BR9913221B1 - composiÇço catalisadora suportada de metaloceno. - Google Patents
composiÇço catalisadora suportada de metaloceno.Info
- Publication number
- BR9913221B1 BR9913221B1 BRPI9913221-4A BR9913221A BR9913221B1 BR 9913221 B1 BR9913221 B1 BR 9913221B1 BR 9913221 A BR9913221 A BR 9913221A BR 9913221 B1 BR9913221 B1 BR 9913221B1
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst composition
- metallocene catalyst
- supported metallocene
- supported
- composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9800798P | 1998-08-26 | 1998-08-26 | |
| PCT/US1999/014577 WO2000012565A1 (en) | 1998-08-26 | 1999-06-24 | Highly active supported catalyst compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR9913221A BR9913221A (pt) | 2001-05-22 |
| BR9913221B1 true BR9913221B1 (pt) | 2008-11-18 |
Family
ID=22266211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI9913221-4A BR9913221B1 (pt) | 1998-08-26 | 1999-06-24 | composiÇço catalisadora suportada de metaloceno. |
Country Status (11)
| Country | Link |
|---|---|
| US (5) | US6368999B1 (pt) |
| EP (1) | EP1109839B1 (pt) |
| JP (1) | JP2002523568A (pt) |
| KR (1) | KR100592621B1 (pt) |
| CN (1) | CN1142190C (pt) |
| BR (1) | BR9913221B1 (pt) |
| CA (1) | CA2338603C (pt) |
| DE (1) | DE69908147T2 (pt) |
| ES (1) | ES2197649T3 (pt) |
| HK (1) | HK1039134A1 (pt) |
| WO (1) | WO2000012565A1 (pt) |
Families Citing this family (103)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6613712B1 (en) * | 1999-11-24 | 2003-09-02 | Phillips Petroleum Company | Organometal catalyst compositions with solid oxide supports treated with fluorine and boron |
| US6548442B1 (en) * | 1999-12-03 | 2003-04-15 | Phillips Petroleum Company | Organometal compound catalyst |
| US6576583B1 (en) * | 2000-02-11 | 2003-06-10 | Phillips Petroleum Company | Organometal catalyst composition |
| US7098277B2 (en) * | 2000-08-22 | 2006-08-29 | Exxonmobil Chemical Patents Inc. | Polypropylene films |
| WO2002016480A2 (en) * | 2000-08-22 | 2002-02-28 | Exxonmobil Chemical Patents Inc. | Polypropylene films |
| US6914027B2 (en) * | 2000-12-01 | 2005-07-05 | Univation Technologies, Llc | Polymerization reactor operability using static charge modifier agents |
| KR100422940B1 (ko) * | 2000-12-23 | 2004-03-12 | 주식회사 엘지화학 | 하프 메탈로센 촉매 및 이를 이용한 입체규칙성을 가진비닐 방향족 중합체의 제조방법 |
| CA2357385C (en) * | 2001-09-17 | 2010-06-15 | Nova Chemicals Corporation | Supported phosphinimine polymerization catalyst |
| US7192901B2 (en) * | 2004-10-27 | 2007-03-20 | Exxonmobil Chemical Patents Inc. | Method of preparing a treated support |
| US7381778B2 (en) | 2002-06-06 | 2008-06-03 | Exxonmobil Chemical Patents Inc. | Method of preparing a treated support |
| EP1509553A1 (en) * | 2002-06-06 | 2005-03-02 | ExxonMobil Chemical Patents Inc. | Catalyst system and olefin polymerisation process |
| US7223823B2 (en) * | 2002-06-06 | 2007-05-29 | Exxon Mobil Chemical Patents Inc. | Catalyst system and process |
| US6884748B2 (en) * | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
| US7232868B2 (en) * | 2002-10-09 | 2007-06-19 | Exxon/Mobil Chemical Patents Inc. | Methods of delivering catalyst systems for propylene polymerization |
| AU2003278856A1 (en) * | 2002-10-09 | 2004-05-04 | Exxonmobil Chemical Patents Inc. | Methods of feed purification for olefin polymerization |
| US7235614B2 (en) * | 2002-10-09 | 2007-06-26 | Exxonmobil Chemical Patents Inc. | Methods for injecting catalyst into a polymerization reactor |
| KR100497172B1 (ko) * | 2002-11-11 | 2005-06-28 | 주식회사 엘지화학 | 양쪽 메탈로센 유도체 화합물을 리간드로 가진 다중핵반쪽 메탈로센 촉매 및 이를 이용한 스티렌 중합체의제조방법 |
| US6900154B2 (en) * | 2002-11-26 | 2005-05-31 | Univation Technologies, Llc | Methods of forming a supported activated catalyst composition |
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| US6992034B2 (en) * | 2003-07-10 | 2006-01-31 | Formosa Plastics Corporation, U.S.A. | Catalyst component for olefin polymerization |
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| US7456021B2 (en) * | 2004-01-16 | 2008-11-25 | Exxonmobil Chemical Patents Inc. | Analysis method |
| JP4988568B2 (ja) * | 2004-07-08 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合触媒系およびその使用方法 |
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| FR2879479B1 (fr) * | 2004-12-17 | 2007-11-09 | Armines Ass Loi De 1901 | Structures composites en etat amorphe pour la photocatalyse |
| KR101075404B1 (ko) * | 2004-12-17 | 2011-10-24 | 양지 페트로케미컬 컴퍼니 코., 리미티드. | 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도 |
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| ES2805782T3 (es) * | 2012-04-27 | 2021-02-15 | Grace W R & Co | Composiciones de activador, su preparación y su uso en catalizadores |
| EP3183059A1 (en) * | 2014-08-19 | 2017-06-28 | Univation Technologies, LLC | Fluorinated catalyst supports and catalyst systems |
| CA2957809C (en) * | 2014-08-19 | 2023-01-03 | Univation Technologies, Llc | Fluorinated catalyst supports and catalyst systems |
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| EP3519450B1 (en) | 2016-09-30 | 2021-10-20 | Univation Technologies, LLC | Biomodal polymerization catalysts |
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| US10676551B2 (en) | 2017-03-01 | 2020-06-09 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| US10844150B2 (en) | 2017-08-04 | 2020-11-24 | Exxonmobil Chemical Patents Inc. | Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes |
| EP3697822A1 (en) | 2017-08-04 | 2020-08-26 | ExxonMobil Chemical Patents Inc. | Mixed catalysts with unbridged hafnocenes with -ch2-sime3 moieties |
| US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
| CN115850552A (zh) | 2017-12-01 | 2023-03-28 | 埃克森美孚化学专利公司 | 催化剂体系和使用其的聚合方法 |
| US10926250B2 (en) | 2017-12-01 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
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-
1999
- 1999-06-24 KR KR1020017002474A patent/KR100592621B1/ko not_active IP Right Cessation
- 1999-06-24 US US09/339,128 patent/US6368999B1/en not_active Expired - Fee Related
- 1999-06-24 CA CA002338603A patent/CA2338603C/en not_active Expired - Fee Related
- 1999-06-24 CN CNB99810146XA patent/CN1142190C/zh not_active Expired - Fee Related
- 1999-06-24 EP EP99930785A patent/EP1109839B1/en not_active Expired - Lifetime
- 1999-06-24 BR BRPI9913221-4A patent/BR9913221B1/pt not_active IP Right Cessation
- 1999-06-24 DE DE69908147T patent/DE69908147T2/de not_active Expired - Fee Related
- 1999-06-24 ES ES99930785T patent/ES2197649T3/es not_active Expired - Lifetime
- 1999-06-24 JP JP2000567578A patent/JP2002523568A/ja active Pending
- 1999-06-24 WO PCT/US1999/014577 patent/WO2000012565A1/en active IP Right Grant
-
2001
- 2001-06-20 US US09/885,809 patent/US6524988B2/en not_active Expired - Fee Related
-
2002
- 2002-01-25 HK HK02100586.8A patent/HK1039134A1/zh unknown
- 2002-02-11 US US10/073,839 patent/US6846770B2/en not_active Expired - Fee Related
- 2002-02-11 US US10/073,840 patent/US6664348B2/en not_active Expired - Fee Related
- 2002-03-26 US US10/106,411 patent/US6667272B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| HK1039134A1 (zh) | 2002-04-12 |
| KR20010079694A (ko) | 2001-08-22 |
| CN1314918A (zh) | 2001-09-26 |
| EP1109839A1 (en) | 2001-06-27 |
| US6368999B1 (en) | 2002-04-09 |
| ES2197649T3 (es) | 2004-01-01 |
| DE69908147D1 (de) | 2003-06-26 |
| US20020123582A1 (en) | 2002-09-05 |
| US6846770B2 (en) | 2005-01-25 |
| US6524988B2 (en) | 2003-02-25 |
| US20010051698A1 (en) | 2001-12-13 |
| KR100592621B1 (ko) | 2006-06-23 |
| JP2002523568A (ja) | 2002-07-30 |
| CA2338603A1 (en) | 2000-03-09 |
| US6667272B2 (en) | 2003-12-23 |
| WO2000012565A1 (en) | 2000-03-09 |
| DE69908147T2 (de) | 2004-02-19 |
| US6664348B2 (en) | 2003-12-16 |
| CN1142190C (zh) | 2004-03-17 |
| US20020169261A1 (en) | 2002-11-14 |
| CA2338603C (en) | 2008-11-18 |
| US20020160914A1 (en) | 2002-10-31 |
| BR9913221A (pt) | 2001-05-22 |
| EP1109839B1 (en) | 2003-05-21 |
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