JP2013507008A5 - - Google Patents
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- JP2013507008A5 JP2013507008A5 JP2012532310A JP2012532310A JP2013507008A5 JP 2013507008 A5 JP2013507008 A5 JP 2013507008A5 JP 2012532310 A JP2012532310 A JP 2012532310A JP 2012532310 A JP2012532310 A JP 2012532310A JP 2013507008 A5 JP2013507008 A5 JP 2013507008A5
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- JP
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- Prior art keywords
- concave structure
- metal
- continuous
- gas
- depth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052751 metal Inorganic materials 0.000 claims description 281
- 239000002184 metal Substances 0.000 claims description 281
- 239000010949 copper Substances 0.000 claims description 269
- 239000007789 gas Substances 0.000 claims description 196
- 239000002243 precursor Substances 0.000 claims description 129
- 238000000034 method Methods 0.000 claims description 104
- 238000007747 plating Methods 0.000 claims description 97
- 239000000758 substrate Substances 0.000 claims description 90
- 238000000137 annealing Methods 0.000 claims description 65
- 230000008569 process Effects 0.000 claims description 55
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 46
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 46
- 238000000151 deposition Methods 0.000 claims description 37
- 239000011261 inert gas Substances 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- 239000001257 hydrogen Substances 0.000 claims description 25
- 238000011049 filling Methods 0.000 claims description 24
- 230000001590 oxidative effect Effects 0.000 claims description 24
- 238000002230 thermal chemical vapour deposition Methods 0.000 claims description 22
- 230000008021 deposition Effects 0.000 claims description 19
- 238000009792 diffusion process Methods 0.000 claims description 19
- 239000010936 titanium Substances 0.000 claims description 19
- 239000012159 carrier gas Substances 0.000 claims description 17
- 238000007740 vapor deposition Methods 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910052715 tantalum Inorganic materials 0.000 claims description 12
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 10
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 9
- 229910052721 tungsten Inorganic materials 0.000 claims description 9
- 239000010937 tungsten Substances 0.000 claims description 9
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 6
- 229910001431 copper ion Inorganic materials 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims description 6
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 6
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 239000002923 metal particle Substances 0.000 claims description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 235000015847 Hesperis matronalis Nutrition 0.000 claims description 2
- 240000004533 Hesperis matronalis Species 0.000 claims description 2
- IVHJCRXBQPGLOV-UHFFFAOYSA-N azanylidynetungsten Chemical compound [W]#N IVHJCRXBQPGLOV-UHFFFAOYSA-N 0.000 claims description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 5
- 238000007654 immersion Methods 0.000 claims 5
- 239000010408 film Substances 0.000 description 147
- 239000010410 layer Substances 0.000 description 127
- 238000012545 processing Methods 0.000 description 60
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 31
- 230000008016 vaporization Effects 0.000 description 31
- 238000009834 vaporization Methods 0.000 description 28
- 239000000463 material Substances 0.000 description 27
- 238000009826 distribution Methods 0.000 description 25
- 229940037201 oris Drugs 0.000 description 21
- 239000006200 vaporizer Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000005240 physical vapour deposition Methods 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 10
- 238000003917 TEM image Methods 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 239000012528 membrane Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 230000005281 excited state Effects 0.000 description 6
- 239000011229 interlayer Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000007983 Tris buffer Substances 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
- 238000000231 atomic layer deposition Methods 0.000 description 5
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910052734 helium Inorganic materials 0.000 description 5
- 229910052743 krypton Inorganic materials 0.000 description 5
- 238000001465 metallisation Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052754 neon Inorganic materials 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 239000003989 dielectric material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- -1 etc. Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910052756 noble gas Inorganic materials 0.000 description 4
- 150000002835 noble gases Chemical class 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 230000004438 eyesight Effects 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001020 plasma etching Methods 0.000 description 3
- 239000010979 ruby Substances 0.000 description 3
- 229910001750 ruby Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910004129 HfSiO Inorganic materials 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910006501 ZrSiO Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- XEADIPZCZVEDJF-UHFFFAOYSA-N carbonic acid;oxosilicon Chemical compound [Si]=O.OC(O)=O XEADIPZCZVEDJF-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 229910021334 nickel silicide Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007781 pre-processing Methods 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 description 2
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 description 2
- 238000000427 thin-film deposition Methods 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- NXHILIPIEUBEPD-UHFFFAOYSA-H tungsten hexafluoride Chemical compound F[W](F)(F)(F)(F)F NXHILIPIEUBEPD-UHFFFAOYSA-H 0.000 description 2
- GWSOSPTYOIRWNO-UHFFFAOYSA-N 2-(dimethylamino)ethanolate;ethanolate;tantalum(5+) Chemical compound [Ta+5].CC[O-].CC[O-].CC[O-].CC[O-].CN(C)CC[O-] GWSOSPTYOIRWNO-UHFFFAOYSA-N 0.000 description 1
- VLJQDHDVZJXNQL-UHFFFAOYSA-N 4-methyl-n-(oxomethylidene)benzenesulfonamide Chemical compound CC1=CC=C(S(=O)(=O)N=C=O)C=C1 VLJQDHDVZJXNQL-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- YZHQWZURESVKOE-UHFFFAOYSA-N CCN(CC)[Ta](N(CC)CC)N(CC)CC Chemical compound CCN(CC)[Ta](N(CC)CC)N(CC)CC YZHQWZURESVKOE-UHFFFAOYSA-N 0.000 description 1
- 229910019001 CoSi Inorganic materials 0.000 description 1
- 229910005881 NiSi 2 Inorganic materials 0.000 description 1
- 241000695274 Processa Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004537 TaCl5 Inorganic materials 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910008484 TiSi Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- PPJPTAQKIFHZQU-UHFFFAOYSA-N bis(tert-butylimino)tungsten;dimethylazanide Chemical compound C[N-]C.C[N-]C.CC(C)(C)N=[W]=NC(C)(C)C PPJPTAQKIFHZQU-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- FQNHWXHRAUXLFU-UHFFFAOYSA-N carbon monoxide;tungsten Chemical group [W].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] FQNHWXHRAUXLFU-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- VJDVOZLYDLHLSM-UHFFFAOYSA-N diethylazanide;titanium(4+) Chemical compound [Ti+4].CC[N-]CC.CC[N-]CC.CC[N-]CC.CC[N-]CC VJDVOZLYDLHLSM-UHFFFAOYSA-N 0.000 description 1
- VSLPMIMVDUOYFW-UHFFFAOYSA-N dimethylazanide;tantalum(5+) Chemical compound [Ta+5].C[N-]C.C[N-]C.C[N-]C.C[N-]C.C[N-]C VSLPMIMVDUOYFW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000005383 fluoride glass Substances 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012804 iterative process Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000012705 liquid precursor Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- 230000004297 night vision Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229910021340 platinum monosilicide Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- HSXKFDGTKKAEHL-UHFFFAOYSA-N tantalum(v) ethoxide Chemical compound [Ta+5].CC[O-].CC[O-].CC[O-].CC[O-].CC[O-] HSXKFDGTKKAEHL-UHFFFAOYSA-N 0.000 description 1
- DHHKPEUQJIEKOA-UHFFFAOYSA-N tert-butyl 2-[6-(nitromethyl)-6-bicyclo[3.2.0]hept-3-enyl]acetate Chemical compound C1C=CC2C(CC(=O)OC(C)(C)C)(C[N+]([O-])=O)CC21 DHHKPEUQJIEKOA-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/571,162 US8076241B2 (en) | 2009-09-30 | 2009-09-30 | Methods for multi-step copper plating on a continuous ruthenium film in recessed features |
| US12/571,162 | 2009-09-30 | ||
| PCT/US2010/050878 WO2011041522A2 (en) | 2009-09-30 | 2010-09-30 | Methods for multi-step copper plating on a continuous ruthenium film in recessed features |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013507008A JP2013507008A (ja) | 2013-02-28 |
| JP2013507008A5 true JP2013507008A5 (enExample) | 2013-12-12 |
Family
ID=43743696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012532310A Pending JP2013507008A (ja) | 2009-09-30 | 2010-09-30 | 切欠構造のなかで長尺状ルテニウム膜上に多段階式銅鍍金を行う方法。 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8076241B2 (enExample) |
| JP (1) | JP2013507008A (enExample) |
| KR (1) | KR20120082901A (enExample) |
| CN (1) | CN102859035A (enExample) |
| TW (1) | TW201113934A (enExample) |
| WO (1) | WO2011041522A2 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101271869B1 (ko) * | 2008-12-09 | 2013-06-07 | 가부시키가이샤 알박 | 질화 탄탈막의 형성 방법 및 그 성막 장치 |
| US20110204518A1 (en) * | 2010-02-23 | 2011-08-25 | Globalfoundries Inc. | Scalability with reduced contact resistance |
| US9257274B2 (en) | 2010-04-15 | 2016-02-09 | Lam Research Corporation | Gapfill of variable aspect ratio features with a composite PEALD and PECVD method |
| US9287113B2 (en) | 2012-11-08 | 2016-03-15 | Novellus Systems, Inc. | Methods for depositing films on sensitive substrates |
| US9997357B2 (en) | 2010-04-15 | 2018-06-12 | Lam Research Corporation | Capped ALD films for doping fin-shaped channel regions of 3-D IC transistors |
| US8637411B2 (en) | 2010-04-15 | 2014-01-28 | Novellus Systems, Inc. | Plasma activated conformal dielectric film deposition |
| US8661664B2 (en) | 2010-07-19 | 2014-03-04 | International Business Machines Corporation | Techniques for forming narrow copper filled vias having improved conductivity |
| KR101780050B1 (ko) * | 2011-02-28 | 2017-09-20 | 삼성전자주식회사 | 반도체 기억 소자 및 반도체 기억 소자의 형성 방법 |
| JP5862353B2 (ja) * | 2011-08-05 | 2016-02-16 | 東京エレクトロン株式会社 | 半導体装置の製造方法 |
| US8518818B2 (en) | 2011-09-16 | 2013-08-27 | Taiwan Semiconductor Manufacturing Co., Ltd. | Reverse damascene process |
| US9214383B2 (en) * | 2013-01-18 | 2015-12-15 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of semiconductor integrated circuit fabrication |
| US9536830B2 (en) | 2013-05-09 | 2017-01-03 | Globalfoundries Inc. | High performance refractory metal / copper interconnects to eliminate electromigration |
| US9171801B2 (en) * | 2013-05-09 | 2015-10-27 | Globalfoundries U.S. 2 Llc | E-fuse with hybrid metallization |
| EP3049555B1 (en) * | 2013-09-26 | 2025-05-14 | Atotech Deutschland GmbH & Co. KG | Novel adhesion promoting process for metallisation of substrate surfaces |
| JP2015160963A (ja) * | 2014-02-26 | 2015-09-07 | 東京エレクトロン株式会社 | ルテニウム膜の成膜方法および成膜装置、ならびに半導体装置の製造方法 |
| FR3017993B1 (fr) * | 2014-02-27 | 2017-08-11 | Commissariat Energie Atomique | Procede de realisation d'une structure par assemblage d'au moins deux elements par collage direct |
| US9564312B2 (en) | 2014-11-24 | 2017-02-07 | Lam Research Corporation | Selective inhibition in atomic layer deposition of silicon-containing films |
| US10566187B2 (en) | 2015-03-20 | 2020-02-18 | Lam Research Corporation | Ultrathin atomic layer deposition film accuracy thickness control |
| US9875890B2 (en) * | 2015-03-24 | 2018-01-23 | Lam Research Corporation | Deposition of metal dielectric film for hardmasks |
| JP6329199B2 (ja) * | 2016-03-30 | 2018-05-23 | 株式会社日立国際電気 | 半導体装置の製造方法、基板処理装置およびプログラム |
| WO2017218044A1 (en) * | 2016-06-15 | 2017-12-21 | Applied Materials, Inc. | Gas distribution plate assembly for high power plasma etch processes |
| US9773643B1 (en) | 2016-06-30 | 2017-09-26 | Lam Research Corporation | Apparatus and method for deposition and etch in gap fill |
| US10062563B2 (en) | 2016-07-01 | 2018-08-28 | Lam Research Corporation | Selective atomic layer deposition with post-dose treatment |
| US10037884B2 (en) | 2016-08-31 | 2018-07-31 | Lam Research Corporation | Selective atomic layer deposition for gapfill using sacrificial underlayer |
| CN107731703A (zh) * | 2017-08-31 | 2018-02-23 | 长江存储科技有限责任公司 | 一种互连结构及其制作方法和半导体器件的制作方法 |
| WO2019050714A1 (en) * | 2017-09-05 | 2019-03-14 | Applied Materials, Inc. | ASCENDING APPROACH FOR HIGH-FORM SHAPE FORMATION IN 3D MEMORY STRUCTURES |
| US10269559B2 (en) | 2017-09-13 | 2019-04-23 | Lam Research Corporation | Dielectric gapfill of high aspect ratio features utilizing a sacrificial etch cap layer |
| KR102789261B1 (ko) * | 2017-10-19 | 2025-04-01 | 램 리써치 코포레이션 | 단일 금속의 멀티배스 (multibath) 도금 |
| US11284510B2 (en) | 2018-04-17 | 2022-03-22 | Board Of Trustees Of Michigan State University | Controlled wetting and spreading of metals on substrates using porous interlayers and related articles |
| US11631680B2 (en) * | 2018-10-18 | 2023-04-18 | Applied Materials, Inc. | Methods and apparatus for smoothing dynamic random access memory bit line metal |
| US12040181B2 (en) | 2019-05-01 | 2024-07-16 | Lam Research Corporation | Modulated atomic layer deposition |
| US12431349B2 (en) | 2019-06-07 | 2025-09-30 | Lam Research Corporation | In-situ control of film properties during atomic layer deposition |
| JP7713456B2 (ja) | 2020-01-10 | 2025-07-25 | ラム リサーチ コーポレーション | Tsv処理窓ならびに長いパルス出力および傾斜部形成による充填性能強化 |
| JP7206355B2 (ja) * | 2020-11-12 | 2023-01-17 | アプライド マテリアルズ インコーポレイテッド | ダイナミックランダムアクセスメモリビット線金属を滑らかにするための方法及び装置 |
| US20220415651A1 (en) * | 2021-06-29 | 2022-12-29 | Applied Materials, Inc. | Methods Of Forming Memory Device With Reduced Resistivity |
| US20230197620A1 (en) * | 2021-12-21 | 2023-06-22 | Intel Corporation | Methods, systems, apparatus, and articles of manufacture for integrated circuit package substrates with high aspect ratio through glass vias |
Family Cites Families (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0524931A (ja) | 1991-07-16 | 1993-02-02 | Hitachi Metals Ltd | 窒化アルミニウム焼結体 |
| US5888870A (en) * | 1997-10-22 | 1999-03-30 | Advanced Micro Devices, Inc. | Memory cell fabrication employing an interpoly gate dielectric arranged upon a polished floating gate |
| JPH11168096A (ja) | 1997-12-04 | 1999-06-22 | Sony Corp | 高誘電酸化膜の形成方法 |
| US6200898B1 (en) * | 1999-10-25 | 2001-03-13 | Vanguard International Semiconductor Corporation | Global planarization process for high step DRAM devices via use of HF vapor etching |
| WO2002071463A1 (en) * | 2001-03-02 | 2002-09-12 | Tokyo Electron Limited | Shower head gas injection apparatus with secondary high pressure pulsed gas injection |
| JP4895430B2 (ja) * | 2001-03-22 | 2012-03-14 | ルネサスエレクトロニクス株式会社 | 半導体装置及び半導体装置の製造方法 |
| US6506668B1 (en) * | 2001-06-22 | 2003-01-14 | Advanced Micro Devices, Inc. | Utilization of annealing enhanced or repaired seed layer to improve copper interconnect reliability |
| JP4921652B2 (ja) * | 2001-08-03 | 2012-04-25 | エイエスエム インターナショナル エヌ.ヴェー. | イットリウム酸化物およびランタン酸化物薄膜を堆積する方法 |
| US6797599B2 (en) * | 2001-08-31 | 2004-09-28 | Texas Instruments Incorporated | Gate structure and method |
| EP1294021A1 (de) * | 2001-08-31 | 2003-03-19 | Infineon Technologies AG | Kondensatoreinrichtung für eine Halbleiterschaltungsanordnung und Verfahren zu deren Herstellung |
| JP3611545B2 (ja) * | 2001-12-20 | 2005-01-19 | 株式会社荏原製作所 | めっき装置 |
| JP3756456B2 (ja) * | 2002-03-07 | 2006-03-15 | 富士通株式会社 | 半導体装置の製造方法 |
| JP3588607B2 (ja) * | 2002-03-29 | 2004-11-17 | 株式会社東芝 | 電界効果トランジスタ |
| US6680130B2 (en) * | 2002-05-28 | 2004-01-20 | Agere Systems, Inc. | High K dielectric material and method of making a high K dielectric material |
| US6730164B2 (en) * | 2002-08-28 | 2004-05-04 | Micron Technology, Inc. | Systems and methods for forming strontium- and/or barium-containing layers |
| US6794284B2 (en) * | 2002-08-28 | 2004-09-21 | Micron Technology, Inc. | Systems and methods for forming refractory metal nitride layers using disilazanes |
| US20040051126A1 (en) * | 2002-09-16 | 2004-03-18 | Structured Materials Inc. | Compositionally engineered CexMnyO3 and semiconductor devices based thereon |
| US6858524B2 (en) * | 2002-12-03 | 2005-02-22 | Asm International, Nv | Method of depositing barrier layer for metal gates |
| JP4647311B2 (ja) | 2002-12-09 | 2011-03-09 | アイメック | 誘電体スタックの形成方法 |
| US6828200B2 (en) * | 2003-01-03 | 2004-12-07 | Texas Instruments Incorporated | Multistage deposition that incorporates nitrogen via an intermediate step |
| US7071519B2 (en) * | 2003-01-08 | 2006-07-04 | Texas Instruments Incorporated | Control of high-k gate dielectric film composition profile for property optimization |
| US6974768B1 (en) * | 2003-01-15 | 2005-12-13 | Novellus Systems, Inc. | Methods of providing an adhesion layer for adhesion of barrier and/or seed layers to dielectric films |
| JP3920235B2 (ja) * | 2003-03-24 | 2007-05-30 | 株式会社ルネサステクノロジ | 半導体装置の製造方法 |
| TW200506093A (en) * | 2003-04-21 | 2005-02-16 | Aviza Tech Inc | System and method for forming multi-component films |
| US20050274621A1 (en) * | 2004-06-10 | 2005-12-15 | Zhi-Wen Sun | Method of barrier layer surface treatment to enable direct copper plating on barrier metal |
| US7378129B2 (en) * | 2003-08-18 | 2008-05-27 | Micron Technology, Inc. | Atomic layer deposition methods of forming conductive metal nitride comprising layers |
| US7135361B2 (en) * | 2003-12-11 | 2006-11-14 | Texas Instruments Incorporated | Method for fabricating transistor gate structures and gate dielectrics thereof |
| US6979623B2 (en) * | 2003-12-17 | 2005-12-27 | Texas Instruments Incorporated | Method for fabricating split gate transistor device having high-k dielectrics |
| JP2005191482A (ja) | 2003-12-26 | 2005-07-14 | Semiconductor Leading Edge Technologies Inc | 半導体装置及びその製造方法 |
| WO2005065402A2 (en) | 2003-12-29 | 2005-07-21 | Translucent Photonics, Inc. | Rare earth-oxides, rare earth-nitrides, rare earth-phosphides and ternary alloys with silicon |
| JP2005340721A (ja) * | 2004-05-31 | 2005-12-08 | Anelva Corp | 高誘電率誘電体膜を堆積する方法 |
| CN1965110A (zh) * | 2004-06-10 | 2007-05-16 | 应用材料公司 | 能够在阻挡金属上直接镀铜的阻挡层表面处理的方法 |
| KR100589040B1 (ko) | 2004-08-05 | 2006-06-14 | 삼성전자주식회사 | 막 형성방법 및 이를 이용한 반도체 장치의 커패시터제조방법 |
| US7138680B2 (en) * | 2004-09-14 | 2006-11-21 | Infineon Technologies Ag | Memory device with floating gate stack |
| US7270848B2 (en) * | 2004-11-23 | 2007-09-18 | Tokyo Electron Limited | Method for increasing deposition rates of metal layers from metal-carbonyl precursors |
| US7279421B2 (en) * | 2004-11-23 | 2007-10-09 | Tokyo Electron Limited | Method and deposition system for increasing deposition rates of metal layers from metal-carbonyl precursors |
| US7442267B1 (en) * | 2004-11-29 | 2008-10-28 | Novellus Systems, Inc. | Anneal of ruthenium seed layer to improve copper plating |
| US7064043B1 (en) * | 2004-12-09 | 2006-06-20 | Texas Instruments Incorporated | Wafer bonded MOS decoupling capacitor |
| US7312139B2 (en) * | 2005-01-03 | 2007-12-25 | United Microelectronics Corp. | Method of fabricating nitrogen-containing gate dielectric layer and semiconductor device |
| US7316962B2 (en) * | 2005-01-07 | 2008-01-08 | Infineon Technologies Ag | High dielectric constant materials |
| EP1853745A2 (en) * | 2005-01-27 | 2007-11-14 | Applied Materials, Inc. | Ruthenium layer deposition apparatus and method |
| JP2006245558A (ja) * | 2005-02-04 | 2006-09-14 | Advanced Lcd Technologies Development Center Co Ltd | 銅配線層、銅配線層の形成方法、半導体装置、及び半導体装置の製造方法 |
| US7498247B2 (en) * | 2005-02-23 | 2009-03-03 | Micron Technology, Inc. | Atomic layer deposition of Hf3N4/HfO2 films as gate dielectrics |
| US7432139B2 (en) * | 2005-06-29 | 2008-10-07 | Amberwave Systems Corp. | Methods for forming dielectrics and metal electrodes |
| US20070077750A1 (en) * | 2005-09-06 | 2007-04-05 | Paul Ma | Atomic layer deposition processes for ruthenium materials |
| US7456102B1 (en) * | 2005-10-11 | 2008-11-25 | Novellus Systems, Inc. | Electroless copper fill process |
| JP2010507263A (ja) * | 2006-10-17 | 2010-03-04 | エントン インコーポレイテッド | 超小型電子デバイスの製造におけるフィチャーを埋め込むための銅堆積 |
| US20080296768A1 (en) * | 2006-12-14 | 2008-12-04 | Chebiam Ramanan V | Copper nucleation in interconnects having ruthenium layers |
| JP4397399B2 (ja) * | 2007-02-15 | 2010-01-13 | 富士通株式会社 | 半導体装置の製造方法 |
| US7470617B2 (en) * | 2007-03-01 | 2008-12-30 | Intel Corporation | Treating a liner layer to reduce surface oxides |
| US7799684B1 (en) * | 2007-03-05 | 2010-09-21 | Novellus Systems, Inc. | Two step process for uniform across wafer deposition and void free filling on ruthenium coated wafers |
| US20080242088A1 (en) * | 2007-03-29 | 2008-10-02 | Tokyo Electron Limited | Method of forming low resistivity copper film structures |
| US8058164B2 (en) * | 2007-06-04 | 2011-11-15 | Lam Research Corporation | Methods of fabricating electronic devices using direct copper plating |
| US20090020434A1 (en) * | 2007-07-02 | 2009-01-22 | Akira Susaki | Substrate processing method and substrate processing apparatus |
| JP2009099585A (ja) * | 2007-10-12 | 2009-05-07 | Panasonic Corp | 埋め込み配線の形成方法 |
| US7964506B1 (en) * | 2008-03-06 | 2011-06-21 | Novellus Systems, Inc. | Two step copper electroplating process with anneal for uniform across wafer deposition and void free filling on ruthenium coated wafers |
| US8247030B2 (en) * | 2008-03-07 | 2012-08-21 | Tokyo Electron Limited | Void-free copper filling of recessed features using a smooth non-agglomerated copper seed layer |
-
2009
- 2009-09-30 US US12/571,162 patent/US8076241B2/en active Active
-
2010
- 2010-09-29 TW TW099133025A patent/TW201113934A/zh unknown
- 2010-09-30 KR KR1020127010660A patent/KR20120082901A/ko not_active Ceased
- 2010-09-30 JP JP2012532310A patent/JP2013507008A/ja active Pending
- 2010-09-30 WO PCT/US2010/050878 patent/WO2011041522A2/en not_active Ceased
- 2010-09-30 CN CN2010800536818A patent/CN102859035A/zh active Pending
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