-06-27 | 华南农业大学 | 二乙氧基硫代磷酸酯类有机磷农药抗体及其制备方法和应用 |
| CN101624403B (zh) * | 2009-08-10 | 2011-11-23 | 浙江工业大学 | 磷氮型季铵盐及其制备方法和应用 |
| BR112013022385A2 (pt) * | 2011-03-23 | 2016-12-06 | Dow Global Technologies Llc | retardante de chama contendo fósforo, método para preparar um retardante de chama contendo fósforo e produto de poliuretano |
-
2011
- 2011-03-23 BR BR112013022385A patent/BR112013022385A2/pt not_active IP Right Cessation
- 2011-03-23 CA CA 2830446 patent/CA2830446A1/en not_active Abandoned
- 2011-03-23 EP EP11861881.8A patent/EP2688898A4/en not_active Withdrawn
- 2011-03-23 MX MX2013010824A patent/MX2013010824A/es unknown
- 2011-03-23 CN CN201180069503.9A patent/CN103534263B/zh active Active
- 2011-03-23 JP JP2014500227A patent/JP2014508841A/ja active Pending
- 2011-03-23 AU AU2011362906A patent/AU2011362906A1/en not_active Abandoned
- 2011-03-23 RU RU2013147165/04A patent/RU2013147165A/ru not_active Application Discontinuation
- 2011-03-23 WO PCT/CN2011/072072 patent/WO2012126179A1/en not_active Ceased
- 2011-03-23 US US14/001,902 patent/US20140018509A1/en not_active Abandoned
-
2012
- 2012-03-22 CA CA2830445A patent/CA2830445C/en active Active
- 2012-03-22 RU RU2013147161/05A patent/RU2595687C2/ru active
- 2012-03-22 BR BR112013022426-6A patent/BR112013022426B1/pt not_active IP Right Cessation
- 2012-03-22 AU AU2012231542A patent/AU2012231542B2/en not_active Ceased
- 2012-03-22 JP JP2014500241A patent/JP2014515044A/ja active Pending
- 2012-03-22 WO PCT/CN2012/072802 patent/WO2012126380A1/en not_active Ceased
- 2012-03-22 US US14/001,903 patent/US9023925B2/en active Active
- 2012-03-22 EP EP12761119.2A patent/EP2688953B1/en active Active
- 2012-03-22 MX MX2013010835A patent/MX362285B/es active IP Right Grant
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