KR900007877A - 과량의 촉매잔류물을 분해하는 바나듐-함유 지글러 촉매시스템을 사용한 에틸렌 중합체의 제법, 및 상기 방법으로 제조된 에틸렌 중합체 - Google Patents

과량의 촉매잔류물을 분해하는 바나듐-함유 지글러 촉매시스템을 사용한 에틸렌 중합체의 제법, 및 상기 방법으로 제조된 에틸렌 중합체 Download PDF

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Publication number
KR900007877A
KR900007877A KR1019890016398A KR890016398A KR900007877A KR 900007877 A KR900007877 A KR 900007877A KR 1019890016398 A KR1019890016398 A KR 1019890016398A KR 890016398 A KR890016398 A KR 890016398A KR 900007877 A KR900007877 A KR 900007877A
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South Korea
Prior art keywords
ethylene polymer
vanadium
zone
preparation
catalyst residue
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KR1019890016398A
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KR0152516B1 (ko
Inventor
자이베 롤란트
풍크 구이도
바우어 페터
콘라트 라인너
Original Assignee
하우프터, 라이싱어
바스프 악티엔게젤샤프트
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/006Removal of residual monomers by chemical reaction, e.g. scavenging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene

Abstract

내용 없음

Description

과량의 촉매잔류물을 분해하는 바나듐-함유 지글러 촉매시스템을 사용한 에틸렌 중합체의 제법, 및 상기 방법으로 제조된 에틸렌 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명을 수행하기 위해 사용하는 루우프반응기를 도시한 도면으로서, 번호 1내지 3은 출발물질의 미터링포인트, 번호 4내지 6은 중합체의 배출포인트.

Claims (1)

  1. 5 내지 60bar, 120℃이하의 중합반응대역에서, 단량체를 바나듐-함유 지글러촉매시스템 존재하의 교반 또는 유동건조상 또는 현탁화제인 낮은 비점의 탄화수소중에서 중합하고, 강하대역에서 압력을 감소시킨 후 생성된 고형 에틸렌 중합체를 미전환 단량체로부터 분리하며, 탈휘발성화 대역에서 잔류량의 단량체를 분활성기류중에 통과시킴으로써 제거하고 고형 에틸렌 중합체를 용융대역으로 이동시킴(여기서 중합체는 처음으로 공기와 접촉하게됨)으로써 에틸렌 중합체를 제조하는 방법으로서, 에틸렌 중합체를 탈휘발성화 대역에서 OH- 함유 첨가제와 반응시킴을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890016398A 1988-11-12 1989-11-13 과량의 촉매 잔류물을 분해하는 바나듐 함유 지글러 촉매 시스템을 사용하여 에틸렌 중합체를 제조하는 방법 KR0152516B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3838492A DE3838492A1 (de) 1988-11-12 1988-11-12 Verfahren zur herstellung von ethylenpolymerisaten mittels eines vanadin enthaltenden ziegler-katalysatorsystems unter zerstoerung ueberschuessiger katalysatorreste und so hergestellte ethylenpolymerisate
DEP3838492.2 1988-11-12

Publications (2)

Publication Number Publication Date
KR900007877A true KR900007877A (ko) 1990-06-02
KR0152516B1 KR0152516B1 (ko) 1998-10-15

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ID=6367104

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KR1019890016398A KR0152516B1 (ko) 1988-11-12 1989-11-13 과량의 촉매 잔류물을 분해하는 바나듐 함유 지글러 촉매 시스템을 사용하여 에틸렌 중합체를 제조하는 방법

Country Status (6)

Country Link
EP (1) EP0372239B1 (ko)
JP (1) JP2918580B2 (ko)
KR (1) KR0152516B1 (ko)
AT (1) ATE89834T1 (ko)
DE (2) DE3838492A1 (ko)
ES (1) ES2042939T3 (ko)

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CN109803986B (zh) 2016-09-28 2020-04-14 博里利斯股份公司 用于制备涂覆管道的方法
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ES2786567T3 (es) 2017-06-23 2020-10-13 Borealis Ag Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido
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KR102498543B1 (ko) 2018-06-14 2023-02-09 보레알리스 아게 개선된 열 균질성을 갖는 기체상 반응기에서 올레핀의 중합 방법
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Also Published As

Publication number Publication date
ATE89834T1 (de) 1993-06-15
EP0372239A3 (de) 1991-09-25
EP0372239B1 (de) 1993-05-26
ES2042939T3 (es) 1993-12-16
EP0372239A2 (de) 1990-06-13
JPH02173005A (ja) 1990-07-04
JP2918580B2 (ja) 1999-07-12
DE3838492A1 (de) 1990-05-17
KR0152516B1 (ko) 1998-10-15
DE58904498D1 (de) 1993-07-01

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