ES2120868A1 - Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. - Google Patents

Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.

Info

Publication number
ES2120868A1
ES2120868A1 ES09501586A ES9501586A ES2120868A1 ES 2120868 A1 ES2120868 A1 ES 2120868A1 ES 09501586 A ES09501586 A ES 09501586A ES 9501586 A ES9501586 A ES 9501586A ES 2120868 A1 ES2120868 A1 ES 2120868A1
Authority
ES
Spain
Prior art keywords
solids
heterogenous
polymerization process
olefin polymerization
metallocene catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES09501586A
Other languages
English (en)
Other versions
ES2120868B1 (es
Inventor
Wilfried Michel Vega
Canas Pilar Lafuente
Lafuente Antoni Munoz-Escalona
Llinas Gerardo Hidalgo
Royo Jose Sancho
Llatas Luis Mendez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol Quimica SA
Original Assignee
Repsol Quimica SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol Quimica SA filed Critical Repsol Quimica SA
Priority to ES009501586A priority Critical patent/ES2120868B1/es
Priority to DE69631723T priority patent/DE69631723T2/de
Priority to EP96500114A priority patent/EP0757992B1/en
Priority to US08/958,880 priority patent/US5824620A/en
Priority to US09/174,997 priority patent/US6133187A/en
Publication of ES2120868A1 publication Critical patent/ES2120868A1/es
Application granted granted Critical
Publication of ES2120868B1 publication Critical patent/ES2120868B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Sistemas de catalizadores heterogéneos tipo metaloceno para procesos de obtención de poliolefinas. Esta invención se refiere a un método de obtención de catalizadores heterogéneos a insolubles en el medio de reacción para la obtención de poliolefinas. El procedimiento está caracterizado por la preparación de los sistemas catalíticos mediante soporte de catalizadores solubles del tipo metaloceno, conteniendo uno a más grupos funcionales capaces de reaccionar con los grupos reactivos, ya existentes a incorporados por modificación química previa, de soportes inorgánicos. Estos sistemas de catalizadores son especialmente apropiados para la polimerización de uno o varios 1-alquenos con 2 a 20 átomos de carbono, así como para la copolimerización de etileno con 1-alquenos con 3 a 20 átomos de carbono, en plantas de producción de poliolefinas que emplean los catalizadores en suspensión en un disolvente o en fase gaseosa así como para la polimerización en masa a altas temperaturas y presiones.
ES009501586A 1995-08-03 1995-08-03 Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas. Expired - Fee Related ES2120868B1 (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES009501586A ES2120868B1 (es) 1995-08-03 1995-08-03 Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
DE69631723T DE69631723T2 (de) 1995-08-03 1996-08-02 Heterogene Metallocenkatalysatoren und ihre Verwendung zur Polymerisation von Olefinen
EP96500114A EP0757992B1 (en) 1995-08-03 1996-08-02 Heterogenous metallocene catalysts and use thereof in olefin polymerization process
US08/958,880 US5824620A (en) 1995-08-03 1997-10-27 Heterogeneous metallocene catalysts and use thereof in olefin polymerization process
US09/174,997 US6133187A (en) 1995-08-03 1998-10-19 Hetergeneous metallocene catalysts and use thereof in olefin polymerization process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009501586A ES2120868B1 (es) 1995-08-03 1995-08-03 Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.

Publications (2)

Publication Number Publication Date
ES2120868A1 true ES2120868A1 (es) 1998-11-01
ES2120868B1 ES2120868B1 (es) 2000-09-16

Family

ID=8291290

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009501586A Expired - Fee Related ES2120868B1 (es) 1995-08-03 1995-08-03 Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.

Country Status (4)

Country Link
US (2) US5824620A (es)
EP (1) EP0757992B1 (es)
DE (1) DE69631723T2 (es)
ES (1) ES2120868B1 (es)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2129323A1 (es) * 1996-04-18 1999-06-01 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de x -olefinas en suspension en fase gas a bajas y altas temeraturas o en masa a altas presiones y altas o bajas temperaturas.
ES2166223A1 (es) * 1996-08-02 2002-04-01 Repsol Quimica Sa "sistemas de catalizadores heterogeneos tipo metaloceno, para procesos de obtencion de poliolefinas".

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US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
DE19622481A1 (de) 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR100205738B1 (ko) * 1996-07-26 1999-07-01 이정국 담지체 계류 담지 촉매 및 그 제조 방법
ATE189822T1 (de) * 1996-10-30 2000-03-15 Repsol Quimica Sa Organometallische katalysatoren für die polymerisation und die copolymerisation von alpha-olefinen
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
PT839836E (pt) 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
ATE236914T1 (de) * 1997-02-01 2003-04-15 Repsol Quimica Sa Metallocene, deren herstellung und verwendung
AU743551B2 (en) * 1997-06-05 2002-01-31 Exxonmobil Chemical Patents Inc Polymeric supported catalysts for olefin polymerization
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) * 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
US7148173B2 (en) 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
DE69904982T2 (de) * 1998-04-29 2004-01-08 Repsol Quimica S.A. Funktionalisierte Metallocene, deren Herstellung und deren Verwendung
BR9913221B1 (pt) * 1998-08-26 2008-11-18 composiÇço catalisadora suportada de metaloceno.
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
US6194343B1 (en) 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6040261A (en) 1999-04-15 2000-03-21 Equistar Chemicals, Lp Supported single-site catalyst and olefin polymerization process
TW548283B (en) * 2000-01-11 2003-08-21 Dow Chemical Co Chemically-modified supports and supported catalyst systems prepared therefrom
US6541410B1 (en) * 2000-06-23 2003-04-01 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization
GB0021301D0 (en) * 2000-08-30 2000-10-18 Borealis Tech Oy Supported catalyst
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
US6632770B2 (en) * 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
ATE264335T1 (de) 2001-01-18 2004-04-15 Repsol Quimica Sa Olefinpolymerisationskatalysatoren
FR2824066B1 (fr) * 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention
JP3961910B2 (ja) * 2002-07-12 2007-08-22 丸善石油化学株式会社 オレフィン重合用触媒及びそれを用いたオレフィンの重合方法
US6908876B2 (en) 2003-04-16 2005-06-21 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization, method for making and using the same
DE102004039877A1 (de) * 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법

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Publication number Priority date Publication date Assignee Title
ES2129323A1 (es) * 1996-04-18 1999-06-01 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de x -olefinas en suspension en fase gas a bajas y altas temeraturas o en masa a altas presiones y altas o bajas temperaturas.
ES2166223A1 (es) * 1996-08-02 2002-04-01 Repsol Quimica Sa "sistemas de catalizadores heterogeneos tipo metaloceno, para procesos de obtencion de poliolefinas".

Also Published As

Publication number Publication date
US6133187A (en) 2000-10-17
DE69631723T2 (de) 2005-03-24
ES2120868B1 (es) 2000-09-16
EP0757992B1 (en) 2004-03-03
US5824620A (en) 1998-10-20
DE69631723D1 (de) 2004-04-08
EP0757992A1 (en) 1997-02-12

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