BR9908887A - Complexos catalìticos de metal contendo ligando tridentado para polimerização de olefina - Google Patents
Complexos catalìticos de metal contendo ligando tridentado para polimerização de olefinaInfo
- Publication number
- BR9908887A BR9908887A BR9908887-8A BR9908887A BR9908887A BR 9908887 A BR9908887 A BR 9908887A BR 9908887 A BR9908887 A BR 9908887A BR 9908887 A BR9908887 A BR 9908887A
- Authority
- BR
- Brazil
- Prior art keywords
- olefin polymerization
- metal complexes
- catalytic metal
- group
- complexes containing
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 title abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000012685 metal catalyst precursor Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Patente de Invenção: <B>"COMPLEXOS CATALìTICOS DE METAL CONTENDO LIGANDO TRIDENTADO PARA POLIMIRIZAçãO DE OLEFINA"<D>. é revelado um catalizador de metal de transição com base em ligando monoaniónico tridentado, ativado em estado de oxidação reduzida para polimerização de olefina. Os precursores de catalisador de metal de transição para estes catalisadores possuem as fórmulas (A), (B), onde M é um metal de transição dos Grupos 4-9 em um estado de oxidação reduzida, X é um ligando monoaniónico, L é um grupo doador neutro, E é um grupo doador neutro dos Grupos 15 e 16, E' é um grupo doador monoaniónico do Grupo 15, T é um grupo de ligação em ponte, n é 1-3 conforme necessário para equilibrar a carga em M, p é 0-3 e q é 1-2. A polimerização de olefina é exemplificada.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8396698P | 1998-05-01 | 1998-05-01 | |
PCT/US1999/009306 WO1999057159A1 (en) | 1998-05-01 | 1999-04-29 | Tridentate ligand-containing metal catalyst complexes for olefin polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9908887A true BR9908887A (pt) | 2000-11-21 |
Family
ID=22181810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9908887-8A BR9908887A (pt) | 1998-05-01 | 1999-04-29 | Complexos catalìticos de metal contendo ligando tridentado para polimerização de olefina |
Country Status (10)
Country | Link |
---|---|
US (1) | US6294495B1 (pt) |
EP (1) | EP1084152B1 (pt) |
JP (1) | JP2002513823A (pt) |
KR (1) | KR100586118B1 (pt) |
CN (1) | CN1149229C (pt) |
BR (1) | BR9908887A (pt) |
CA (1) | CA2321712C (pt) |
DE (1) | DE69904469T2 (pt) |
ES (1) | ES2184448T3 (pt) |
WO (1) | WO1999057159A1 (pt) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4195138B2 (ja) * | 1998-12-10 | 2008-12-10 | 出光興産株式会社 | アルミニウムオキシ化合物、オレフィン重合用触媒成分及びポリオレフィンの製造方法 |
GB9914200D0 (en) * | 1999-06-17 | 1999-08-18 | Borealis As | Catalysts |
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6300439B1 (en) * | 1999-11-08 | 2001-10-09 | Univation Technologies, Llc | Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process |
US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
KR20020063242A (ko) * | 1999-12-20 | 2002-08-01 | 엑손 케미칼 패턴츠 인코포레이티드 | 지지된 이온 촉매를 이용한 폴리올레핀 수지의 제조 방법 |
KR100567100B1 (ko) * | 2000-03-24 | 2006-03-31 | 에스케이 주식회사 | 폴리에틸렌 제조용 균일활성종 촉매, 이의 제조방법 및이를 이용한 중합방법 |
US6627711B2 (en) * | 2001-04-04 | 2003-09-30 | Dow Global Technologies Inc. | Transition metal donor complexes and olefin polymerization process |
US6984602B2 (en) * | 2001-05-10 | 2006-01-10 | Univation Technologies, Llc | Olefin polymerization catalysts containing a pyrrole bisimine ligand |
EP1426385B1 (en) | 2001-07-23 | 2012-08-22 | Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences | Catalyst for polymerization or copolymerization of olefins, preparation and use of the same |
DE10163884A1 (de) | 2001-12-22 | 2003-07-10 | Henkel Kgaa | Neue Alkalische Protease aus Bacillus sp. (DSM 14392) und Wasch- und Reinigungsmittel enthaltend diese neue Alkalische Protease |
EP1325925A1 (en) * | 2002-01-03 | 2003-07-09 | Repsol Quimica S.A. | Chromium catalysts active in olefin polymerization |
EP1325924B1 (en) * | 2002-01-03 | 2005-03-16 | Repsol Quimica S.A. | Chromium catalysts active in olefin polymerisation |
US7943700B2 (en) * | 2002-10-01 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Enhanced ESCR of HDPE resins |
EP2261292B1 (en) | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
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US20070117713A1 (en) * | 2005-11-21 | 2007-05-24 | Abbas Razavi | Tridentate metal catalyst for olefin polymerization |
EP2045014B8 (en) * | 2006-07-25 | 2014-02-26 | National University Corporation Hokkaido University | Polymer-supported metal complex catalyst |
US8198373B2 (en) * | 2006-10-02 | 2012-06-12 | Exxonmobil Chemical Patents Inc. | Plastic toughened plastics |
CN101274968B (zh) * | 2007-03-28 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于生产宽分子量分布的聚乙烯的复合催化剂 |
CN104235795A (zh) * | 2013-06-17 | 2014-12-24 | 欧司朗有限公司 | 用于照明装置的散热装置和照明装置 |
US9598444B2 (en) | 2015-06-30 | 2017-03-21 | Exxonmobil Chemical Patents Inc. | Transition metal complexes of tridentate dianionic CNN ligands, production and use thereof |
WO2017003565A1 (en) * | 2015-06-30 | 2017-01-05 | Exxonmobil Chemical Patents Inc. | Transition metal complexes of tridentate dianionic cnn ligands, production and use thereof |
WO2018022263A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Polymerization processes using high molecular weight polyhydric quenching agents |
CN110678488B (zh) * | 2017-06-20 | 2023-06-27 | 陶氏环球技术有限责任公司 | 用于烯烃聚合的联芳基苯氧基第iv族过渡金属催化剂 |
TW202120432A (zh) | 2019-10-08 | 2021-06-01 | 法商液態空氣喬治斯克勞帝方法研究開發股份有限公司 | 用於沉積含鋰層、島或簇的鋰前驅體 |
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US6096676A (en) * | 1997-07-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
DE19728126A1 (de) * | 1997-07-02 | 1999-01-07 | Bayer Ag | Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen |
US5977393A (en) * | 1997-11-21 | 1999-11-02 | California Institute Of Technology | Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts |
JP4062756B2 (ja) * | 1997-12-18 | 2008-03-19 | 東ソー株式会社 | オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法 |
JP4103161B2 (ja) * | 1997-12-18 | 2008-06-18 | 東ソー株式会社 | オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法 |
US6060568A (en) * | 1998-12-18 | 2000-05-09 | The Governors Of The University Of Alberta | Carbene transition metal catalysts |
-
1999
- 1999-04-29 BR BR9908887-8A patent/BR9908887A/pt active Search and Examination
- 1999-04-29 WO PCT/US1999/009306 patent/WO1999057159A1/en active IP Right Grant
- 1999-04-29 JP JP2000547127A patent/JP2002513823A/ja active Pending
- 1999-04-29 US US09/302,243 patent/US6294495B1/en not_active Expired - Lifetime
- 1999-04-29 ES ES99920143T patent/ES2184448T3/es not_active Expired - Lifetime
- 1999-04-29 CA CA002321712A patent/CA2321712C/en not_active Expired - Fee Related
- 1999-04-29 KR KR1020007011335A patent/KR100586118B1/ko not_active IP Right Cessation
- 1999-04-29 EP EP99920143A patent/EP1084152B1/en not_active Expired - Lifetime
- 1999-04-29 CN CNB998052124A patent/CN1149229C/zh not_active Expired - Fee Related
- 1999-04-29 DE DE69904469T patent/DE69904469T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2321712C (en) | 2008-03-18 |
WO1999057159A1 (en) | 1999-11-11 |
US6294495B1 (en) | 2001-09-25 |
KR100586118B1 (ko) | 2006-06-02 |
JP2002513823A (ja) | 2002-05-14 |
DE69904469T2 (de) | 2003-04-17 |
ES2184448T3 (es) | 2003-04-01 |
EP1084152B1 (en) | 2002-12-11 |
CN1297456A (zh) | 2001-05-30 |
CN1149229C (zh) | 2004-05-12 |
DE69904469D1 (de) | 2003-01-23 |
CA2321712A1 (en) | 1999-11-11 |
KR20010071147A (ko) | 2001-07-28 |
EP1084152A1 (en) | 2001-03-21 |
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