HUP9801818A2 - Eljárás kismolekulájú, nagy reakcióképességű poliizobutének előállítására - Google Patents

Eljárás kismolekulájú, nagy reakcióképességű poliizobutének előállítására

Info

Publication number
HUP9801818A2
HUP9801818A2 HU9801818A HUP9801818A HUP9801818A2 HU P9801818 A2 HUP9801818 A2 HU P9801818A2 HU 9801818 A HU9801818 A HU 9801818A HU P9801818 A HUP9801818 A HU P9801818A HU P9801818 A2 HUP9801818 A2 HU P9801818A2
Authority
HU
Hungary
Prior art keywords
polymerization
low molecular
polymerized resin
highly reactive
butene
Prior art date
Application number
HU9801818A
Other languages
English (en)
Inventor
Hans Peter Rath
Original Assignee
Basf Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Aktiengesellschaft filed Critical Basf Aktiengesellschaft
Publication of HUP9801818A2 publication Critical patent/HUP9801818A2/hu
Publication of HUP9801818A3 publication Critical patent/HUP9801818A3/hu

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • C08F110/10Isobutene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Abstract

A találmány tárgya eljárás kismőlekűlájú, nagy reakcióképességű, 500és 2000 közötti közepes relatív mőlekűlatömegű (Mn) és 80 mól% felettiarányban végállású kettős kötést tartalmazó pőliizőbűtén előállításáraizőbűtén vagy izőbűtént tartalmazó szénhidrőgénáram főlyadékfázisban,bór-triflűőrid-kőmplex katalizátőr segítségével, 0 és -40 řC közöttihőmérsékleten, 1 és 20 bar közötti nyőmásőn történőpőlimerizációjával. A találmány szerinti úgy árnak el, hőgy apőlimerizációs reakciót legalább két pőlimerizációs lépcsőben hajtjákvégre, ahől is az első pőlimerizációs lépcsőben a betáplált izőbűtén95%-ig terjedő részét alakítják át, majd a visszamaradó izőbűténpőlimerizációjának tővábbvitelét, az első lépcsőben keletkezettpőliizőbűtén eltávőlítása nélkül vagy azt követően, egy vagy többpőlimerizációs lépcsőben hajtják végre. ŕ
HU9801818A 1995-06-07 1996-06-04 Process for preparing low molecular, highly reactive polyisobutylenes HUP9801818A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19520078A DE19520078A1 (de) 1995-06-07 1995-06-07 Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten

Publications (2)

Publication Number Publication Date
HUP9801818A2 true HUP9801818A2 (hu) 1998-11-30
HUP9801818A3 HUP9801818A3 (en) 1999-03-01

Family

ID=7763391

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9801818A HUP9801818A3 (en) 1995-06-07 1996-06-04 Process for preparing low molecular, highly reactive polyisobutylenes

Country Status (14)

Country Link
US (1) US5962604A (hu)
EP (1) EP0830397B1 (hu)
JP (1) JP3761578B2 (hu)
KR (1) KR100424825B1 (hu)
CN (1) CN1104448C (hu)
AU (1) AU702804B2 (hu)
BR (1) BR9609425A (hu)
CA (1) CA2217848C (hu)
CZ (1) CZ357197A3 (hu)
DE (2) DE19520078A1 (hu)
ES (1) ES2137701T3 (hu)
HU (1) HUP9801818A3 (hu)
NO (1) NO975702L (hu)
WO (1) WO1996040808A1 (hu)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19645430A1 (de) * 1996-11-04 1998-05-07 Basf Ag Polyolefine und deren funktionalisierte Derivate
US6407186B1 (en) * 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
DE19825334A1 (de) * 1998-06-05 1999-12-09 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
DE19834593A1 (de) 1998-07-31 2000-02-03 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
WO2000011040A1 (fr) * 1998-08-25 2000-03-02 Nippon Petrochemicals Company, Limited Procede de production de polymere butenique
CN1156494C (zh) * 1999-02-23 2004-07-07 日本石油化学株式会社 丁烯聚合物的制造方法
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
JP5670874B2 (ja) * 1999-09-16 2015-02-18 ティーピーシー グループ リミティド ライアビリティ カンパニー ポリイソブチレンの液相重合方法
US6884858B2 (en) * 1999-10-19 2005-04-26 Texas Petrochemicals Lp Process for preparing polyolefin products
DE60045897D1 (de) 1999-09-16 2011-06-09 Tpc Group Llc Verfahren zur herstellung von polyolefinprodukten
DE19948947A1 (de) * 1999-10-11 2001-04-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polyisobutenen
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US6858188B2 (en) 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
US7037999B2 (en) 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
DE19952030A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
DE19952031A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
KR100486044B1 (ko) * 2000-11-13 2005-04-29 대림산업 주식회사 폴리부텐의 제조방법
AU2002221856A1 (en) 2000-11-17 2002-05-27 Basf Aktiengesellschaft Method for deactivating and recovering boron trifluoride when producing polyisobutenes
DE10125583A1 (de) * 2001-05-25 2002-11-28 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
MXPA03008425A (es) * 2001-06-08 2004-01-29 Texas Petrochemicals Lp Pelicula con adherencia mejorada con fijador de poliisobutileno reforzado.
DE10161250B4 (de) * 2001-12-13 2004-05-06 Daimlerchrysler Ag Verfahren zum mechanischen Fügen von Blechen
DE10361633A1 (de) 2003-12-30 2005-07-28 Basf Ag Herstellung hochreaktiver Polyisobutene mit niedrigem Halogengehalt
EP1598380A1 (de) 2004-05-19 2005-11-23 Basf Aktiengesellschaft Polymerisation von Isobuten in Gegenwart von Komplexen von Donor mit Fluor-haltigen Säuren
US20060287202A1 (en) * 2005-06-15 2006-12-21 Malcolm Waddoups Low ash or ashless two-cycle lubricating oil with reduced smoke generation
US20100105847A1 (en) 2006-01-24 2010-04-29 Intertape Polymer Corp. Plug flow bulk polymerization of vinyl monomers
US7906598B2 (en) * 2006-08-30 2011-03-15 Intertape Polymer Corp. Recirculation loop reactor bulk polymerization process
CA2661231C (en) * 2006-08-30 2015-12-01 Intertape Polymer Corp. Recirculation loop reactor bulk polymerization process
KR100787851B1 (ko) 2006-12-05 2007-12-27 대림산업 주식회사 폴리부텐 중합체 조성물 및 그 제조방법
US8193402B2 (en) 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
EP2225351A4 (en) 2007-12-03 2016-11-09 Gevo Inc RENEWABLE COMPOSITIONS
US20100298507A1 (en) * 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
CA2786607A1 (en) 2010-01-08 2011-07-14 Gevo, Inc. Integrated methods of preparing renewable chemicals
EP2566830B1 (en) 2010-05-07 2017-03-22 GEVO, Inc. Renewable jet fuel blendstock from isobutanol
US20130059927A1 (en) 2010-05-12 2013-03-07 Basf Se Emulsions of Polyisobutenes, Substance and Process
CN101921352B (zh) * 2010-09-28 2011-10-26 潍坊滨海石油化工有限公司 一种低分子量高活性聚异丁烯的生产方法
EP2699618A4 (en) 2011-04-19 2014-12-17 Gevo Inc VARIATIONS OF A PRINS REACTION FOR THE PREPARATION OF 2,5-DIMETHYLHEXADIENE FROM ISOBUTANOL
CN102807640B (zh) * 2011-06-02 2014-04-02 北京化工大学 一种基于三氟化硼的引发体系及用于制备聚异丁烯的方法
US8524843B2 (en) 2011-06-08 2013-09-03 Tpc Group Llc Production of highly reactive low molecular weight PIB oligomers
SG194908A1 (en) 2011-06-08 2013-12-30 Tpc Group L L C Production of highly reactive low molecular weight pib oligomers
CA2853060A1 (en) 2011-10-26 2013-05-02 Tpc Group Llc Polyisobutylene prepared with low diluent content reaction medium
MX354421B (es) 2011-10-26 2018-03-02 Tpc Group Llc Polimeros de poliisobutileno de alta viscosidad, con contenido de vinilideno de intervalo medio.
SG11201401508QA (en) 2011-10-26 2014-05-29 Tpc Group Llc Polyisobutylene prepared at high velocity and circulation rate
WO2013068272A1 (en) 2011-11-11 2013-05-16 Basf Se Self-emulsifiable polyolefine compositions
US20130118531A1 (en) 2011-11-11 2013-05-16 The Procter & Gamble Company Emulsions containing polymeric cationic emulsifiers, substance and process
CN104023705B (zh) 2011-11-11 2017-02-15 巴斯夫欧洲公司 可自乳化的聚烯烃组合物
KR20140093264A (ko) 2011-11-11 2014-07-25 바스프 에스이 중합체성 양이온성 에멀전화제를 함유하는 에멀전, 성분 및 방법
US8759274B2 (en) 2011-11-11 2014-06-24 Basf Se Self-emulsifiable polyolefine compositions
SG10201605034SA (en) * 2012-01-09 2016-08-30 Basf Se Method for the continuous production of polyisobutylene
US11072570B2 (en) 2012-01-09 2021-07-27 Basf Se Process for continuously preparing polyisobutylene
KR101523568B1 (ko) 2013-05-16 2015-05-28 대림산업 주식회사 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법
KR101457452B1 (ko) * 2013-06-05 2014-11-03 대림산업 주식회사 다양한 분자량을 가지는 폴리부텐의 제조 장치 및 방법
KR101511707B1 (ko) 2014-02-20 2015-04-13 대림산업 주식회사 분자량 조절이 용이한 폴리부텐의 제조장치 및 방법
SG11201509878RA (en) 2013-06-05 2016-01-28 Daelim Ind Co Ltd Apparatus and method for preparing polybutene having various molecular weights
US9688791B2 (en) * 2013-07-17 2017-06-27 Basf Se High-reactivity polyisobutylene having a high content of vinylidene double bonds in the side chains
KR101511701B1 (ko) * 2013-07-30 2015-04-13 대림산업 주식회사 폴리부텐 제조 시 사용되는 원료의 재순환 장치 및 방법
US9759830B2 (en) * 2013-10-30 2017-09-12 Schlumberger Technology Corporation Method and apparatus for determining mud contamination of formation fluid
KR101628897B1 (ko) 2014-06-18 2016-06-09 대림산업 주식회사 노르말 프로판올을 포함한 촉매를 이용한 폴리부텐의 제조방법
WO2016138939A1 (en) 2015-03-03 2016-09-09 Basf Se Pib as high viscosity lubricant base stock
US10066035B2 (en) 2015-12-07 2018-09-04 Bridgestone Corporation Catalyst systems and methods for preparation of 1,4-polybutadiene rubber
US9617363B1 (en) * 2016-03-03 2017-04-11 Tpc Group Llc Low-fluoride, reactive polyisobutylene
WO2017151339A1 (en) * 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
US9617366B1 (en) * 2016-03-03 2017-04-11 Tpc Group Llc Low-fluoride, reactive polyisobutylene
WO2018007165A1 (en) * 2016-07-06 2018-01-11 Ineos Europe Ag Polymerisation process
EP3585822A4 (en) 2017-02-21 2021-03-03 NTP Tec, LLC PROCESS FOR THE PREPARATION OF POLYISOBUTYLENE COMPOSITIONS
CN111315788B (zh) 2017-10-14 2023-08-15 Tpc集团有限责任公司 异丁烯共聚物、制作异丁烯共聚物的方法及异丁烯共聚物产物
BR112020026773A2 (pt) 2018-06-29 2021-04-06 Ntp Tec, Llc Processos para a fabricação de isobutileno, poli-isobutileno e seus derivados
KR102203006B1 (ko) 2019-04-24 2021-01-13 대림산업 주식회사 고반응성 폴리부텐의 제조 방법
EP3943518A1 (en) 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene
CN116023570A (zh) * 2021-10-27 2023-04-28 中国石油天然气股份有限公司 异丁烯与马来酸酐共聚的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702604C2 (de) * 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) * 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
DE3509272A1 (de) * 1985-03-15 1986-09-18 Basf Ag, 6700 Ludwigshafen Katalysatorsystem fuer die kationische polymerisation von isobutylen
US4849572A (en) * 1987-12-22 1989-07-18 Exxon Chemical Patents Inc. Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647)
DE4033195A1 (de) * 1990-10-19 1992-04-23 Basf Ag Verfahren zur herstellung von polyisobuten
US5286823A (en) * 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
ATE157338T1 (de) * 1991-11-18 1997-09-15 Amoco Corp Bf3-tertiäre etheratkomplexe zur isobuthylen- polymerisation

Also Published As

Publication number Publication date
DE19520078A1 (de) 1996-12-12
CN1104448C (zh) 2003-04-02
JPH11506492A (ja) 1999-06-08
BR9609425A (pt) 1999-05-25
AU702804B2 (en) 1999-03-04
KR19990022346A (ko) 1999-03-25
JP3761578B2 (ja) 2006-03-29
KR100424825B1 (ko) 2004-06-23
CA2217848A1 (en) 1996-12-19
WO1996040808A1 (de) 1996-12-19
MX9708837A (es) 1998-03-31
CZ357197A3 (cs) 1998-05-13
NO975702D0 (no) 1997-12-05
AU6004896A (en) 1996-12-30
CN1187208A (zh) 1998-07-08
HUP9801818A3 (en) 1999-03-01
CA2217848C (en) 2004-11-09
NO975702L (no) 1997-12-05
US5962604A (en) 1999-10-05
DE59603014D1 (de) 1999-10-14
EP0830397B1 (de) 1999-09-08
ES2137701T3 (es) 1999-12-16
EP0830397A1 (de) 1998-03-25

Similar Documents

Publication Publication Date Title
HUP9801818A2 (hu) Eljárás kismolekulájú, nagy reakcióképességű poliizobutének előállítására
CA2078777C (en) Process for preparing polyolefins having a bimodal molecular weight distribution
KR960022599A (ko) 폴리에틸렌의 제조방법
MY132302A (en) Vapor phase synthesis of rubbery polymers
HUP0002090A2 (hu) Eljárás blokk-polimer előállítására szabályzott gyökös polimerizációval és az előállított blokk-polimer
EP0854156A3 (en) Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
KR940011493A (ko) α-올레핀 중합체의 제조방법
HUP0203150A2 (hu) Eljárás poliizobutén folyamatos előállítására
RU97111880A (ru) Способ получения полиэтилена
NZ332880A (en) process for producing elastomers comprising ethylene, alpha olefins and optionally an diene
ES2120868A1 (es) Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
KR900007877A (ko) 과량의 촉매잔류물을 분해하는 바나듐-함유 지글러 촉매시스템을 사용한 에틸렌 중합체의 제법, 및 상기 방법으로 제조된 에틸렌 중합체
AU4256889A (en) Method for the synthesis of polymers based on boron and nitrogen
DE60011897D1 (de) Verfahren zur herstellung von alpha-olefin polymeren
AU2240999A (en) Improved olefin polymerization process
IE63798B1 (en) Preparation of propylene/ethylene polymers of the toughened polypropylene type
HUP0301859A2 (hu) Eljárás bór-trifluorid dezaktiválására és visszanyerésére poliizobutének gyártásakor
KR19990022517A (ko) 에틸렌과 시클릭 실록산 단량체의 음이온 중합 블록공중합체
GB1562557A (en) Process for polymerization of ethylene under high pressure
BR9101318A (pt) Processo para obtencao de copolimeros de propileno com outros alquenos-1
KR940005678A (ko) 에틸렌을 중합 및 공중합시켜 초고분자량 에틸렌 중합체를 제조하기 위한 촉매 시스템의 제조방법
AU5282699A (en) Method for producing halogen-free reactive polyisobutene
KR910014409A (ko) 프로필렌-에틸렌 중합체
JPH01217014A (ja) プロピレン重合体の製造法
KR970070021A (ko) 이피(디)엠 엘라스토머 공중합체 기재 중합성 혼합물의 제조 방법