EP1703013A1 - Plüschware und herstellungsverfahren dafür - Google Patents
Plüschware und herstellungsverfahren dafür Download PDFInfo
- Publication number
- EP1703013A1 EP1703013A1 EP04807314A EP04807314A EP1703013A1 EP 1703013 A1 EP1703013 A1 EP 1703013A1 EP 04807314 A EP04807314 A EP 04807314A EP 04807314 A EP04807314 A EP 04807314A EP 1703013 A1 EP1703013 A1 EP 1703013A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cut
- pile
- cut pile
- pile portion
- pile fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 229920000728 polyester Polymers 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 31
- 238000007599 discharging Methods 0.000 claims description 26
- 238000011282 treatment Methods 0.000 claims description 18
- 238000005530 etching Methods 0.000 claims description 17
- 238000003486 chemical etching Methods 0.000 claims description 13
- 238000007639 printing Methods 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 3
- -1 alkylene glycols Chemical class 0.000 description 21
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- 239000003795 chemical substances by application Substances 0.000 description 13
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- 238000009835 boiling Methods 0.000 description 9
- 239000003086 colorant Substances 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000009940 knitting Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 238000002788 crimping Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 244000273256 Phragmites communis Species 0.000 description 2
- 235000014676 Phragmites communis Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000009981 jet dyeing Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- JLQFVGYYVXALAG-CFEVTAHFSA-N yasmin 28 Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C([C@]12[C@H]3C[C@H]3[C@H]3[C@H]4[C@@H]([C@]5(CCC(=O)C=C5[C@@H]5C[C@@H]54)C)CC[C@@]31C)CC(=O)O2 JLQFVGYYVXALAG-CFEVTAHFSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/02—Pile fabrics or articles having similar surface features
- D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B21/02—Pile fabrics or articles having similar surface features
- D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2403/00—Details of fabric structure established in the fabric forming process
- D10B2403/02—Cross-sectional features
Definitions
- the present invention relates to a pile fabric composed of a ground structure portion and a cut pile portion, and to a method for producing the same.
- the present invention relates to a pile fabric having moderately inclined portions on the surface of the cut pile portion and giving a rich high grade sense, and to a method for producing the same.
- pile fabrics have been used in the fields of vehicle interior materials, interior materials, clothes and the like as central fields.
- pile fabrics having three-dimensional patterns on their surfaces among such the pile fabrics have been noted as pile fabrics giving rich high grade senses.
- methods for forming such the three-dimensional patterns methods for physically forming concaves and convexes and methods for chemically forming the concaves and the convexes have been known.
- the method for spraying the fiber-shrinking agent on the pile fabric has had a problem that a nozzle portion is clogged and a problem that a computer-controlled special spraying device is needed, because the fiber-shrinking agent is usually highly viscous.
- the object of the present invention is to provide a pile fabric giving a rich high grade sense and a method for producing the same.
- the above-mentioned object can be achieved by the pile fabric of the present invention and the method for producing the same.
- the pile fabric of the present invention is a pile fabric composed of a ground structure portion having a knitted or woven structure comprising organic fiber yarns and a cut pile portion comprising polyester-based yarns, characterized in that the height of the cut pile portion is gradually reduced to form inclined portions having inclination angles of 0.5 to 10 degree, respectively, in one or more partial regions of the above-mentioned cut pile portion.
- two or more kinds of cut piles having mutually different brightness and / or mutually different hues, respectively, are contained in the above-mentioned cut pile portion to gradually change the color along the slopes of the inclined portions.
- a depth difference between the maximum cut pile portion height and the minimum cut pile portion height in each of the above-mentioned inclined portions is in a range of 0.6 to 1.0 mm.
- a plurality of the inclined portions are formed in the cut pile portion and a pattern is formed with a plurality of the inclined portions.
- the number of fine concaves having areas of not less than 0.05 mm 2 , respectively, is not more than 120 fine concaves / cm 2 in the maximum cut pile portion height side 40 % region of each of the above-mentioned inclined portions.
- the total area of the fine concaves having areas of not less than 0.05 mm 2 , respectively, in the maximum cut pile portion height side 40 % region is not more than 20 % based on the total area of the above-mentioned 40 % region.
- color printing is applied to the pile fabric of the present invention.
- the pile fabric of the present invention can be obtained by a method for producing the pile fabric, characterized by partially removing the cut pile portion of the pile fabric composed of a ground structure portion having a knitted or woven structure comprising organic fiber yarns and a cut pile portion comprising polyester-based yarns, by a chemical etching method, to gradually reduce the height of the cut pile portion, thereby forming inclined portions having inclination angles of 0.5 to 10 degree, respectively.
- two or more kinds of cut piles having mutually different cut pile heights, respectively, are contained in the cut pile portion, before the cut pile portion is partially removed by a chemical etching method, and the cut piles have mutually different brightness and / or mutually different hues, respectively.
- a rotary screen having portions where the diameters of etching treating liquid-discharging holes are gradually increased is used, when the cut pile portion is partially removed by the chemical etching method.
- the pile fabric of the present invention comprises (A) a ground structure portion having a knitted or woven structure comprising organic fiber yarns and (B) a cut pile portion comprising polyester-based yarns, wherein the above-mentioned cut pile portion comprises a plurality of cut piles knitted or woven in the above-mentioned ground structure portion and extended from at least one side of the above-mentioned ground structure portion.
- the above-mentioned cut pile portion is composed of the cut piles comprising the polyester fibers.
- the cut piles constituting the cut pile portion may be one kind or more kinds.
- the cut piles may be two or more kinds, and may have mutually different cut pile heights, brightness, hues, and the like.
- Such the cut piles may be conventional crimped cut piles or non-crimped cut piles.
- the cut pile portion may be composed of the crimped cut piles and the non-crimped piles. It is preferable that the crimped cut piles are contained in the cut pile portion, because the lodging resistance of the cut piles is improved.
- a method for imparting the crimps includes a false-twisting and crimping method, an air jet processing method, and a compression-crimping method.
- the polyester resin for forming the above-mentioned cut piles is produced from a dicarboxylic acid component and a diglycol component. It is preferable that terephthalic acid is mainly used as the dicarboxylic acid component, and it is also preferable that one or more alkylene glycols selected from ethylene glycol, trimethylene glycol and tetramethylene glycol are mainly used as the diglycol component. Additionally, the polyester resin may contain the third component except the above-mentioned dicarboxylic acid component and the above-mentioned glycol component.
- a cationic dye-dyeable anionic component such as sodium sulfoisophthatic acid
- a dicarboxylic acid except the terephthalic acid such as isophthalic acid, naphthalene dicarboxylic acid, adipic acid, sebacic acid
- a glycol compound except the alkylene glycol such as diethylene glycol, polyethylene glycol, bisphenol A, biphenol sulfone.
- Such the polyester resin may, if necessary, contain one or more of a matting agent (titanium dioxide), a micropore-forming agent, (a metal organic sulfonate), an anti-coloring agent, a thermal stabilizer, a flame retardant (antimony trioxide), a fluorescent brightening agent, a colored pigment, an antistatic agent (a metal sulfonate), a moisture absorbent (a polyoxyalkylene glycol), an anti-microbial agent, and other inorganic particles.
- the single fiber fineness (count) of the polyester fibers, the total fineness (count) of the yarn comprising one or more kinds of the polyester fibers and used for forming the cut pile portion, and the like are not limited, but it is preferable that the single fiber fineness is 0.5 to 5 dtex or that the total fineness of the yarn for forming the cut pile portion is 30 to 300 dtex.
- the single fiber fineness is less than 0.1 dtex, the obtained lodging resistance is often insufficient, and the hand of the obtained cut pile portion is often excessively soft.
- the single fiber fineness exceeds 10 dtex the hand of the obtained cut pile portion is often excessively hard.
- the cross-sectional shape of the single fiber is not limited, but the single fiber may have a triangular, flat, constricted flat, cruciate, hexa-lobar, or hollow cross-sectional shape, in addition to an ordinary circular cross-sectional shape.
- the yarns for forming the cut pile portion may be composite yarns each comprising two or more constituting yarns, wherein the polyester resins for the constituting yarns may be different from each other or kneaded with one or more colorants to give different colors or differently dyeing properties.
- inclined portions 1 are formed by gradually reducing the height L of the cut pile portion in one or more portion areas of the pile portion, as typically shown in Fig. 1. Such the inclined portions are obtained by removing the tip portions of the polyester-based cut piles constituting cut pile portion.
- the high portions of the cut pile portion appear to have a light color, while the low portions of the cut pile portion are shaded and appear to have a deep color. Further, since the color is changed from the light color to the deep color along the slope, a high grade sense is obtained.
- the inclination angle A of said inclined portions is in a range of 0.5 to 10 degree (preferably 1 to 3 degree).
- said inclination angle A is a larger acute angle than 10 degree, a satisfactory high grade sense is liable to be not obtained, because brightness is sharply changed from a light color to a deep color.
- said inclination angle A is smaller than 0.5 degree, the brightness is sufficiently not changed, and the satisfactory high grade sense is liable to be still not obtained.
- a case wherein unevenness having slope-free steps is formed in the cut pile portion is also not preferable, because a high grade sense is not obtained.
- a depth difference H between the maximum cut pile portion height and the minimum cut pile portion height of the inclined portion in the above-mentioned inclined portion is in a range of 0.6 to 1.0 mm.
- the maximum cut pile portion height L of the cut pile portion is in a range of 1 to 5 mm (more preferably 1.5 to 3 mm).
- the number of the fine concaves having areas of not less than 0.05 mm 2 is not more than 120 concaves / cm 2 (more preferably, 10 to 100 concaves / cm 2 ) in the maximum height side 40 % region of the inclined portion, as a standard of the fewness of the fine concaves.
- the total area of said concaves is not more than 20 % (more preferably 2 to 10 %) based on the total area of the above-mentioned 40 % range.
- Such the smooth slope little having the fine concaves can be obtained by sequentially putting a plurality of rotary screens on the cut pile portion and performing etching treatments as mentioned later.
- the maximum height side 40 % region of the inclined portion is the inclined portion surface area of the region corresponding to 0.4 W in Fig. 1.
- a plurality of the inclined portions are formed in the partial regions of the cut pile portion to totally form a pattern with the inclined portions, because the high grade sense is further enhanced.
- the pattern includes a pattern wherein squares (it is proper that the length of one side of each square is about 1 to 3 cm) are continued on a plane as exemplified in Fig. 5, a pattern of repeated dots, a chequered, and a checkerd pattern.
- the light color portions in Fig. 5 are the higher places of the cut pile portion, while the deep color portions are the lower places of the cut pile portions.
- the knitted or woven structure of the pile fabric of the present invention is not limited, and is a cut pile fabric obtained by cutting loop piles, such as a warp pile woven fabric, a weft pile woven fabric, a sinker pile knitted fabric, a Raschel pile knitted fabric, or a tricot pile knitted fabric.
- the kind of yarns used in the ground structure portion, the kind of the fibers, single fiber fineness and total fineness are especially not limited, and organic fiber yarns used in ordinary pile fabrics can be used.
- organic fiber yarns include cotton, wool, linen, viscose rayon fibers, polyester fibers, nylon fibers, polyolefin fibers, and cellulose acetate fibers.
- yarns for the ground structure portion of the pile fabric of the present invention are selected from polyester multifilament yarns, whereby the ground structure portion having good hand and good dyeability can be obtained.
- the distribution of the cut piles in the cut pile portion of the pile fabric of the present invention is in the range of 34,000 to 220,000 dtex / cm 2 .
- the density of the cut piles is less than 34,000 dtex / cm 2 , the cut piles in the cut pile portion are liable to easily lodge on an etching treatment to unstabilize the etching action.
- the density of the cut piles inversely exceeds 220,000 dtex / cm 2 , the permeability of an alkali treating liquid into the cut pile portion on the etching treatment is liable to be deteriorated to disable a satisfactory etching treatment.
- the pile fabric of the present invention can be produced, for example, by the following method.
- a pile fabric composed of a ground structure portion having a knitted or woven structure comprising the above-mentioned organic fiber yarns and a loop pile portion comprising the above-mentioned polyester-based fibers is produced, and the loop piles of said fabric are subsequently cut by an ordinary method to produce the pile fabric.
- the cut piles constituting the cut pile portion may comprise one kind of cut piles, but preferably comprise two or more kinds of cut piles having mutually different cut pile heights and mutually different brightness and / or mutually different hues.
- the cut piles having the mutually different cut pile heights and the mutually different colors are thus contained in the cut pile portions, an especially excellent high grade sense is obtained, because the colors are gradually changed along the slopes of the inclined portions on the formation of the inclined portions.
- a cut pile portion is composed of colorless (while) cut piles having a large cut pile height and colored cut piles having a small cut pile height, and then subjected to an etching treatment to form inclined portions
- the high cut pile portions are looked to be white, while the low cut pile portions are looked to be colored.
- the color is gradually changed from the white to the color along the slopes.
- cut piles having a middle cut pile height between the cut pile height of the high cut piles and the cut pile height of the low cut piles are contained, and dyed in another color, the changes of the many colors are obtained.
- the high grade sense is further improved.
- a method for obtaining the cut piles having the mutually different heights includes a method comprising using two or more kinds of yarns having different shrinkages in boiling water as yarns for the cut piles to form the cut pile portion and then thermally treating the formed cut pile portion, when the pile knitted or woven fabric is produced, and a method comprising using bended yarns prepared by simultaneously paralleling and bending non-crimped yarns and crimped yarns to form the cut pile portion having inclination angles of 5 to 10 degree, and then developing crimps in the cut pile portion.
- the cut pile portion of said pile fabric is partially removed by a chemical etching method to gradually reduce the height of the cut pile portion, thereby forming the inclined portions. Therefore, the pile fabric of the present invention can easily be produced.
- the cut pile portion when the cut pile portion is partially removed by the chemical etching method, it is preferable to use a rotary screen having a portion wherein the diameters of etching treatment liquid-discharging holes are gradually enlarged.
- a plurality of holes for discharging the etching treatment liquid are formed in the surface of the rotary screen, and there is at least a portion where the diameters of the discharging holes are gradually enlarged. Since a large amount of the etching treatment liquid is discharged from the discharging holes having the large hole diameters, the cut pile portion is deeply etched to reduce the height of the pile portion.
- the cut pile portion is shallowly etched. Consequently, the slopes can be formed in one or more portion regions of the above-mentioned cut pile portion.
- a pattern is formed in the cut pile portion by an etching method, it is needed to arrange discharging holes in said rotary screen in a pattern state corresponding to the pattern.
- a pattern comprising squares continued on a plane as exemplified in Fig. 4 is formed, it is needed that discharging holes are arranged in a pattern state corresponding to the pattern.
- the number of the above-mentioned rotary screens is 2 to 5.
- the second rotary screen and the other rotary screens are sequentially used to repeatedly apply the etching treatments, thereby obtaining such the smooth slopes little having fine concaves and fine convexes as mentioned above.
- the sufficient number of the rotary screens is five, but six or more rotary screens are liable to enhance the cost.
- a discharging amount from the rotary screen is in a range of 15 to 25 cm 3 / m 2 .
- said discharging amount is more than 25 cm 3 / m 2 , the alkali-treating agent is liable to cause clogging.
- said discharging amount is less than 15 cm 3 / m 2 , the alkali-treating agent is liable to unevenly adhere, when adhered to the cut pile portion.
- the number and / or arrangement of the discharging holes may be identical or different.
- the discharging number and / or arrangement of the discharging holes of the second rotary screen may be changed, so that a slope is formed in the cut pile portion with the first rotary screen and then the minimum height side of the slope is again etched with the second rotary screen.
- the discharging numbers and / or arrangements of the discharging holes of the third rotary screen and the following rotary screens may be changed, so that only the minimum height side of the slope is repeatedly etched.
- the kind of the above-mentioned alkali-treating agent is especially not limited, but a printing paste comprising 30 to 70 percent by weight of a 30 % sodium hydroxide liquid alkali and 70 to 30 percent by weight of an undiluted paste having a solid content of 15 % and used for etching, and having a viscosity of 400 to 800 poises (for example, Seruparu 587, produced by Adachi Senryo (Ltd.)) is suitably exemplified.
- a known color printing for example, an ink jet type printing disclosed in JP-A 2000-345483
- a conventional dyeing finishing processing may be applied to the pile fabric obtained thus.
- various processing treatments for imparting the functions of a conventional waterproof processing, ultraviolet light screening or anti-microbial agent, a deodorant, an insecticide, a luminous agent, a retroreflector, a minus ion-producing agent and the like may added and applied.
- a counter wheel having a circumferential length of 1.125 m was rotated on a sample ten revolutions to make a skein, and the skein was hung from a hanging nail of a scale plate.
- a load of 1/30 based on the total weight of the skein was hung from the lower portion of the skein, and the length L1 of the untreated skein was read. Then, the load was detached, and the skein was put in a cotton bag and then immersed in boiling water for 30 minutes. Subsequently, the skein was taken out, dehydrated with filter paper, dried in air for 24 hours, and then again hung from the hanging nail of the scale plate.
- BWS boiling water shrinkage
- a counter wheel having a circumferential length of 1.125 m was used to make a skein having a total fineness of 3333 dtex, and the skein was hung from a hanging nail of a scale plate.
- An initial load of 6g and a load of 600g were hung from the lower portion of the skein, and the length L0 of the skein was read. Then, the load was detached, and the skein was separated from scale plate and immersed in boiling water for 30 minutes to develop the crimps. Subsequently, the skein was taken out, dehydrated with filter paper, dried in air for 24 hours, and then again hung on the scale plate.
- a 5 cm ⁇ 5 cm long square sample was cut in the longitudinal direction and in the latitudinal direction to the length direction of the fabric, and an inclination angle A (degree) between a horizontal direction and an inclination direction from the highest top portion of the cut pile portion to the alkali-treated lowest portion was measured with a digital microscope VHX manufactured by Keyence (Ltd.).
- the number of n was 5, and the average value was determined.
- a 5 cm ⁇ 5 cm long square sample was cut in the longitudinal direction and in the latitudinal direction to the length direction of the fabric, and a depth H (mm) from the highest top portion of the cut pile portion to the alkali-treated lowest portion was measured with a digital microscope VHX manufactured by Keyence (Ltd.).
- the number of n was 5, and the average value was determined.
- a 5 cm ⁇ 5 cm long square sample was cut in the longitudinal direction and in the latitudinal direction to the length direction of the fabric, and a length W (mm) of an inclined portion shown in Fig. 1 was measured with a digital microscope VHX manufactured by Keyence (Ltd.).
- the number of n was 5, and the average value was determined.
- the number (concaves / cm 2 ) of concaves having areas of not less than 0.05 mm 2 in the maximum height side 40 % area of the inclined portion was measured as the number of the concaves. Further, the ratio (%) of the concaves was calculated from the following expression. Herein, the number of n was 5, and the average value was determined.
- Ratio (%) of concaves (total area of concaves having areas of not less than 0.05 mm 2 ) / (area of maximum height side 40 % area of inclined portion) ⁇ 100
- the high grade sense was classified into the following grades and evaluated by three testers.
- a polyester filament mixed yarn (yarn count : 140 dtex / 96 filaments) prepared by air-blending a usual polyethylene terephthalate multifilament yarn (yarn count : 56 dtex / 24 filaments, boiling water shrinkage : 10 %, produced by Teijin Fiber (Ltd.)) with a usual polyethylene terephthalate false-twisted crimped yarn (yarn count : 84 dtex / 72 filaments, percentage crimp : 25 %, produced by Teijin Fiber (Ltd.)) by use of a known interlace nozzle was used as a yarn for the cut piles of a pile fabric.
- Ground structure back half structure (a knitting method comprising back : 23 / 20 and front : 10 / 12).
- the obtained knitted fabric was dyed by use of a jet dyeing machine manufactured by (Ltd.) Hisaka Seisakusho at 130°C for 30 minutes. After dyed, the knitted fabric was subjected to conventional preliminary treatments (full cut raising ⁇ shearing ⁇ splitting ⁇ shearing ⁇ presetting) to obtain the pile fabric (cut pile density : 97217 dtex / cm 2 ) having cut piles (cut pile length : 2 mm) and a knit density of 64 courses /2.54 cm and 35 wales / 2.54 cm.
- the cut piles having a large cut pile height were formed from the polyethylene terephthalate multifilament yarns, and the cut piles having a small cut pile height were formed from the polyethylene terephthalate false-twisted crimped yarns.
- an alkali-treating agent having a viscosity of 600 poises and comprising 54 percent by weight of a 30 % sodium hydroxide liquid alkali and 46 percent by weight of an undiluted paste used for etching and having a solid content of 15 % (for example, Seruparu 587, produced by Adachi Senryo (Ltd.)).
- the discharging holes were distributed (the discharging holes having the largest hole diameters were arranged at positions corresponding to the deepest color portions, and discharging holes having gradually reduced hole diameters were arranged from the deepest color portions to the light color portions. Positions corresponding to the lightest color portion were free from the holes).
- Shape of the discharging hole diameter of 0.068 mm
- Said fabric was subjected to a dry heat drying treatment at a temperature of 130°C for a time of 5 minutes, to a high temperature streamer treatment at a temperature of 165°C for a time of 8 minutes, to a hot water washing treatment and then to a water washing treatment.
- the cut pile portion was partially removed by the chemical etching method to obtain the pile fabric in whose cut pile portion a plurality of inclined portions were formed.
- the inclination angle A, depth difference H, and length W of each of the inclined portions were 2 degree, 0.8 mm, and 10 mm, respectively.
- the number of concaves per unit area was 90 concaves / cm 2 , and the rate of the concaves was 2 %. Therefore, the surface of each of the inclined portions scarcely had the fine concaves and the fine convexes and was smooth.
- the high places of the cut pile portions are looked in a light color, while the low places of the cut pile portions were shaded and looked in a deep color. The color was gradually changed from the light color to the deep color along the slopes. Hence, the pile fabric was excellent (grade 4) at the point of high grade sense.
- a polyethylene terephthalate multi-filament yarn (yarn count : 56 dtex / 72 filaments, produced by Teijin Fiber (Ltd.)) was thermally treated under conditions comprising a heater length : 2 m, a thermal treatment temperature : 200°C, a thermal treatment speed : 500 m/min, and an overfeed rate : 5 % to obtain the non-crimped polyethylene terephthalate multifilament yarn having a boiling water shrinkage of 3 %.
- a polyethylene terephthalate false-twisted crimped yarn (yarn count : 84 dtex / 36 filaments, a percentage crimp : 25 %, produced by Teijin Fiber (Ltd.)) resin-dyed with a black pigment.
- a cationic dye-dyeable polyethylene terephthalate (produced by Teijin Fiber (Ltd.)) was melt-spun and wound up at a winding rate of 3,500 m / minutes.
- the obtained cationic dye-dyeable partially oriented undrawn polyethylene terephthalate yarn was drawn between the 65°C first roller and the 75°C second roller of a drawing apparatus at a draw ratio of 1.4' without thermally setting, thereby obtaining the non-crimped polyethylene terephthalate yarn (yarn count : 56 dtex / 24 filaments) having a boiling water shrinkage of 45 %.
- polyester filament mixed yarn (yarn count : 205 dtex / 132 filaments) was used as a yarn for the cut piles of a pile fabric, while a conventional polyethylene terephthalate filament yarn (yarn count : 167 dtex / 48 filaments, a boiling water shrinkage of 10 %, produced by Teijin Fiber (Ltd.)) as a yarn for forming a ground structure.
- the obtained loop pile fabric was supplied to a shearing machine (manufactured by Nikki (Ltd.)), and the 0.2 mm tip portions of the loop piles were cut to form the cut piles.
- the cut pile fabric was supplied to a dry heat setter, and thermally treated at a temperature of 180°C for a time of 45 seconds to stabilize the non-crimped polyethylene terephthalate multifilament yarns in the cut piles, sufficiently form the crimps of the polyethylene terephthalate multi false-twisted crimped yarns resin-dyed with the pigment, and sufficiently thermally shrink the non-crimped cationic dye-dyeable polyethylene terephthalate yarns.
- cut piles 2 having the largest cut pile height, cut piles 4 having the lowest cut pile height, and cut piles 3 having the middle cut pile height were formed from the non-crimped polyethylene terephthalate multifilament yarns, the non-crimped cationic dye-dyeable polyethylene terephthalate yarns, and the polyethylene terephthalate multi false-twisted crimped yarns resin-dyed with the pigment, respectively.
- the obtained cut pile fabric was dyed with a cationic dye (blue) at 130°C for 30 minutes by use of a,jet dyeing machine manufactured by (Ltd.) Hisaka Seisakusho, dried, and then pre-set to obtain the pile fabric (cut pile density : 129,642 dtex / cm 2 ) having the cut piles (the height of the cut piles : 2 mm) and having a knit density of 68 courses / 2.54 cm and 30 wales / 2.54 cm.
- a cationic dye blue
- the inclined portions formed were the inclined portions as typically shown in Fig. 2, and the inclination angle A, depth difference H, and inclination length W of each of the inclined portions were 2 degree, 0.8 mm, and 10 mm, respectively.
- the number of concaves per unit area was 100 concaves /cm 2
- the rate of the concaves was 5 %
- the surface of each of the inclined portions scarcely had fine concaves and fine convexes, and was smooth.
- the highest portions, middle portions, and lowest portions of the cut pile portion along the slopes of the inclined portions were looked in a white color, a black color, and a black-blue mixed color, respectively. Therefore, the pile fabric was greatly excellent (grade 5) at the point of high grade sense.
- Example 2 Similarly as in Example 2 except that the number of the rotary screens was changed to 2, the cut pile portion was partially removed by a chemical etching method to obtain the pile fabric in whose cut pile portion the slopes were formed.
- the inclination angle A, depth difference H, and length W of each of the inclined portions were 2 degree, 0.8 mm, and 10 mm, respectively.
- the number of concave portions per unit area was 120 concaves / cm 2 , and the rate of the concaves was 20 %. Fine concaves and fine convexes were somewhat looked on the surfaces of the inclined portions, but the pile fabric was excellent (grade 4) at the point of high grade sense.
- the pile fabric obtained in Example 2 was color-printed with a usual ink jet. Said fabric subjected to the color-printing had an appearance having good depth and compact inclination differences in response to a looking angle, and was excellent.
- Example 2 Similarly as in Example 1 except that the discharging amount of each rotary screen was changed to 26.3 cm 3 /m 2 and the number of the rotary screens was changed to 1, the cut pile portion was partially removed by a chemical etching method to obtain the pile fabric in whose cut pile portion the slopes having many fine concaves and convexes were formed.
- the inclination angle A, depth difference H, and length W of each of the inclined portions were 2 degree, 0.8 mm, and 10 mm, respectively.
- the number of concave portions per unit area was 150 concaves / cm 2 , and the rate of the concaves was 25 %. Fine concaves and convexes were looked on the surfaces of the inclined portions, but the pile fabric was somewhat good (grade 3) at the point of high grade sense.
- the pile fabric of the present invention can suitably be used in fields such as vehicle interior materials, interior materials, and clothes, and has high practicality, because of having moderate inclined portions on the surface of the cut pile portion and thereby giving rich high grade sense.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
- Knitting Of Fabric (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003417640 | 2003-12-16 | ||
PCT/JP2004/018957 WO2005059237A1 (ja) | 2003-12-16 | 2004-12-13 | 立毛布帛およびその製造方法 |
Publications (1)
Publication Number | Publication Date |
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EP1703013A1 true EP1703013A1 (de) | 2006-09-20 |
Family
ID=34697071
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04807314A Withdrawn EP1703013A1 (de) | 2003-12-16 | 2004-12-13 | Plüschware und herstellungsverfahren dafür |
Country Status (7)
Country | Link |
---|---|
US (1) | US20070122585A1 (de) |
EP (1) | EP1703013A1 (de) |
JP (1) | JP4500266B2 (de) |
KR (1) | KR20060129254A (de) |
CN (1) | CN1914369A (de) |
TW (1) | TW200525065A (de) |
WO (1) | WO2005059237A1 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101040075B (zh) * | 2005-04-08 | 2011-02-23 | 精炼株式会社 | 凹凸加工用布帛 |
KR101093542B1 (ko) * | 2006-04-12 | 2011-12-13 | 코오롱글로텍주식회사 | 원단의 3차원 에칭 방법, 및 이로부터 제조되는 원단 |
US7575027B2 (en) * | 2007-01-05 | 2009-08-18 | Min-San Huang | Weave with visual color variation |
US7673378B1 (en) * | 2007-02-22 | 2010-03-09 | Product Concepts Residential, L.L.C. | Method of manufacturing decorative carpet tile |
JP5682628B2 (ja) * | 2010-11-08 | 2015-03-11 | 株式会社ワコール | 編地及び股付衣類 |
CN104032464B (zh) * | 2014-05-29 | 2016-05-18 | 宁波大千纺织品有限公司 | 一种立体拉毛绒布面料及其制备方法 |
CN111005135B (zh) * | 2018-10-05 | 2024-07-02 | 尤尼吉可贸易有限公司 | 单绒头针织物及鞋内装件 |
KR20210090627A (ko) * | 2018-11-16 | 2021-07-20 | 덴카 주식회사 | 모상체를 가지는 열가소성 수지 시트 및 그의 성형품 |
CH716114A1 (de) * | 2019-04-24 | 2020-10-30 | Schoeller Tech Ag | Flächige Velourmaschenware. |
CN112981693A (zh) * | 2021-02-24 | 2021-06-18 | 浙江真爱时尚家居有限公司 | 一种拉舍尔毛毯的经编割绒生产方法 |
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US3755051A (en) * | 1970-10-05 | 1973-08-28 | Kimberly Clark Co | High-loft, nonwoven paneling material and covering |
JPS5631073A (en) * | 1979-08-20 | 1981-03-28 | Teijin Ltd | Production of artificial leather |
US4255231A (en) * | 1979-06-13 | 1981-03-10 | Congoleum Corporation | Carpet etching |
JPS56140167A (en) * | 1980-03-31 | 1981-11-02 | Teijin Ltd | Production of artificial leather |
JPS5771485A (en) * | 1980-10-20 | 1982-05-04 | Teijin Ltd | Production of swede like raised fabric with pattern |
JPS57121643A (en) * | 1981-01-21 | 1982-07-29 | Kanebo Gosen Kk | Raised product and method |
JPS58136855A (ja) * | 1982-01-22 | 1983-08-15 | カネボウ株式会社 | 毛皮様繊維構造物 |
JPS59187685A (ja) * | 1983-04-04 | 1984-10-24 | 帝人株式会社 | ポリエステル立毛布帛の立体模様付与方法 |
US4576848A (en) * | 1985-06-24 | 1986-03-18 | Fieldcrest Mills, Inc. | Pile fabrics as woven terry fabrics with diagonal grooves of cut pile |
JP3401730B2 (ja) * | 1992-10-13 | 2003-04-28 | 株式会社クラレ | 先細繊維、その製造方法およびそれからなる立毛製品 |
JPH10298863A (ja) * | 1997-04-25 | 1998-11-10 | Suminoe Textile Co Ltd | 凹凸模様を有するパイル布帛の製造方法 |
US6035749A (en) * | 1997-07-22 | 2000-03-14 | Haselwander; Jack G. | Patterned shearing of pile fabrics |
US6640680B2 (en) * | 1999-01-27 | 2003-11-04 | Eagle Automation, Inc. | Apparatus and methods for sculpting carpet |
EP1041193A1 (de) * | 1999-04-02 | 2000-10-04 | Seiren Co., Ltd. | Verfahren zur Herstellung von Geweben mit dreidimensionalen Mustern, sowie daraus hergestellte Gewebe |
JP2000345483A (ja) * | 1999-04-02 | 2000-12-12 | Seiren Co Ltd | 立体模様を形成するための布帛の処理方法及び処理された布帛 |
JP2002155451A (ja) * | 2000-11-16 | 2002-05-31 | Yamazaki Corp | パイル製品及びその製法 |
US7021085B2 (en) * | 2002-09-26 | 2006-04-04 | Teijin Fibers Limited | Concave and convex-patterned multi-colored fiber pile fabric |
US7435264B2 (en) * | 2003-11-12 | 2008-10-14 | Milliken & Company | Sculptured and etched textile having shade contrast corresponding to surface etched regions |
JP4343014B2 (ja) * | 2004-04-13 | 2009-10-14 | 帝人ファイバー株式会社 | 緻密超短立毛布帛およびその製造方法およびカーシート部材 |
JP2006045731A (ja) * | 2004-08-06 | 2006-02-16 | Teijin Fibers Ltd | ソフトな風合いと耐摩耗性を有する深色性立毛布帛および繊維製品 |
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2004
- 2004-12-09 TW TW093138137A patent/TW200525065A/zh unknown
- 2004-12-13 KR KR1020067013898A patent/KR20060129254A/ko not_active Application Discontinuation
- 2004-12-13 US US10/582,789 patent/US20070122585A1/en not_active Abandoned
- 2004-12-13 JP JP2005516376A patent/JP4500266B2/ja not_active Expired - Fee Related
- 2004-12-13 WO PCT/JP2004/018957 patent/WO2005059237A1/ja active Application Filing
- 2004-12-13 EP EP04807314A patent/EP1703013A1/de not_active Withdrawn
- 2004-12-13 CN CNA2004800416350A patent/CN1914369A/zh active Pending
Non-Patent Citations (1)
Title |
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See references of WO2005059237A1 * |
Also Published As
Publication number | Publication date |
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US20070122585A1 (en) | 2007-05-31 |
KR20060129254A (ko) | 2006-12-15 |
JP4500266B2 (ja) | 2010-07-14 |
JPWO2005059237A1 (ja) | 2007-07-12 |
WO2005059237A1 (ja) | 2005-06-30 |
TW200525065A (en) | 2005-08-01 |
CN1914369A (zh) | 2007-02-14 |
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