ATE394166T1 - Olefinpolymerisationsverfahren mit einem auf einem magnesiumchlorid-alkohol-träger geträgerten organometallkomplex mit einem indenoindolylliganden - Google Patents

Olefinpolymerisationsverfahren mit einem auf einem magnesiumchlorid-alkohol-träger geträgerten organometallkomplex mit einem indenoindolylliganden

Info

Publication number
ATE394166T1
ATE394166T1 AT05789274T AT05789274T ATE394166T1 AT E394166 T1 ATE394166 T1 AT E394166T1 AT 05789274 T AT05789274 T AT 05789274T AT 05789274 T AT05789274 T AT 05789274T AT E394166 T1 ATE394166 T1 AT E394166T1
Authority
AT
Austria
Prior art keywords
magnesium chloride
organometall
polymerization process
olefin polymerization
alcohol
Prior art date
Application number
AT05789274T
Other languages
English (en)
Inventor
Shaotian Wang
Douglas Klendworth
Mark Reinking
Original Assignee
Equistar Chem Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Equistar Chem Lp filed Critical Equistar Chem Lp
Application granted granted Critical
Publication of ATE394166T1 publication Critical patent/ATE394166T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT05789274T 2004-09-23 2005-08-16 Olefinpolymerisationsverfahren mit einem auf einem magnesiumchlorid-alkohol-träger geträgerten organometallkomplex mit einem indenoindolylliganden ATE394166T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/948,019 US6967231B1 (en) 2004-09-23 2004-09-23 Olefin polymerization process

Publications (1)

Publication Number Publication Date
ATE394166T1 true ATE394166T1 (de) 2008-05-15

Family

ID=35344871

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05789274T ATE394166T1 (de) 2004-09-23 2005-08-16 Olefinpolymerisationsverfahren mit einem auf einem magnesiumchlorid-alkohol-träger geträgerten organometallkomplex mit einem indenoindolylliganden

Country Status (6)

Country Link
US (1) US6967231B1 (de)
EP (1) EP1791641B1 (de)
AT (1) ATE394166T1 (de)
CA (1) CA2580990A1 (de)
DE (1) DE602005006588D1 (de)
WO (1) WO2006036340A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101142115B1 (ko) * 2008-01-07 2012-07-06 에스케이이노베이션 주식회사 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및이를 이용한 에틸렌 단독중합체 또는 에틸렌과α-올레핀의 공중합체의 제조방법
KR101186489B1 (ko) * 2008-01-07 2012-09-27 에스케이이노베이션 주식회사 전이금속 화합물 및 이를 포함하는 에틸렌 단독중합체 또는공중합체 제조용 전이금속 촉매 조성물
WO2016099117A1 (ko) 2014-12-15 2016-06-23 주식회사 엘지화학 메탈로센 화합물, 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
CN116675285B (zh) * 2023-05-15 2023-11-10 苏州科技大学 一种全氟化合物的降解方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1553197A (en) * 1975-08-21 1979-09-26 British Petroleum Co Polymersiation catalyst
JPS56811A (en) 1979-06-18 1981-01-07 Mitsui Petrochem Ind Ltd Preparation of olefin polymer or copolymer
IT1136627B (it) 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
JPS57205408A (en) * 1981-06-11 1982-12-16 Toyo Sutoufuaa Chem:Kk Catalytic component for alpha-olefin polymerization and homopolymerization or copolymerization of alpha-olefin
US4634750A (en) * 1984-12-12 1987-01-06 Exxon Research & Engineering Co. Polymerization catalyst, production and use
US4937300A (en) * 1987-06-22 1990-06-26 Phillips Petroleum Company Catalyst and polymerization of olefins
US5192731A (en) * 1988-05-13 1993-03-09 Mitsui Petrochemical Industries, Ltd. Titanium catalyst components, process for preparing same, catalysts containing same for preparing ethylene polymers and process for preparing said ethylene polymers
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1248981B (it) 1990-06-22 1995-02-11 Enichem Anic Spa Procedimento per la preparazione di un componente solido di catalizzatore per la (co)polimerizzazione dell'etilene
US5534472A (en) 1995-03-29 1996-07-09 Quantum Chemical Corporation Vanadium-containing catalyst system
US6090740A (en) * 1996-02-08 2000-07-18 Exxon Chemical Patents Inc. Supported metallocene catalyst systems
ES2190131T3 (es) 1997-11-12 2003-07-16 Basell Polyolefine Gmbh Metalocenos y catalizadores para la polimerizacion de olefinas.
EP0989139A1 (de) * 1998-09-25 2000-03-29 Union Carbide Chemicals & Plastics Technology Corporation Katalysator auf Basis von unverbrücktem Monocyclopentadienylmetallkomplex für Olefinpolmerisation umgesetzt mit partikelförmigen Feststoffen dass funktionelle Gruppen enthält
US6171993B1 (en) 1998-12-04 2001-01-09 Equistar Chemicals, Lp Enhanced-impact LLDPE with a shear modifiable network structure
US6211311B1 (en) 1999-05-25 2001-04-03 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6232260B1 (en) 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
SG83223A1 (en) * 1999-12-27 2001-09-18 Sumitomo Chemical Co Modified particles, catalyst for olefin polymerization using the same, and process of producing olefin polymer
ATE292148T1 (de) 2000-01-18 2005-04-15 Basell Polyolefine Gmbh Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
US6541583B2 (en) 2001-05-17 2003-04-01 Equistar Chemicals, Lp Polypropylene preparation
US6583242B2 (en) * 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
US6440889B1 (en) 2001-08-15 2002-08-27 Equistar Chemicals, Lp Amine elimination process for making single-site catalysts
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US7211534B2 (en) * 2003-02-12 2007-05-01 Formosa Plastics Corporation, U.S.A. Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same

Also Published As

Publication number Publication date
WO2006036340A1 (en) 2006-04-06
DE602005006588D1 (de) 2008-06-19
US6967231B1 (en) 2005-11-22
CA2580990A1 (en) 2006-04-06
EP1791641A1 (de) 2007-06-06
EP1791641B1 (de) 2008-05-07

Similar Documents

Publication Publication Date Title
Ricci et al. Dienes polymerization: Where we are and what lies ahead
Thiele et al. Alternate transition metal complex based diene polymerization
ATE392442T1 (de) Olefinpolymerisationsverfahren zur herstellung von verzweigtes polymer enthaltenden zusammensetzungen
Georges et al. Efficient one-pot synthesis of end-functionalized trans-stereoregular polydiene macromonomers
CN105646785B (zh) 采用双活性中心复合催化剂制备环烯烃共聚物的方法
DE60318594D1 (de) Verfahren zur herstellung eines teilchenförmigen metallocenkatalysators mit modifiziertem aluminoxan und verwendung zur polymerisierung von olefinen
Dong et al. Homogeneous neodymium iso-propoxide/modified methylaluminoxane catalyst for isoprene polymerization
Moscato et al. Mechanistic investigations into the behavior of a labeled zirconocene polymerization catalyst
BRPI0407665A (pt) catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados
ATE268785T1 (de) Katalysatorzusammensetzungen für die polymerisation von olefinen zu polymeren mit multimodaler molekulargewichtsverteilung, verfahren zur herstellung und verwendung des katalysators
Akram et al. Effect of alkylaluminum cocatalyst on ethylene/1-hexene copolymerization and active center distribution of MgCl2-supported Ziegler-Natta catalyst
Yu et al. Alkynyl ether labeling: a selective and efficient approach to count active sites of olefin polymerization catalysts
CN109694434A (zh) 一种烯烃-不饱和羧酸聚合物及其制备方法
CN1309674A (zh) 共轭二烯采用稀土催化剂在乙烯基芳族溶剂存在下的聚合方法
Wang et al. Randomly coordinative chain transfer copolymerization of 1, 3-butadiene and isoprene: a highly atom-economic way for accessing butadiene/isoprene rubber
ES2556626T3 (es) Sistemas catalíticos de metales de transición y métodos para preparar homopolímeros de etileno o copolímeros de etileno y olefinas usando los mismos
ATE432296T1 (de) Bimetallische indenoindolyl katalysatoren
ATE394166T1 (de) Olefinpolymerisationsverfahren mit einem auf einem magnesiumchlorid-alkohol-träger geträgerten organometallkomplex mit einem indenoindolylliganden
IN2012DN01974A (de)
JP6162894B2 (ja) 触媒系
Friebe et al. A Comparison of Neodymium Versatate, Neodymium Neopentanolate and Neodymium Bis (2‐ethylhexyl) phosphate in Ternary Ziegler Type Catalyst Systems With Regard to their Impact on the Polymerization of 1, 3‐Butadiene
JPH1017617A (ja) ポリエチレン及びポリエチレンの製造方法
Xiao et al. Recent research progress of branched and functional branched polyethylene prepared using NI-and pd–based catalysts
CN1342717A (zh) 一种长链支化聚乙烯弹性体的制备方法
ATE361327T1 (de) Herstellung von olefin-acryl-copolymeren mit katalysatoren auf basis von späten übergangsmetallen

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties