EP1172229A1 - Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie - Google Patents

Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie Download PDF

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Publication number
EP1172229A1
EP1172229A1 EP00917315A EP00917315A EP1172229A1 EP 1172229 A1 EP1172229 A1 EP 1172229A1 EP 00917315 A EP00917315 A EP 00917315A EP 00917315 A EP00917315 A EP 00917315A EP 1172229 A1 EP1172229 A1 EP 1172229A1
Authority
EP
European Patent Office
Prior art keywords
heat sensitive
plate material
sensitive layer
hydrophilic polymer
lithography
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00917315A
Other languages
German (de)
English (en)
Other versions
EP1172229B1 (fr
EP1172229A4 (fr
Inventor
Youichiroh Ide
Hironobu Shirataki
Kei Tomeba
Taro Suzuki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujifilm Corp
Original Assignee
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Fuji Photo Film Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Corp, Asahi Chemical Industry Co Ltd, Fuji Photo Film Co Ltd filed Critical Asahi Kasei Corp
Publication of EP1172229A1 publication Critical patent/EP1172229A1/fr
Publication of EP1172229A4 publication Critical patent/EP1172229A4/fr
Application granted granted Critical
Publication of EP1172229B1 publication Critical patent/EP1172229B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/10Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
    • B41C1/1041Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by modification of the lithographic properties without removal or addition of material, e.g. by the mere generation of a lithographic pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/10Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
    • B41C1/1008Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
    • B41C1/1025Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials using materials comprising a polymeric matrix containing a polymeric particulate material, e.g. hydrophobic heat coalescing particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/04Negative working, i.e. the non-exposed (non-imaged) areas are removed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/20Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by inorganic additives, e.g. pigments, salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/24Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41NPRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N1/00Printing plates or foils; Materials therefor
    • B41N1/12Printing plates or foils; Materials therefor non-metallic other than stone, e.g. printing plates or foils comprising inorganic materials in an organic matrix
    • B41N1/14Lithographic printing foils

Definitions

  • polyvalent metal oxides adsorb the oleophilic component of the oleophilic area forming particles during the course of the plate making since they have high adsorbability, whereby the effects of enhancing the plate wear of the oleophilic area can be obtained.
  • the contact area of the hydrophilic polymer and the polyvalent metal oxide becomes small, whereby the effects as described above cannot sometimes be obtained satisfactorily.
  • the present invention provides a liquid heat sensitive material for use in making lithography characterized in that it includes: fine particles changed when heated and thereby forming an oleophilic area on the plate surface; a hydrophilic polymer having Lewis base moieties containing nitrogen, oxygen or sulfur; a polyvalent metal oxide; and a stabilizer for making the polyvalent metal oxide inert to the above hydrophilic polymer.
  • the liquid at room temperature not only the liquid at room temperature but also the heated or cooled liquid can be used.
  • the liquid temperature at the time of removing the stabilizer must be determined according to the bloating tendency and mechanical strength of the coat and the temperature characteristics of the oleophilic area forming particles so as to be within the range of not destroying the satisfactory characteristics thereof.
  • the previously formed coat contain the polyvalent metal oxide or the precursor thereof in the dispersed state
  • an aqueous solution or dispersion containing the polyvalent metal oxide or the precursor thereof is made to penetrate into the coat (heat sensitive layer) from its surface.
  • the solvent of the aqueous solution or the dispersion medium of the dispersion is evaporated from the coat.
  • any one of the above described processes may be adopted.
  • the molecular weight of the hydrophilic polymer added to the heat sensitive material is preferably 1,000 or more and 2,000,000 or less, more preferably 5,000 or more and 1, 000, 000 or less in terms of number average molecular weight. If the molecular weight is too low, the mechanical strength of the heat sensitive layer of the plate material cannot be ensured. If the molecular weight is too high, the viscosity of the heat sensitive material becomes high and thereby it becomes difficult to form a coat on a support by coating the same with the heat sensitive material.
  • the process for allowing the recording layer (heat sensitive layer) to contain a protective agent is, for example, as follows.
  • liquid heat sensitive material which contained microcapsules containing an oleophilic component (oleophilic area forming particles), a hydrophilic polymer having Lewis base moieties and water.
  • Propylene glycol alginate ester was added so as to improve the dispersion properties of the microcapsules in the heat sensitive material and make it easier to apply the heat sensitive material on the support.
  • a coat was formed on the surface of the same support as that of the plate material No. 1 by coating the same with the same heat sensitive material as No. 3 using a bar coater (rod number 20) and then it was air-dried at room temperature overnight to evaporate the water contained therein.
  • the support with the coat formed thereon was immersed in the above treatment liquid for 3 minutes and stood up vertically to be dried at 110°C for 5 minutes.
  • a plate material including: a support; and a heat sensitive layer containing the hydrophilic polymer (BP-A) having Lewis base moieties, the oleophilic area forming particles (microcapsules MC-A), the substance A, and polyacrylic acid as a protective agent was obtained as a plate material No. 8 for use in lithography.
  • the thickness of the obtained heat sensitive layer was 2.0 ⁇ m.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Thermal Sciences (AREA)
  • Printing Plates And Materials Therefor (AREA)
  • Materials For Photolithography (AREA)
EP00917315A 1999-04-15 2000-04-14 Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie Expired - Lifetime EP1172229B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP10752599 1999-04-15
JP10752599 1999-04-15
JP19279199 1999-07-07
JP19279199 1999-07-07
PCT/JP2000/002459 WO2000063026A1 (fr) 1999-04-15 2000-04-14 Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie

Publications (3)

Publication Number Publication Date
EP1172229A1 true EP1172229A1 (fr) 2002-01-16
EP1172229A4 EP1172229A4 (fr) 2009-03-04
EP1172229B1 EP1172229B1 (fr) 2011-08-24

Family

ID=26447550

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00917315A Expired - Lifetime EP1172229B1 (fr) 1999-04-15 2000-04-14 Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie

Country Status (9)

Country Link
US (1) US6821704B1 (fr)
EP (1) EP1172229B1 (fr)
JP (1) JP4020184B2 (fr)
KR (1) KR20010112426A (fr)
AU (1) AU3837500A (fr)
BR (1) BR0009710A (fr)
CA (1) CA2367401C (fr)
TW (1) TW524759B (fr)
WO (1) WO2000063026A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6805052B2 (en) 2000-12-20 2004-10-19 Agfa-Gevaert Printing system with a negative working thermal plate for onpress development
US6821704B1 (en) * 1999-04-15 2004-11-23 Fuji Photo Film Co., Ltd. Thermosensible plate material for forming lithography and method for preparing the same, liquid thermosensible plate material for forming lithography, and lithography
US6911298B2 (en) 2001-03-26 2005-06-28 Fuji Photo Film Co., Ltd. Thermosensitive plate material for lithographic plate formation, process for producing the same, coating fluid, and lithographic plate
US7316891B2 (en) 2002-03-06 2008-01-08 Agfa Graphics Nv Method of developing a heat-sensitive lithographic printing plate precursor with a gum solution

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1462247B1 (fr) * 2003-03-28 2008-05-07 Agfa Graphics N.V. Précurseur thermosensible de type positif pour plaque d'impression lithographique
JP6488023B2 (ja) * 2015-03-30 2019-03-20 ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC ハイブリッド粒子を含む透明感圧膜

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH071850A (ja) * 1993-04-22 1995-01-06 Asahi Chem Ind Co Ltd 新規な感熱ダイレクト平版原版とその製版方法
JPH071849A (ja) * 1993-04-20 1995-01-06 Asahi Chem Ind Co Ltd 平版印刷原版およびその製版方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR7506524A (pt) 1974-10-10 1976-08-17 Hoechst Ag Processo para a producao de impressao plana com raios laser
DE2607207C2 (de) 1976-02-23 1983-07-14 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Flachdruckformen mit Laserstrahlen
JPH0723030B2 (ja) 1986-01-16 1995-03-15 株式会社巴川製紙所 平版印刷原版およびその製版方法
JPS62164596A (ja) 1986-01-16 1987-07-21 Tomoegawa Paper Co Ltd 感熱性平版印刷原版およびその製版方法
JPH082701B2 (ja) 1986-09-04 1996-01-17 株式会社リコー 平版印刷用原版
JPH01113290A (ja) 1987-10-27 1989-05-01 Ricoh Co Ltd 感熱記録型平版印刷用原版
JPH03108588A (ja) 1989-09-22 1991-05-08 Toppan Printing Co Ltd 平版印刷用版材及び平版印刷版の製造方法
JPH058575A (ja) 1991-07-03 1993-01-19 Nippon Shokubai Co Ltd 平版印刷用原版
CN1077048C (zh) 1993-04-20 2002-01-02 旭化成株式会社 平版印刷原版及用其制版的方法
JPH106468A (ja) 1996-06-21 1998-01-13 Asahi Chem Ind Co Ltd 改良された感熱ダイレクト平版原版
JP3654473B2 (ja) 1996-10-15 2005-06-02 富士写真フイルム株式会社 改良された感熱ダイレクト平版原版の製造方法
WO1998029258A1 (fr) * 1996-12-26 1998-07-09 Asahi Kasei Kogyo Kabushiki Kaisha Plaque pour lithographie thermique directe et procede de production de cette plaque
US6014930A (en) 1997-07-25 2000-01-18 Kodak Polychrome Graphics Llc Single layer direct write lithographic printing plates
WO2000063026A1 (fr) * 1999-04-15 2000-10-26 Asahi Kasei Kabushiki Kaisha Materiau de plaque thermosensible pour fabriquer des lithographies et son procede de preparation, materiau de plaque thermosensible liquide pour fabriquer des lithographies, et lithographie

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH071849A (ja) * 1993-04-20 1995-01-06 Asahi Chem Ind Co Ltd 平版印刷原版およびその製版方法
JPH071850A (ja) * 1993-04-22 1995-01-06 Asahi Chem Ind Co Ltd 新規な感熱ダイレクト平版原版とその製版方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO0063026A1 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6821704B1 (en) * 1999-04-15 2004-11-23 Fuji Photo Film Co., Ltd. Thermosensible plate material for forming lithography and method for preparing the same, liquid thermosensible plate material for forming lithography, and lithography
US6805052B2 (en) 2000-12-20 2004-10-19 Agfa-Gevaert Printing system with a negative working thermal plate for onpress development
US6911298B2 (en) 2001-03-26 2005-06-28 Fuji Photo Film Co., Ltd. Thermosensitive plate material for lithographic plate formation, process for producing the same, coating fluid, and lithographic plate
US7316891B2 (en) 2002-03-06 2008-01-08 Agfa Graphics Nv Method of developing a heat-sensitive lithographic printing plate precursor with a gum solution

Also Published As

Publication number Publication date
BR0009710A (pt) 2002-01-08
CA2367401A1 (fr) 2000-10-26
WO2000063026A1 (fr) 2000-10-26
KR20010112426A (ko) 2001-12-20
EP1172229B1 (fr) 2011-08-24
AU3837500A (en) 2000-11-02
US6821704B1 (en) 2004-11-23
CA2367401C (fr) 2006-03-14
TW524759B (en) 2003-03-21
EP1172229A4 (fr) 2009-03-04
JP4020184B2 (ja) 2007-12-12

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