JP2006518742A5 - - Google Patents
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- Publication number
- JP2006518742A5 JP2006518742A5 JP2006503716A JP2006503716A JP2006518742A5 JP 2006518742 A5 JP2006518742 A5 JP 2006518742A5 JP 2006503716 A JP2006503716 A JP 2006503716A JP 2006503716 A JP2006503716 A JP 2006503716A JP 2006518742 A5 JP2006518742 A5 JP 2006518742A5
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbyl
- group
- substituted hydrocarbyl
- hydrocarbylsilyl
- atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims 33
- 239000003054 catalyst Substances 0.000 claims 17
- -1 hydrocarbyl sodium Chemical compound 0.000 claims 10
- 150000001875 compounds Chemical class 0.000 claims 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 8
- 150000004696 coordination complex Chemical class 0.000 claims 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 6
- 239000012190 activator Substances 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 229910052744 lithium Inorganic materials 0.000 claims 6
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical class [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 239000011734 sodium Substances 0.000 claims 6
- 229910052708 sodium Inorganic materials 0.000 claims 6
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 4
- 229910052779 Neodymium Inorganic materials 0.000 claims 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 125000004429 atom Chemical group 0.000 claims 4
- ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 claims 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 4
- 239000011777 magnesium Substances 0.000 claims 4
- 229910052749 magnesium Inorganic materials 0.000 claims 4
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 239000011591 potassium Substances 0.000 claims 4
- 229910052700 potassium Inorganic materials 0.000 claims 4
- 239000012429 reaction media Substances 0.000 claims 4
- 229910052684 Cerium Inorganic materials 0.000 claims 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims 3
- 229910052773 Promethium Inorganic materials 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 229910052746 lanthanum Inorganic materials 0.000 claims 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 3
- 230000000737 periodic effect Effects 0.000 claims 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims 3
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 claims 3
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims 2
- 229910015900 BF3 Inorganic materials 0.000 claims 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- HFKJQIJFRMRSKM-UHFFFAOYSA-N [3,5-bis(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1 HFKJQIJFRMRSKM-UHFFFAOYSA-N 0.000 claims 2
- 229910052768 actinide Inorganic materials 0.000 claims 2
- 150000001255 actinides Chemical class 0.000 claims 2
- 239000013543 active substance Substances 0.000 claims 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 2
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 125000000129 anionic group Chemical group 0.000 claims 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 150000001639 boron compounds Chemical class 0.000 claims 2
- 239000006229 carbon black Substances 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- 238000007334 copolymerization reaction Methods 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 150000005826 halohydrocarbons Chemical class 0.000 claims 2
- 150000004678 hydrides Chemical class 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- 229910052740 iodine Inorganic materials 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 2
- 229910052698 phosphorus Chemical group 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- OEKDNFRQVZLFBZ-UHFFFAOYSA-K scandium fluoride Chemical compound F[Sc](F)F OEKDNFRQVZLFBZ-UHFFFAOYSA-K 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 claims 2
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000002879 Lewis base Substances 0.000 claims 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 125000002252 acyl group Chemical class 0.000 claims 1
- 125000003368 amide group Chemical group 0.000 claims 1
- 125000005129 aryl carbonyl group Chemical class 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000460 chlorine Chemical group 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000011630 iodine Chemical group 0.000 claims 1
- 229910052747 lanthanoid Inorganic materials 0.000 claims 1
- 150000002602 lanthanoids Chemical class 0.000 claims 1
- 150000007527 lewis bases Chemical class 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 125000004437 phosphorous atom Chemical group 0.000 claims 1
- 239000011574 phosphorus Chemical group 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44907603P | 2003-02-21 | 2003-02-21 | |
| US44907703P | 2003-02-21 | 2003-02-21 | |
| US60/449,076 | 2003-02-21 | ||
| US60/449,077 | 2003-02-21 | ||
| PCT/US2004/004941 WO2004076504A2 (en) | 2003-02-21 | 2004-02-18 | Process for homo- or copolymerization of conjugated olefines |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011020777A Division JP5363515B2 (ja) | 2003-02-21 | 2011-02-02 | 共役オレフィンのホモ重合又は共重合方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006518742A JP2006518742A (ja) | 2006-08-17 |
| JP2006518742A5 true JP2006518742A5 (https=) | 2007-04-05 |
| JP5001000B2 JP5001000B2 (ja) | 2012-08-15 |
Family
ID=32930501
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006503716A Expired - Fee Related JP5001000B2 (ja) | 2003-02-21 | 2004-02-18 | 共役オレフィンのホモ重合又は共重合方法 |
| JP2011020777A Expired - Fee Related JP5363515B2 (ja) | 2003-02-21 | 2011-02-02 | 共役オレフィンのホモ重合又は共重合方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011020777A Expired - Fee Related JP5363515B2 (ja) | 2003-02-21 | 2011-02-02 | 共役オレフィンのホモ重合又は共重合方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US7612009B2 (https=) |
| EP (2) | EP1597292A2 (https=) |
| JP (2) | JP5001000B2 (https=) |
| KR (2) | KR101126452B1 (https=) |
| AU (1) | AU2004215465A1 (https=) |
| BR (1) | BRPI0407665A (https=) |
| CA (2) | CA2516232C (https=) |
| ES (1) | ES2427626T3 (https=) |
| MX (1) | MXPA05008841A (https=) |
| RU (1) | RU2348653C2 (https=) |
| WO (1) | WO2004076504A2 (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004076504A2 (en) | 2003-02-21 | 2004-09-10 | Dow Global Technologies, Inc. | Process for homo- or copolymerization of conjugated olefines |
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
| US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
| EP2311889A1 (de) * | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
| US9266978B2 (en) | 2010-07-30 | 2016-02-23 | Bridgestone Corporation | Copolymer and method of manufacturing the same |
| RU2537385C2 (ru) * | 2010-07-30 | 2015-01-10 | Бриджстоун Корпорейшн | Сополимер, каучуковая композиция, сшитая каучуковая композиция и покрышка |
| CN103140521B (zh) | 2010-07-30 | 2015-07-01 | 株式会社普利司通 | 共聚物中链结构的控制方法 |
| JP5918133B2 (ja) * | 2010-07-30 | 2016-05-18 | 株式会社ブリヂストン | 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| BR112013019814B1 (pt) * | 2011-02-05 | 2022-07-12 | Bridgestone Corporation | Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo |
| US8680210B2 (en) * | 2011-05-02 | 2014-03-25 | Bridgestone Corporation | Method for making functionalized polymer |
| JP5739991B2 (ja) * | 2011-06-02 | 2015-06-24 | 株式会社ブリヂストン | 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| ITMI20111650A1 (it) * | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-imminico di lantanidi, sistema catalitico comprendente detto complesso bis-imminico e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20111651A1 (it) * | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-immino piridinico di lantanidi, sistema catalitico comprendente detto complesso bis-immino piridinico e procedimento per la (co)polimerizzazione di dieni coniugati |
| RU2487137C2 (ru) * | 2011-10-04 | 2013-07-10 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения разветвленных функционализированных диеновых (со)полимеров |
| WO2013127448A1 (en) * | 2012-02-29 | 2013-09-06 | Styron Europe Gmbh | Process for producing diene polymers |
| CN104558451B (zh) * | 2013-10-17 | 2017-02-15 | 中国石油化工股份有限公司 | 一种高顺式丁二烯‑异戊二烯嵌段共聚物及其制备方法 |
| JP6665779B2 (ja) * | 2014-07-09 | 2020-03-13 | 宇部興産株式会社 | 共役ジエン重合用触媒、共役ジエン重合体、変性共役ジエン重合体、及びポリブタジエン、並びに、それらを含む組成物 |
| WO2017100315A1 (en) * | 2015-12-07 | 2017-06-15 | Bridgestone Corporation | Polybutadiene polymers and rubber compositions incorporating same for low temperature applications |
| JP7160620B2 (ja) * | 2018-03-05 | 2022-10-25 | 株式会社ブリヂストン | 共重合体、共重合体の製造方法、ゴム組成物及びタイヤ |
| EP3622843B1 (en) | 2018-09-13 | 2023-01-25 | The Goodyear Tire & Rubber Company | Resin modified oil extended rubber |
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-
2004
- 2004-02-18 WO PCT/US2004/004941 patent/WO2004076504A2/en not_active Ceased
- 2004-02-18 EP EP04712406A patent/EP1597292A2/en not_active Withdrawn
- 2004-02-18 RU RU2005129337/04A patent/RU2348653C2/ru not_active IP Right Cessation
- 2004-02-18 CA CA2516232A patent/CA2516232C/en not_active Expired - Fee Related
- 2004-02-18 JP JP2006503716A patent/JP5001000B2/ja not_active Expired - Fee Related
- 2004-02-18 EP EP10179828.8A patent/EP2267046B1/en not_active Expired - Lifetime
- 2004-02-18 AU AU2004215465A patent/AU2004215465A1/en not_active Abandoned
- 2004-02-18 US US10/543,986 patent/US7612009B2/en not_active Expired - Fee Related
- 2004-02-18 BR BRPI0407665-6A patent/BRPI0407665A/pt not_active Application Discontinuation
- 2004-02-18 KR KR1020117025798A patent/KR101126452B1/ko not_active Expired - Fee Related
- 2004-02-18 ES ES10179828T patent/ES2427626T3/es not_active Expired - Lifetime
- 2004-02-18 CA CA2807874A patent/CA2807874A1/en not_active Abandoned
- 2004-02-18 KR KR1020057015433A patent/KR101092349B1/ko not_active Expired - Fee Related
- 2004-02-18 MX MXPA05008841A patent/MXPA05008841A/es unknown
-
2009
- 2009-09-10 US US12/557,121 patent/US7915194B2/en not_active Expired - Fee Related
-
2011
- 2011-02-02 JP JP2011020777A patent/JP5363515B2/ja not_active Expired - Fee Related
- 2011-02-25 US US13/035,376 patent/US8153545B2/en not_active Expired - Fee Related
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