HUP0301859A2 - Eljárás bór-trifluorid dezaktiválására és visszanyerésére poliizobutének gyártásakor - Google Patents
Eljárás bór-trifluorid dezaktiválására és visszanyerésére poliizobutének gyártásakorInfo
- Publication number
- HUP0301859A2 HUP0301859A2 HU0301859A HUP0301859A HUP0301859A2 HU P0301859 A2 HUP0301859 A2 HU P0301859A2 HU 0301859 A HU0301859 A HU 0301859A HU P0301859 A HUP0301859 A HU P0301859A HU P0301859 A2 HUP0301859 A2 HU P0301859A2
- Authority
- HU
- Hungary
- Prior art keywords
- boron trifluoride
- separated
- deactivating
- polyisobutenes
- isobutene
- Prior art date
Links
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 title abstract 12
- 229910015900 BF3 Inorganic materials 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 229920002367 Polyisobutene Polymers 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 4
- 230000001476 alcoholic effect Effects 0.000 abstract 3
- 239000012071 phase Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 230000009849 deactivation Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/06—Treatment of polymer solutions
- C08F6/08—Removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A találmány tárgya eljárás bór-trifluorid dezaktiválására ésvisszanyerésére a poliizobutének olyan gyártásakor, amikor izobuténtvagy izobutén-tartalmú szénhidrogénáramokat folyékony fázisban, bór-trifluorid vagy bór-trifluorid-katalizátorkomplex jelenlétébenkationosan polimerizálnak, és amikor a katalizátorkomplexet lényegébenfolyékony fázis formájában a reaktorból kilépő reakcióelegytőlelválasztják, hogy a) a polimerizációs reaktorból kilépőreakcióelegyhez -60 °C és 0°Cközötti hőmérsékleten metanolt, etanoltvagy metanol és etanol elegyét olyan mennyiségben adagolják, hogy egybór-trifluoridban gazdag alkoholos fázis különüljön el, és b) az a)pont szerinti alkoholos fázist elválasztják, és c) a b) pont szerintialkoholos fázisban található bór-trifluoridot adott esetben megfelelőmódon az eljárásba visszavezetik. Ó
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10057318 | 2000-11-17 | ||
DE10127818 | 2001-06-07 | ||
PCT/EP2001/013269 WO2002040553A1 (de) | 2000-11-17 | 2001-11-16 | Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0301859A2 true HUP0301859A2 (hu) | 2003-08-28 |
HUP0301859A3 HUP0301859A3 (en) | 2005-03-29 |
Family
ID=26007708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0301859A HUP0301859A3 (en) | 2000-11-17 | 2001-11-16 | Method for deactivating and recovering boron trifluoride when producing polyisobutenes |
Country Status (14)
Country | Link |
---|---|
US (1) | US6939943B2 (hu) |
EP (1) | EP1337564B1 (hu) |
JP (1) | JP4106265B2 (hu) |
KR (1) | KR100787076B1 (hu) |
CN (1) | CN1204152C (hu) |
AT (1) | ATE300560T1 (hu) |
AU (1) | AU2002221856A1 (hu) |
CA (1) | CA2426077A1 (hu) |
DE (1) | DE50106917D1 (hu) |
HU (1) | HUP0301859A3 (hu) |
MX (1) | MXPA03003377A (hu) |
MY (1) | MY127194A (hu) |
TW (1) | TW574240B (hu) |
WO (1) | WO2002040553A1 (hu) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030196411A1 (en) | 2002-04-19 | 2003-10-23 | Schroeder Alfred A. | Flexible packaging |
DE10303212A1 (de) | 2003-01-24 | 2004-08-05 | Basf Ag | Verfahren zur Herstellung von Polyisobuten |
ES2313291T3 (es) * | 2004-02-16 | 2009-03-01 | Juan Ramon Goma Ayats | Transmision continuamente variable. |
WO2005105860A1 (ja) * | 2004-04-27 | 2005-11-10 | Kaneka Corporation | イソブチレン系ブロック共重合体の製造方法 |
US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
KR102008548B1 (ko) * | 2012-01-09 | 2019-08-07 | 바스프 에스이 | 폴리아이소부틸렌의 연속 제조 방법 |
US11072570B2 (en) | 2012-01-09 | 2021-07-27 | Basf Se | Process for continuously preparing polyisobutylene |
US9156924B2 (en) | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
KR101511701B1 (ko) * | 2013-07-30 | 2015-04-13 | 대림산업 주식회사 | 폴리부텐 제조 시 사용되는 원료의 재순환 장치 및 방법 |
KR101511708B1 (ko) * | 2013-08-28 | 2015-04-13 | 대림산업 주식회사 | 폴리부텐 제조 시 발생되는 할로겐의 제거 장치 및 방법 |
US9631038B2 (en) | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US9771442B2 (en) | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10167352B1 (en) | 2017-06-28 | 2019-01-01 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10047174B1 (en) | 2017-06-28 | 2018-08-14 | Infineum International Limited | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10174138B1 (en) | 2018-01-25 | 2019-01-08 | University Of Massachusetts | Method for forming highly reactive olefin functional polymers |
CN111321002A (zh) | 2018-12-14 | 2020-06-23 | 中国石油天然气股份有限公司 | 一种低粘度聚α-烯烃润滑油及其合成方法 |
US10829573B1 (en) | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
CN113522191B (zh) | 2020-04-20 | 2022-11-15 | 中国石油化工股份有限公司 | 制备聚α-烯烃的装置和方法 |
CN114605441B (zh) * | 2020-12-04 | 2024-04-30 | 中国石油天然气股份有限公司 | 一种烯烃聚合反应中三氟化硼及其络合物的分离回收方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2702604C2 (de) | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
GB8329082D0 (en) | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
US4849572A (en) | 1987-12-22 | 1989-07-18 | Exxon Chemical Patents Inc. | Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647) |
DE4033195A1 (de) | 1990-10-19 | 1992-04-23 | Basf Ag | Verfahren zur herstellung von polyisobuten |
US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
EP0646103B1 (en) | 1991-11-18 | 1997-08-27 | Amoco Corporation | Bf3-tertiary etherate complexes for isobutylene polymerization |
US6075174A (en) | 1995-05-08 | 2000-06-13 | Bp Amoco Corporation | BF3 removal from BF3 catalyzed olefin oligomer |
DE19520078A1 (de) | 1995-06-07 | 1996-12-12 | Basf Ag | Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten |
CN1217726A (zh) | 1997-02-26 | 1999-05-26 | 日本石油化学株式会社 | 三氟化硼配合物的回收方法及利用该方法进行的烯烃低聚物的制造方法 |
GB9707075D0 (en) * | 1997-04-08 | 1997-05-28 | Bp Chem Int Ltd | Polymerisation process |
US6407186B1 (en) * | 1997-12-12 | 2002-06-18 | Basf Aktiengesellschaft | Method for producing low-molecular, highly reactive polyisobutylene |
-
2001
- 2001-11-16 AU AU2002221856A patent/AU2002221856A1/en not_active Abandoned
- 2001-11-16 DE DE50106917T patent/DE50106917D1/de not_active Expired - Lifetime
- 2001-11-16 CN CNB018190707A patent/CN1204152C/zh not_active Expired - Fee Related
- 2001-11-16 JP JP2002543560A patent/JP4106265B2/ja not_active Expired - Fee Related
- 2001-11-16 WO PCT/EP2001/013269 patent/WO2002040553A1/de active IP Right Grant
- 2001-11-16 MX MXPA03003377A patent/MXPA03003377A/es not_active Application Discontinuation
- 2001-11-16 MY MYPI20015269A patent/MY127194A/en unknown
- 2001-11-16 CA CA002426077A patent/CA2426077A1/en not_active Abandoned
- 2001-11-16 AT AT01996562T patent/ATE300560T1/de not_active IP Right Cessation
- 2001-11-16 KR KR1020037006680A patent/KR100787076B1/ko not_active IP Right Cessation
- 2001-11-16 EP EP01996562A patent/EP1337564B1/de not_active Expired - Lifetime
- 2001-11-16 HU HU0301859A patent/HUP0301859A3/hu unknown
- 2001-11-16 US US10/432,045 patent/US6939943B2/en not_active Expired - Lifetime
- 2001-11-19 TW TW090128619A patent/TW574240B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1204152C (zh) | 2005-06-01 |
MXPA03003377A (es) | 2004-12-13 |
EP1337564A1 (de) | 2003-08-27 |
DE50106917D1 (de) | 2005-09-01 |
CA2426077A1 (en) | 2003-04-15 |
EP1337564B1 (de) | 2005-07-27 |
US20040030076A1 (en) | 2004-02-12 |
HUP0301859A3 (en) | 2005-03-29 |
MY127194A (en) | 2006-11-30 |
WO2002040553A1 (de) | 2002-05-23 |
KR100787076B1 (ko) | 2007-12-21 |
KR20030051840A (ko) | 2003-06-25 |
CN1474834A (zh) | 2004-02-11 |
JP2004514032A (ja) | 2004-05-13 |
TW574240B (en) | 2004-02-01 |
ATE300560T1 (de) | 2005-08-15 |
AU2002221856A1 (en) | 2002-05-27 |
US6939943B2 (en) | 2005-09-06 |
JP4106265B2 (ja) | 2008-06-25 |
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