BR0113238A - Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes - Google Patents

Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes

Info

Publication number
BR0113238A
BR0113238A BR0113238-5A BR0113238A BR0113238A BR 0113238 A BR0113238 A BR 0113238A BR 0113238 A BR0113238 A BR 0113238A BR 0113238 A BR0113238 A BR 0113238A
Authority
BR
Brazil
Prior art keywords
polymers
catalysts
provides
transition metal
metal complexes
Prior art date
Application number
BR0113238-5A
Other languages
English (en)
Inventor
Robert Timothy Stibrany
Smita Kacker
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of BR0113238A publication Critical patent/BR0113238A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/08—Copper compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

"COMPLEXOS DE METAL DE TRANSIçãO TARDIA, SEU USO COMO CATALISADORES E POLìMEROS DESTES". A invenção fornece um novo complexo de metal que, quando usado com um co-catalisador de ativação, fornece uma nova composição catalisadora. A invenção também fornece um método de polimerização que utiliza a composição catalisadora para produzir polímeros e copolímeros contendo grupos de monómeros. Mais especificamente, a invenção compreende uma composição compreendendo a fórmula LMXZ~ n~, em que X é selecionado do grupo que consiste de haletos, hidreto, triflato, acetatos, boratos, alquila C~ 1~ a C~ 12~, alcóxi C~ 1~ a C~ 12~, cicloalquila C~ 3~ a C~ 12~, cicloalcóxi C~ 3~ a C~ 12~, arila, tiolatos, monóxido de carbono, cianato, olefinas, e qualquer outra porção na qual um monómero pode inserir. M é selecionado do grupo que consiste de Cu, Ag e Au. L é um ligando bidentado contendo nitrogênio tendo mais que dois átomos de nitrogênio. Z é um ligando de coordenação neutro e n é igual a 0, 1 ou 2.
BR0113238-5A 2000-08-18 2001-08-03 Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes BR0113238A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/642,488 US6479425B1 (en) 2000-08-18 2000-08-18 Late transition metal complexes, their use as catalysts and polymers therefrom
PCT/US2001/024290 WO2002016373A1 (en) 2000-08-18 2001-08-03 Late transition metal complexes, their use as catalysts and polymers therefrom

Publications (1)

Publication Number Publication Date
BR0113238A true BR0113238A (pt) 2003-07-08

Family

ID=24576773

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0113238-5A BR0113238A (pt) 2000-08-18 2001-08-03 Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes

Country Status (9)

Country Link
US (2) US6479425B1 (pt)
EP (1) EP1311512A1 (pt)
JP (1) JP2004507466A (pt)
CN (1) CN1447813A (pt)
AU (1) AU2001281004A1 (pt)
BR (1) BR0113238A (pt)
CA (1) CA2415856A1 (pt)
WO (1) WO2002016373A1 (pt)
ZA (1) ZA200300421B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6809058B2 (en) * 2001-08-28 2004-10-26 Exxonmobil Research And Engineering Company Multi-dentate late transition metal catalyst complexes and polymerization methods using those complexes
DE10211418A1 (de) * 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
JP4742647B2 (ja) * 2005-03-31 2011-08-10 住友化学株式会社 極性モノマー−オレフィン共重合体の製造方法
FR2937643B1 (fr) 2008-10-27 2011-10-14 Arkema France Nouveaux copolymeres a blocs d'olefines polaires et apolaires

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3703561A (en) 1968-03-28 1972-11-21 Phillips Petroleum Co Olefin conversion using complexes of cu,ag and au with organoaluminums
US3558520A (en) 1968-03-28 1971-01-26 Phillips Petroleum Co Complexes of cu,ag and au with organoaluminums as olefin reaction catalysts
CA2091413A1 (en) 1992-03-11 1993-09-12 Anna Sommazzi Homogeneous catalytic system and process for copolymerizing olefins with carbon monoxide
US5556823A (en) 1994-11-28 1996-09-17 Enichem S.P.A. Catalytic system and process for the copolymerization of olefins with carbon monoxide
US5880241A (en) 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
TW505665B (en) 1996-08-09 2002-10-11 Du Pont Process for polymerization of olefinic monomers
CA2281540A1 (en) 1997-02-17 1998-08-20 Koichi Shibayama Process for preparing polymer by using copper compound
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
GB9722447D0 (en) * 1997-10-23 1997-12-24 Borealis As Process
WO1999030822A1 (en) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Group 11 transition metal amine catalysts for olefin polymerization
US6037297A (en) 1997-12-16 2000-03-14 Exxon Research And Engineering Co. Catalyst complexes and polymers therefrom
CA2294731C (en) 1998-04-28 2008-04-01 Kaneka Corporation Block copolymer

Also Published As

Publication number Publication date
CA2415856A1 (en) 2002-02-28
JP2004507466A (ja) 2004-03-11
US20030027714A1 (en) 2003-02-06
WO2002016373A1 (en) 2002-02-28
AU2001281004A1 (en) 2002-03-04
ZA200300421B (en) 2003-11-07
CN1447813A (zh) 2003-10-08
EP1311512A1 (en) 2003-05-21
US6479425B1 (en) 2002-11-12
US6642327B2 (en) 2003-11-04

Similar Documents

Publication Publication Date Title
WO2003054038A3 (en) Catalyst composition and olefin polymerization using same
DE69809957T2 (de) Katalysator mit ketimidem ligand
NZ332843A (en) Pyrrolaldimine transition metal catalyst, compositions and processes for olefin oligomerization and polymerization thereof
DE60226010D1 (de) Mehrkerniger metallocenkatalysator
CA2278130A1 (en) Group 5 transition metal compounds
FR2541683B1 (fr) Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
BR9908887A (pt) Complexos catalìticos de metal contendo ligando tridentado para polimerização de olefina
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
KR950024924A (ko) 에틸렌 중합체와 그 제조방법, 에틸렌 중합용 고체 티타늄 촉매성분 및 에틸렌 중합용 촉매
DE69925630D1 (de) Polymerisationskatalysatoren
DE69310583T2 (de) Homogenes Katalysatorsystem und Verfahren zur Copolymerisation eines oder mehrerer Olefine mit Kohlenmonoxid
BR0113238A (pt) Complexos de metal de transição tardia, seu uso como catalisadores e polìmeros destes
BR0009460A (pt) Processos para a copolimerização de etileno ou propileno um com o outro ou com outros compostos olefinicamente insaturados e para a polimerização ou copolimerização de olefinas, catalisador para a polimerização de olefinas, complexo de metal de transição e uso de complexo
DE69311601T2 (de) Homogenes Katalysatorsystem und Verfahren zur Copolymerisation von Olefinen mit Kohlenmonoxid
BG103994A (en) Activation composition of metallocene complexes in the catalysis of co-polymerization of olefins
DE59804679D1 (de) Katalysatorlösung zur polymerisation von alpha-olefinen
MY113420A (en) Process for polymerising olefin
BR0113302A (pt) Método para produzir uma composição de catalisador ativado in situ e produzir polìmeros ou copolìmeros a partir da mesma
KR920006374A (ko) 크롬 함유 착체 중합화용 촉매
EP0522643A3 (en) Method for preparing polymers of carbon monoxide and unsaturated compounds
ATE325139T1 (de) Dianionische, chelatierende liganden enthaltende olefinpolymerisationkatalysatoren
KR880701742A (ko) α-올레핀의 중합용 촉매 및 중합법
JPS5626905A (en) Polymerization of alpha-olefin
EP0792902A3 (en) A process for the preparation of copolymers
ES439297A1 (es) Procedimiento para la fabricacion de catalizadores activos para la polimerizacion de olefinas.

Legal Events

Date Code Title Description
B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired