EP1603999B2 - Textilbehandlungsmittel - Google Patents

Textilbehandlungsmittel Download PDF

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Publication number
EP1603999B2
EP1603999B2 EP04717600.3A EP04717600A EP1603999B2 EP 1603999 B2 EP1603999 B2 EP 1603999B2 EP 04717600 A EP04717600 A EP 04717600A EP 1603999 B2 EP1603999 B2 EP 1603999B2
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EP
European Patent Office
Prior art keywords
oil
skin
treatment agent
use according
fabric treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP04717600.3A
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German (de)
English (en)
French (fr)
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EP1603999A1 (de
EP1603999B1 (de
Inventor
Wilfried Rähse
Ulrike Ruffer
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Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL04717600T priority Critical patent/PL1603999T5/pl
Publication of EP1603999A1 publication Critical patent/EP1603999A1/de
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Publication of EP1603999B2 publication Critical patent/EP1603999B2/de
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

Definitions

  • the invention relates to the use of a textile treatment agent as a rinse aid or as a fabric softener.
  • the classical treatment of textile garments with textile treatment agents fulfills a variety of needs with regard to the textiles to be treated, e.g. hygiene, fragrance or softness.
  • rinsing agents are sometimes used to remove detergent residues, for example, in order to obtain skin-friendly textiles. That's how it describes DE 199 23 303 C2 Detergents containing certain minimum amounts of citric acid, lactic acid, cyclodextrin and ascorbic acid and are suitable for the production of skin-friendly textiles.
  • US 5,610,189 describes a composition for treating household laundry containing tea tree oil.
  • DE 197 37 072 A1 describes the use of a mixture containing a citrus oil concentrate and castor oil for laundry cleaning.
  • DE 198 21 106 A1 discloses a miticidal detergent with a high content of essential oils.
  • the essential oils may be tree oils such as tea tree oil or cedar oil, or vegetable oils such as cumin oil and dill oil.
  • US Pat. No. 6,494,920 B1 describes fabric softeners containing aloe vera and ester quats.
  • JP 06136386 discloses cleanser with skin protection agent based on Aspalathus Linearis.
  • WO 00/40687 A1 describes a fabric care composition comprising a plasticizer and a protein, wherein the protein can deposit on the fiber. It can later be released to the skin from the fiber.
  • US 3,640,883 discloses powdered mild detergents comprising 1-5% by weight of a skin-protecting substance.
  • laundry treatment means in the context of a holistic and multi-functional approach also take on special functions, for example, in addition directly or indirectly to the skin health are beneficial.
  • Such textile treatment agents are to be seen as supplements to the classic textile treatment agents such as detergents or softeners.
  • the aim is to enable the treatment of textile garments with skin-functional laundry detergents which make an active positive contribution to the health of the skin, which comes into contact with the textiles treated therewith.
  • the Applicant believes that upon contact of the skin with a textile, one or more skin aiding or even curative agents will be at least partially delivered to the skin, with the natural skin flora of human beings is not impaired by the substances released, but is advantageously supported in their self-regulatory powers.
  • the term skin healing or the attribute skin-healing can be defined most simply by the state of the healthy human skin.
  • Healthy human skin is characterized by the fact that it provides sufficient protection against microorganisms, germs and pathogens by means of their intact acid mantle that their buffering capacity and alkali neutralizing capacity sufficient to ward off the harmful effects of surrounding fluids, that there is a high degree of freedom from redness and that freedom from skin damage such as cuts, abrasions and burns, irritation, inflammation and allergies, and that it is neither cracked nor dried out.
  • it is healthy Skin by taking on a depot function for fat, water and blood and an important role in the metabolism.
  • Skin healing in the context of the present invention is now all that helps the skin to return to its original state. It is also all skin-healing, which stimulates, trains, supports and promotes the self-regulation of the skin, so that it is able to fulfill their functions, in that it returns to the natural state of equilibrium. Furthermore, the term skin healing in the context of this invention is understood to mean all the influences which lead to at least alleviate, if not heal, obvious skin diseases such as eczema, rashes, redness, itching, swelling, blistering, oozing, crusting in various forms ,
  • the term skin protection means everything that is necessary to maintain the normal performance of the skin in terms of its functions under specific stress situations and goes beyond its own protective mechanisms.
  • this term also differs significantly from the skin care, because the skin care achieved only a cosmetic benefit in terms of sensory needs, for. softness or shine under normal conditions.
  • the skin protection supports the skin with additional agents that help the skin, for example, even in adverse conditions, to fulfill their multifaceted functions.
  • adverse conditions can e.g. Friction, cold, heat, UV radiation, aggressive ambient fluids, contact with irritating materials.
  • textile, textile fiber or linen all conceivable textile fibers and textile fabrics produced from it but also unformed structures are understood, for example, natural fibers of plant and animal and mineral origin, as well as man-made fibers Also referred to as synthetic fibers or as synthetic fibers, of natural and synthetic polymers and inorganic substances.
  • selected synthetic fibers such as polyamide or polyester and many others are especially cotton, cellulose fibers, jute, wool, flax, sisal, hemp, silk in a very special way suitable to be used with the textile treatment agents according to the invention. All other fibers are also very well suited for a treatment according to this invention.
  • textiles are intended to mean those which serve the purposes of clothing or, more typically, often come into contact with the skin, e.g. Towels, handkerchiefs, bedding or the like more.
  • all other textile structures in the context of the invention can be treated, with the only proviso that these textile structures, if they come into contact with human skin, in the sense of Invention skin-healing and / or skin-protecting active ingredients are able to deliver at least in traces to the skin assets.
  • the term textiles or textile in the context of this invention for example, carpets and other home textiles and technical purposes textile structures to understand.
  • the treatable textiles also all imaginable unshaped structures such as flakes, linear structures such as twine, yarn, linen, cords, ropes, threads and sheet-like or body structures such as felts, fabrics, nonwovens u. Watten,
  • textile in the context of this invention, paper, cardboard, cardboard to understand, especially when the paper, cardboard, cardboard clothing purposes.
  • such substances or active substances are particularly advantageous if they are antiseptic active.
  • the attribute of anti-spasmodic efficacy means an effect that is beneficial to the self-regulating forces of human skin.
  • This efficacy is not in its expression with that of classical germicidal or germicidal agents such. Phenols, halogens, alcohols with which e.g. Skin and Mucous membranes Wounds or even medical instruments treated to achieve asepsis (germ-free) compare.
  • the classical antiseptic includes antimicrobial measures at the point of origin or at the portal of entry of a possible infection or at the site of infection on the body surface.
  • the particular advantage of the antiseptic active ingredients used in the invention results from a synergistic interaction of these substances with the general functional mechanisms of human skin, since these mildly antiseptic substances such as germs, including harmful bacteria reduce, but not perfect, so to sterility , destroy. So there are enough germs on the skin that are sufficient to train and strengthen the self-regulating powers of human skin.
  • the interaction of the self-regulating forces of the skin with the antiseptic capacity of the active ingredients in the middle of the skin supports the general functioning of the skin. This is especially with regard to already irritated and / or otherwise damaged skin of great Advantage.
  • the self-regulatory powers of the skin are sometimes no longer able, even temporarily, to ensure skin health on their own.
  • these self-regulatory powers are supported, trained and strengthened.
  • the textile treatment agent or the laundry treated with it supports the natural skin flora of humans.
  • textile treatment agents of such an embodiment is particularly useful for their purposes when the antiseptic agent is an oil, preferably an essential oil.
  • This antiseptic oil is preferably an essential oil selected from the group consisting of Angelica fine - Angelica archangelica, Anis - Pimpinella anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus, Cajeput - Melaleuca leucadendron, Cistrose - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltann needle - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce Spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle (Strawflower) Helichrysum ang., Ginger extra - Zingiber off., St.
  • an essential oil selected from the group consisting of Angelica fine - Angelica
  • Another advantage of the aforementioned essential oils lies in their particular multifunctionality, which, in addition to the described mild antiseptic activity, results from a multitude of other desirable organoleptic properties attributable to these oils.
  • These oils are in most cases an expectorant effect as they exert on the mucous membranes of the respiratory organs a mild, positive stimulus. Furthermore, a desirable feeling of warmth can be established. Deodorizing, analgesic, circulation-promoting, calming effects could be observed in connection with the use according to the invention of these designated oils by the applicant and be recognized as particularly advantageous.
  • the organoleptic properties of these oils are usually not influenced by the main components, but by the minor or trace constituents, which can often go into the hundreds and sometimes interact synergistically.
  • Another advantage associated with the oils mentioned is their harmonious fragrance and scent, which in many cases leads to positive feelings in humans.
  • the textile treatment agent used according to the invention or the laundry treated with it not only supports the natural skin flora of humans, but also helps the human organism to obtain additional advantages of the type just described.
  • tea tree oil is of great advantage for the subject invention.
  • tea tree oil In addition to its considerable germicidal, antiseptic, fungicidal, antiviral, wound-healing, anti-inflammatory, scarring-promoting effect, it has excellent skin compatibility and offers a wide range of other applications, for example with regard to the supportive treatment of colds or diseases of the rheumatic type, gout, muscle pain.
  • oils are natural emollients, d. H. Means that soften and soften body tissues and reduce the roughness of the skin. So these oils have a skin conditioning effect. On the other hand, it is precisely these oils which have further specific effects which result in a synergistic interaction with the skin and its self-regulating forces and also enable protection under adverse conditions.
  • a particularly preferred oil in the context of this invention is, for example, the hemp oil.
  • Hemp oil which contains a high proportion of essential fatty acids and also contains up to 6% by weight of valuable ⁇ -linolenic acid (GLA), also has an anti-inflammatory, slightly analgesic, healing, nourishing, skin structure improving, preventing the appearance of old age. It improves tissue regeneration processes and has a high regenerative effect on injured tissue. In addition, it may increase the care properties or other properties of other oils in particular of all oils explicitly mentioned here.
  • hemp oil Since essential fatty acids are significantly involved in maintaining the barrier function of the skin, because they help to regulate and normalize the transepidermal water loss through the skin, the hemp oil for the purposes of this invention, as a result of its high GLA content, a special role, since In case of disturbed transepidermal water loss, topical treatment with GLA leads to the greatest reduction in transepidermal water loss. Furthermore, hemp oil has further positive effects on the human organism in terms of arteriosclerosis, rheumatoid arthritis, diabetic neuropathy to heart problems.
  • Another preferred oil for the purposes of this invention is the borage oil.
  • the textile treatment agents contain skin-healing active substances which have a minimum content of 0.1% by weight of GLA, preferably of 0.3% by weight, particularly preferably of 0.5% by weight.
  • skin-healing active substances which have a minimum content of 0.1% by weight of GLA, preferably of 0.3% by weight, particularly preferably of 0.5% by weight.
  • GLA skin-healing active substances
  • these include, for example, black cumin oil, evening primrose oil, Echiumöl, Trichodesmaöl and the blackcurrant seed oil.
  • almond oil is characterized by the fact that it can enhance the effect of other oils, which is why it is advantageously used in combination with other oils.
  • the Textilbaticiansmittel contain at least 1 wt .-%, preferably at least 5 wt .-%, more preferably at least 10 wt .-%, most preferably at least 15 wt .-% of one or more skin-protecting and / or skin-healing Active substances or oils or essential oils, wherein it is even more advantageous if even at least 20% by weight, in particular even more than 25% by weight, more preferably even more than 30% by weight, of one or more skin-protecting and / or or skin-healing active substances or oils or essential oils are contained in the textile treatment agent.
  • the textile treatment agent is dye-free.
  • the Fardstoff snap is particularly advantageous because dyes generally hold a significant allergy potential.
  • the usual colorants e.g. Pigments, but preferably used organic dyes.
  • Organic dyes are more skin-friendly in the context of the invention.
  • the colorant content is preferably below 0.002% by weight of the composition, in particular it is 0% by weight.
  • non-aqueous form is understood to mean water contents of less than 15% by weight, preferably water contents of less than 10% by weight, more preferably less than 8% by weight, and in turn water contents of less than 6% by weight. are preferred in particular, however, water contents of between 2 and 0.001% by weight, based on the agent, are preferred.
  • the advantage of a reduction of the proportion of water on average is that the ingredients of the textile treatment agent can be used in concentrated and therefore more effective form in the application, as well as that the agents are better processable, for example emulsifiable.
  • the textile treatment agents contain no additional perfumes or perfume oils. This is particularly advantageous, since most of these fragrances or perfume oils, which are not skin-healing and / or skin-protecting active substances in the context of the invention, have an allergy potential which counteracts the present invention. In addition, there are large groups of people who show safe proven allergic reactions to a variety of such fragrances and / or perfume oils.
  • the textile treatment agents are preferably free of the aforementioned fragrances, it may be desirable to produce a particularly attractive fragrance which can not be generated solely from the skin-healing active ingredients according to the invention and their inherent odor effects. Therefore, in a preferred embodiment it is possible to add a small amount of such fragrances, which are not skin-healing and / or skin-protecting active substances according to the invention, to the respective agents. It must be ensured that no allergic reactions are caused by these additional fragrances.
  • fragrances or perfume oils include e.g. the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are known e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzyl carbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate.
  • the ethers include, for example, benzyl ethyl ether, to the aldehydes e.g. the linear alkanals having 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, to the ketones e.g.
  • Perfume oils may also contain natural fragrance mixtures such as are available from vegetable sources, e.g. Pine oil, muscatel, clove oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, galbanum oil and labdanum oil as well as orange blossom oil, orange peel oil. However, these latter oils are not skin-healing and / or skin-protecting oils in the context of the invention.
  • the textile treatment agent is a rinse aid.
  • rinsing agents are generally understood to mean those agents which are added to the liquor only after the actual textile cleaning and are preferably applied in an acidic medium. Such rinsing agents thus usually enter the liquor only after the last rinse, so as not to be removed during rinsing with the actual wash liquor without leaving or unfolding an effect.
  • a proper application of a rinse aid can be done manually, ie by a subsequent manual addition of the rinse aid as a separate means.
  • a proper application can also be accomplished via a controlled-release mechanism.
  • a controlled-release mechanism means the time-controlled release of active substances. Such control of the release of the active ingredient can be controlled via various actuators.
  • a sensitive material preferably with mixtures of polyvinyl alcohol and cellulose leather (methylhydroxycellulose, methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, hydroxyethycellulose).
  • the characteristic dissolution behavior of the cladding material as a function of specific parameters is utilized.
  • the dissolution behavior may be a function of time, temperature, pH, ionic strength, mechanical stress or corresponding parameters.
  • a rinse aid it is e.g. appropriate to choose a pH-sensitive, but temperaturbestustes wrapping material.
  • the rinsing agent can be released after the wash cycle, characterized in that the pH is shifted from alkaline to acidic environment, so that the coating material dissolves.
  • laundry or textiles of any kind are treated with a corresponding textile treatment agent such that the respective textile at least briefly or partially comes into contact with the textile treatment agent.
  • a corresponding textile treatment agent such that the respective textile at least briefly or partially comes into contact with the textile treatment agent.
  • Such contact may be made in the ordinary laundry treatment, e.g. in the course of machine washing, fabric softening, hand washing, machine drying.
  • the textile treatment agent is used as a post-treatment agent, i. You can use it as a rinse aid after washing in the washing machine. It is only in one way or another to make contact of the textile treatment agent with the textile, so that the textile treatment agent is enabled to remain after application at least partially on the textile.
  • compositions are particularly useful for their purpose when the substances mentioned in the embodiments according to the Textile treatment at least partially remain on the textile and, upon contact of the skin with the textile, are partially released to the skin.
  • the only factor is that the substances mentioned in contact textile / skin at least in traces on the skin.
  • a further preferred embodiment of this invention are thus textile treatment agents, which are characterized in that the skin-healing and / or skin-protecting active in the course of textile treatment with such an agent on the textile passes, at least partially remains on the textile and at least partially from the textile back to the Skin is released when the textile comes into contact with the skin.
  • the agents additionally contain urea and / or its derivatives.
  • Urea and / or its derivatives promote the health of the skin, as they can be antimicrobial, water-binding, quenching itching, dandruff, skin-smoothing and can inhibit excessive cell growth.
  • they can serve the skin as a moisturizing factor, i. H. they can help the skin to retain moisture.
  • the agents additionally contain lactic acid and / or citric acid and / or salts thereof.
  • These two skin-friendly acids and / or their salts are used, inter alia, to support or renew the natural acid mantle or hydrolipid film of the skin.
  • the hydrolipidic film of the skin is attacked or destroyed by alkaline influences, resulting in a loss of the barrier function of the skin, so that microorganisms or pollutants can more easily penetrate into the skin.
  • the lactic and / or citric acid in the compositions for example, residual alkali can be removed from the clothing and the pH of the textiles can be adjusted to a pH range around 5.
  • the additional lactic acid which is already part of the epidermis, additionally stabilizes the acidic pH of the skin (pH ca. 5.2) and serves as Moisturizing factor, as it can improve the water binding capacity of the skin. Furthermore, the lactic acid smoothes the skin and supports the detachment of dander.
  • the pH of the textile treatment agent is between 4 and 6.5, measured at a temperature of 20 ° C., in particular on a 1% strength aqueous solution of the textile treatment agent. This corresponds to the pH of the skin of a healthy person.
  • the skin surface is only weakly acidic (pH 5.5 - 6.5), just there is a reduced defenses against germs or bacteria, so that it is particularly advantageous in the context of the invention, if the pH of the fabric treatment agent is not greater than pH 5.5 measured at a temperature of 20 ° C.
  • Such a pH range is particularly advantageous with regard to a group of people with particularly sensitive skin, such as babies or toddlers, or a group of people with already existing skin problems, e.g. Allergy.
  • baby skin is significantly thinner than the skin of an adult human. Since the sebum production of the baby skin is significantly reduced, it has only an incomplete barrier function and a very thin hydrolipid film.
  • the advantage of using the textile treatment agent having a pH as described above is that textiles treated therewith are able to assist the skin's self-regulating powers in terms of its alkali neutralizing ability, in that the textile contacting the skin, such as a Abtrockentuch or underwear, has a skin-optimal pH.
  • the textile treatment agent or the laundry treated with it supports the natural skin flora of humans.
  • compositions may contain further moisturizing factors, for example those selected from the following group: amino acids, chitosan or chitosan salts / derivatives, ethylene glycol, glucosamine, glycerol, diglycerol, triglycerol, uric acid, honey and hardened honey , Creatinine, cleavage products of collagen, lactitol, polyols and polyol derivatives (for example, butylene glycol, Erythritol, propylene glycol, 1,2,6-hexanetriol, polyethylene glycols such as PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18, PEG-20), pyrrolidonecarboxylic acid, sugar and sugar derivatives (for example, fructose, glucose, maltose, maltitol, mannito
  • moisturizing factors for example those selected from the following group: amino
  • the textile treatment agent is used as a fabric softener.
  • the agents preferably contain small amounts of quaternary ammonium compounds, e.g. However, the agents preferably do not contain quaternary ammonium compounds, e.g. Esterquats as ingredients.
  • Ester quats are quaternary ammonium compounds in which hydrophobic groups are linked via ester bonds with a quaternized di- or tri-ethanolamine or an analogous compound.
  • the advantage of extensive to complete esterquat freedom or freedom from quaternary ammonium compounds results from their mode of action.
  • the characteristic softening achieved by using quaternary ammonium compounds or esterquats results from the fact that these substances are applied to the textile fibers.
  • the fabric treatment agent may contain nonionic fabric softening agents, such as silicone oils.
  • a particular advantage of the textile treatment agents is that, in a preferred embodiment, they act as fabric softeners, despite extensive or absolute freedom from quaternary ammonium compounds or esterquats.
  • ingredients of the fabric treatment agent that have been or are already listed, e.g. various oils, e.g. Almond oil, e.g. Hemp oil, e.g. Citric acid and / or lactic acid have some fasenreveichletsde properties or are effective in a meadow that sets a softer feel of textiles.
  • various oils e.g. Almond oil, e.g. Hemp oil, e.g. Citric acid and / or lactic acid have some fasenreveichletsde properties or are effective in a meadow that sets a softer feel of textiles.
  • the textile treatment agent contains an ironing relief agent and / or crease-reducing agent, for example those which will be mentioned elsewhere in the course of the description.
  • the advantage of this embodiment is that the ironing time can be reduced by the ease of ironing and crease reduction effect, so that the valuable ingredients of the textile treatment agent according to the invention are not exposed to excessive thermal stress by ironing, and thus retain their full effectiveness.
  • the textile treatment agent is reversibly fixed to a polymeric carrier, e.g. Adsorption forces, optionally with the participation of surfactants, so that a delayed release of the healing active ingredients is possible.
  • a polymeric carrier e.g. Adsorption forces
  • surfactants optionally with the participation of surfactants
  • Particularly preferred polymeric carriers belong to the class of silicic acid esters. However, it can also be any conceivable other carriers, with the only provisos that they allow delayed release of active ingredient and as such have no negative or irritating effect on the skin, if used in the context of this invention.
  • the textile treatment agent receives in addition to the curative active ingredients one or more deodorizing agents.
  • oils as such also have a deodorizing effect.
  • the particular advantage of adding one or more deodorizing agents to the fabric treatment agent is that these ingredients, together with the said oils, provide a particularly enhanced, because of synergistic, effect on deodorizing activity. The effect is only in one facet of the covering of evil-smelling or unpleasant odors.
  • an additional effect which is based on the synergistic interaction of the healing active ingredients according to the invention with the added deodorizing agent and the self-regulatory forces, so that not alone the symptom, the bad smell, but the smell triggering this moment is eliminated.
  • bacteria that are located on the skin or in hair or pubic hair in varying numbers. These bacteria can be proteins and fats, e.g. from body perspiration, decompose into foul-smelling sulfur compounds. These bacteria are effectively counteracted by the synergistic interaction of these factors.
  • the self-regulating powers of the skin are stimulated and trained.
  • the textile treatment agent is in the form of a microemulsion.
  • Emulsions are disperse systems of at least two immiscible liquids, one phase being dispersed in the form of fine droplets in the other continuous phase.
  • macroemulsions and microemulsions this invention encompassing both emulsion types.
  • microemulsions are particularly advantageous.
  • microemulsions in the disperse phase active ingredients can be much finer dispersed than in the disperse phase of macroemulsions. Another advantage is that they are well sprinkled due to their usually low viscosity.
  • the emulsions are prepared according to the classical procedures, e.g. by shaking, whipping, stirring, turbulent mixing, injecting one liquid into another, by emulsifying centrifuges, colloid mills, homogenizers, by vibration and cavitation in the mixture and many more.
  • the emulsions can also spontaneously form from the components.
  • the emulsions can be stabilized with so-called emulsifiers or stabilizers, so that a possible creaming or sedimentation or the tendency of the dispersed particles to agglomerate is difficult.
  • emulsifiers or stabilizers usually have an amphiphilic character, ie they have at least one polar and one nonpolar group, and there may also be a preponderance of the apolar group, which is referred to as co-emulsifiers.
  • Saturated or unsaturated, branched or unbranched alkyl radicals and aryl or alkylaryl radicals are generally used as nonpolar groups.
  • polar engroups occur carboxylate, sulfonate, sulfate, phosphate, polyphosphate, lactate, citrate, tartrate, amine salts, quaternary ammonium compounds, betaines, alcohol, polyethers, - glycerol, sorbitol, pentaerythritol, sucrose, acetic acid, Lactic acid residues, as polar intermediates function hydroxy, ester, sulfamide, amide, polyamide, polyamine, amine, ether, polyether, glycerol, sorbitol, pentaerythritol and sucrose groups, to only to name a few.
  • anionic, cationic, amphoteric and zwitterionic and nonionic emulsifiers which in principle can be used in the context of this invention, all of these emulsifiers and those that do not fit into the above categories.
  • a physiological and toxicological safety of the emulsifier when used according to the invention which is in accordance with the spirit of the invention, namely to give the skin an advantage.
  • Nonionic emulsifiers are preferably used.
  • all conceivable and customary emulsifying aids can advantageously be used.
  • Penetration accelerators include. These are substances that accelerate the penetration of the active ingredients from the textile into the skin. These are, for example, phenoxyethanol or phenylethanol.
  • the textile treatment agent is incorporated in a water-soluble packaging, preferably portioned in a disposable portion.
  • a water-soluble packaging preferably portioned in a disposable portion.
  • one-time serving means that amount of textile treatment agent which is required for a treatment process, in particular for a rinsing process, in particular in the machine.
  • disposable portions are each preferably incorporated in water-soluble packages. This has the advantage that the valuable ingredients of the agent are better protected from external influences.
  • the compositions in addition to the skin-protecting and / or skin-healing substances, contain one or more additional substances which have an effect on the human organism, e.g. have the respiratory organs and / or the human psyche.
  • additional substances may also be skin-functional in terms of the attributes according to the invention, but they do not need skin-healing and / or skin-protecting properties.
  • the olfactory bulb in the nose enter the essential oils of such substances into the limbic system of the brain.
  • the essential oils z. T. without the essential oils have previously been detected by the sense of smell, since the effective concentrations are often below the consciously noticeable concentration.
  • the classic fragrances listed above for the purposes of which it is essential that they are covered by the sense of smell. In this context according to the invention, however, it is not about the generation of a fragrance, but about the production of certain effects on the human organism.
  • For supportive, expectorant or cough-alleviating or decongestant treatment for flu, cough or bronchitis or other diseases of this type can be, for example, on the pajama top or a tissue cloth substances such. Apply benzoin, eucalyptus, thyme, lime, mint, grapefruit, lemon, petitgrain, bergamot, citronella, mountain pine, peppermint, hyssop or lavender. Thus, advantageously, the healing of the respiratory tract and the bronchi can be supported.
  • For the supportive treatment of difficulty falling asleep or nervous restlessness or depressive states of depression one can e.g. Apply substances such as camomile, lavender, melissa, neroli, sandalwood, rose, geranium, frankincense in the same way.
  • textiles that provide supportive treatment of skin diseases, e.g. Skin fungus (use of tea tree oil) or the physical dysfunctions, such as Hyperhidrosis (use of sage), counteract.
  • skin diseases e.g. Skin fungus (use of tea tree oil) or the physical dysfunctions, such as Hyperhidrosis (use of sage), counteract.
  • the textile treatment agents contain one or more of all those active ingredients which are described in U.S. Pat EP 0 789 070 A1 are disclosed active ingredients from the groups of waxes, the hydrophobic plant extracts, certain hydrocarbons, higher fatty acids and esters, essential oils, lipids, vitamins, sunscreens, phospholipids derivatives of alpha-hydroxy acids and / or mixtures of the aforementioned components in each case to the extent mentioned and even beyond this, at the same time no quaternary ammonium compounds or other relevant fabric softening compounds are included.
  • the textile treatment agents are surfactant-free.
  • the emulsion was prepared in a laboratory homogenizer (rotor-stator system, type Janke & Kunkel) at 30 ° C, then cooling to 20 ° C.
  • the mined starch is natural starch from rice, corn, wheat, potato, oats and the like. a., Preferably, partially hydrolyzed starch (acid or enzyme hydrolysis).
  • the solids citric acid, sodium citrate, urea and starch are dissolved successively with stirring at about 30 ° C. in the initially introduced water. Subsequently, the addition of the oils and the emulsifier (ethoxylated castor oil) takes place successively.
  • the emulsion is produced by using a homogenizer.
  • this emulsion can be carried out in all the ways described above in the context of a textile treatment.
  • Sebutapes® are applied at three points on the inside of the forearm or body parts where the textile / skin contact was present for one minute each. With a roller (1000g) is standardized six times rolled over the pasted area.
  • Sebutapes® To quantify the proteins on the Sebutapes®, they are each mixed with 1.5 ml of the lysis buffer (0.9% by weight NaCl + 0.1% by weight Triton X in double-distilled water). The treatment took place in 6 corrugated dishes, which were carefully closed with Parafilm. Each three plates are treated together in an ultrasonic bath for 10 minutes. The quantification of the total protein is carried out according to a common method, e.g. with the MicroBCA protein assay from Pierce according to the manufacturer's instructions.
  • the active substance is eluted from the sebum tapes with a suitable buffer.
  • the analysis is carried out by suitable methods (e.g., HPLC / GC / MS or others).
  • the active ingredients are extracted from the skin using a cotton pad with 2 ml of reagent grade ethanol.
  • a plastic ring with an inner diameter of 40 mm is placed on the skin, and extracted the skin area to be tested 3 times with circular motion.
  • the pad is placed in 8 ml units of analytical ethanol.
  • the quantification of the active substances then takes place, for example, via HPLC / GC / MS or other customary analytical methods.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
EP04717600.3A 2003-03-17 2004-03-05 Textilbehandlungsmittel Expired - Lifetime EP1603999B2 (de)

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DE10311852 2003-03-17
DE10311852A DE10311852A1 (de) 2003-03-17 2003-03-17 Textilbehandlungsmittel
PCT/EP2004/002232 WO2004083355A1 (de) 2003-03-17 2004-03-05 Textilbehandlungsmittel

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JP2006520434A (ja) 2006-09-07
WO2004083355A1 (de) 2004-09-30
PL1603999T3 (pl) 2013-11-29
US20060070189A1 (en) 2006-04-06
EP1603999A1 (de) 2005-12-14
JP4425268B2 (ja) 2010-03-03
ES2420931T3 (es) 2013-08-27
EP1603999B1 (de) 2013-06-19
PL1603999T5 (pl) 2017-09-29
ES2420931T5 (es) 2016-12-01
DE10311852A1 (de) 2004-10-14

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