JP2002069085A5 - - Google Patents
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- Publication number
- JP2002069085A5 JP2002069085A5 JP2001174045A JP2001174045A JP2002069085A5 JP 2002069085 A5 JP2002069085 A5 JP 2002069085A5 JP 2001174045 A JP2001174045 A JP 2001174045A JP 2001174045 A JP2001174045 A JP 2001174045A JP 2002069085 A5 JP2002069085 A5 JP 2002069085A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- twenty
- substituted
- unsubstituted
- once
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000000217 alkyl group Chemical group 0.000 description 66
- 229910052760 oxygen Inorganic materials 0.000 description 49
- 229910052717 sulfur Inorganic materials 0.000 description 47
- 229910052736 halogen Inorganic materials 0.000 description 35
- 150000002367 halogens Chemical class 0.000 description 35
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 31
- -1 anthracyl Chemical group 0.000 description 25
- 150000001875 compounds Chemical class 0.000 description 25
- 125000000753 cycloalkyl group Chemical group 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 17
- 125000003342 alkenyl group Chemical group 0.000 description 14
- 239000001257 hydrogen Substances 0.000 description 14
- 125000002947 alkylene group Chemical group 0.000 description 13
- 150000002431 hydrogen Chemical class 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 10
- 125000003545 alkoxy group Chemical group 0.000 description 9
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 150000001266 acyl halides Chemical class 0.000 description 8
- 125000000392 cycloalkenyl group Chemical group 0.000 description 8
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 8
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 125000001624 naphthyl group Chemical group 0.000 description 8
- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical compound P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 8
- 125000004430 oxygen atom Chemical group O* 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 125000004350 aryl cycloalkyl group Chemical group 0.000 description 5
- 125000005724 cycloalkenylene group Chemical group 0.000 description 5
- 125000002993 cycloalkylene group Chemical group 0.000 description 5
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 4
- 101150065749 Churc1 gene Proteins 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 102100038239 Protein Churchill Human genes 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000000976 ink Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 4
- 125000004450 alkenylene group Chemical group 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000005486 sulfidation Methods 0.000 description 3
- 125000002373 5 membered heterocyclic group Chemical group 0.000 description 2
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 2
- 0 Cc1c(*)c(C)c(*)c(C)c1* Chemical compound Cc1c(*)c(C)c(*)c(C)c1* 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 125000004414 alkyl thio group Chemical group 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 1
- XVZXOLOFWKSDSR-UHFFFAOYSA-N Cc1cc(C)c([C]=O)c(C)c1 Chemical group Cc1cc(C)c([C]=O)c(C)c1 XVZXOLOFWKSDSR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NZMPLBWNYXKUMR-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethylphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(C)C=CC=C1C NZMPLBWNYXKUMR-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000005548 dental material Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH11332000 | 2000-06-08 | ||
| CH20001133/00 | 2000-06-08 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011133344A Division JP2011251965A (ja) | 2000-06-08 | 2011-06-15 | 有機金属モノアシルアルキルホスフィン |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002069085A JP2002069085A (ja) | 2002-03-08 |
| JP2002069085A5 true JP2002069085A5 (enExample) | 2008-07-24 |
| JP4850353B2 JP4850353B2 (ja) | 2012-01-11 |
Family
ID=4559286
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001174045A Expired - Fee Related JP4850353B2 (ja) | 2000-06-08 | 2001-06-08 | 有機金属モノアシルアルキルホスフィン |
| JP2011133344A Pending JP2011251965A (ja) | 2000-06-08 | 2011-06-15 | 有機金属モノアシルアルキルホスフィン |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011133344A Pending JP2011251965A (ja) | 2000-06-08 | 2011-06-15 | 有機金属モノアシルアルキルホスフィン |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US6737549B2 (enExample) |
| JP (2) | JP4850353B2 (enExample) |
| KR (1) | KR100829076B1 (enExample) |
| CN (1) | CN1198831C (enExample) |
| BE (1) | BE1014218A5 (enExample) |
| BR (1) | BR0102319B1 (enExample) |
| CA (1) | CA2349829A1 (enExample) |
| DE (1) | DE10127171A1 (enExample) |
| ES (1) | ES2194584B1 (enExample) |
| FR (1) | FR2810041B1 (enExample) |
| GB (1) | GB2365430B (enExample) |
| IT (1) | ITMI20011201A1 (enExample) |
| MX (1) | MXPA01005780A (enExample) |
| NL (1) | NL1018251C2 (enExample) |
| TW (1) | TWI268932B (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2365430B (en) * | 2000-06-08 | 2002-08-28 | Ciba Sc Holding Ag | Acylphosphine photoinitiators and intermediates |
| CN1264876C (zh) * | 2000-09-14 | 2006-07-19 | 西巴特殊化学品控股有限公司 | 在甲基丙烯酸酯铸模树脂中的酰基膦氧化物光引发剂 |
| KR100903939B1 (ko) | 2001-08-21 | 2009-06-25 | 시바 홀딩 인크 | 광개시제로서의 장파장 모노- 및 비스-아실포스핀 옥사이드 및 설파이드 |
| AU2002366198A1 (en) * | 2001-11-20 | 2003-06-10 | Ciba Specialty Chemicals Holding Inc. | Multimer forms of acylphosphines and their derivatives |
| CN1653297B (zh) | 2002-05-08 | 2010-09-29 | 佛森技术公司 | 高效固态光源及其使用和制造方法 |
| KR20050009744A (ko) * | 2002-06-11 | 2005-01-25 | 시바 스페셜티 케미칼스 홀딩 인크. | 모노- 및 비스아실포스핀 옥사이드의 다량체 형태 |
| CA2522898A1 (en) * | 2003-05-23 | 2004-12-02 | Ciba Specialty Chemicals Holding Inc. | Strongly adherent surface coatings |
| WO2005041632A2 (en) | 2003-10-31 | 2005-05-12 | Phoseon Technology, Inc. | Collection optics for led array with offset hemispherical or faceted surfaces |
| EP1735844B1 (en) | 2004-03-18 | 2019-06-19 | Phoseon Technology, Inc. | Use of a high-density light emitting diode array comprising micro-reflectors for curing applications |
| EP1814891B1 (en) * | 2004-11-23 | 2011-01-26 | Basf Se | Bisacylphosphanes and their use as photoinitiators; process for preparing acylphosphanes |
| US20060160917A1 (en) | 2004-12-21 | 2006-07-20 | Seiko Epson Corporation | Ink composition |
| KR101288758B1 (ko) | 2004-12-30 | 2013-07-23 | 포세온 테크날러지 인코퍼레이티드 | 산업 공정에서 광원을 사용하는 시스템 및 방법 |
| GB2422678B (en) * | 2005-01-25 | 2009-03-11 | Photocentric Ltd | Method of making a photopolymer plate |
| US8115213B2 (en) | 2007-02-08 | 2012-02-14 | Phoseon Technology, Inc. | Semiconductor light sources, systems, and methods |
| EP2107347B1 (en) * | 2008-04-04 | 2016-08-31 | Sensirion AG | Flow detector with a housing |
| DE102008018704B4 (de) * | 2008-04-07 | 2013-11-28 | Sächsische Walzengravur GmbH | Tiefdruck-oder Prägeform als Sleeve oder Zylinder |
| DE102008029195A1 (de) * | 2008-06-19 | 2009-12-24 | Koenig & Bauer Aktiengesellschaft | Druckplatte zum Aufspannen auf einem Plattenzylinder einer Rotationsdruckmaschine |
| US8653737B2 (en) | 2009-04-14 | 2014-02-18 | Phoseon Technology, Inc. | Controller for semiconductor lighting device |
| US8678612B2 (en) | 2009-04-14 | 2014-03-25 | Phoseon Technology, Inc. | Modular light source |
| US8465172B2 (en) | 2009-12-17 | 2013-06-18 | Phoseon Technology, Inc. | Lighting module with diffractive optical element |
| US8669697B2 (en) | 2010-03-11 | 2014-03-11 | Phoseon Technology, Inc. | Cooling large arrays with high heat flux densities |
| US8591078B2 (en) | 2010-06-03 | 2013-11-26 | Phoseon Technology, Inc. | Microchannel cooler for light emitting diode light fixtures |
| DK2588549T3 (en) * | 2010-06-30 | 2015-01-12 | Dsm Ip Assets Bv | D1479-STABLE LIQUID BAP photoinitiator AND ITS USE IN radiation-FORMATIONS |
| US9357592B2 (en) | 2010-11-18 | 2016-05-31 | Phoseon Technology, Inc. | Light source temperature monitor and control |
| GB201021603D0 (en) * | 2010-12-21 | 2011-02-02 | Fujifilm Imaging Colorants Ltd | Inks & printing process |
| US8872137B2 (en) | 2011-09-15 | 2014-10-28 | Phoseon Technology, Inc. | Dual elliptical reflector with a co-located foci for curing optical fibers |
| US9126432B2 (en) | 2011-09-20 | 2015-09-08 | Phoseon Technology, Inc. | Differential Ultraviolet curing using external optical elements |
| EP2766762B1 (en) | 2011-10-12 | 2019-07-17 | Phoseon Technology, Inc. | Multiple light collection and lens combinations with co-located foci for curing optical fibers |
| US8823279B2 (en) | 2011-10-27 | 2014-09-02 | Phoseon Technology, Inc. | Smart FET circuit |
| US8931928B2 (en) | 2011-11-01 | 2015-01-13 | Phoseon Technology, Inc. | Removable window frame for lighting module |
| US8851715B2 (en) | 2012-01-13 | 2014-10-07 | Phoseon Technology, Inc. | Lamp ventilation system |
| US8888336B2 (en) | 2012-02-29 | 2014-11-18 | Phoseon Technology, Inc. | Air deflectors for heat management in a lighting module |
| US8678622B2 (en) | 2012-04-27 | 2014-03-25 | Phoseon Technology, Inc. | Wrap-around window for lighting module |
| DE102012212429A1 (de) | 2012-07-16 | 2014-01-16 | Voco Gmbh | Dentalhandgerät, Verfahren und Verwendung desselben zum Aushärten lichthärtbaren Materials |
| CN105284797A (zh) * | 2014-07-14 | 2016-02-03 | 国家电网公司 | 一种微胶囊型缓释驱鸟合剂的制备方法 |
| CN110023058B (zh) | 2017-02-06 | 2021-08-10 | 惠普发展公司,有限责任合伙企业 | 3d打印 |
| US10781228B2 (en) | 2017-02-06 | 2020-09-22 | Hewlett-Packard Development Company, L.P. | Fusing agent including a metal bis(dithiolene) complex |
| CN110267797B (zh) | 2017-04-17 | 2021-07-30 | 惠普发展公司,有限责任合伙企业 | 熔合剂 |
| EP3409680B1 (en) * | 2017-05-30 | 2021-01-06 | IGM Group B.V. | Synthesis of bis(acyl)phosphines by activation of unreactive metal phosphides |
| TWI782066B (zh) | 2017-08-03 | 2022-11-01 | 德商漢高股份有限及兩合公司 | 可固化的聚矽氧光學透明黏著劑及其用途 |
| JP2020531594A (ja) * | 2017-08-24 | 2020-11-05 | スージョウ・レインボー・マテリアルズ・カンパニー・リミテッドSuzhou Rainbow Materials Co., Ltd. | シリコーン高分子光開始剤およびその使用 |
| MX2020006710A (es) | 2017-12-27 | 2020-08-20 | Henkel IP & Holding GmbH | Adhesivos sensibles a la presion opticamente transparentes y usos de los mismos. |
| KR102693603B1 (ko) | 2018-10-01 | 2024-08-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 유기 규소 화합물, 이의 제조 방법 및 그 사용 |
| EP3686252A1 (en) * | 2019-01-24 | 2020-07-29 | Agfa-Gevaert Nv | Radiation curable inkjet ink for manufacturing printed circuit boards |
| CN115701282A (zh) * | 2020-05-14 | 2023-02-07 | 3M创新有限公司 | 包含至少一个使用氟化光引发剂制备的氟化(共)聚合物层的多层光学膜及其制备和使用方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2909992A1 (de) * | 1979-03-14 | 1980-10-02 | Basf Ag | Photopolymerisierbare aufzeichnungsmassen, insbesondere zur herstellung von druckplatten und reliefformen |
| DE2830927A1 (de) * | 1978-07-14 | 1980-01-31 | Basf Ag | Acylphosphinoxidverbindungen und ihre verwendung |
| DE2909994A1 (de) * | 1979-03-14 | 1980-10-02 | Basf Ag | Acylphosphinoxidverbindungen, ihre herstellung und verwendung |
| DE3020092A1 (de) | 1980-05-27 | 1981-12-10 | Basf Ag, 6700 Ludwigshafen | Acylphosphinverbindungen und ihre verwendung |
| DE3034697A1 (de) * | 1980-09-15 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Acylphosphinsulfidverbindungen, ihre herstellung und verwendung |
| DE3139984A1 (de) | 1981-10-08 | 1983-04-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von acylphosphinoxiden |
| DE3443221A1 (de) * | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| US5218009A (en) | 1989-08-04 | 1993-06-08 | Ciba-Geigy Corporation | Mono- and di-acylphosphine oxides |
| EP0413657B1 (de) * | 1989-08-04 | 1996-12-27 | Ciba SC Holding AG | Mono- und Diacylphosphinoxide |
| KR0168316B1 (ko) * | 1989-08-04 | 1999-03-30 | 시바 스페셜티 케미칼스 홀딩 인코포레이티드 | 모노-및 디-아실포스핀 옥사이드 |
| US5368985A (en) | 1991-01-14 | 1994-11-29 | Ciba-Geigy Corporation | Bisacylphosphine sulfides |
| EP0495751A1 (de) * | 1991-01-14 | 1992-07-22 | Ciba-Geigy Ag | Bisacylphosphine |
| DE59201477D1 (de) * | 1991-01-14 | 1995-04-06 | Ciba Geigy Ag | Bisacylphosphinsulfide. |
| GB9104050D0 (en) * | 1991-02-27 | 1991-04-17 | Ciba Geigy Ag | Compounds |
| RU2091385C1 (ru) * | 1991-09-23 | 1997-09-27 | Циба-Гейги АГ | Бисацилфосфиноксиды, состав и способ нанесения покрытий |
| ES2059261B1 (es) | 1992-10-08 | 1995-11-16 | Ciba Geigy Ag | Alquil-bisacilfosfinoxidos. |
| ZA941879B (en) * | 1993-03-18 | 1994-09-19 | Ciba Geigy | Curing compositions containing bisacylphosphine oxide photoinitiators |
| TW381106B (en) | 1994-09-02 | 2000-02-01 | Ciba Sc Holding Ag | Alkoxyphenyl-substituted bisacylphosphine oxides |
| WO1996007662A1 (en) | 1994-09-08 | 1996-03-14 | Ciba Specialty Chemicals Holding Inc. | Novel acylphosphine oxides |
| US5744511A (en) * | 1995-04-19 | 1998-04-28 | Tokuyama Corporation | Visible ray polymerization initiator and visible ray polymerizable composition |
| SE520727C2 (sv) * | 1996-03-04 | 2003-08-19 | Ciba Sc Holding Ag | Alkylfenylbisacylfosfinoxid och fotoinitiatorblandningar |
| SG53043A1 (en) | 1996-08-28 | 1998-09-28 | Ciba Geigy Ag | Molecular complex compounds as photoinitiators |
| JPH11199610A (ja) * | 1998-01-16 | 1999-07-27 | Showa Denko Kk | 光硬化性組成物及び組成物中のビスアシルホスフィンオキサイド系化合物の安定化方法 |
| DE19907957A1 (de) | 1998-02-27 | 1999-09-02 | Ciba Geigy Ag | Pigmentierte photohärtbare Zusammensetzung |
| DE19812859A1 (de) * | 1998-03-24 | 1999-09-30 | Basf Ag | Photoinitiatorgemische |
| ATE221893T1 (de) * | 1998-11-30 | 2002-08-15 | Ciba Sc Holding Ag | Verfahren zur herstellung von acylphosphinen und derivaten |
| ES2208250T3 (es) | 1999-12-08 | 2004-06-16 | Ciba Specialty Chemicals Holding Inc. | Nuevos sistemas de fotoiniciadores de oxido de fosfina y composiciones reticulables de color bajo. |
| JP2001200007A (ja) * | 2000-01-19 | 2001-07-24 | Shin Etsu Chem Co Ltd | 光硬化性樹脂組成物及び光ファイバー用被覆材 |
| GB2360283B (en) * | 2000-02-08 | 2002-08-21 | Ciba Sc Holding Ag | Monoacylarylphosphines and acylphosphine oxides and sulphides |
| GB2365430B (en) * | 2000-06-08 | 2002-08-28 | Ciba Sc Holding Ag | Acylphosphine photoinitiators and intermediates |
-
2001
- 2001-05-24 GB GB0112580A patent/GB2365430B/en not_active Expired - Fee Related
- 2001-05-31 US US09/871,373 patent/US6737549B2/en not_active Expired - Fee Related
- 2001-06-05 DE DE10127171A patent/DE10127171A1/de not_active Withdrawn
- 2001-06-06 TW TW090113664A patent/TWI268932B/zh not_active IP Right Cessation
- 2001-06-06 CA CA002349829A patent/CA2349829A1/en not_active Abandoned
- 2001-06-07 KR KR1020010031746A patent/KR100829076B1/ko not_active Expired - Fee Related
- 2001-06-07 IT IT2001MI001201A patent/ITMI20011201A1/it unknown
- 2001-06-07 CN CNB011208988A patent/CN1198831C/zh not_active Expired - Fee Related
- 2001-06-07 ES ES200101326A patent/ES2194584B1/es not_active Expired - Fee Related
- 2001-06-07 BE BE2001/0389A patent/BE1014218A5/fr not_active IP Right Cessation
- 2001-06-07 FR FR0107438A patent/FR2810041B1/fr not_active Expired - Fee Related
- 2001-06-08 MX MXPA01005780A patent/MXPA01005780A/es active IP Right Grant
- 2001-06-08 NL NL1018251A patent/NL1018251C2/nl not_active IP Right Cessation
- 2001-06-08 BR BRPI0102319-5A patent/BR0102319B1/pt not_active IP Right Cessation
- 2001-06-08 JP JP2001174045A patent/JP4850353B2/ja not_active Expired - Fee Related
-
2002
- 2002-10-25 US US10/280,819 patent/US7026017B2/en not_active Expired - Fee Related
- 2002-10-25 US US10/280,820 patent/US6969733B2/en not_active Expired - Fee Related
-
2011
- 2011-06-15 JP JP2011133344A patent/JP2011251965A/ja active Pending
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