JP2005533645A5 - - Google Patents
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- JP2005533645A5 JP2005533645A5 JP2004524797A JP2004524797A JP2005533645A5 JP 2005533645 A5 JP2005533645 A5 JP 2005533645A5 JP 2004524797 A JP2004524797 A JP 2004524797A JP 2004524797 A JP2004524797 A JP 2004524797A JP 2005533645 A5 JP2005533645 A5 JP 2005533645A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- composition according
- molar ratio
- taah
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 22
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims description 16
- 239000010936 titanium Substances 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 230000032050 esterification Effects 0.000 claims description 4
- 238000005886 esterification reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 238000006068 polycondensation reaction Methods 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 238000005809 transesterification reaction Methods 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- -1 aralkyl hydrocarbon Chemical group 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- HMBHAQMOBKLWRX-UHFFFAOYSA-N 2,3-dihydro-1,4-benzodioxine-3-carboxylic acid Chemical compound C1=CC=C2OC(C(=O)O)COC2=C1 HMBHAQMOBKLWRX-UHFFFAOYSA-N 0.000 description 1
- KIZQNNOULOCVDM-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)azanium;hydroxide Chemical compound [OH-].C[N+](C)(C)CCO KIZQNNOULOCVDM-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
- NWEKXBVHVALDOL-UHFFFAOYSA-N butylazanium;hydroxide Chemical compound [OH-].CCCC[NH3+] NWEKXBVHVALDOL-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229940075419 choline hydroxide Drugs 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39867502P | 2002-07-26 | 2002-07-26 | |
| US60/398,675 | 2002-07-26 | ||
| US10/269,363 | 2002-10-11 | ||
| US10/269,363 US6841505B2 (en) | 2002-07-26 | 2002-10-11 | Titanium-zirconium catalyst compositions and use thereof |
| PCT/US2003/023227 WO2004011139A1 (en) | 2002-07-26 | 2003-07-23 | Titanium-zirconium catalyst compositions and use thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005533645A JP2005533645A (ja) | 2005-11-10 |
| JP2005533645A5 true JP2005533645A5 (enExample) | 2006-08-10 |
| JP4708021B2 JP4708021B2 (ja) | 2011-06-22 |
Family
ID=30772617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004524797A Expired - Fee Related JP4708021B2 (ja) | 2002-07-26 | 2003-07-23 | チタン−ジルコニウム触媒組成物およびその使用 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6841505B2 (enExample) |
| EP (1) | EP1562704A4 (enExample) |
| JP (1) | JP4708021B2 (enExample) |
| KR (1) | KR100967769B1 (enExample) |
| AU (1) | AU2003256776A1 (enExample) |
| CA (1) | CA2493344A1 (enExample) |
| MX (1) | MXPA05000933A (enExample) |
| TW (1) | TW200401668A (enExample) |
| WO (1) | WO2004011139A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7799942B2 (en) * | 2005-08-12 | 2010-09-21 | Eastman Chemical Company | Production of terephthalic acid di-esters |
| US20070129503A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles |
| US20070128459A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films |
| US7666501B2 (en) * | 2005-12-07 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments |
| US7741509B2 (en) * | 2007-01-30 | 2010-06-22 | Eastman Chemical Company | Conversion of terephthalic acid to Di-n-butyl terephthalate |
| KR101109045B1 (ko) * | 2008-01-07 | 2012-01-31 | 주식회사 엘지화학 | 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법 |
| TWI417283B (zh) * | 2010-04-27 | 2013-12-01 | Kuo Tseng Li | 乳酸酯之製備方法 |
| JP2012046734A (ja) * | 2010-07-30 | 2012-03-08 | Fujifilm Corp | ポリエステルシートの製造方法、並びに、ポリエステルフィルム及びポリエステルフィルムの製造方法 |
| JP6016886B2 (ja) | 2011-04-12 | 2016-10-26 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 溶剤含有クリヤーラッカー被覆組成物、その製造法および該溶剤含有クリヤーラッカー被覆組成物の使用 |
| JP5799636B2 (ja) * | 2011-07-26 | 2015-10-28 | 三菱化学株式会社 | ポリエステルの製造方法 |
| WO2015045969A1 (ja) * | 2013-09-25 | 2015-04-02 | 株式会社Adeka | エステル化合物の製造方法 |
| EP2933019A1 (en) * | 2014-04-15 | 2015-10-21 | Henkel AG&Co. KGAA | Storage stable heat activated quaternary ammonium catalysts for epoxy cure |
| EP4174051B1 (en) * | 2020-06-29 | 2025-11-19 | Nitto Kasei Co., Ltd. | Curing catalyst used for curing polymer, method for producing same, moisture-curable composition, and method for producing cured product |
| TWI817105B (zh) * | 2021-04-14 | 2023-10-01 | 長春人造樹脂廠股份有限公司 | 聚酯組合物及其製備方法、製品及應用 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1039748B (de) | 1953-06-30 | 1958-09-25 | Bayer Ag | Verfahren zur Herstellung von Polyestern |
| US3056818A (en) | 1955-10-13 | 1962-10-02 | Goodrich Co B F | Titanium and zirconium esterification catalysts |
| FR2252328B1 (enExample) | 1973-11-24 | 1979-06-08 | Teijin Ltd | |
| JPS5946253B2 (ja) | 1976-05-11 | 1984-11-12 | 帝人株式会社 | ポリエステルの製造方法 |
| JPS5385891A (en) | 1977-01-05 | 1978-07-28 | Teijin Ltd | Preparation of polyester |
| JPS5840321A (ja) * | 1981-09-04 | 1983-03-09 | Toyobo Co Ltd | 易滑性ポリエステルの製造法 |
| US5120822A (en) | 1990-08-21 | 1992-06-09 | E. I. Du Pont De Nemours And Company | Polyester process comprising the addition of a tetraalkyl zirconate catalyst |
| JPH06234701A (ja) | 1992-03-16 | 1994-08-23 | Mitsui Toatsu Chem Inc | α,β−不飽和カルボン酸エステルの製造方法 |
| US5268503A (en) | 1992-03-16 | 1993-12-07 | Mitsui Toatsu Chemicals, Incorporated | Process for producing α,β-unsaturated carboxylic acid esters |
| JP2823739B2 (ja) | 1992-06-09 | 1998-11-11 | 帝人株式会社 | 金属板貼合せ成形加工用ポリエステルフイルム |
| DE4400300A1 (de) | 1994-01-07 | 1995-07-13 | Akzo Nobel Nv | Verfahren zur Herstellung von film- und faserbildenden Polyestern und Copolyestern |
| GB9612161D0 (en) * | 1996-06-11 | 1996-08-14 | Tioxide Specialties Ltd | Esterification process |
| GB9725419D0 (en) | 1997-12-02 | 1998-01-28 | Tioxide Specialties Ltd | Esterification catalysts |
| US5840957A (en) | 1998-03-16 | 1998-11-24 | E. I. Du Pont De Nemours And Company | Transesterification process using lanthanum compound catalyst |
| US5981690A (en) | 1998-04-17 | 1999-11-09 | E. I. Du Pont De Nemours And Company | Poly(alkylene arylates) having improved optical properties |
| WO1999054379A1 (en) | 1998-04-17 | 1999-10-28 | E.I. Du Pont De Nemours And Company | Poly(alkylene arylates) having optical properties |
| US6255441B1 (en) * | 1998-04-17 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
| US6346070B1 (en) * | 1998-12-25 | 2002-02-12 | Mitsui Chemicals Inc | Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester |
| US5969056A (en) * | 1999-01-14 | 1999-10-19 | Reichhold, Inc. | Process for preparing esterification products from cyclic organic carbonates using catalysts comprising quaternary ammonium salts |
| IT1307751B1 (it) | 1999-02-04 | 2001-11-19 | Gen Electric | Composizione di catalizzatore contenente fosfati per la preparazionedi poliesteri e procedimenti relativi. |
| US6512080B2 (en) | 1999-04-22 | 2003-01-28 | Shell Oil Company | Process of producing polytrimethylene terephthalate (PTT) |
| GB9912210D0 (en) | 1999-05-25 | 1999-07-28 | Acma Ltd | Esterification catalysts |
| US6407269B2 (en) | 1999-06-08 | 2002-06-18 | Kao Corporation | Catalyst for transesterification |
| MXPA02001942A (es) | 1999-08-25 | 2002-10-31 | Du Pont | Preparacion de poli(trimetilen tereftalato) con bajo nivel de di(1,3-propilenglicol). |
| US6043335A (en) | 1999-10-04 | 2000-03-28 | General Electric Company | Phosphate-containing catalyst composition for the preparation of polyesters, and related processes |
| US6075115A (en) | 1999-10-19 | 2000-06-13 | E. I. Du Pont De Nemours And Company | Process for the production of 5-sulfo isophthalate bis-glycolate ester metal salts and oxysulfonated polyesters made therefrom |
| US6166170A (en) | 1999-12-02 | 2000-12-26 | E. I. Du Pont De Nemours And Company | Esterification catalysts and processes therefor and therewith |
| GB0002156D0 (en) | 2000-02-01 | 2000-03-22 | Acma Ltd | Esterification catalyst compositions |
| US6255442B1 (en) | 2000-02-08 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Esterification process |
| US6353062B1 (en) | 2000-02-11 | 2002-03-05 | E. I. Du Pont De Nemours And Company | Continuous process for producing poly(trimethylene terephthalate) |
| ATE265486T1 (de) | 2000-02-11 | 2004-05-15 | Du Pont | Kontinuierliches verfahren zur herstellung von polytrimethylenterephthalat |
| US6576774B2 (en) | 2000-07-20 | 2003-06-10 | Shell Oil Company | Process for recycling polytrimethylene terephthalate cyclic dimer |
| BR0115879A (pt) * | 2000-11-21 | 2005-02-01 | Ici Plc | Catalisador de esterificação, processo de poliéster e artigo de poliéster |
| DE10059612A1 (de) * | 2000-12-01 | 2002-06-20 | Bayer Ag | Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern |
-
2002
- 2002-10-11 US US10/269,363 patent/US6841505B2/en not_active Expired - Fee Related
-
2003
- 2003-07-23 MX MXPA05000933A patent/MXPA05000933A/es active IP Right Grant
- 2003-07-23 KR KR1020057001343A patent/KR100967769B1/ko not_active Expired - Fee Related
- 2003-07-23 AU AU2003256776A patent/AU2003256776A1/en not_active Abandoned
- 2003-07-23 EP EP03771817A patent/EP1562704A4/en not_active Withdrawn
- 2003-07-23 JP JP2004524797A patent/JP4708021B2/ja not_active Expired - Fee Related
- 2003-07-23 WO PCT/US2003/023227 patent/WO2004011139A1/en not_active Ceased
- 2003-07-23 CA CA002493344A patent/CA2493344A1/en not_active Abandoned
- 2003-07-25 TW TW092120410A patent/TW200401668A/zh unknown
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