EP3371564A1 - Sensoranordnung und verfahren zur herstellung einer sensoranordnung - Google Patents
Sensoranordnung und verfahren zur herstellung einer sensoranordnungInfo
- Publication number
- EP3371564A1 EP3371564A1 EP16782249.3A EP16782249A EP3371564A1 EP 3371564 A1 EP3371564 A1 EP 3371564A1 EP 16782249 A EP16782249 A EP 16782249A EP 3371564 A1 EP3371564 A1 EP 3371564A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sensor
- contacting
- contacting element
- sensor arrangement
- sensor element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K7/00—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
- G01K7/16—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements
- G01K7/22—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements the element being a non-linear resistance, e.g. thermistor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
- B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K7/00—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
- G01K7/16—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K7/00—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements
- G01K7/16—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements
- G01K7/18—Measuring temperature based on the use of electric or magnetic elements directly sensitive to heat ; Power supply therefor, e.g. using thermoelectric elements using resistive elements the element being a linear resistance, e.g. platinum resistance thermometer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
- H01C17/06—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
- H01C17/075—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin-film techniques
- H01C17/08—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin-film techniques by vapour deposition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
- H01C17/06—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
- H01C17/075—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin-film techniques
- H01C17/12—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin-film techniques by sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
- H01C17/28—Apparatus or processes specially adapted for manufacturing resistors adapted for applying terminals
- H01C17/281—Apparatus or processes specially adapted for manufacturing resistors adapted for applying terminals by thick film techniques
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
- H01C17/28—Apparatus or processes specially adapted for manufacturing resistors adapted for applying terminals
- H01C17/281—Apparatus or processes specially adapted for manufacturing resistors adapted for applying terminals by thick film techniques
- H01C17/283—Precursor compositions therefor, e.g. pastes, inks, glass frits
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/008—Thermistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/04—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient
- H01C7/042—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient mainly consisting of inorganic non-metallic substances
- H01C7/043—Oxides or oxidic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
- H01C17/06—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
- H01C17/075—Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin-film techniques
Definitions
- a sensor arrangement is specified.
- the sensor arrangement can be used in particular for measuring a temperature. Furthermore, a method for producing a sensor arrangement is described.
- thermocouples Monitoring and control in a wide range of applications predominantly with ceramic thermistor thermistor elements (NTC), silicon temperature sensors (KTY), platinum temperature sensors (PRTD) or thermocouples (TC).
- NTC ceramic thermistor thermistor elements
- KTY silicon temperature sensors
- PRTD platinum temperature sensors
- TC thermocouples
- the NTC thermistors are the most widespread due to the low production costs.
- thermocouples and metallic resistive elements e.g. Pt elements, consists in the pronounced negative resistance temperature characteristic.
- NTC ceramic metallic electrodes For electrical contacting of the NTC ceramic metallic electrodes must be applied. According to the state of the art, thick-film electrodes predominantly of silver or gold pastes are applied by way of a screen printing process with subsequent penetration.
- the silver metallizations are particularly suitable for
- Terminal contacts such as bonding and welding
- Copper wires require another electrode, as a Connection to silver does not have sufficient reliability.
- NTC temperature sensors used, which are soldered.
- NTC chips are alternatively used, which are mounted on the underside by means of Ag sintering paste, soldering or gluing and whose
- Top is contacted via a bonding wire.
- NTC temperature sensors which can be applied to the board / DCB board without solder mounting and which have a high long-term stability and higher
- An object to be solved is to provide a sensor arrangement which has improved properties.
- the sensor arrangement has a Sensor element on.
- the sensor element preferably has a ceramic sensor material.
- the sensor element is
- the sensor element has at least one electrode. Preferably, this has
- the electrodes may also be arranged on one side, for example the top side.
- the sensor arrangement further comprises at least one
- the contacting element has an electrically conductive material.
- the sensor arrangement can have exactly one contacting element.
- Sensor arrangement may also have more than one contacting element, for example two contacting elements.
- the contacting element is designed and arranged for wireless contacting of the sensor element.
- the contacting element has an external structure, which makes it possible to contact the sensor element wirelessly. Furthermore, that is
- Sensor element and contacting element is chosen so that a wireless contact is made possible. Furthermore, the contacting element is designed and arranged to increase a stability of the sensor element or of the sensor arrangement. Preferably, the contacting of the
- the Sensor element in a process step with the mounting of the sensor assembly on a circuit board.
- the Kunststofftechniks ⁇ element on Aufliegeflachen has at least one first support surface and at least one second support surface. At least one of the
- the first resting surface rests on a part of the outer surface. This is what the
- Pressure loads for example in the context of Ag sintering, can be compensated by the contacting element.
- This provides a particularly stable sensor arrangement.
- the other is the
- the second bearing surface of the contacting element rests on or is fastened to the printed circuit board.
- a wireless contacting of the sensor element is achieved.
- the support surfaces each have a horizontally extending region.
- the horizontally extending region of the support surfaces forms an upper side and / or a lower side of the
- the top of the contacting element can be two defined horizontal
- the underside of the contacting element may have two defined horizontal areas, which serve as resting surfaces.
- the top have at least one defined horizontal area and the bottom can at least one defined
- the bearing surfaces are preferably connected to one another by a vertically extending region of the contacting element.
- the contacting element is step-shaped.
- the contacting element may have a metal strap.
- the metal bracket is preferably formed in a stepped shape, so that with the aid of the metal bracket, a connection of sensor element and circuit board can take place.
- the contacting element may be wave-shaped. In other words, that
- the metal bracket is preferably formed in a wave shape, so that with the help of the metal bracket, a compound of
- the contacting element is designed such that it can rest on both a surface or outer surface of the sensor element as well as on a further surface, for example the surface of a circuit board.
- the selected design allows the processing of the
- the pressure sintering of the component is thereby made possible without any damage such as micro-cracks or the like to induce or even cause a fracture of the component.
- Temperature sensor should be mounted in one process step together with the other components. In case of
- the component undergoes a pressure load of up to 30 MPa or higher at temperatures of up to 300 ° C.
- the sensor element has an upper side.
- the contacting element is at least partially connected to the top.
- Contacting element is sintered, for example, on the top.
- the contacting element is sintered without pressure with an Ag paste on the top.
- the contacting element but also by means of a soldering process or by gluing on the
- the sensor arrangement has a further contacting element.
- Contacting element is designed to another Make connection between the sensor element and the circuit board.
- Another advantage is the ability to press the sensor element over the two surfaces of the contacting during Ag sintering, soldering or gluing so without having to be pressed on the NTC chip itself.
- the sensor element has a bottom side.
- the further contacting element is at least partially on the
- the underside of the sensor element - after its mounting on a printed circuit board - which faces the circuit board
- the contacting element is
- the contacting element is pressure-less sintered with an Ag paste on the underside.
- the contacting element is pressure-less sintered with an Ag paste on the underside.
- a method of making a sensor assembly is described.
- the method preferably produces the sensor arrangement described above. All the properties disclosed with respect to the sensor element, the contacting element, the sensor arrangement or the method are also correspondingly with reference to FIGS other respective aspects and vice versa, even if the respective property is not explicitly mentioned in the context of the respective aspect.
- the method comprises the following steps.
- the ceramic base body has a perovskite structure.
- the ceramic can be based on the system Y-Ca-Cr-Al-0 with various dopants.
- the ceramic may have a spinel structure.
- the ceramic on the Ni-Co-Mn-0 system may be based on various dopants.
- the contacting element is sintered on a portion of the outer surface.
- low-cost electrode system which allows a wireless contact of the NTC temperature sensor.
- the contacting of the temperature sensor can be carried out during assembly together with other components in one process step.
- Temperature measurement indicated comprising at least one
- Electrode wherein the sensor element has an upper side, and wherein a contacting element at the top
- the contacting element is formed in the form of a bracket.
- FIG. 1 shows a sensor arrangement
- FIG. 2 shows the sensor arrangement according to FIG. 1 in one
- FIG. 3 shows the sensor arrangement according to FIG. 2 according to a further exemplary embodiment
- Figure 4 shows a mounted on a DCB board
- FIG. 1 shows a sensor arrangement 10.
- FIG. 2 shows the sensor arrangement 10 in a side view.
- the sensor arrangement 10 has a sensor element 1.
- the sensor element 1 (sensor 1) from a chip NTC thermistor.
- the chip NTC thermistor is based on perovskites in the system Y-Ca-Cr-Al-0 with various dopings or based on spinels in the system Ni-Co-Mn-0 with various dopants produced.
- the sensor element 1 in particular has a ceramic base body 7.
- the ceramic base body 7 is manufactured on the basis of the above-mentioned structures.
- the sensor element 1 may have a further ceramic reinforcement or a carrier (not explicitly shown).
- the chip NTC thermistor 1 can either be produced directly by pressing granules or be built up from ceramic films.
- On the top and bottom 5, 6 of the sensor 1 are by screen printing or thin-film technology, such as
- the base electrode consists of a layer (eg a nickel layer, which may contain vanadium, or a copper layer) or, in a second embodiment, two layers (eg Cr / Ni, Ti / Ni or Ni / Cu) may also have levels of vanadium.
- the base electrode can be protected by a cover layer consisting of an oxidation-inhibiting metal. In the case of a connection by means of Ag sintering with finely dispersed silver pastes, a silver cover electrode is advantageous.
- the thickness of the base electrode is less than 10 ⁇ , advantageously less than 3 ⁇ , ideally less than 0.5 ⁇ .
- the thickness of the cover electrode can be up to 1 ⁇ , in exceptional cases up to 20 ⁇ .
- the production of thick film electrodes can be carried out by a screen printing process followed by firing.
- the pastes used can be Ag, Au or any Contain admixtures.
- the electrodes 2, 3 are - as mentioned above - on the top and bottom 5, 6 of the chip NTC thermistor
- the sensor arrangement 10 has a contacting element 4. Furthermore, the sensor arrangement 10 can also be further
- the contacting element 4 is arranged.
- the contacting element 4 is at least partially on the electrode 2, which is arranged on the upper side 5.
- the contacting element 4 is according to this
- the contacting element 4 is configured in steps.
- other shapes for the contacting element 4 are conceivable, for example a curved shape of the contacting element 4.
- the contacting element 4 has a first support surface 4a and a second support surface 4b
- the support surfaces 4a, 4b are on the same side, for example a lower side, of the
- Contacting element 4 is formed.
- the tractor treads 4a, 4b also be formed on different sides, so the top and bottom of the Kunststofftechniks ⁇ elements 4 can.
- the support surfaces 4a, 4b are in this embodiment as horizontal sections of the bottom of the
- Contacting element 4 is formed.
- the berth surfaces 4a, 4b are interconnected by a vertical web 4c
- the underside of the contacting element 4 opposite upper side is formed accordingly. That is, the upper side of the contacting element also has two horizontal regions and a vertical web arranged therebetween.
- the first bed surface 4a is located at the top
- the first covers
- Electrode 2 at least partially.
- the contacting element 4 is sintered without pressure on the upper side 5 of the chip NTC thermistor with an Ag paste.
- the second support surface 4b rests, for example, on a printed circuit board or board or a DCB board 11 (see FIG. 4).
- the second bed surface 4b can open
- the board can be done by Ag sintering, soldering or gluing, the chip NTC thermistor 1 on a
- the chip NTC thermistor with Contacting element 4 consists in this
- Embodiment thus essentially of a chip NTC thermistor, which is contacted by a metal bracket on the top side 5.
- the contacting element 4 is used in addition to the contact with the board as protection for the chip NTC thermistor 1 during Ag pressure sintering.
- the resistance of the individual components can be adjusted with an additional trimming process. It will be appreciated that
- Ceramic material or electrode material by e.g.
- the assembly of the metal bracket takes place after the adaptation of the resistor.
- the sensor 1 can - as described above - be sintered under pressure on the patina / the DCB Board. It is also possible to contact the sensor 1 on the conductor tracks by gluing or soldering. As a result of the direct contacting in one process step, a further contacting, e.g. by bonding no more
- the chip NTC thermistor 1 with metal bracket can therefore be mounted wirelessly.
- the selected design allows the processing of a
- Powder These include sample weight, wet pre-grinding, drying, screening, calcination, wet post-grinding, drying, screening.
- the resistance of the thermistor can on the one hand over the
- Sinter parameters / ceramic composition and the other on the chip geometry can be adjusted. Before separating the substrates, the total resistance is determined at nominal temperature. Based on the Vormesswill the geometry of each chip NTC thermistor is defined. Through a separation process, the final geometry is produced. In the case of very closely tolerated resistors, a trimming process can be carried out to set the resistance at nominal temperature by partial laser ablation.
- FIG. 3 shows a side view of a sensor arrangement 10 according to a further exemplary embodiment.
- the sensor arrangement 10 from FIG. 3 has two
- Lying surface 4a at least partially rests on the top 5 of the sensor 1.
- the second support surface 4b this
- Contacting element 4 is designed to be arranged, for example, on a printed circuit board or DCB board 11 in order to contact the sensor 1 (see FIG. 4).
- Electrode pad 12 b of the DCB board 11 are arranged, as shown in Figure 4 can be seen.
- Figures 1 and 2 described contacting element thicker be formed (not explicitly shown). This allows a greater distance, in particular a greater height, to be bridged between the sensor 1 and the printed circuit board.
- the senor 1 can thus be configured higher here or - as in this case - to another
- Contacting element 4 ⁇ are arranged.
- the vertical web 4c which connects the support surfaces 4a, 4b, longer
- the further contacting element 4 ⁇ is arranged so that its first support surface 4a ⁇ rests on an underside 6 of the sensor 1 at least partially.
- Embodiment is one of the first support surface 4a ⁇ opposite third support surface 8, for example, on the circuit board or the DCB board 11.
- Bearing surface 8 is here at the top of the
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Electromagnetism (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Nonlinear Science (AREA)
- Structural Engineering (AREA)
- Measuring Temperature Or Quantity Of Heat (AREA)
- Thermistors And Varistors (AREA)
- Measuring Fluid Pressure (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102015118720 | 2015-11-02 | ||
| DE102016101246.7A DE102016101246A1 (de) | 2015-11-02 | 2016-01-25 | Sensoranordnung und Verfahren zur Herstellung einer Sensoranordnung |
| PCT/EP2016/074963 WO2017076638A1 (de) | 2015-11-02 | 2016-10-18 | Sensoranordnung und verfahren zur herstellung einer sensoranordnung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3371564A1 true EP3371564A1 (de) | 2018-09-12 |
Family
ID=58545722
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16782250.1A Active EP3371565B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
| EP16782249.3A Withdrawn EP3371564A1 (de) | 2015-11-02 | 2016-10-18 | Sensoranordnung und verfahren zur herstellung einer sensoranordnung |
| EP16782242.8A Active EP3371562B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
| EP16782243.6A Active EP3371563B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16782250.1A Active EP3371565B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16782242.8A Active EP3371562B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
| EP16782243.6A Active EP3371563B1 (de) | 2015-11-02 | 2016-10-18 | Sensorelement und verfahren zur herstellung eines sensorelements |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US10908030B2 (de) |
| EP (4) | EP3371565B1 (de) |
| JP (5) | JP6585844B2 (de) |
| CN (4) | CN108351258A (de) |
| DE (4) | DE102016101248A1 (de) |
| WO (4) | WO2017076639A1 (de) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016101248A1 (de) * | 2015-11-02 | 2017-05-04 | Epcos Ag | Sensorelement und Verfahren zur Herstellung eines Sensorelements |
| WO2017151965A1 (en) * | 2016-03-02 | 2017-09-08 | Watlow Electric Manufacturint Company | Heater element having targeted decreasing temperature resistance characteristics |
| DE102017116533A1 (de) * | 2017-07-21 | 2019-01-24 | Tdk Electronics Ag | Anlegetemperaturmessfühler |
| CN107819293B (zh) * | 2017-11-30 | 2024-02-27 | 杭州泽济电子科技有限公司 | 具有小型化电子标签的动触头 |
| DE102019127924B3 (de) * | 2019-10-16 | 2021-01-21 | Tdk Electronics Ag | Bauelement und Verfahren zur Herstellung eines Bauelements |
| DE102019127915A1 (de) | 2019-10-16 | 2021-04-22 | Tdk Electronics Ag | Sensorelement und Verfahren zur Herstellung eines Sensorelements |
| EP4060759A4 (de) | 2019-11-15 | 2023-12-06 | Vehicle Energy Japan Inc. | Positivelektrode für lithium-ionen-sekundärbatterien und lithium-ionen-sekundärbatterie |
| DE102019131306A1 (de) * | 2019-11-20 | 2021-05-20 | Tdk Electronics Ag | Sensorelement und Verfahren zur Herstellung eines Sensorelements |
| DE202020101197U1 (de) | 2020-03-04 | 2020-03-12 | Heraeus Nexensos Gmbh | Temperatursensorverbund |
| DE102020122923A1 (de) | 2020-09-02 | 2022-03-03 | Tdk Electronics Ag | Sensorelement und Verfahren zur Herstellung eines Sensorelements |
| DE102020133985A1 (de) | 2020-12-17 | 2022-06-23 | Tdk Electronics Ag | Sensoranordnung und Verfahren zur Herstellung einer Sensoranordnung |
| WO2025105222A1 (ja) * | 2023-11-13 | 2025-05-22 | Semitec株式会社 | 温度センサ及び温度センサを備えた装置 |
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2016
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| DE102016101248A1 (de) | 2017-05-04 |
| WO2017076639A1 (de) | 2017-05-11 |
| JP2019502898A (ja) | 2019-01-31 |
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| US20180321091A1 (en) | 2018-11-08 |
| WO2017076631A1 (de) | 2017-05-11 |
| EP3371562A1 (de) | 2018-09-12 |
| DE102016101246A1 (de) | 2017-05-04 |
| JP6585844B2 (ja) | 2019-10-02 |
| EP3371563B1 (de) | 2020-01-01 |
| US20180306647A1 (en) | 2018-10-25 |
| CN108139276A (zh) | 2018-06-08 |
| CN108351256A (zh) | 2018-07-31 |
| CN108351258A (zh) | 2018-07-31 |
| JP2019500589A (ja) | 2019-01-10 |
| EP3371565A1 (de) | 2018-09-12 |
| DE102016101247A1 (de) | 2017-05-04 |
| JP2018535412A (ja) | 2018-11-29 |
| EP3371565B1 (de) | 2020-01-01 |
| JP2018535413A (ja) | 2018-11-29 |
| US10908030B2 (en) | 2021-02-02 |
| CN108351257A (zh) | 2018-07-31 |
| US20180306646A1 (en) | 2018-10-25 |
| JP2019207241A (ja) | 2019-12-05 |
| JP6564533B2 (ja) | 2019-08-21 |
| US10788377B2 (en) | 2020-09-29 |
| WO2017076638A1 (de) | 2017-05-11 |
| EP3371562B1 (de) | 2020-05-13 |
| EP3371563A1 (de) | 2018-09-12 |
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