BRPI0407665A - catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados - Google Patents
catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturadosInfo
- Publication number
- BRPI0407665A BRPI0407665A BRPI0407665-6A BRPI0407665A BRPI0407665A BR PI0407665 A BRPI0407665 A BR PI0407665A BR PI0407665 A BRPI0407665 A BR PI0407665A BR PI0407665 A BRPI0407665 A BR PI0407665A
- Authority
- BR
- Brazil
- Prior art keywords
- metal complexes
- polymerization
- ethylenically unsaturated
- complex catalyst
- metal complex
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000004696 coordination complex Chemical class 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 239000002184 metal Substances 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000002879 Lewis base Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000007527 lewis bases Chemical class 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Chemical group 0.000 abstract 1
- 239000011574 phosphorus Chemical group 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/37—Lanthanum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44907603P | 2003-02-21 | 2003-02-21 | |
| US44907703P | 2003-02-21 | 2003-02-21 | |
| PCT/US2004/004941 WO2004076504A2 (en) | 2003-02-21 | 2004-02-18 | Process for homo- or copolymerization of conjugated olefines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0407665A true BRPI0407665A (pt) | 2006-03-01 |
Family
ID=32930501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0407665-6A BRPI0407665A (pt) | 2003-02-21 | 2004-02-18 | catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US7612009B2 (https=) |
| EP (2) | EP1597292A2 (https=) |
| JP (2) | JP5001000B2 (https=) |
| KR (2) | KR101126452B1 (https=) |
| AU (1) | AU2004215465A1 (https=) |
| BR (1) | BRPI0407665A (https=) |
| CA (2) | CA2807874A1 (https=) |
| ES (1) | ES2427626T3 (https=) |
| MX (1) | MXPA05008841A (https=) |
| RU (1) | RU2348653C2 (https=) |
| WO (1) | WO2004076504A2 (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2348653C2 (ru) | 2003-02-21 | 2009-03-10 | Дау Глобал Текнолоджиз Инк. | Способ гомо- или сополимеризации сопряженных олефинов |
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| US7825201B2 (en) * | 2007-12-31 | 2010-11-02 | Bridgestone Corporation | Process for producing polydienes |
| US7741418B2 (en) * | 2007-12-31 | 2010-06-22 | Bridgestone Corporation | Process for producing polydienes |
| EP2311889A1 (de) * | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
| WO2012014420A1 (ja) | 2010-07-30 | 2012-02-02 | 株式会社ブリヂストン | 共重合体の連鎖構造を制御する方法 |
| EP2599800B1 (en) * | 2010-07-30 | 2017-06-21 | Bridgestone Corporation | Copolymer and manufacturing method for same |
| WO2012014457A1 (ja) | 2010-07-30 | 2012-02-02 | 株式会社ブリヂストン | 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| EP2599804B1 (en) * | 2010-07-30 | 2019-02-20 | Bridgestone Corporation | Copolymer, rubber composition, cross-linked rubber composition, and tire |
| BR112013019814B1 (pt) * | 2011-02-05 | 2022-07-12 | Bridgestone Corporation | Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo |
| US8680210B2 (en) * | 2011-05-02 | 2014-03-25 | Bridgestone Corporation | Method for making functionalized polymer |
| WO2012164914A1 (ja) * | 2011-06-02 | 2012-12-06 | 株式会社ブリヂストン | 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| ITMI20111651A1 (it) * | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-immino piridinico di lantanidi, sistema catalitico comprendente detto complesso bis-immino piridinico e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20111650A1 (it) * | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso bis-imminico di lantanidi, sistema catalitico comprendente detto complesso bis-imminico e procedimento per la (co)polimerizzazione di dieni coniugati |
| RU2487137C2 (ru) * | 2011-10-04 | 2013-07-10 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения разветвленных функционализированных диеновых (со)полимеров |
| JP6073379B2 (ja) * | 2012-02-29 | 2017-02-01 | トリンゼオ ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング | ジエンポリマーの製造工程 |
| CN104558451B (zh) * | 2013-10-17 | 2017-02-15 | 中国石油化工股份有限公司 | 一种高顺式丁二烯‑异戊二烯嵌段共聚物及其制备方法 |
| TWI681982B (zh) * | 2014-07-09 | 2020-01-11 | 日商宇部興產股份有限公司 | 共軛二烯聚合用觸媒、共軛二烯聚合物、改性共軛二烯聚合物、及聚丁二烯、以及含此等成分的組成物 |
| EP3387067B1 (en) | 2015-12-07 | 2021-07-28 | Bridgestone Corporation | Polybutadiene polymers and rubber compositions incorporating same for low temperature applications |
| JP7160620B2 (ja) * | 2018-03-05 | 2022-10-25 | 株式会社ブリヂストン | 共重合体、共重合体の製造方法、ゴム組成物及びタイヤ |
| EP3622843B1 (en) * | 2018-09-13 | 2023-01-25 | The Goodyear Tire & Rubber Company | Resin modified oil extended rubber |
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|---|---|---|---|---|
| DE1301491B (de) | 1966-10-11 | 1969-08-21 | Basf Ag | Verfahren zur Herstellung von 1, 3-Dienpolymerisaten |
| CA1212932A (en) * | 1982-04-01 | 1986-10-21 | Derek K. Jenkins | Polymerisation of conjugated dienes |
| FR2567135B1 (fr) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | Polymere ou copolymere de butadiene et procede de preparation |
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-
2004
- 2004-02-18 RU RU2005129337/04A patent/RU2348653C2/ru not_active IP Right Cessation
- 2004-02-18 CA CA2807874A patent/CA2807874A1/en not_active Abandoned
- 2004-02-18 BR BRPI0407665-6A patent/BRPI0407665A/pt not_active Application Discontinuation
- 2004-02-18 ES ES10179828T patent/ES2427626T3/es not_active Expired - Lifetime
- 2004-02-18 CA CA2516232A patent/CA2516232C/en not_active Expired - Fee Related
- 2004-02-18 KR KR1020117025798A patent/KR101126452B1/ko not_active Expired - Fee Related
- 2004-02-18 JP JP2006503716A patent/JP5001000B2/ja not_active Expired - Fee Related
- 2004-02-18 MX MXPA05008841A patent/MXPA05008841A/es unknown
- 2004-02-18 US US10/543,986 patent/US7612009B2/en not_active Expired - Fee Related
- 2004-02-18 EP EP04712406A patent/EP1597292A2/en not_active Withdrawn
- 2004-02-18 WO PCT/US2004/004941 patent/WO2004076504A2/en not_active Ceased
- 2004-02-18 AU AU2004215465A patent/AU2004215465A1/en not_active Abandoned
- 2004-02-18 KR KR1020057015433A patent/KR101092349B1/ko not_active Expired - Fee Related
- 2004-02-18 EP EP10179828.8A patent/EP2267046B1/en not_active Expired - Lifetime
-
2009
- 2009-09-10 US US12/557,121 patent/US7915194B2/en not_active Expired - Fee Related
-
2011
- 2011-02-02 JP JP2011020777A patent/JP5363515B2/ja not_active Expired - Fee Related
- 2011-02-25 US US13/035,376 patent/US8153545B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20100248947A1 (en) | 2010-09-30 |
| US20060142145A1 (en) | 2006-06-29 |
| RU2348653C2 (ru) | 2009-03-10 |
| JP2011093934A (ja) | 2011-05-12 |
| EP2267046B1 (en) | 2013-08-07 |
| JP5001000B2 (ja) | 2012-08-15 |
| US8153545B2 (en) | 2012-04-10 |
| KR101126452B1 (ko) | 2012-03-29 |
| JP2006518742A (ja) | 2006-08-17 |
| JP5363515B2 (ja) | 2013-12-11 |
| CA2516232C (en) | 2013-05-14 |
| CA2516232A1 (en) | 2004-09-10 |
| RU2005129337A (ru) | 2006-03-20 |
| AU2004215465A1 (en) | 2004-09-10 |
| US7915194B2 (en) | 2011-03-29 |
| US7612009B2 (en) | 2009-11-03 |
| KR101092349B1 (ko) | 2011-12-09 |
| KR20110125676A (ko) | 2011-11-21 |
| WO2004076504A2 (en) | 2004-09-10 |
| KR20050103301A (ko) | 2005-10-28 |
| EP2267046A1 (en) | 2010-12-29 |
| CA2807874A1 (en) | 2004-09-10 |
| US20110160041A1 (en) | 2011-06-30 |
| MXPA05008841A (es) | 2005-10-18 |
| WO2004076504A3 (en) | 2005-01-27 |
| ES2427626T3 (es) | 2013-10-31 |
| EP1597292A2 (en) | 2005-11-23 |
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