JP2013542310A5 - - Google Patents
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- Publication number
- JP2013542310A5 JP2013542310A5 JP2013538856A JP2013538856A JP2013542310A5 JP 2013542310 A5 JP2013542310 A5 JP 2013542310A5 JP 2013538856 A JP2013538856 A JP 2013538856A JP 2013538856 A JP2013538856 A JP 2013538856A JP 2013542310 A5 JP2013542310 A5 JP 2013542310A5
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbon
- polymerization
- containing surfactant
- dispersion
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims description 26
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 238000006116 polymerization reaction Methods 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 25
- 239000006185 dispersion Substances 0.000 claims description 16
- 229920002313 fluoropolymer Polymers 0.000 claims description 11
- 239000004811 fluoropolymer Substances 0.000 claims description 11
- 239000012736 aqueous medium Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 239000003505 polymerization initiator Substances 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 238000002955 isolation Methods 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 230000009849 deactivation Effects 0.000 description 10
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- -1 A fluoromonomer Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical class [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41162610P | 2010-11-09 | 2010-11-09 | |
| US61/411,626 | 2010-11-09 | ||
| US201161434994P | 2011-01-21 | 2011-01-21 | |
| US201161434987P | 2011-01-21 | 2011-01-21 | |
| US61/434,987 | 2011-01-21 | ||
| US61/434,994 | 2011-01-21 | ||
| US201161498816P | 2011-06-20 | 2011-06-20 | |
| US201161498795P | 2011-06-20 | 2011-06-20 | |
| US61/498,816 | 2011-06-20 | ||
| US61/498,795 | 2011-06-20 | ||
| PCT/US2011/059995 WO2012064858A1 (en) | 2010-11-09 | 2011-11-09 | Reducing the telogenic behavior of hydrocarbon-containing surfactants in aqueous dispersion fluoromonomer polymerization |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013542310A JP2013542310A (ja) | 2013-11-21 |
| JP2013542310A5 true JP2013542310A5 (enExample) | 2014-12-25 |
| JP6030562B2 JP6030562B2 (ja) | 2016-11-24 |
Family
ID=45034189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013538856A Active JP6030562B2 (ja) | 2010-11-09 | 2011-11-09 | 水性分散体フルオロモノマーの重合における炭化水素含有界面活性剤のテロゲン性挙動の低下 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9074025B2 (enExample) |
| EP (1) | EP2638083B1 (enExample) |
| JP (1) | JP6030562B2 (enExample) |
| CN (1) | CN103210003B (enExample) |
| WO (1) | WO2012064858A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012064846A1 (en) * | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Nucleation in aqueous polymerization of fluoromonomer |
| US20150217247A1 (en) * | 2012-09-14 | 2015-08-06 | Dow Global Technologies Llc | Surfactant composition with low dynamic surface tension |
| US11643484B2 (en) * | 2015-03-16 | 2023-05-09 | Arkema Inc. | Modified fluoropolymers |
| JP6983778B2 (ja) * | 2015-11-30 | 2021-12-17 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ化ビニリデンとトリフルオロエチレンのコポリマー及びフッ素化エラストマーを含むフルオロポリマー組成物 |
| CN117986414A (zh) | 2017-08-10 | 2024-05-07 | 大金工业株式会社 | 精制聚四氟乙烯水性分散液的制造方法、改性聚四氟乙烯粉末的制造方法、聚四氟乙烯成型体的制造方法以及组合物 |
| EP3666802A4 (en) | 2017-08-10 | 2021-05-26 | Daikin Industries, Ltd. | PROCESS FOR THE PRODUCTION OF A LIQUID CONSISTING OF AN AQUEOUS DISPERSION OF PURIFIED POLYTETRAFLUORETHYLENE, PROCESS FOR THE PRODUCTION OF A MODIFIED POLYTETRAFLUORETHYLENE POWDER, PROCESS FOR THE PRODUCTION OF A MOLDED OBJECT IN POLYTETRAFLUORETHYLENE, ETHYLORETHYLENE COMPOSITION |
| US11518826B2 (en) | 2017-12-25 | 2022-12-06 | Daikin Industries, Ltd. | Method for producing polytetrafluoroethylene powder |
| EP3763747B1 (en) | 2018-03-07 | 2025-10-29 | Daikin Industries, Ltd. | Method for producing fluoropolymer |
| WO2020022355A1 (ja) | 2018-07-23 | 2020-01-30 | ダイキン工業株式会社 | ポリテトラフルオロエチレン及び延伸体 |
| CN116041605B (zh) * | 2018-10-03 | 2025-07-08 | 大金工业株式会社 | 聚四氟乙烯的制造方法 |
| CN112771006A (zh) | 2018-10-03 | 2021-05-07 | 大金工业株式会社 | 从排水除去含氟化合物的方法 |
| EP3862368A4 (en) | 2018-10-03 | 2022-06-29 | Daikin Industries, Ltd. | Polytetrafluoroethylene production method |
| EP3919527B1 (en) | 2019-02-01 | 2025-12-10 | Daikin Industries, Ltd. | Method for producing polytetrafluoroethylene |
| US20220119556A1 (en) | 2019-02-07 | 2022-04-21 | Daikin Industries, Ltd. | Composition, stretched body and method of manufacturing thereof |
| JPWO2020213691A1 (ja) * | 2019-04-16 | 2021-11-25 | ダイキン工業株式会社 | フルオロポリマー粉末の製造方法 |
| EP3960774A4 (en) | 2019-04-26 | 2023-01-04 | Daikin Industries, Ltd. | METHOD FOR PRODUCING AN AQUEOUS FLUOROPOLYMER DISPERSION |
| US20220251251A1 (en) | 2019-04-26 | 2022-08-11 | Daikin Industries, Ltd. | Fluoropolymer aqueous dispersion production method and fluoropolymer aqueous dispersion |
| WO2021010443A1 (ja) | 2019-07-16 | 2021-01-21 | ダイキン工業株式会社 | 含フッ素エラストマーの製造方法および組成物 |
| WO2021015291A1 (ja) | 2019-07-23 | 2021-01-28 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレン組成物及びポリテトラフルオロエチレン粉末 |
| JP7265205B2 (ja) | 2019-10-03 | 2023-04-26 | ダイキン工業株式会社 | ポリテトラフルオロエチレンおよびその製造方法 |
| JP6989792B2 (ja) | 2019-12-25 | 2022-01-12 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| WO2022072693A1 (en) | 2020-10-01 | 2022-04-07 | The Chemours Company Fc, Llc | Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers |
| EP4310114A4 (en) | 2021-03-18 | 2025-03-26 | Daikin Industries, Ltd. | Method for producing fluororesin, fluororesin, and aqueous dispersion liquid |
| JP7323832B2 (ja) | 2021-03-31 | 2023-08-09 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| CN117043264A (zh) | 2021-03-31 | 2023-11-10 | 大金工业株式会社 | 氟树脂组合物和成型体 |
| WO2022211093A1 (ja) | 2021-03-31 | 2022-10-06 | ダイキン工業株式会社 | フッ素樹脂組成物の製造方法、フッ素樹脂組成物、及び、成形体 |
| TWI882214B (zh) | 2021-03-31 | 2025-05-01 | 日商大金工業股份有限公司 | 氟樹脂組成物、及成形體 |
| JP7785034B2 (ja) | 2022-03-31 | 2025-12-12 | ダイキン工業株式会社 | フッ素樹脂組成物、及び、成形体 |
| WO2024154786A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス |
| CN120548629A (zh) | 2023-01-18 | 2025-08-26 | 大金工业株式会社 | 四氟乙烯系聚合物组合物、固态二次电池用粘结剂、电解质层用合剂、电极合剂、电极和固态二次电池 |
| JP7538458B2 (ja) | 2023-01-18 | 2024-08-22 | ダイキン工業株式会社 | ポリテトラフルオロエチレン組成物 |
| KR20250128385A (ko) | 2023-01-18 | 2025-08-27 | 다이킨 고교 가부시키가이샤 | 테트라플루오로에틸렌계 폴리머 조성물, 전기 화학 디바이스용 바인더, 전극 합제, 전극, 및 이차 전지 |
| WO2024154806A1 (ja) | 2023-01-18 | 2024-07-25 | ダイキン工業株式会社 | 電気化学デバイス用合剤自立膜、電極、及び、電気化学デバイス |
| JP7719418B1 (ja) | 2024-01-18 | 2025-08-06 | ダイキン工業株式会社 | 組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| WO2025154813A1 (ja) | 2024-01-18 | 2025-07-24 | ダイキン工業株式会社 | テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池 |
| EP4645423A1 (en) | 2024-01-18 | 2025-11-05 | Daikin Industries, Ltd. | Electrochemical device, composition, electrode mixture, electrode, and secondary battery |
Family Cites Families (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA878571A (en) * | 1971-08-17 | H. Porter Verleon | Dispersion polymerization of tetrafluoroethylene | |
| US2559752A (en) | 1951-03-06 | 1951-07-10 | Du Pont | Aqueous colloidal dispersions of polymers |
| NL102460C (enExample) | 1957-01-11 | |||
| US3000892A (en) | 1959-11-16 | 1961-09-19 | Paul A J Janssen | 1-aroylalkyl-4-aroylpiperazines |
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3271341A (en) | 1961-08-07 | 1966-09-06 | Du Pont | Aqueous colloidal dispersions of polymer |
| US3282875A (en) | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| US3391099A (en) | 1966-04-25 | 1968-07-02 | Du Pont | Polymerization process |
| DE2015279A1 (de) | 1969-04-01 | 1970-10-08 | E.I. du Pont de Nemours and'Company, Wilmington, Del. (V.St.A.) | Dispersionspolymerisation von Tetrafluoräthylen |
| DE2037028C2 (de) | 1970-07-25 | 1982-07-08 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung fluorhaltiger Copolymerisate |
| US4036802A (en) | 1975-09-24 | 1977-07-19 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer fine powder resin |
| US4098978A (en) | 1975-11-12 | 1978-07-04 | The B. F. Goodrich Company | Process for emulsion polymerization of vinylidene halides and product thereof |
| US4342675A (en) * | 1978-06-16 | 1982-08-03 | E. I. Du Pont De Nemours And Company | Process for preparing aqueous dispersion of polytetrafluoroethylene |
| US4358545A (en) | 1980-06-11 | 1982-11-09 | The Dow Chemical Company | Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000 |
| US4463144A (en) | 1980-09-10 | 1984-07-31 | Asahi Glass Company Ltd. | Process for producing propylene-tetrafluoroethylene copolymer |
| US4552631A (en) | 1983-03-10 | 1985-11-12 | E. I. Du Pont De Nemours And Company | Reinforced membrane, electrochemical cell and electrolysis process |
| US4940525A (en) | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| JP3172983B2 (ja) | 1993-09-20 | 2001-06-04 | ダイキン工業株式会社 | ビニリデンフルオライド系重合体の水性分散液およびその製法 |
| DE4335705A1 (de) | 1993-10-20 | 1995-04-27 | Hoechst Ag | Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung |
| IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
| US5637748A (en) | 1995-03-01 | 1997-06-10 | E. I. Du Pont De Nemours And Company | Process for synthesizing fluorinated nitrile compounds |
| US5955556A (en) * | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5866711A (en) | 1996-09-13 | 1999-02-02 | E. I. Du Pont De Nemours And Company | Fluorocyanate and fluorocarbamate monomers and polymers thereof |
| US5969067A (en) | 1996-09-13 | 1999-10-19 | E.I. Dupont De Nemours And Company | Phosphorus-containing fluoromonomers and polymers thereof |
| US6512063B2 (en) * | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| DE60227508D1 (de) | 2001-05-02 | 2008-08-21 | 3M Innovative Properties Co | Emulgatorfreies wässriges emulsionspolymerisationsverfahren zur herstellung von fluorpolymeren |
| US6833414B2 (en) * | 2002-02-12 | 2004-12-21 | Arkema Inc. | Cross-linkable aqueous fluoropolymer based dispersions containing silanes |
| US6824872B2 (en) * | 2002-04-23 | 2004-11-30 | Laurel Products Llc | Surface-treating fluoropolymer powders using atmospheric plasma |
| US7064170B2 (en) | 2002-10-31 | 2006-06-20 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin |
| US6841616B2 (en) | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| US6869997B2 (en) | 2003-05-06 | 2005-03-22 | Arkema, Inc. | Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant |
| JP2004359870A (ja) | 2003-06-05 | 2004-12-24 | Daikin Ind Ltd | 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液 |
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| WO2007046377A1 (ja) | 2005-10-20 | 2007-04-26 | Asahi Glass Company, Limited | 溶融成形可能なフッ素樹脂の製造方法 |
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| EP1942118B1 (en) | 2005-10-26 | 2013-09-11 | Asahi Glass Company, Limited | Fluororesin with low fluorine-containing emulsifier residual and method for producing same |
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| WO2008019155A1 (en) * | 2006-08-11 | 2008-02-14 | The University Of North Carolina At Chapel Hill | Process of fluoromonomer polymerization |
| EP2084195B1 (en) | 2006-11-09 | 2011-06-08 | E.I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant |
| ATE509960T1 (de) | 2006-11-09 | 2011-06-15 | Du Pont | Wässrige polymerisation eines fluorinierten monomers mithilfe eines polymerisationsmittels mit einer fluorpolyethersäure oder einem salz daraus und einem fluorpolyethersäuretensid oder - salztensid von hohem molekulargewicht |
| ATE510858T1 (de) | 2006-11-09 | 2011-06-15 | Du Pont | Wässrige polymerisation eines fluorinierten monomers mithilfe eines polymerisationsmittels mit einer fluorpolyethersäure oder einem salz daraus und einem siloxantensid |
| US7521513B2 (en) | 2006-11-29 | 2009-04-21 | Dupont Performance Elastomers Llc | Semi-batch process for producing fluoroelastomers |
| US20080146757A1 (en) | 2006-12-19 | 2008-06-19 | Lyons Donald F | Process for producing fluoroelastomers |
| US20080262177A1 (en) | 2006-12-19 | 2008-10-23 | Lyons Donald F | Process for producing fluoroelastomers |
| WO2009013214A1 (en) | 2007-07-20 | 2009-01-29 | Solvay Solexis S.P.A. | Process for polymer dispersions |
| EP2274345B1 (en) | 2008-04-07 | 2017-01-04 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| US8153738B2 (en) | 2008-12-23 | 2012-04-10 | E I Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| JP5673541B2 (ja) | 2009-08-28 | 2015-02-18 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| WO2011024856A1 (ja) | 2009-08-28 | 2011-03-03 | ダイキン工業株式会社 | 含フッ素重合体の製造方法 |
| WO2012064846A1 (en) * | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Nucleation in aqueous polymerization of fluoromonomer |
-
2011
- 2011-11-09 EP EP11787985.8A patent/EP2638083B1/en active Active
- 2011-11-09 WO PCT/US2011/059995 patent/WO2012064858A1/en not_active Ceased
- 2011-11-09 US US13/292,373 patent/US9074025B2/en active Active
- 2011-11-09 JP JP2013538856A patent/JP6030562B2/ja active Active
- 2011-11-09 CN CN201180054055.5A patent/CN103210003B/zh active Active
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