JP2012517507A - 2液型液体シム組成物 - Google Patents
2液型液体シム組成物 Download PDFInfo
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Abstract
Description
本出願は、その開示内容の全体を本明細書に援用する米国特許仮出願第61/151076号(2009年2月9日出願)の恩典を主張するものである。
本開示は、硬化性組成物、及び、液体シムの用途において有用でありうる硬化剤液とエポキシ樹脂液とからなる2液型組成物、並びにその使用方法に関する。
H2N−[(CH2)xO]y−(CH2)x−NH2 [I]
[式中、yは1、2、3又は4であり、xはそれぞれ独立して2、3又は4から選択される]の化合物である。特定のこうした実施形態では、過剰量の非分枝ポリエーテルジアミンのエポキシ樹脂との付加物は、エポキシ樹脂1部当たり2〜8部の非分枝ポリエーテルジアミンの付加物である。特定の実施形態では、エポキシ硬化剤は、少なくとも1種類の硝酸カルシウム硬化促進剤を更に含む。特定の実施形態では、エポキシ硬化剤が粒子状金属を含まない。
H2N−[(CH2)xO]y−(CH2)x−NH2 [I]
(式中、yは1、2、3又は4であり、より一般的には2又は3であり、xはそれぞれ独立して2、3又は4、より一般的には2又は3から選択される)の化合物であってよい。特定の実施形態では、yは2である。特定の実施形態では、yは2であり、xはそれぞれ独立して2又は3から選択される。特定の実施形態では、yは3である。特定の実施形態では、yは3であり、xはそれぞれ独立して2又は3から選択される。特定の実施形態では、非分枝ポリエーテルジアミンは4,7,10−トリオキサトリデカン1,13−ジアミン(TTD)であってよい。特定の実施形態では、非分枝ポリエーテルジアミンは、Jeffamine(登録商標)EDR 176として市販される4,7−ジオキサデカン1,10−ジアミンであってよい。
表Iに示されるエポキシ樹脂組成物を、小型の実験用ミキサー中で混合することによって調製した。配合物B4の製造は、2Lのdoppel Z実験用モーグル(mogul)中で行なった。ノボラック樹脂をモーグルに導入し、Kane Ace 156と混合した。約30分間の混合後、Aerosilを加え、次いで二酸化チタン粉末を加えた。次いで、全体を真空下で少なくとも40分間混合した。これにより均質な白色のペーストを得た。
表IIに示す硬化剤組成物を、小型の実験用ミキサー中で混合することによって調製した。配合物A1及びA2の製造は、B4液について述べたものと同じモーグル中で行なった。最初の工程として、Ancamine 2167及び硝酸カルシウムを導入した。これらを80℃に加熱して1時間混合した。室温(RT)にまで冷却した後、Aerosilを加え、均一になるまで混合した。この後、TTDとEpikote 828との付加物を導入し、室温で約30分間混合した。この後、Minsil及びカーボンブラックを加え、真空下で1時間混合した。TTDとEpikote 828との付加物は、180部のTTDを60部のEpikote 828と反応させることによって調製した。これら2成分を室温で1時間混合した後、80℃まで加熱した。温度を1時間維持して予備重合反応を完了させた。
本開示では、B1/A0、B1/A1、B1/A2、B2/A0、B2/A1、B2/A2、B3/A0、B3/A1、B3/A2、B4/A0、B4/A1及びB4/A2など、B液とA液との任意の組み合わせについても検討する。以下のB液とA液との組み合わせを1体積部のAに対して2体積部のBの比で調製した。すなわち、B1/A0、B2/A0、B3/A0、B4/A1及びB4/A2。配合物B4/A1及びB4/A2の混合粘度をHaake RheoWin装置で測定したところ、600パスカル(Pa)よりも低かった。
配合物B1/A0、B2/A0及びB3/A0の可使時間をDSC測定法によって調べた(硬化度)。表IIIは、これら3つの組み合わせについて硬化性能を混合後の時間の関数として示したものである。
Airbus AIMS資格10−07−001に従って機械的試験を行なった。結果を表IV、V及びVIに開示する。
Claims (20)
- 少なくとも1種類の脂環式ポリアミン硬化剤と、a)脂肪族ポリアミドアミン及びb)過剰量の非分枝ポリエーテルジアミンのエポキシ樹脂との付加物から選択される少なくとも1種類の第2の硬化剤と、を含む、エポキシ硬化剤。
- 前記少なくとも1種類の第2の硬化剤が、a)脂肪族ポリアミドアミンである、請求項1に記載のエポキシ硬化剤。
- 前記少なくとも1種類の第2の硬化剤が、b)過剰量の非分枝ポリエーテルジアミンのエポキシ樹脂との付加物である、請求項1に記載のエポキシ硬化剤。
- 前記非分枝ポリエーテルジアミンが式I:
H2N−[(CH2)xO]y−(CH2)x−NH2 [I]
[式中、yは1、2、3又は4であり、xはそれぞれ独立して2、3又は4から選択される]の化合物である、請求項3に記載のエポキシ硬化剤。 - 前記過剰量の非分枝ポリエーテルジアミンのエポキシ樹脂との付加物が、エポキシ樹脂1部当たり2〜8部の非分枝ポリエーテルジアミンの付加物である、請求項3に記載のエポキシ硬化剤。
- 前記過剰量の非分枝ポリエーテルジアミンのエポキシ樹脂との付加物が、エポキシ樹脂1部当たり2〜8部の非分枝ポリエーテルジアミンの付加物である、請求項4に記載のエポキシ硬化剤。
- 前記エポキシ硬化剤が、少なくとも1種類の硝酸カルシウム硬化促進剤を更に含む、請求項1に記載のエポキシ硬化剤。
- 前記エポキシ硬化剤が粒子状金属を含まない、請求項1に記載のエポキシ硬化剤。
- 隙間を充填するための方法であって、
a)エポキシ樹脂を含むエポキシ成分と、請求項1に記載のエポキシ硬化剤とを混合して混合物を形成する工程と、
b)前記隙間を前記混合物で充填する工程と、
c)前記混合物を硬化させる工程と、を含む、方法。 - 隙間を充填するための方法であって、
a)テトレグリシジルm−キシレンジアミンを含むエポキシ成分と、請求項2に記載のエポキシ硬化剤とを混合して混合物を形成する工程と、
b)前記隙間を前記混合物で充填する工程と、
c)前記混合物を硬化させる工程と、を含む、方法。 - 隙間を充填するための方法であって、
a)エポキシノボラック樹脂を含むエポキシ成分と、請求項3に記載のエポキシ硬化剤とを混合して混合物を形成する工程と、
b)前記隙間を前記混合物で充填する工程と、
c)前記混合物を硬化させる工程と、を含む、方法。 - 前記エポキシ成分がコアシェル型耐衝撃性改良剤を更に含む、請求項9に記載の方法。
- a)エポキシ樹脂を含むエポキシ成分と、b)請求項1に記載のエポキシ硬化剤とを混合して硬化させることによって得られる組成物。
- a)エポキシ樹脂を含むエポキシ成分と、b)請求項2に記載のエポキシ硬化剤とを混合して硬化させることによって得られる組成物。
- 前記エポキシ成分がテトラグリシジルm−キシレンジアミンを含む、請求項14に記載の組成物。
- a)エポキシ樹脂を含むエポキシ成分と、b)請求項3に記載のエポキシ硬化剤とを混合して硬化させることによって得られる組成物。
- 前記エポキシ成分がエポキシノボラック樹脂を含む、請求項16に記載の組成物。
- a)エポキシ樹脂を含むエポキシ成分と、b)請求項4に記載のエポキシ硬化剤とを混合して硬化させることによって得られる組成物。
- a)エポキシ樹脂を含むエポキシ成分と、b)請求項5に記載のエポキシ硬化剤とを混合して硬化させることによって得られる組成物。
- 前記エポキシ成分がコアシェル型耐衝撃性改良剤を更に含む、請求項13に記載の組成物。
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US15107609P | 2009-02-09 | 2009-02-09 | |
US61/151,076 | 2009-02-09 | ||
PCT/US2010/023597 WO2010091395A1 (en) | 2009-02-09 | 2010-02-09 | Two-part liquid shim compositions |
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JP2015197171A Division JP2016014153A (ja) | 2009-02-09 | 2015-10-02 | 2液型液体シム組成物 |
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US (2) | US20100203249A1 (ja) |
EP (1) | EP2393863B1 (ja) |
JP (2) | JP6162360B2 (ja) |
KR (2) | KR20170049641A (ja) |
CN (2) | CN102307923A (ja) |
BR (1) | BRPI1007981A2 (ja) |
CA (1) | CA2751849C (ja) |
ES (1) | ES2644010T3 (ja) |
PL (1) | PL2393863T3 (ja) |
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JP2016523313A (ja) * | 2013-06-28 | 2016-08-08 | スリーエム イノベイティブ プロパティズ カンパニー | シム処理用途のための高弾性率エポキシ接着剤 |
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Also Published As
Publication number | Publication date |
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KR20170049641A (ko) | 2017-05-10 |
WO2010091395A1 (en) | 2010-08-12 |
CN103232588A (zh) | 2013-08-07 |
US20100203249A1 (en) | 2010-08-12 |
BRPI1007981A2 (pt) | 2018-02-14 |
CN103232588B (zh) | 2017-09-26 |
JP2016014153A (ja) | 2016-01-28 |
JP6162360B2 (ja) | 2017-07-12 |
PT2393863T (pt) | 2017-11-02 |
US10233280B2 (en) | 2019-03-19 |
ES2644010T3 (es) | 2017-11-27 |
EP2393863B1 (en) | 2017-08-09 |
CN102307923A (zh) | 2012-01-04 |
CA2751849C (en) | 2017-06-27 |
PL2393863T3 (pl) | 2017-12-29 |
US20170044306A1 (en) | 2017-02-16 |
KR20110124278A (ko) | 2011-11-16 |
EP2393863A1 (en) | 2011-12-14 |
CA2751849A1 (en) | 2010-08-12 |
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