NO975702L - Fremgansmåte for fremstilling av lavmolekylært, höyreaktivt polyisobuten - Google Patents

Fremgansmåte for fremstilling av lavmolekylært, höyreaktivt polyisobuten

Info

Publication number
NO975702L
NO975702L NO975702A NO975702A NO975702L NO 975702 L NO975702 L NO 975702L NO 975702 A NO975702 A NO 975702A NO 975702 A NO975702 A NO 975702A NO 975702 L NO975702 L NO 975702L
Authority
NO
Norway
Prior art keywords
molecular weight
preparation
low molecular
polymerized
isobutene
Prior art date
Application number
NO975702A
Other languages
English (en)
Other versions
NO975702D0 (no
Inventor
Hans Peter Rath
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of NO975702D0 publication Critical patent/NO975702D0/no
Publication of NO975702L publication Critical patent/NO975702L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Det beskrives en fremgangsmåte for fremstilling av et lavmolekylært, høyreaktivt polyisobuten som har en midlere molekylvekt M på 500-20.000 dalton, og som inneholder mer enn 80 mol% endestående dobbeltbindinger. For dette formål polymeriseres isobuten eller isobutenholdige hydrokarbon- strømmer i en flytende fase med en bortrifluorid-kompleks- katalysator ved temperaturer fra -40°C til 0°C og trykk fra l til 20 bar. Polymerisasjonsreaksjonen utføres i minst to polymerisasjonstrinn. I første polymerisasjonstrinn poly- meriseres opp til 95% av det tilførte isobuten. Det således oppnådde polyisobuten separeres deretter eller ikke, og det gjenværende isobuten polymeriseres i ett eller flere poly- merisasjonstrinn.
NO975702A 1995-06-07 1997-12-05 Fremgansmåte for fremstilling av lavmolekylært, höyreaktivt polyisobuten NO975702L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19520078A DE19520078A1 (de) 1995-06-07 1995-06-07 Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten
PCT/EP1996/002414 WO1996040808A1 (de) 1995-06-07 1996-06-04 Verfahren zur herstellung von niedermolekularem, hochreaktivem polyisobuten

Publications (2)

Publication Number Publication Date
NO975702D0 NO975702D0 (no) 1997-12-05
NO975702L true NO975702L (no) 1997-12-05

Family

ID=7763391

Family Applications (1)

Application Number Title Priority Date Filing Date
NO975702A NO975702L (no) 1995-06-07 1997-12-05 Fremgansmåte for fremstilling av lavmolekylært, höyreaktivt polyisobuten

Country Status (14)

Country Link
US (1) US5962604A (no)
EP (1) EP0830397B1 (no)
JP (1) JP3761578B2 (no)
KR (1) KR100424825B1 (no)
CN (1) CN1104448C (no)
AU (1) AU702804B2 (no)
BR (1) BR9609425A (no)
CA (1) CA2217848C (no)
CZ (1) CZ357197A3 (no)
DE (2) DE19520078A1 (no)
ES (1) ES2137701T3 (no)
HU (1) HUP9801818A3 (no)
NO (1) NO975702L (no)
WO (1) WO1996040808A1 (no)

Families Citing this family (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19645430A1 (de) * 1996-11-04 1998-05-07 Basf Ag Polyolefine und deren funktionalisierte Derivate
US6407186B1 (en) * 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
DE19825334A1 (de) * 1998-06-05 1999-12-09 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
DE19834593A1 (de) 1998-07-31 2000-02-03 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
KR20010031186A (ko) * 1998-08-25 2001-04-16 사이카와 겐조오 부텐중합체의 제조 방법
ID27304A (id) * 1999-02-23 2001-03-22 Nippon Petrochemicals Co Ltd Metode dehalogenasi hidrokarbon yang mengandung ikatan rangkap dua karbon-karbon
JP5670874B2 (ja) * 1999-09-16 2015-02-18 ティーピーシー グループ リミティド ライアビリティ カンパニー ポリイソブチレンの液相重合方法
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
US6884858B2 (en) 1999-10-19 2005-04-26 Texas Petrochemicals Lp Process for preparing polyolefin products
KR100600256B1 (ko) * 1999-09-16 2006-07-13 텍사스 페트로케미칼스 엘피 폴리올레핀 생성물을 제조하기 위한 방법
DE19948947A1 (de) * 1999-10-11 2001-04-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polyisobutenen
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US6858188B2 (en) 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
US7037999B2 (en) * 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
DE19952031A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
DE19952030A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
KR100486044B1 (ko) * 2000-11-13 2005-04-29 대림산업 주식회사 폴리부텐의 제조방법
KR100787076B1 (ko) 2000-11-17 2007-12-21 바스프 악티엔게젤샤프트 폴리이소부텐의 제조시 삼플루오르화붕소의 탈활성화 및회수 방법
DE10125583A1 (de) * 2001-05-25 2002-11-28 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
WO2002100153A2 (en) * 2001-06-08 2002-12-19 Texas Petrochemicals Lp Improved cling film with enhanced polyisobutylene tackifier
DE10161250B4 (de) * 2001-12-13 2004-05-06 Daimlerchrysler Ag Verfahren zum mechanischen Fügen von Blechen
DE10361633A1 (de) 2003-12-30 2005-07-28 Basf Ag Herstellung hochreaktiver Polyisobutene mit niedrigem Halogengehalt
EP1598380A1 (de) 2004-05-19 2005-11-23 Basf Aktiengesellschaft Polymerisation von Isobuten in Gegenwart von Komplexen von Donor mit Fluor-haltigen Säuren
US20060287202A1 (en) * 2005-06-15 2006-12-21 Malcolm Waddoups Low ash or ashless two-cycle lubricating oil with reduced smoke generation
US7906598B2 (en) * 2006-08-30 2011-03-15 Intertape Polymer Corp. Recirculation loop reactor bulk polymerization process
US20100105847A1 (en) 2006-01-24 2010-04-29 Intertape Polymer Corp. Plug flow bulk polymerization of vinyl monomers
JP2010502786A (ja) * 2006-08-30 2010-01-28 インターテープ ポリマー コーポレーション 再循環ループ反応装置によるバルク重合方法
KR100787851B1 (ko) 2006-12-05 2007-12-27 대림산업 주식회사 폴리부텐 중합체 조성물 및 그 제조방법
US8193402B2 (en) 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
KR20100095004A (ko) 2007-12-03 2010-08-27 게보 인코포레이티드 재생 조성물
US20100298507A1 (en) * 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
EP2521705A4 (en) 2010-01-08 2014-06-18 Gevo Inc INTEGRATED METHODS OF MANUFACTURING RENEWABLE CHEMICALS
WO2011140560A1 (en) 2010-05-07 2011-11-10 Gevo, Inc. Renewable jet fuel blendstock from isobutanol
CA2796574C (en) 2010-05-12 2016-12-06 Basf Se Emulsions of polyisobutenes, substance and process
CN101921352B (zh) * 2010-09-28 2011-10-26 潍坊滨海石油化工有限公司 一种低分子量高活性聚异丁烯的生产方法
EP2699618A4 (en) 2011-04-19 2014-12-17 Gevo Inc VARIATIONS OF A PRINS REACTION FOR THE PREPARATION OF 2,5-DIMETHYLHEXADIENE FROM ISOBUTANOL
CN102807640B (zh) * 2011-06-02 2014-04-02 北京化工大学 一种基于三氟化硼的引发体系及用于制备聚异丁烯的方法
MX360891B (es) * 2011-06-08 2018-11-20 Tpc Group Llc Producción de oligómeros de poliisobutileno de bajo peso molecular altamente reactivos.
US8524843B2 (en) 2011-06-08 2013-09-03 Tpc Group Llc Production of highly reactive low molecular weight PIB oligomers
MX354421B (es) 2011-10-26 2018-03-02 Tpc Group Llc Polimeros de poliisobutileno de alta viscosidad, con contenido de vinilideno de intervalo medio.
KR101929082B1 (ko) 2011-10-26 2018-12-13 티피씨 그룹 엘엘씨 낮은 희석제 함량 반응 매질로 제조된 폴리아이소부틸렌
BR112014009478B1 (pt) 2011-10-26 2021-09-21 Tpc Group Llc Método de preparação de um polímero de poli-isobutileno em um reator loop de recirculação
WO2013068272A1 (en) 2011-11-11 2013-05-16 Basf Se Self-emulsifiable polyolefine compositions
US20130118531A1 (en) 2011-11-11 2013-05-16 The Procter & Gamble Company Emulsions containing polymeric cationic emulsifiers, substance and process
US8759274B2 (en) 2011-11-11 2014-06-24 Basf Se Self-emulsifiable polyolefine compositions
RU2014123613A (ru) 2011-11-11 2015-12-20 Басф Се Эмульсии, содержащие полимерные катионные эмульгаторы, вещества и способ их получения
CA2853248A1 (en) 2011-11-11 2013-05-16 Basf Se Self-emulsifiable polyolefine compositions
US11072570B2 (en) 2012-01-09 2021-07-27 Basf Se Process for continuously preparing polyisobutylene
SG11201403143VA (en) * 2012-01-09 2014-10-30 Basf Se Method for the continuous production of polyisobutylene
KR101523568B1 (ko) 2013-05-16 2015-05-28 대림산업 주식회사 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법
JP2016526091A (ja) 2013-06-05 2016-09-01 テリム インダストリアル カンパニー リミテッド 多様な分子量を有するポリブテンの製造装置および方法
KR101457452B1 (ko) * 2013-06-05 2014-11-03 대림산업 주식회사 다양한 분자량을 가지는 폴리부텐의 제조 장치 및 방법
KR101511707B1 (ko) 2014-02-20 2015-04-13 대림산업 주식회사 분자량 조절이 용이한 폴리부텐의 제조장치 및 방법
WO2015007553A1 (de) * 2013-07-17 2015-01-22 Basf Se Hochreaktives polyisobutylen mit einem hohen gehalt an vinyliden-doppelbindungen in den seitenketten
KR101511701B1 (ko) 2013-07-30 2015-04-13 대림산업 주식회사 폴리부텐 제조 시 사용되는 원료의 재순환 장치 및 방법
US9759830B2 (en) * 2013-10-30 2017-09-12 Schlumberger Technology Corporation Method and apparatus for determining mud contamination of formation fluid
KR101628897B1 (ko) 2014-06-18 2016-06-09 대림산업 주식회사 노르말 프로판올을 포함한 촉매를 이용한 폴리부텐의 제조방법
WO2016138939A1 (en) 2015-03-03 2016-09-09 Basf Se Pib as high viscosity lubricant base stock
US10066035B2 (en) 2015-12-07 2018-09-04 Bridgestone Corporation Catalyst systems and methods for preparation of 1,4-polybutadiene rubber
US9617363B1 (en) * 2016-03-03 2017-04-11 Tpc Group Llc Low-fluoride, reactive polyisobutylene
US9617366B1 (en) * 2016-03-03 2017-04-11 Tpc Group Llc Low-fluoride, reactive polyisobutylene
WO2017151339A1 (en) * 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
HUE062160T2 (hu) 2016-07-06 2023-10-28 Ineos Europe Ag Polimerizációs folyamat
WO2018156514A1 (en) 2017-02-21 2018-08-30 Ntp Tec, Llc Processes for making polyisobutylene compositions
CN111315788B (zh) 2017-10-14 2023-08-15 Tpc集团有限责任公司 异丁烯共聚物、制作异丁烯共聚物的方法及异丁烯共聚物产物
BR112020026773A2 (pt) 2018-06-29 2021-04-06 Ntp Tec, Llc Processos para a fabricação de isobutileno, poli-isobutileno e seus derivados
KR102203006B1 (ko) 2019-04-24 2021-01-13 대림산업 주식회사 고반응성 폴리부텐의 제조 방법
EP3943518A1 (en) 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene
CN116023570A (zh) * 2021-10-27 2023-04-28 中国石油天然气股份有限公司 异丁烯与马来酸酐共聚的方法
KR102701702B1 (ko) * 2022-03-15 2024-08-30 디엘케미칼 주식회사 폴리알파올레핀의 제조 방법과 그에 따라 제조된 폴리알파올레핀, 및 이를 위한 반응 장치
US12116426B1 (en) 2023-05-19 2024-10-15 Ntp Tec, Llc Processes for converting C4 feeds to isobutylene, polyisobutylene, or derivatives thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702604C2 (de) * 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) * 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
DE3509272A1 (de) * 1985-03-15 1986-09-18 Basf Ag, 6700 Ludwigshafen Katalysatorsystem fuer die kationische polymerisation von isobutylen
US4849572A (en) * 1987-12-22 1989-07-18 Exxon Chemical Patents Inc. Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647)
DE4033195A1 (de) * 1990-10-19 1992-04-23 Basf Ag Verfahren zur herstellung von polyisobuten
BE1006694A5 (fr) * 1991-06-22 1994-11-22 Basf Ag Procede de preparation de polyisobutenes extremement reactifs.
DE69127473T2 (de) * 1991-11-18 1998-02-19 Amoco Corp Bf3-tertiäre etheratkomplexe zur isobuthylen-polymerisation

Also Published As

Publication number Publication date
EP0830397A1 (de) 1998-03-25
CZ357197A3 (cs) 1998-05-13
MX9708837A (es) 1998-03-31
HUP9801818A3 (en) 1999-03-01
HUP9801818A2 (hu) 1998-11-30
AU702804B2 (en) 1999-03-04
ES2137701T3 (es) 1999-12-16
WO1996040808A1 (de) 1996-12-19
JP3761578B2 (ja) 2006-03-29
AU6004896A (en) 1996-12-30
KR19990022346A (ko) 1999-03-25
CA2217848A1 (en) 1996-12-19
CA2217848C (en) 2004-11-09
BR9609425A (pt) 1999-05-25
NO975702D0 (no) 1997-12-05
DE59603014D1 (de) 1999-10-14
JPH11506492A (ja) 1999-06-08
KR100424825B1 (ko) 2004-06-23
CN1104448C (zh) 2003-04-02
DE19520078A1 (de) 1996-12-12
US5962604A (en) 1999-10-05
CN1187208A (zh) 1998-07-08
EP0830397B1 (de) 1999-09-08

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