JP2001516775A - 水性ポリマー分散液中の残留モノマー含量を減少させる方法 - Google Patents
水性ポリマー分散液中の残留モノマー含量を減少させる方法Info
- Publication number
- JP2001516775A JP2001516775A JP2000511796A JP2000511796A JP2001516775A JP 2001516775 A JP2001516775 A JP 2001516775A JP 2000511796 A JP2000511796 A JP 2000511796A JP 2000511796 A JP2000511796 A JP 2000511796A JP 2001516775 A JP2001516775 A JP 2001516775A
- Authority
- JP
- Japan
- Prior art keywords
- polymer dispersion
- acid
- monomers
- aqueous polymer
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000178 monomer Substances 0.000 title claims abstract description 60
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000006185 dispersion Substances 0.000 title abstract description 15
- 229920000642 polymer Polymers 0.000 title description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 25
- 239000003999 initiator Substances 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011975 tartaric acid Substances 0.000 claims abstract description 8
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 8
- 150000003254 radicals Chemical class 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 1
- 150000004965 peroxy acids Chemical class 0.000 abstract description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 description 25
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 239000012966 redox initiator Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 8
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 7
- 238000010626 work up procedure Methods 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- -1 thiol compounds Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical group CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 235000010350 erythorbic acid Nutrition 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 229940026239 isoascorbic acid Drugs 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ZKBSDMGDEJPNGS-UHFFFAOYSA-N 2,3-dihydroxypropanoic acid Chemical compound OCC(O)C(O)=O.OCC(O)C(O)=O ZKBSDMGDEJPNGS-UHFFFAOYSA-N 0.000 description 1
- YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 1
- UPZFLZYXYGBAPL-UHFFFAOYSA-N 2-ethyl-2-methyl-1,3-dioxolane Chemical compound CCC1(C)OCCO1 UPZFLZYXYGBAPL-UHFFFAOYSA-N 0.000 description 1
- OORRCVPWRPVJEK-UHFFFAOYSA-N 2-oxidanylethanoic acid Chemical compound OCC(O)=O.OCC(O)=O OORRCVPWRPVJEK-UHFFFAOYSA-N 0.000 description 1
- KVZLHPXEUGJPAH-UHFFFAOYSA-N 2-oxidanylpropanoic acid Chemical compound CC(O)C(O)=O.CC(O)C(O)=O KVZLHPXEUGJPAH-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- FVWNMKXGVVFMNM-UHFFFAOYSA-N OC(C(=O)O)O.O.C(C=O)(=O)O Chemical compound OC(C(=O)O)O.O.C(C=O)(=O)O FVWNMKXGVVFMNM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000001727 glucose Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229960001031 glucose Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000012038 nucleophile Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- VSVCAMGKPRPGQR-UHFFFAOYSA-N propan-2-one;sulfurous acid Chemical compound CC(C)=O.OS(O)=O VSVCAMGKPRPGQR-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19741187A DE19741187A1 (de) | 1997-09-18 | 1997-09-18 | Verfahren zur Verminderung des Restmonomerengehalts in wässrigen Polymerdispersionen |
| DE19741187.8 | 1997-09-18 | ||
| PCT/EP1998/005928 WO1999014249A1 (de) | 1997-09-18 | 1998-09-17 | Verfahren zur verminderung des restmonomerengehalts in wässrigen polymerdispersionen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001516775A true JP2001516775A (ja) | 2001-10-02 |
| JP2001516775A5 JP2001516775A5 (https=) | 2009-02-26 |
Family
ID=7842827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000511796A Pending JP2001516775A (ja) | 1997-09-18 | 1998-09-17 | 水性ポリマー分散液中の残留モノマー含量を減少させる方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6444760B1 (https=) |
| EP (1) | EP1023335B1 (https=) |
| JP (1) | JP2001516775A (https=) |
| AU (1) | AU9541198A (https=) |
| BR (1) | BR9812464A (https=) |
| DE (2) | DE19741187A1 (https=) |
| WO (1) | WO1999014249A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008208192A (ja) * | 2007-02-26 | 2008-09-11 | Nichigo-Mowinyl Co Ltd | 水性エマルジョン、水性エマルジョンの製造方法、および再乳化性樹脂粉末 |
| JP2016098268A (ja) * | 2014-11-19 | 2016-05-30 | 日油株式会社 | 酢酸ビニル系重合体エマルジョン |
| US10745500B2 (en) | 2016-02-24 | 2020-08-18 | Lg Chem, Ltd. | Preparation method for acrylic acid-based polymer |
Families Citing this family (116)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19743759A1 (de) | 1997-10-02 | 1999-04-08 | Brueggemann L Kg | Sulfinsäurederivate und deren Herstellung und Verwendung |
| DE19840586A1 (de) | 1998-09-05 | 2000-03-09 | Basf Ag | Verfahren zur Verminderung der Restmonomerenmenge in wässrigen Polymerdispersionen |
| DE19911170A1 (de) | 1999-03-12 | 2000-09-14 | Basf Ag | Verfahren zum Herstellen von W/O-Emulsionen |
| DE10107044A1 (de) | 2001-02-13 | 2002-08-14 | Basf Ag | Verfahren zur Überführung wässriger Polymerisatdispersionen von einem Behälter in einen anderen Behälter |
| DE10317434A1 (de) | 2003-04-15 | 2004-10-28 | Basf Ag | Verfahren zur Reduzierung der Restmonomerenmenge in wässrigen Polymerdispersionen |
| DE102004002650A1 (de) * | 2004-01-16 | 2005-08-11 | Basf Ag | Acrylat-Polymerisate auf Basis von tert.-Butylacrylat zur Verwendung in Sprayformulierungen |
| DE102005028989A1 (de) * | 2005-06-21 | 2007-01-04 | Basf Ag | Verfahren zur Herstellung einer wässrigen Polymerdispersion |
| ATE425996T1 (de) * | 2005-10-07 | 2009-04-15 | Basf Se | Haarfestiger auf basis von t-butylacrylat und hydroxyalkylmethacrylat |
| US7960477B2 (en) | 2006-12-13 | 2011-06-14 | Basf Se | Polyamides with acrylate rubbers |
| DE102008000269A1 (de) | 2007-02-13 | 2008-10-02 | Basf Se | Wässrige Polymerisatdispersionen |
| WO2008152017A1 (de) | 2007-06-11 | 2008-12-18 | Basf Se | Verfahren zur herstellung einer wässrigen polymerisatdispersion |
| WO2009153162A1 (de) | 2008-06-17 | 2009-12-23 | Basf Se | Verfahren zur herstellung einer wässrigen polymerisatdispersion |
| WO2011009838A2 (de) | 2009-07-22 | 2011-01-27 | Basf Se | Wässrige polymerisatdispersion und deren verwendung als bindemittel für die beschichtung von untergründen |
| CN102597023B (zh) | 2009-09-09 | 2015-09-16 | 巴斯夫欧洲公司 | 制备含水粘合剂分散体的方法 |
| WO2011039177A1 (de) | 2009-10-02 | 2011-04-07 | Basf Se | Gipsbauplatte enthaltend mikroverkapselte latentwärmespeichermaterialien |
| WO2011058163A1 (en) | 2009-11-16 | 2011-05-19 | Dsm Ip Assets B.V. | Acrylic polymer |
| EP2507300A1 (de) | 2009-12-04 | 2012-10-10 | Basf Se | Verfahren zur herstellung einer polymerisatdispersion |
| US20110133110A1 (en) * | 2009-12-04 | 2011-06-09 | Basf Se | Process for producing a polymer dispersion |
| WO2011069891A1 (de) | 2009-12-08 | 2011-06-16 | Basf Se | Verfahren zur herstellung von ladungsstrukturierten beschichtungen |
| CN102666657B (zh) | 2009-12-17 | 2014-09-03 | 巴斯夫欧洲公司 | 水性涂料制剂 |
| US8629207B2 (en) | 2009-12-17 | 2014-01-14 | Basf Se | Aqueous coating formulation |
| US8722796B2 (en) | 2010-01-20 | 2014-05-13 | Basf Se | Process for preparing an aqueous polymer dispersion |
| JP5755249B2 (ja) | 2010-01-20 | 2015-07-29 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 水性重合体分散液の製造方法 |
| DE102011005638A1 (de) | 2010-03-19 | 2011-12-15 | Basf Se | Verfahren zur Herstellung eines Formkörpers aus körnigen und/oder faserförmigen Substraten |
| DE102011079112A1 (de) | 2010-08-09 | 2013-01-03 | Basf Se | Wässrige Beschichtungsformulierung |
| AU2011298374B2 (en) | 2010-09-01 | 2015-04-23 | Basf Se | Aqueous emulsion polymers, production of same and use thereof |
| US8722756B2 (en) | 2010-09-01 | 2014-05-13 | Basf Se | Aqueous emulsion polymers, their preparation and use |
| BR112013012584A2 (pt) | 2010-12-02 | 2016-08-09 | Dsm Ip Assets Bv | polímero acrílico |
| AU2011347669B2 (en) | 2010-12-21 | 2016-03-17 | Basf Se | Multistage polymer dispersions, method for producing same, and use thereof |
| US8754151B2 (en) | 2010-12-21 | 2014-06-17 | Basf Se | Multistage polymer dispersions, processes for preparing them, and use thereof |
| US20120225978A1 (en) | 2011-03-02 | 2012-09-06 | Basf Se | Aqueous binders for granular and/or fibrous substrates |
| EP2681271B1 (de) | 2011-03-02 | 2018-04-04 | Basf Se | Wässrige bindemittel für körnige und/oder faserförmige substrate |
| TR201904462T4 (tr) | 2011-03-30 | 2019-05-21 | Basf Se | Çok kademeli sulu polimer dispersiyonlarının üretimi için metot ve bunların zeminlerin kaplanması için bağ maddesi olarak kullanımı. |
| US8877842B2 (en) | 2011-04-04 | 2014-11-04 | Basf Se | Aqueous binders for granular and/or fibrous substrates |
| CN103582667B (zh) | 2011-04-04 | 2017-03-15 | 巴斯夫欧洲公司 | 用于颗粒状和/或纤维状基底的水性粘合剂 |
| EP2744837B1 (de) | 2011-08-18 | 2016-06-01 | Basf Se | Verfahren zur herstellung eines wässrigen bindemittelsystems |
| US8957174B2 (en) | 2011-09-28 | 2015-02-17 | Basf Se | Process for preparing an aqueous polymer dispersion |
| AU2012314726B2 (en) | 2011-09-28 | 2015-09-17 | Basf Se | Process for preparing an aqueous polymer dispersion |
| BR112014018874B1 (pt) | 2012-02-08 | 2020-10-20 | Basf Se | dispersão aquosa livre de cimento, processos para preparar uma dispersão aquosa, e uma composição de polímero em pó, composição de polímero em pó, uso de uma dispersão aquosa, formulação aquosa de composições de fixação hidráulicas, e, composição de fixação hidráulica na forma de pó |
| JP2015512967A (ja) | 2012-02-14 | 2015-04-30 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 水性バインダー組成物 |
| US9023919B2 (en) | 2012-02-14 | 2015-05-05 | Basf Se | Aqueous binder composition |
| JP2015527413A (ja) | 2012-05-31 | 2015-09-17 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 結合剤 |
| AU2013273573B2 (en) | 2012-06-05 | 2016-05-26 | Basf Se | Use of multi-stage polymerizate dispersions to coat metal sheets |
| KR20150085525A (ko) | 2012-11-15 | 2015-07-23 | 바스프 에스이 | 색상 보유력을 개선하기 위한, 코팅제에서의 수성 중합체 분산액의 용도 |
| CN105073842A (zh) | 2013-03-18 | 2015-11-18 | 巴斯夫欧洲公司 | 制备可容易地再分散于水中的聚合物粉末的方法 |
| WO2014161817A1 (de) | 2013-04-03 | 2014-10-09 | Basf Se | Verfahren zur reduzierung der restmonomerenmenge in einer wässrigen polymerisatdispersion |
| CA2937581A1 (en) | 2014-01-22 | 2015-07-30 | Basf Se | Binder composition |
| WO2015150213A1 (de) | 2014-04-04 | 2015-10-08 | Basf Se | Verfahren zur herstellung von formkörpern |
| US10544249B2 (en) | 2014-04-11 | 2020-01-28 | Basf Se | Method for preparing an aqueous polymer dispersion |
| WO2016005468A1 (de) | 2014-07-10 | 2016-01-14 | Basf Se | Verfahren zur herstellung gefrier-auftau-stabiler, waessriger dispersionen |
| DE202014005635U1 (de) | 2014-07-10 | 2014-07-29 | Basf Se | Gefrier-Auftau-stabile, wässrige Dispersion |
| EP2965785A1 (en) | 2014-07-11 | 2016-01-13 | DSM IP Assets B.V. | Novel use |
| JP2017526768A (ja) | 2014-07-15 | 2017-09-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 床材用接着剤のための結合剤 |
| MX2017001518A (es) | 2014-08-01 | 2017-05-08 | Basf Se | Procedimiento para la preparacion y el uso de dispersiones hibridas acuosas de poliuretano-poliacrilato, asi como su uso en agentes de revestimiento. |
| EP3018148B1 (de) | 2014-11-04 | 2017-06-28 | Basf Se | Verfahren zur Herstellung einer wässrigen Polymerdispersion |
| WO2016087240A1 (de) | 2014-12-03 | 2016-06-09 | Basf Se | Bindemittelsystem für hochglänzende anstriche |
| WO2016096816A1 (en) | 2014-12-16 | 2016-06-23 | Basf Se | Novel polymer compositions and use of these polymer compositions as viscosity modifiers |
| AU2016299778A1 (en) | 2015-07-29 | 2018-03-08 | Basf Se | Aqueous dispersion of an oxazoline group-containing polymer |
| JP6869245B2 (ja) | 2015-09-23 | 2021-05-12 | ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ | 二成分コーティング組成物 |
| JP2018538384A (ja) | 2015-10-20 | 2018-12-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 繊維セメント板を被覆するためのコーティング組成物 |
| US10604608B2 (en) | 2015-11-06 | 2020-03-31 | Basf Se | Method for producing an aqueous binder |
| WO2017081233A1 (de) | 2015-11-13 | 2017-05-18 | Basf Se | Wässrige zusammensetzungen auf basis von polyalkenameren |
| CN108368208A (zh) | 2015-12-11 | 2018-08-03 | 巴斯夫欧洲公司 | 聚合物水分散体的制备方法 |
| WO2017140520A1 (de) | 2016-02-15 | 2017-08-24 | Basf Se | Thermoverformbares polymer/faser-komposit |
| WO2017191167A1 (en) | 2016-05-04 | 2017-11-09 | Basf Se | Process for preparing an aqueous polymer latex |
| EP3263209A1 (en) | 2016-06-30 | 2018-01-03 | Basf Se | Membranes comprising polymeric particle layers |
| BR112018076908A2 (pt) | 2016-07-20 | 2019-04-02 | Basf Se | processo para produzir uma dispersão aquosa de polímero, dispersão aquosa de polímero, polímero em pó, usos de uma dispersão aquosa de polímero e de uma formulação aquosa, e, formulação aquosa. |
| AU2017339556B2 (en) | 2016-10-07 | 2021-09-09 | Basf Se | Latex paint containing titanium dioxide pigment |
| US20190241762A1 (en) | 2016-10-07 | 2019-08-08 | Basf Se | Latex paint containing titanium dioxide pigment |
| WO2019043024A1 (en) | 2017-08-30 | 2019-03-07 | Basf Se | ETHYLENE-BASED POLYMER COMPOSITIONS FOR SOFT ROOF COVERINGS |
| WO2019091889A1 (de) | 2017-11-10 | 2019-05-16 | Basf Se | Wässrige polymerdispersionen |
| EP3713970A1 (en) | 2017-11-20 | 2020-09-30 | Basf Se | Aqueous acrylic polymer latexes and their use as binders |
| EP3728354A1 (en) | 2017-12-22 | 2020-10-28 | DSM IP Assets B.V. | Adhesive compositions and their use in 3d printing |
| WO2019145265A1 (en) | 2018-01-23 | 2019-08-01 | Basf Se | Aqueous binder compositions |
| EP3765531B1 (de) | 2018-03-15 | 2024-08-28 | Basf Se | Wässrige bindemittel |
| ES2991465T3 (es) | 2018-07-05 | 2024-12-03 | Basf Se | Procedimiento para producir una dispersión polimérica acuosa |
| WO2020025383A1 (en) | 2018-08-02 | 2020-02-06 | Basf Se | Process for producing an aqueous polymer dispersion |
| EP3833522B1 (de) | 2018-08-10 | 2025-08-20 | Basf Se | Verfahren zur herstellung eines thermoverformbaren polymer/faser-komposits |
| DE102019217820A1 (de) | 2018-11-21 | 2020-05-28 | Basf Se | Verfahren zur Herstellung von Dekorbeschichtungen auf mineralischen Substraten |
| WO2020221605A1 (en) | 2019-05-02 | 2020-11-05 | Basf Se | Aqueous binder composition |
| FI3966260T3 (fi) | 2019-05-08 | 2023-06-21 | Basf Se | Vesipitoinen polymeerilateksi |
| ES3040747T3 (en) | 2019-05-22 | 2025-11-04 | Basf Se | Fibre mouldings |
| CN114127135B (zh) | 2019-07-26 | 2024-05-31 | 巴斯夫欧洲公司 | 制备聚合物水分散体的方法 |
| EP4097183B1 (en) | 2020-01-30 | 2025-11-19 | Basf Se | Process of coating wood |
| EP4136130A1 (en) | 2020-04-17 | 2023-02-22 | Basf Se | Aqueous polymer dispersions |
| JP2023532812A (ja) | 2020-07-09 | 2023-07-31 | ベーアーエスエフ・エスエー | 接着剤配合物用の水性ポリマー分散液 |
| CN116134056B (zh) | 2020-07-20 | 2025-02-25 | 巴斯夫欧洲公司 | 适合作为水性涂料组合物中的粘合剂的成膜共聚物的水性聚合物胶乳 |
| ES3018708T3 (en) | 2020-11-26 | 2025-05-19 | Basf Se | Waterbased binder for two-component coating composition |
| EP4251665B1 (en) | 2020-11-30 | 2025-01-08 | Basf Se | Process of producing polymer dispersions |
| EP4255865A1 (en) | 2020-12-02 | 2023-10-11 | Basf Se | Composition for watertight coverings |
| WO2022161998A1 (en) | 2021-01-26 | 2022-08-04 | Basf Se | Aqueous polymer latex |
| CN117136203A (zh) | 2021-04-01 | 2023-11-28 | 巴斯夫欧洲公司 | 空心聚合物颗粒的水性聚合物分散体 |
| EP4326804A1 (en) | 2021-04-22 | 2024-02-28 | Basf Se | Process for preparing coated shaped bodies and their use |
| WO2023012213A1 (en) | 2021-08-04 | 2023-02-09 | Basf Se | Process for modifying an aqueous polymer latex |
| CN118055984A (zh) | 2021-10-04 | 2024-05-17 | 巴斯夫欧洲公司 | 水性聚合物组合物作为多孔材料的着色剂的用途 |
| WO2023117394A1 (de) | 2021-12-20 | 2023-06-29 | Basf Se | Verfahren zur herstellung eines thermoverformbaren polymer/faser-komposits |
| AU2022422307A1 (en) | 2021-12-23 | 2024-07-04 | Basf Se | Use of polymer dispersions in waterborne coating formulations and polymer dispersions therefor |
| WO2023209082A1 (en) | 2022-04-29 | 2023-11-02 | Basf Se | Combinations of an organic polymer and calcium silicate hydrate for producing mineral water-proofing membranes |
| WO2023232832A1 (en) | 2022-06-01 | 2023-12-07 | Basf Se | Composition for waterproofing membranes |
| CN119947876A (zh) | 2022-09-12 | 2025-05-06 | 巴斯夫欧洲公司 | 用于由有机废料生产水性聚合物分散体的方法 |
| CN120187764A (zh) | 2022-11-18 | 2025-06-20 | 巴斯夫欧洲公司 | 适合作为水性涂料组合物中的粘合剂的成膜共聚物的水性聚合物胶乳 |
| EP4389778A1 (en) | 2022-12-21 | 2024-06-26 | Basf Se | Aqueous polymer dispersion for coating compositions |
| EP4393970A1 (en) * | 2022-12-28 | 2024-07-03 | Arkema France | Composition comprising an aqueous polymer dispersion and a hydraulic binder |
| TW202502831A (zh) | 2023-03-24 | 2025-01-16 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中黏合劑的成膜共聚物的水性聚合物膠乳 |
| AU2024256180A1 (en) | 2023-04-20 | 2025-10-30 | Basf Se | Polymer dispersions of polymers p |
| WO2024256160A1 (en) | 2023-06-14 | 2024-12-19 | Basf Se | Compositions for construction purposes |
| TW202509091A (zh) | 2023-08-16 | 2025-03-01 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中之黏合劑之共聚物之含水聚合物乳膠 |
| WO2025078362A1 (en) | 2023-10-09 | 2025-04-17 | Basf Se | Process for the manufacture of styrene acrylic copolymers having a renewably-sourced carbon content |
| WO2025093409A1 (en) | 2023-10-30 | 2025-05-08 | Basf Se | Two-component coating composition |
| WO2025103901A1 (en) | 2023-11-14 | 2025-05-22 | Basf Se | Polymer dispersions for coatings |
| TW202546015A (zh) | 2023-12-13 | 2025-12-01 | 德商巴斯夫歐洲公司 | 適合作為水性塗料組成物中之黏合劑之共聚物之水性聚合物乳膠 |
| WO2025125067A1 (de) | 2023-12-15 | 2025-06-19 | Basf Se | Schnellhärtende, wässrige, intumeszierende brandschutzzusammensetzung mit hoher anwendungsschichtdicke auf oberflächen beliebiger neigung |
| EP4570865A1 (de) | 2023-12-15 | 2025-06-18 | Hilti Aktiengesellschaft | Wässrige brandschutzzusammensetzung mit hoher anwendungsschichtdicke und brandschutzbeschichtung mit verbesserter widerstandsfähigkeit gegen schimmelbildung |
| WO2025132646A1 (en) | 2023-12-19 | 2025-06-26 | Basf Se | Waterborne coating compositions requiring reduced amounts of biocides |
| WO2025252549A1 (en) | 2024-06-07 | 2025-12-11 | Basf Se | Polyamide particle foam moldings with low oil uptake |
| WO2026052438A1 (en) | 2024-09-03 | 2026-03-12 | Basf Se | Two-component coating composition |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1272584A (en) | 1968-07-05 | 1972-05-03 | Fisons Ind Chemicals Ltd | Process for deodorising polymers of unsaturated esters |
| AU529858B2 (en) | 1979-05-24 | 1983-06-23 | Maltini Pty. Ltd. | Removal of free monomer for alkyl acrylate polymers |
| US4278582A (en) | 1980-02-25 | 1981-07-14 | The B. F. Goodrich Company | Removal of residual acrylonitrile monomer |
| DE3037967A1 (de) | 1980-10-08 | 1982-05-13 | Röhm GmbH, 6100 Darmstadt | Verfahren zur polymerisation von wasserloeslichen monomeren oder monomerengemischen |
| US4360632A (en) | 1981-10-23 | 1982-11-23 | Air Products And Chemicals, Inc. | Ketone bisulfites as reducing agent for free radical polymerization |
| DE3619721A1 (de) | 1986-06-12 | 1987-12-17 | Wolff Walsrode Ag | Verfahren zur herstellung wasserloeslicher copolymerisate und deren verwendung als schlichtmittel |
| DE3718520A1 (de) | 1987-06-03 | 1988-12-15 | Bayer Ag | Emulsionspolymerisate |
| DE3834734A1 (de) * | 1988-10-12 | 1990-04-19 | Basf Ag | Verfahren zur herstellung von polymerisaten aus olefinisch ungesaettigten monomeren |
| DE3902103A1 (de) | 1989-01-25 | 1990-08-02 | Roehm Gmbh | Bindemittel fuer waessrige glanzfarben |
| DE4232194A1 (de) * | 1992-09-25 | 1994-03-31 | Roehm Gmbh | Verfahren zur Verringerung des Restmonomerengehaltes bei der Herstellung von Perlpolymerisaten |
| TW363978B (en) | 1994-05-06 | 1999-07-11 | Akzo Nobel Nv | A method of radically (co)polymerizing at least one vinyl halide or vinylidene halide |
| CN1120180C (zh) | 1994-06-03 | 2003-09-03 | 巴斯福股份公司 | 聚合物水分散液的制备 |
| DE4435422A1 (de) | 1994-10-04 | 1996-04-18 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
| DE19529599A1 (de) * | 1995-08-11 | 1997-02-13 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
-
1997
- 1997-09-18 DE DE19741187A patent/DE19741187A1/de not_active Withdrawn
-
1998
- 1998-09-17 EP EP98948987A patent/EP1023335B1/de not_active Expired - Lifetime
- 1998-09-17 BR BR9812464-1A patent/BR9812464A/pt not_active IP Right Cessation
- 1998-09-17 WO PCT/EP1998/005928 patent/WO1999014249A1/de not_active Ceased
- 1998-09-17 AU AU95411/98A patent/AU9541198A/en not_active Abandoned
- 1998-09-17 DE DE59809028T patent/DE59809028D1/de not_active Expired - Fee Related
- 1998-09-17 JP JP2000511796A patent/JP2001516775A/ja active Pending
- 1998-09-17 US US09/508,104 patent/US6444760B1/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008208192A (ja) * | 2007-02-26 | 2008-09-11 | Nichigo-Mowinyl Co Ltd | 水性エマルジョン、水性エマルジョンの製造方法、および再乳化性樹脂粉末 |
| JP2016098268A (ja) * | 2014-11-19 | 2016-05-30 | 日油株式会社 | 酢酸ビニル系重合体エマルジョン |
| US10745500B2 (en) | 2016-02-24 | 2020-08-18 | Lg Chem, Ltd. | Preparation method for acrylic acid-based polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| US6444760B1 (en) | 2002-09-03 |
| AU9541198A (en) | 1999-04-05 |
| BR9812464A (pt) | 2000-09-19 |
| DE19741187A1 (de) | 1999-03-25 |
| EP1023335A1 (de) | 2000-08-02 |
| EP1023335B1 (de) | 2003-07-16 |
| DE59809028D1 (de) | 2003-08-21 |
| WO1999014249A1 (de) | 1999-03-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2001516775A (ja) | 水性ポリマー分散液中の残留モノマー含量を減少させる方法 | |
| ES2235510T3 (es) | Procedimiento para la reduccion de la cantidad en monomeros residuales en dispersiones acuosas de polimeros. | |
| JP4294727B2 (ja) | 水性分散液の製法 | |
| JP2002523572A (ja) | 水性ポリマー分散液中の残存モノマーの量を低下させる方法 | |
| JPH0813923B2 (ja) | 常温架橋型重合体分散体組成物 | |
| CN100503652C (zh) | 仅含极少残留单体的聚合物水分散体的生产方法及其用途 | |
| JPH0145486B2 (https=) | ||
| JPH0250923B2 (https=) | ||
| JP3296580B2 (ja) | 超高分子量重合体エマルジョンの製造法 | |
| US2451180A (en) | Catalysts for the polymerization of butadiene-1,3 hydrocarbons | |
| JPS6154321B2 (https=) | ||
| JP3263063B2 (ja) | 水性ビニルアロマート−１，３−ジエン−コポリマー分散液および該分散液から得られる再分散粉末の臭気放出を減少させるための方法、および該方法により得られた生成物の使用 | |
| US7332565B2 (en) | Method for the reduction of the residual monomer content in aqueous polymer dispersions | |
| McKenzie et al. | Hydroxyl radical activated RAFT polymerization | |
| Elgood et al. | The emulsion polymerisation of vinyl acetate by redox initiation | |
| US6639048B1 (en) | Method for reducing the quantity of residual monomers in aqueous polymerisate dispersions | |
| JPH0129484B2 (https=) | ||
| JPH0316363B2 (https=) | ||
| JPH0615567B2 (ja) | 重合体スケールの付着防止方法 | |
| JPH10139801A (ja) | 塩化ビニルの重合方法 | |
| JP3472990B2 (ja) | 重合体製造法 | |
| JPH09165523A (ja) | 常温架橋型合成樹脂水性エマルジョン組成物 | |
| JPS63156802A (ja) | ビニル系重合体の製造方法 | |
| JPH02117901A (ja) | 重合体スケールの付着防止方法 | |
| JPH0615564B2 (ja) | 重合体スケールの付着防止方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050914 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080702 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080709 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081003 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081010 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081107 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081114 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20081208 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20081215 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20090108 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20090520 |