JP2013542308A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2013542308A5 JP2013542308A5 JP2013538851A JP2013538851A JP2013542308A5 JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5 JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013538851 A JP2013538851 A JP 2013538851A JP 2013542308 A5 JP2013542308 A5 JP 2013542308A5
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- reactor
- aqueous medium
- dispersion
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 43
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 229920002313 fluoropolymer Polymers 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000006185 dispersion Substances 0.000 claims description 22
- 239000004811 fluoropolymer Substances 0.000 claims description 22
- 239000012736 aqueous medium Substances 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 14
- 230000006641 stabilisation Effects 0.000 claims description 9
- 238000011105 stabilization Methods 0.000 claims description 9
- 239000003505 polymerization initiator Substances 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YSYRISKCBOPJRG-UHFFFAOYSA-N 4,5-difluoro-2,2-bis(trifluoromethyl)-1,3-dioxole Chemical compound FC1=C(F)OC(C(F)(F)F)(C(F)(F)F)O1 YSYRISKCBOPJRG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229920001973 fluoroelastomer Polymers 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- -1 perfluoro Chemical group 0.000 description 2
- 229920005548 perfluoropolymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920002009 Pluronic® 31R1 Polymers 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41162210P | 2010-11-09 | 2010-11-09 | |
| US61/411,622 | 2010-11-09 | ||
| US201161498806P | 2011-06-20 | 2011-06-20 | |
| US61/498,806 | 2011-06-20 | ||
| PCT/US2011/059972 WO2012064841A1 (en) | 2010-11-09 | 2011-11-09 | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013542308A JP2013542308A (ja) | 2013-11-21 |
| JP2013542308A5 true JP2013542308A5 (enExample) | 2014-12-25 |
| JP6109073B2 JP6109073B2 (ja) | 2017-04-05 |
Family
ID=45034187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013538851A Active JP6109073B2 (ja) | 2010-11-09 | 2011-11-09 | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
Country Status (5)
| Country | Link |
|---|---|
| US (4) | US9255164B2 (enExample) |
| EP (2) | EP2638081B1 (enExample) |
| JP (1) | JP6109073B2 (enExample) |
| CN (2) | CN103201300B (enExample) |
| WO (1) | WO2012064841A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012064841A1 (en) * | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
| US9574027B2 (en) | 2013-03-11 | 2017-02-21 | The Chemours Company Fc, Llc | Fluoropolymer resin treatment employing sorbent to reduce fluoropolymer resin discoloration |
| JP6269671B2 (ja) * | 2013-07-18 | 2018-01-31 | 旭硝子株式会社 | 含フッ素重合体水性分散液の製造方法、含フッ素重合体水性分散液および含フッ素重合体 |
| CN106414510B (zh) * | 2013-11-26 | 2018-11-30 | 得凯莫斯公司弗罗里达有限公司 | 采用聚环氧烷在含氟单体的水相聚合中成核 |
| EP3320040B1 (en) * | 2015-07-09 | 2023-03-22 | Arkema, Inc. | Compositions based on semi-crystalline fluorinated polymer and nucleating agent useful for preparing high gloss coatings |
| US11999681B2 (en) | 2017-03-31 | 2024-06-04 | Daikin Industries, Ltd. | Alkyl sulfate ester or salt of same |
| EP3858871A1 (en) * | 2017-03-31 | 2021-08-04 | Daikin Industries, Ltd. | Composition comprising a fluoropolymer |
| WO2019031617A1 (ja) | 2017-08-10 | 2019-02-14 | ダイキン工業株式会社 | 精製ポリテトラフルオロエチレン水性分散液の製造方法、改質ポリテトラフルオロエチレン粉末の製造方法、ポリテトラフルオロエチレン成形体の製造方法、及び、組成物 |
| SG11202000862YA (en) | 2017-08-10 | 2020-02-27 | Daikin Ind Ltd | Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition |
| EP3684861B1 (en) * | 2017-11-30 | 2023-12-27 | Hewlett-Packard Development Company, L.P. | 3d-printed articles |
| JP7014976B2 (ja) | 2017-12-25 | 2022-02-15 | ダイキン工業株式会社 | ポリテトラフルオロエチレン粉末の製造方法 |
| JP7193747B2 (ja) | 2018-03-07 | 2022-12-21 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| CN112638957A (zh) * | 2018-07-23 | 2021-04-09 | 大金工业株式会社 | 聚四氟乙烯和拉伸体 |
| US11952441B2 (en) | 2018-10-03 | 2024-04-09 | Daikin Industries, Ltd. | Polytetrafluoroethylene production method |
| WO2020071503A1 (ja) * | 2018-10-03 | 2020-04-09 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| JP7216304B2 (ja) | 2018-10-03 | 2023-02-01 | ダイキン工業株式会社 | 排水から含フッ素化合物を除去する方法 |
| CN113366034B (zh) | 2019-02-01 | 2022-11-11 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| WO2020162623A1 (ja) | 2019-02-07 | 2020-08-13 | ダイキン工業株式会社 | 組成物、延伸体及びその製造方法 |
| EP3960774A4 (en) | 2019-04-26 | 2023-01-04 | Daikin Industries, Ltd. | METHOD FOR PRODUCING AN AQUEOUS FLUOROPOLYMER DISPERSION |
| CN120025473A (zh) | 2019-04-26 | 2025-05-23 | 大金工业株式会社 | 氟聚合物水性分散液的制造方法和氟聚合物水性分散液 |
| WO2021010443A1 (ja) | 2019-07-16 | 2021-01-21 | ダイキン工業株式会社 | 含フッ素エラストマーの製造方法および組成物 |
| JP7201948B2 (ja) * | 2019-07-23 | 2023-01-11 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレン組成物及びポリテトラフルオロエチレン粉末 |
| CN114514253B (zh) | 2019-10-03 | 2024-12-06 | 大金工业株式会社 | 聚四氟乙烯及其制造方法 |
| US12460026B2 (en) | 2019-10-11 | 2025-11-04 | Gujarat Fluorochemicals Limited | Process for preparing fluoropolymers and fluoroelastomers in presence of a non fluorinated sulfonate type hydrocarbon containing surfactant thereof |
| EP4063405A4 (en) * | 2019-11-19 | 2024-01-10 | Daikin Industries, Ltd. | PROCESS FOR PRODUCING POLYTETRAFLUOROETHYLENE |
| JP6989792B2 (ja) | 2019-12-25 | 2022-01-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| WO2021149022A1 (en) * | 2020-01-24 | 2021-07-29 | Gujarat Fluorochemicals Limited | Process for polymerizing fluoromonomers using a combination of fluorinated and non-fluorinated surfactant |
| CA3166267A1 (en) | 2020-05-14 | 2021-11-18 | Gujarat Fluorochemicals Limited | Process for polymerizing fluoromonomers using a combination of fluorinated and non-fluorinated surfactant |
| JP7708107B2 (ja) * | 2020-07-21 | 2025-07-15 | Ａｇｃ株式会社 | 撥水撥油剤組成物、その製造方法及び物品 |
| JP2023543807A (ja) * | 2020-10-01 | 2023-10-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロポリマーの水性重合における低反応性炭化水素分散剤 |
| JP7648942B2 (ja) | 2021-03-18 | 2025-03-19 | ダイキン工業株式会社 | フッ素樹脂の製造方法、フッ素樹脂および水性分散液 |
| WO2022211094A1 (ja) | 2021-03-31 | 2022-10-06 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| CN117043258A (zh) | 2021-03-31 | 2023-11-10 | 大金工业株式会社 | 氟树脂组合物和成型体 |
| EP4317220A4 (en) | 2021-03-31 | 2025-04-23 | Daikin Industries, Ltd. | FLUORINE RESIN COMPOSITION AND MOLDED BODIES |
| JP7323833B2 (ja) | 2021-03-31 | 2023-08-09 | ダイキン工業株式会社 | フッ素樹脂組成物の製造方法、フッ素樹脂組成物、及び、成形体 |
| WO2023059320A1 (en) * | 2021-10-06 | 2023-04-13 | Surface Technology, Inc. | Composite ptfe plating |
| WO2023191061A1 (ja) | 2022-03-31 | 2023-10-05 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| JP7583340B2 (ja) | 2023-01-18 | 2024-11-14 | ダイキン工業株式会社 | 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス |
| JP7538458B2 (ja) | 2023-01-18 | 2024-08-22 | ダイキン工業株式会社 | ポリテトラフルオロエチレン組成物 |
| KR20250128385A (ko) | 2023-01-18 | 2025-08-27 | 다이킨 고교 가부시키가이샤 | 테트라플루오로에틸렌계 폴리머 조성물, 전기 화학 디바이스용 바인더, 전극 합제, 전극, 및 이차 전지 |
| KR20250129106A (ko) | 2023-01-18 | 2025-08-28 | 다이킨 고교 가부시키가이샤 | 테트라플루오로에틸렌계 폴리머 조성물, 고체 이차 전지용 바인더, 전해질층용 합제, 전극 합제, 전극, 및 고체 이차 전지 |
| JP7560797B2 (ja) | 2023-01-18 | 2024-10-03 | ダイキン工業株式会社 | 電気化学デバイス用合剤自立膜、電極、及び、電気化学デバイス |
| WO2025033327A1 (ja) * | 2023-08-08 | 2025-02-13 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液、粒子及び組成物 |
| WO2025033328A1 (ja) * | 2023-08-08 | 2025-02-13 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液、粒子、及び組成物 |
| EP4657572A1 (en) | 2024-01-18 | 2025-12-03 | Daikin Industries, Ltd. | Composition, electrochemical device binder, electrode mixture, electrode, and secondary battery |
| WO2025154813A1 (ja) | 2024-01-18 | 2025-07-24 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| JP2025112286A (ja) | 2024-01-18 | 2025-07-31 | ダイキン工業株式会社 | 電気化学デバイス、組成物、電極合剤、電極、及び、二次電池 |
Family Cites Families (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA878571A (en) | 1971-08-17 | H. Porter Verleon | Dispersion polymerization of tetrafluoroethylene | |
| US2559752A (en) | 1951-03-06 | 1951-07-10 | Du Pont | Aqueous colloidal dispersions of polymers |
| BE563881A (enExample) | 1957-01-11 | |||
| US3000892A (en) | 1959-11-16 | 1961-09-19 | Paul A J Janssen | 1-aroylalkyl-4-aroylpiperazines |
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3271341A (en) | 1961-08-07 | 1966-09-06 | Du Pont | Aqueous colloidal dispersions of polymer |
| US3282875A (en) | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| US3391099A (en) | 1966-04-25 | 1968-07-02 | Du Pont | Polymerization process |
| DE2015279A1 (de) | 1969-04-01 | 1970-10-08 | E.I. du Pont de Nemours and'Company, Wilmington, Del. (V.St.A.) | Dispersionspolymerisation von Tetrafluoräthylen |
| DE2037028C2 (de) | 1970-07-25 | 1982-07-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung fluorhaltiger Copolymerisate |
| US4036802A (en) | 1975-09-24 | 1977-07-19 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer fine powder resin |
| US4098978A (en) | 1975-11-12 | 1978-07-04 | The B. F. Goodrich Company | Process for emulsion polymerization of vinylidene halides and product thereof |
| US4342675A (en) * | 1978-06-16 | 1982-08-03 | E. I. Du Pont De Nemours And Company | Process for preparing aqueous dispersion of polytetrafluoroethylene |
| US4358545A (en) | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US4463144A (en) | 1980-09-10 | 1984-07-31 | Asahi Glass Company Ltd. | Process for producing propylene-tetrafluoroethylene copolymer |
| US4552631A (en) | 1983-03-10 | 1985-11-12 | E. I. Du Pont De Nemours And Company | Reinforced membrane, electrochemical cell and electrolysis process |
| US4469846A (en) * | 1983-05-20 | 1984-09-04 | E. I. Du Pont De Nemours And Company | Core/shell fluoropolymer compositions |
| US4940525A (en) | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| JP3172983B2 (ja) | 1993-09-20 | 2001-06-04 | ダイキン工業株式会社 | ビニリデンフルオライド系重合体の水性分散液およびその製法 |
| DE4335705A1 (de) | 1993-10-20 | 1995-04-27 | Hoechst Ag | Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung |
| IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
| US5637748A (en) | 1995-03-01 | 1997-06-10 | E. I. Du Pont De Nemours And Company | Process for synthesizing fluorinated nitrile compounds |
| US5955556A (en) * | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5866711A (en) | 1996-09-13 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Fluorocyanate and fluorocarbamate monomers and polymers thereof |
| US5969067A (en) | 1996-09-13 | 1999-10-19 | E.I. Dupont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
| US6512063B2 (en) | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| EP1383811B1 (en) | 2001-05-02 | 2009-11-25 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| US6833414B2 (en) * | 2002-02-12 | 2004-12-21 | Arkema Inc. | Cross-linkable aqueous fluoropolymer based dispersions containing silanes |
| US6824872B2 (en) * | 2002-04-23 | 2004-11-30 | Laurel Products Llc | Surface-treating fluoropolymer powders using atmospheric plasma |
| WO2003106556A1 (ja) * | 2002-05-20 | 2003-12-24 | ダイキン工業株式会社 | 含フッ素樹脂水性分散体組成物及び含フッ素水性塗料組成物 |
| ATE430169T1 (de) | 2002-10-31 | 2009-05-15 | 3M Innovative Properties Co | Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung fluorierter olefine und olefinischer kohlenwasserstoffcopolymere |
| JP4433145B2 (ja) * | 2003-02-12 | 2010-03-17 | 日東電工株式会社 | 光学部材用粘着剤組成物、光学部材用粘着剤層、粘着型光学部材および画像表示装置 |
| US6841616B2 (en) | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| US6869997B2 (en) | 2003-05-06 | 2005-03-22 | Arkema, Inc. | Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant |
| JP2004359870A (ja) | 2003-06-05 | 2004-12-24 | Daikin Ind Ltd | 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液 |
| US7589234B2 (en) | 2003-07-02 | 2009-09-15 | Daikin Industries, Ltd. | Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer |
| WO2005007745A1 (ja) * | 2003-07-18 | 2005-01-27 | Kaneka Corporation | 硬化性組成物 |
| US20050090613A1 (en) | 2003-10-22 | 2005-04-28 | Daikin Industries, Ltd. | Process for preparing fluorine-containing polymer latex |
| EP1533325B1 (en) * | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| EP1726599B1 (en) | 2003-12-25 | 2013-07-24 | Daikin Industries, Ltd. | Process for producing fluoropolymer |
| US7122610B2 (en) | 2004-04-27 | 2006-10-17 | Arkema Inc. | Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants |
| JP2006111722A (ja) * | 2004-10-14 | 2006-04-27 | Daikin Ind Ltd | 含フッ素重合体の製造方法 |
| US20060178472A1 (en) * | 2005-02-10 | 2006-08-10 | Johnson David W | Process for producing low fluorosurfactant-containing aqueous fluoropolymer dispersions with controlled pH |
| US8338518B2 (en) | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| US8080621B2 (en) | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US20060281845A1 (en) | 2005-06-10 | 2006-12-14 | Ramin Amin-Sanayei | Aqueous process for making fluoropolymers |
| GB0514398D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant |
| GB0514387D0 (en) | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant |
| US7795332B2 (en) | 2005-07-15 | 2010-09-14 | 3M Innovative Properties Company | Method of removing fluorinated carboxylic acid from aqueous liquid |
| US8124699B2 (en) | 2005-08-08 | 2012-02-28 | Arkema Inc. | Polymerization of fluoropolymers using alkyl phosphonate surfactants |
| KR101298057B1 (ko) | 2005-08-08 | 2013-08-20 | 알케마 인코포레이티드 | 비불소화 계면활성제를 사용하는 플루오로중합체의 중합 |
| RU2425056C2 (ru) | 2005-10-17 | 2011-07-27 | Асахи Гласс Компани, Лимитед | Водная политетрафторэтиленовая эмульсия, политетрафторэтиленовый мелкодисперсный порошок и пористый материал, полученный из него |
| WO2007046377A1 (ja) | 2005-10-20 | 2007-04-26 | Asahi Glass Company, Limited | 溶融成形可能なフッ素樹脂の製造方法 |
| WO2007046482A1 (ja) | 2005-10-20 | 2007-04-26 | Asahi Glass Company, Limited | ポリテトラフルオロエチレン水性分散液およびその製品 |
| CN101296950B (zh) | 2005-10-26 | 2011-01-26 | 旭硝子株式会社 | 含氟乳化剂的残留量少的氟树脂及其制造方法 |
| CN101309942B (zh) | 2005-11-18 | 2012-06-20 | 纳幕尔杜邦公司 | 核/壳聚合物 |
| US7728087B2 (en) | 2005-12-23 | 2010-06-01 | 3M Innovative Properties Company | Fluoropolymer dispersion and method for making the same |
| US20070282044A1 (en) | 2006-05-31 | 2007-12-06 | Robert John Cavanaugh | Concentrated fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents |
| US20100016531A1 (en) * | 2006-08-11 | 2010-01-21 | Libin Du | Process of fluoromonomer polymerization |
| JP5439186B2 (ja) | 2006-11-09 | 2014-03-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合 |
| US7932333B2 (en) | 2006-11-09 | 2011-04-26 | E.I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomer using polymerization agent comprising high molecular weight fluoropolyether acid or salt and fluoropolyether acid or salt surfactant |
| EP2087018B1 (en) | 2006-11-09 | 2011-05-25 | E.I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and siloxane surfactant |
| US7521513B2 (en) | 2006-11-29 | 2009-04-21 | Dupont Performance Elastomers Llc | Semi-batch process for producing fluoroelastomers |
| US20080146757A1 (en) | 2006-12-19 | 2008-06-19 | Lyons Donald F | Process for producing fluoroelastomers |
| US20080262177A1 (en) | 2006-12-19 | 2008-10-23 | Lyons Donald F | Process for producing fluoroelastomers |
| US7694203B2 (en) * | 2007-07-03 | 2010-04-06 | Sun Microsystems, Inc. | On-chip samplers for asynchronously triggered events |
| WO2009013214A1 (en) | 2007-07-20 | 2009-01-29 | Solvay Solexis S.P.A. | Process for polymer dispersions |
| EP2274345B1 (en) | 2008-04-07 | 2017-01-04 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| US9192915B2 (en) * | 2008-05-10 | 2015-11-24 | Brigham Young University | Porous composite particulate materials, methods of making and using same, and related apparatuses |
| US8153738B2 (en) | 2008-12-23 | 2012-04-10 | E I Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| WO2011024856A1 (ja) | 2009-08-28 | 2011-03-03 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| WO2011024857A1 (ja) | 2009-08-28 | 2011-03-03 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| CN101787091B (zh) * | 2010-01-18 | 2011-08-24 | 上海三爱富新材料股份有限公司 | 一种含氟聚合物水性分散乳液及其制备方法 |
| CN103201301B (zh) | 2010-11-09 | 2017-02-08 | 纳幕尔杜邦公司 | 含氟单体的含水聚合反应中的成核作用 |
| WO2012064841A1 (en) * | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluoromonomer using hydrocarbon surfactant |
-
2011
- 2011-11-09 WO PCT/US2011/059972 patent/WO2012064841A1/en not_active Ceased
- 2011-11-09 CN CN201180053781.5A patent/CN103201300B/zh active Active
- 2011-11-09 US US13/292,356 patent/US9255164B2/en active Active
- 2011-11-09 CN CN201610525774.5A patent/CN106188353B/zh active Active
- 2011-11-09 JP JP2013538851A patent/JP6109073B2/ja active Active
- 2011-11-09 EP EP11787983.3A patent/EP2638081B1/en active Active
- 2011-11-09 EP EP19171483.1A patent/EP3539995B1/en active Active
-
2016
- 2016-01-11 US US14/992,421 patent/US9518170B2/en active Active
- 2016-11-03 US US15/342,189 patent/US10703829B2/en active Active
-
2020
- 2020-06-01 US US16/888,938 patent/US11655312B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2013542308A5 (enExample) | ||
| EP2638082B1 (en) | Nucleation in aqueous polymerization of fluoromonomer | |
| JP5217090B2 (ja) | テトラフルオロエチレン重合体水性分散液、その製造方法、テトラフルオロエチレン重合体粉末及びテトラフルオロエチレン重合体成形体 | |
| CN103210003B (zh) | 减弱含烃表面活性剂在含氟单体含水分散体聚合反应中的调聚性能 | |
| US7776946B2 (en) | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant | |
| CN103201300B (zh) | 使用烃表面活性剂的含氟单体的含水聚合 | |
| JP2013542310A5 (enExample) | ||
| US12448472B2 (en) | Method for producing fluorine-containing polymer, aqueous dispersion liquid, and fluorine-containing polymer composition | |
| CN101341179B (zh) | 含氟聚合物分散体及其制备方法 | |
| CN106414510A (zh) | 采用聚环氧烷在含氟单体的水相聚合中成核 | |
| CN101652392B (zh) | 采用了含氟羧酸化合物的含氟聚合物的制造方法 | |
| JP5598476B2 (ja) | 含フッ素重合体の製造方法 | |
| JP5673541B2 (ja) | 含フッ素重合体の製造方法 | |
| EP3201242B1 (en) | Method of making fluoropolymer dispersions | |
| CN103739756B (zh) | 一种改善热稳定性的聚偏氟乙烯聚合物制备方法 | |
| CN102428106A (zh) | 热致减少含氟聚合物分散体中的氟代醚羧酸或盐 | |
| WO2010017665A1 (zh) | 一种含氟聚醚过氧化物及其在含氟单体乳液聚合中的应用 | |
| CN115466343B (zh) | 一种聚醚二酸或其盐类表面活性剂及其应用 | |
| RU2814921C2 (ru) | Способ получения фторсодержащего полимера, водная дисперсионная жидкость и композиция фторсодержащего полимера | |
| CN117510698A (zh) | 一种反应性含氟表面活性剂及其制备方法和应用 |