EP0762365A1 - Etiquette adhésive - Google Patents
Etiquette adhésive Download PDFInfo
- Publication number
- EP0762365A1 EP0762365A1 EP96113097A EP96113097A EP0762365A1 EP 0762365 A1 EP0762365 A1 EP 0762365A1 EP 96113097 A EP96113097 A EP 96113097A EP 96113097 A EP96113097 A EP 96113097A EP 0762365 A1 EP0762365 A1 EP 0762365A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- adhesive label
- cover film
- label according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 84
- 239000000853 adhesive Substances 0.000 title claims abstract description 81
- 239000010410 layer Substances 0.000 claims abstract description 187
- 230000002093 peripheral effect Effects 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000013039 cover film Substances 0.000 claims description 78
- 238000003475 lamination Methods 0.000 claims description 41
- 229910052751 metal Inorganic materials 0.000 claims description 41
- 239000002184 metal Substances 0.000 claims description 41
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 40
- 239000004922 lacquer Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 14
- 239000010408 film Substances 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 230000004888 barrier function Effects 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000004848 polyfunctional curative Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000976 ink Substances 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 238000007740 vapor deposition Methods 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 230000001699 photocatalysis Effects 0.000 claims description 2
- 230000000284 resting effect Effects 0.000 claims description 2
- 239000012790 adhesive layer Substances 0.000 abstract description 14
- 239000011888 foil Substances 0.000 description 10
- 239000012876 carrier material Substances 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 238000010292 electrical insulation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000012939 laminating adhesive Substances 0.000 description 3
- 239000005026 oriented polypropylene Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/08—Fastening or securing by means not forming part of the material of the label itself
- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2848—Three or more layers
Definitions
- the invention relates to an adhesive label for application to a circumferential surface of a dry cell battery having an axis and top and bottom end surfaces, comprising an stretched, shrinkable, transparent cover film with a top and a bottom, a print located under the cover film and visible from the top, and one the pressure-sensitive adhesive layer located under the print, the adhesive label having first edge sections which can be overlapped along a production line of the peripheral surface of the battery and second edge sections which project over the end faces of the battery and which lie on the end faces by shrinking of the cover film.
- the cover film forms a leak protection for the battery and also protects the label layers underneath, in particular the print, from mechanical damage.
- the cover film forms an electrical insulation of the peripheral surface of the battery from the environment. If a layer under the cover film is electrically conductive, the cover film isolates this layer from the environment.
- the aim of the invention is therefore to provide an adhesive label of the type mentioned, which in particular is easier to produce by another method. In particular, it should make it possible to meet different requirements of different battery designs with a greater variability of the layer structure.
- the print is applied directly to the underside of the cover film in the adhesive label according to the invention.
- the structure of the various layers of the adhesive label is based on the cover film.
- the cover film is printed immediately.
- the printed cover film can be placed on a composite of prepared label layers, but the further layers are preferably placed one after the other on the printed cover film. You get by with a single shrinkable film, the cover film.
- a layer is preferably applied to the print and to partial areas of the cover film which are free of the print and which in turn carries the pressure-sensitive adhesive layer on its underside.
- This layer carrying the pressure-sensitive adhesive can have a predominant carrier function have for the label material or a subordinate carrier function of the cover film.
- the layer carrying the pressure sensitive adhesive can lie directly on the print and on the partial areas of the cover film that are free of the print. Depending on the material combinations chosen, however, the adhesive connection between the layer carrying the pressure-sensitive adhesive and the cover film may not be sufficient under unfavorable conditions.
- a transparent primer layer is preferably applied to the printed cover film, preferably thermosensitive, and in turn the layer carrying the pressure-sensitive adhesive.
- the pressure-sensitive adhesive-bearing layer can be formed from non-metallic materials such as paper or plastic, whereby it is preferably limited to the partial areas of the pressure-sensitive label excluded from the second edge sections and thus corresponds exactly to the length of the peripheral surface of the battery.
- the layer carrying the pressure-sensitive adhesive can also be formed from metallic material, in particular from aluminum vapor deposition applied in a vacuum. The choice of material also depends on the desired appearance of the label, because the layer carrying the pressure sensitive adhesive forms a background for the print that is visible from the outside.
- the layer bearing pressure-sensitive adhesive can be formed from a composite of a lower, non-metallic partial layer, in particular paper, and a metallic partial layer, in particular aluminum foil, lying thereon, wherein it is preferably limited to the partial areas of the adhesive label that are excluded from the second edge sections, and thus corresponds exactly to the height of the battery cylinder of the battery.
- a particularly thin aluminum foil is used without the strength of the adhesive label being impaired, in particular when using a very thin cover foil.
- the metallic partial layer is preferably applied as a foil to the non-metallic partial layer in the foil transfer process, vapor-deposited or sputtered onto the latter.
- the pressure-sensitive adhesive layer lies directly on the print and on partial areas of the cover film that are free of the print.
- the layer carrying the pressure-sensitive adhesive of the above statements is omitted.
- the cover film is the only solid layer of the label and only takes on the carrier function. This version can be made particularly thin because of the small number of layers, which increases the space available for the battery filling of the standard dimensions dry cell battery.
- the print is preferably printed on the cover film in colors from the organic solution or solvent-free photocatalytic system in mirror-image reverse printing, i.e. a mirror image from below directly onto the cover film, so that the print can be seen from the top in the correct direction.
- These ink systems are particularly suitable for printing on the shrinkable film without changing or detaching from the film during the shrinking process.
- they have the electrical properties required for dry cell batteries and are resistant to chemicals, which is particularly important with regard to the leakage protection function of the battery label.
- the cover film is preferably made of shrinkable rigid PVC, polypropylene, polystyrene, polyamide, in particular a thickness of 25 to 60 micrometers, or polyethylene terephthalate, or polycarbonate, in particular a thickness of 10 to 60 micrometers. So that the adhesive label adheres as firmly as possible to the battery after shrink-fitting and the adhesive label does not detach from the body of the battery even under unfavorable environmental conditions, the cover film has been stretched in the circumferential direction of the dry cell battery, so that after the shrink-fitting, the adhesive label has the greatest pretension in the circumferential direction.
- Fig. 2 shows a schematic section of a first embodiment of the adhesive label.
- a cover film 3 made of stretched, shrinkable, transparent film made of hard PVC (polyvinyl chloride), PP (polypropylene), OPP (oriented polypropylene), PET (polyethylene terephthalate), PS (polystyrene), PE (polyethylene), PC ( Polycarbonate) or polyamide with a thickness of 20 to 70 microns underside directly with one from the outside visible imprint 5 provided.
- thicknesses of 10 to 60 ⁇ m are preferred.
- the cover film is provided with an adhesion-promoting primer layer 3a as a pressure improver with a thickness of approximately 2 ⁇ m before application of the print 5 Mistake.
- the primer layer 3a increases the surface tension.
- the cover film 3 can be polarized in the high-frequency field with carboxyl formation (corona treatment).
- the cover film 3, the primer layer 3a and the print 5 are permanently elastic, so that the label can be shrunk onto a battery even after storage for several months without the print 5 detaching from the cover film 3.
- the cover film 3 is the only shrinkable plastic film layer of the adhesive label. It can have additional layers on the top and bottom.
- the print 5 and partial areas of the cover film 3 free of the print are vapor-coated or sputtered with a metal layer 7, in particular made of aluminum.
- the metal layer 7 forms a background for the imprint 5 which is visible from the outside and is electrically insulated from the outside by the cover film 3.
- a non-metallic layer 9 made of plastic film or paper is applied to the underside of the metal layer 7. The metal layer 7 and the non-metallic layer 9 together form a carrier material 11 of the label 1.
- the metal layer 7 can be applied separately from the cover film 3 to the non-metallic layer 9, for example by vapor deposition or sputtering, and the carrier material 11 resulting from these two sub-layers 7, 9 becomes - optionally by means of a primer layer - on the printed underside of the cover film 3 attached in particular by exposure to heat.
- the carrier material 11 is provided on the underside with pressure-sensitive adhesive 13, and the thus finished label 1 is placed on an adhesive-repellent, approximately siliconized carrier tape 15, from which it is later transferred to a battery body by means of a dispensing device, not shown.
- the imprint 5 is shown only schematically with spaces.
- the imprint 5 can also be closed over the entire area, multi-colored, multi-layered, a combination of opaque printing inks and / or opaque printing inks.
- FIG. 1 schematically shows the application of the adhesive label 1 to a cylindrical battery body 50 of a rechargeable or non-rechargeable dry cell or device battery.
- the adhesive label 1 is placed with its adhesive layer 13 on the circumference of the battery body 50 in such a way that its non-printed and non-printed longitudinal edges 17 protrude beyond end faces 51, 51 of the battery body 50, in particular the stretching direction of the cover film 3 in the circumferential direction of the battery body 50 runs. Then the adhesive label 1 is placed around the circumference of the battery body 50 so that end regions 19, 19 of the adhesive label 1 overlap one another.
- the adhesive label 1 is then shrunk onto the battery body 50 under the influence of heat, so that the longitudinal edges 17 rest on the end faces 51, 51 of the battery body 50 and additionally adhere to the end faces 51, 51 by means of the pressure sensitive adhesive 13. Due to the overlapping end regions 19, 19 and the longitudinal edges 17 resting on the end faces of the battery body 50, the adhesive label encapsulates the battery body 50 and forms a leakage protection in addition to the electrical insulation of the cell.
- the outer cover layer 3 protects the layers below from damage, in particular during the manufacturing process of the battery from the application of the Labels up to the packaging of the finished battery and also withstands mechanical stress in the battery layers of the devices used.
- FIG. 3 shows a second embodiment of the adhesive label 1. It differs from the embodiment according to FIG. 2 in that the carrier material 11 has one layer. If the carrier material 11 is made of metal, such as aluminum, it can be sputtered or evaporated onto the printed underside of the cover film 3, for example to a thickness of 2 to 7 ⁇ . Alternatively, the metal layer 11 can be applied separately from the cover film 3 to a support, not shown, from which it is then transferred to the print 5 by means of a thermosensitive intermediate layer. As a system-related aid, this carrier preferably represents a film which is pulled off and rolled up again after the transfer of the metal layer, and is therefore no longer incorporated into the layer structure. The pressure sensitive adhesive 13 is applied directly to the metal layer 11. Here too, if necessary, the cover film 3 can be provided with a primer layer 3a before printing or subjected to a high-frequency treatment.
- the carrier material 11 has one layer. If the carrier material 11 is made of metal, such as aluminum, it can be sputtered or evaporated onto the
- FIG. 4 shows a third embodiment of the adhesive label 1 similar to that in FIG. 3 with a single-layer carrier material 11.
- the carrier material 11 is made of paper or plastic and is applied to the printed underside of the cover film 3 by means of an intermediate liner layer 21.
- the lamination layer 21 is applied as a lacquer or adhesive in the liquid or semi-liquid phase and hardens by chemical reaction of the binder and hardener constituents, by radiation or / and by the release of solvents.
- the lamination layer 21 can be pigmented when the overprint is not closed over a large area and form an optical background for the overprint 5.
- the liner layer 21 improves the adhesion of the carrier material 11 to the printed underside of the cover film 3.
- the liner layer 21 has a thickness of 3.5 to 5 ⁇ m, corresponding to 2.5-4 g / m 2, and forms a barrier against immigration of solvents the underlying adhesive layer 13 in the print and thereby its change in long storage time.
- the liner layer 21 is an additional barrier against migration of electrolyte and at the same time improves the electrical insulation properties of the label without the need for an additional insulation layer.
- the cover film 3 can be provided with a primer layer 3a before printing or subjected to a high-frequency treatment.
- Fig. 5 shows a fourth embodiment.
- the cover film 3 is provided with the imprint 5 directly on its underside.
- the adhesive layer 13 is applied directly to the printed underside of the cover film 3.
- the cover film 3 assumes the sole carrier function of the adhesive label here.
- the imprint 5 can be closed flat so that the surface of the battery body underneath cannot be seen.
- the imprint 5 improves the electrical insulation of the label and prevents diffusion of solvents from the adhesive layer 13 or of electrolyte residues on the battery surface.
- the adhesive layer 13 can be colored and then forms an optical background for a non-planar, closed opaque print.
- the cover film 3 can be provided with a primer layer 3a before printing or subjected to a high-frequency treatment.
- FIG. 6 shows a fifth embodiment similar to FIG. 5, the imprint 5 of which, however, bears a laminating layer 21 on the underside similar to the embodiment of FIG. 4.
- the lamination layer 21 is applied as a lacquer or adhesive in the liquid or semi-liquid phase and hardens by chemical reaction of the binder and hardener constituents, by radiation or / and by the release of solvents.
- the lamination layer 21 can be pigmented when the overprint is not closed over a large area and form an optical background for the overprint 5.
- the lamination layer 21 has the function of a barrier against diffusion of solvents from the adhesive layer 13 applied on the underside to the lamination layer 21 and of electrolytes on the surface of the battery body in the imprint 5 and protects it from change. This improves the durability and shelf life of the label even under unfavorable conditions such as high temperature and humidity.
- the cover film 3 can be provided with a primer layer 3a before printing or subjected to a high-frequency treatment.
- Fig. 7 shows a sixth embodiment.
- the cover layer 3, the primer layer 3a which may be present in the case of a non-polar film and the imprint 5 correspond to the embodiment in FIG. 3.
- the lamination layer 21 improves the adhesion of a metal layer 11, for example made of aluminum, applied to it, in accordance with the embodiment of FIG. 3.
- This metal layer 11 is sputtered or evaporated with a thickness of 2-7 ⁇ . Because of the micropartial layering of metal particles, the metal layer 11 is porous and has a significantly higher electrical resistance than metal foil.
- the metal layer 11 additionally covers inevitable impurities and stains on the battery body 50.
- the metal layer 11 can also be transferred to the lamination layer 21 as a film in the transfer process.
- a metal foil 11 adhering to its own carrier tape is placed on the more strongly adhering lamination layer 21. Then the weakly adhering carrier tape is peeled off from the metal layer firmly adhering to the label material.
- the lamination layer 21 forms a flexible connection between the metal layer 11 and the cover film 3.
- This flexible connection prevents the film from shrinking and Labeling on tight radii of the battery body will distort the metal layer.
- the flexible connection absorbs shear forces and tension in the label.
- the flexible connection forms the barrier described above for FIG. 4, which prevents solvents from the pressure-sensitive adhesive 13, which may have penetrated into the pores of the metal layer 11, from immigrating and changing the print, and which improves the electrical insulation, in particular .
- the laminating adhesive 21 which has penetrated into the pores of the metal layer solidifies the metal layer.
- the lamination layer 21 can be a lacquer which solidifies after application in a liquid or semi-liquid state by chemical reaction of binder and hardener constituents, radiation or / and by evaporation of solvents. Before the metal layer 11 is sputtered on or vapor-deposited, the lamination layer 21 can be solidified. In the case of a metal foil being deposited, for example in the foil transfer process, the metal foil can be placed on the as yet unconsolidated lamination layer 21 in order to utilize the adhesive effect of the as yet unconsolidated lacquer.
- the lamination layer 21 can contain pigments to form an optical background for the imprint 5.
- the adhesive layer 13 has a thickness of 10 to 25 ⁇ m and electrically insulates the metal layer 11 from the battery body 50.
- the adhesive layer 13 can be thinner than 15 ⁇ m because the lamination layer 21 is also insulating Has properties.
- the pressure-sensitive adhesive 13 that has penetrated into the pores of the metal layer 11 insulates the pores and thus increases the electrical resistance of the metal layer 11.
- the adhesion of the individual label layers in the overlap area 19 (FIG. 1) of the adhesive label must be such that at the label on the battery body 50 the tension of the shrunk cover film 3 does not tear open the lamination layer 21.
- the laminating adhesive 21 is preferably a two-component adhesive or varnish with a binder and hardener, and the pressure-sensitive adhesive 13 generally represents a permanently elastic one-component adhesive with stabilizers such as antioxidants, which prevent hardening and thus chipping as a result of a surface breakage and at the same time high shear force in the contact area .
- the lamination layer 21 adheres more strongly in the hardened state than the non-hardening and thus permanently elastic pressure-sensitive adhesive 13.
- the adhesive effect of the pressure-sensitive adhesive 13 in the overlap region 19 with the cover film 3 is adapted to the adhesive effect with the battery body 50 between the overlap regions so that the overlap bursts open 19 is prevented.
- FIG. 8 shows a seventh embodiment which differs from the embodiment of FIG. 7 in terms of the layer structure between the imprint 5 and the metal layer 11, but otherwise is identical to the embodiment of FIG. 7 with all of its embodiment variants.
- a coating layer 22 is applied to the underside of the lamination layer 21, which is harder and / or denser than the lamination layer 21 and the barrier function described in FIG. 7 against the migration of solvents from the adhesive layer 13 or from electrolytes of the battery surface into the print 5 takes over. Because of its strength, the lacquer layer 22 can be sputtered or vaporized with metal and prevents the passage of such solvents from the adhesive layer 13 and from electrolytes of the battery surface which have already penetrated the pores of the metal layer 11.
- the lamination layer 21 and / or the lacquer layer 22 can be pigmented and form an optical background for the print.
- FIG. 9 shows an eighth embodiment similar to FIGS. 7 and 8, but with a modified lamination layer 21 which, in terms of its components, can be designed in accordance with the embodiment of FIG. 7.
- the lamination layer 21 is applied in the liquid or semi-liquid state to the imprint 5 and then partially solidified by curing the binder and hardener components, irradiation and / or evaporation of solvent in such a way that one flexible sublayer 21a lying on the imprint 5 and one of the imprint 5 forms distant, harder sublayer 21b, which can subsequently be sputtered or vaporized particularly well with the metal layer 11.
- the flexible partial layer 21a serves as a flexible connection between the cover film 3 and the metal layer 11, with the effect of the lamination layer 21 of the embodiment of FIG.
- the harder partial layer 21b forms the barrier layer with the effect of the lacquer layer 22 of the embodiment of FIG Immigration of solvent from the adhesive layer 13 and of electrolytes of the battery surface through pores of the metal layer 11 into the print 5.
- the lamination layer 21 and / or the lacquer layer 22 can be pigmented to form an optical background for the print 5.
- a large number of adhesive labels releasably adhere to a siliconized carrier tape 15.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99113150A EP0947971B1 (fr) | 1995-08-16 | 1996-08-14 | Etiquette adhésive |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE29513170U DE29513170U1 (de) | 1995-08-16 | 1995-08-16 | Haftetikett |
DE29513170U | 1995-08-16 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99113150A Division EP0947971B1 (fr) | 1995-08-16 | 1996-08-14 | Etiquette adhésive |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0762365A1 true EP0762365A1 (fr) | 1997-03-12 |
EP0762365B1 EP0762365B1 (fr) | 2000-06-28 |
Family
ID=8011845
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96113097A Expired - Lifetime EP0762365B1 (fr) | 1995-08-16 | 1996-08-14 | Etiquette adhésive |
EP99113150A Expired - Lifetime EP0947971B1 (fr) | 1995-08-16 | 1996-08-14 | Etiquette adhésive |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99113150A Expired - Lifetime EP0947971B1 (fr) | 1995-08-16 | 1996-08-14 | Etiquette adhésive |
Country Status (10)
Country | Link |
---|---|
US (1) | US6248427B1 (fr) |
EP (2) | EP0762365B1 (fr) |
JP (1) | JP2869963B2 (fr) |
CN (1) | CN1107299C (fr) |
AT (2) | ATE215721T1 (fr) |
CA (1) | CA2183593C (fr) |
DE (3) | DE29513170U1 (fr) |
DK (2) | DK0947971T3 (fr) |
EA (1) | EA000086B1 (fr) |
HK (2) | HK1009302A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999050811A2 (fr) * | 1998-03-27 | 1999-10-07 | Steinbeis Ppl Gmbh | Etiquette de securite a caracteristique garantissant l'inviolabilite |
WO2009156588A1 (fr) * | 2008-06-25 | 2009-12-30 | Upm Raflatac Oy | Étiquette pour batterie et batterie |
CN102029683A (zh) * | 2010-10-20 | 2011-04-27 | 天津市中环高科技有限公司 | 镶嵌式金属装饰件应用于模内贴标的工艺 |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE29513170U1 (de) | 1995-08-16 | 1997-01-02 | Zweckform Etikettiertechnik | Haftetikett |
US6537634B2 (en) * | 1999-12-29 | 2003-03-25 | Tesa Ag | Adhesive security tape for detecting unauthorized broaching of a package |
US20020092607A1 (en) * | 2001-01-17 | 2002-07-18 | Hassenzahl Steven Lee | Label with adhesive on two sides |
US7316832B2 (en) | 2001-12-20 | 2008-01-08 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US7709070B2 (en) | 2001-12-20 | 2010-05-04 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US7299657B2 (en) * | 2002-07-12 | 2007-11-27 | Corning Incorporated | Method of making high strain point glass |
US6883286B2 (en) * | 2002-11-08 | 2005-04-26 | Wright Of Thomasville, Inc. | Flooring display panel with durable label |
US20040185235A1 (en) * | 2003-02-06 | 2004-09-23 | Philip Emery | Shrinkable battery label |
US20040161564A1 (en) | 2003-02-14 | 2004-08-19 | Truog Keith L. | Dry paint transfer laminate |
BRPI0407483A (pt) | 2003-02-14 | 2006-02-14 | Avery Dennison Corp | laminado decorativo de tinta seca de multi-camada tendo barreira de prevenção à descoloração |
DE10317577A1 (de) * | 2003-04-16 | 2004-10-28 | Steinbeis Ibl Gmbh | Etikett mit korrosionsgeschützter Metallisierungsschicht |
US20050196607A1 (en) | 2003-06-09 | 2005-09-08 | Shih Frank Y. | Multi-layer dry paint decorative laminate having discoloration prevention barrier |
US20040247837A1 (en) * | 2003-06-09 | 2004-12-09 | Howard Enlow | Multilayer film |
CA2512659A1 (fr) * | 2004-02-13 | 2005-08-13 | The Procter & Gamble Company | Articles resistant a la decoloration pour l'application de couleurs sur des surfaces, et methodes de reduction de la decoloration des articles pour l'application de couleurs sur des surfaces |
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JP6444155B2 (ja) * | 2014-12-10 | 2018-12-26 | 株式会社フジシール | 筒状ラベル |
CN110428723A (zh) * | 2019-08-01 | 2019-11-08 | 王炳阳 | 一种无底纸免不干胶的干电池标签膜及干电池标签的包装方法 |
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- 1996-08-12 CN CN96111657A patent/CN1107299C/zh not_active Expired - Fee Related
- 1996-08-14 DK DK99113150T patent/DK0947971T3/da active
- 1996-08-14 AT AT99113150T patent/ATE215721T1/de active
- 1996-08-14 AT AT96113097T patent/ATE194246T1/de active
- 1996-08-14 DE DE59609038T patent/DE59609038D1/de not_active Expired - Lifetime
- 1996-08-14 EP EP96113097A patent/EP0762365B1/fr not_active Expired - Lifetime
- 1996-08-14 DE DE59605489T patent/DE59605489D1/de not_active Expired - Lifetime
- 1996-08-14 DK DK96113097T patent/DK0762365T3/da active
- 1996-08-14 EP EP99113150A patent/EP0947971B1/fr not_active Expired - Lifetime
- 1996-08-15 EA EA199600054A patent/EA000086B1/ru not_active IP Right Cessation
- 1996-08-15 CA CA002183593A patent/CA2183593C/fr not_active Expired - Fee Related
- 1996-08-16 JP JP8233677A patent/JP2869963B2/ja not_active Expired - Fee Related
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1998
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999050811A2 (fr) * | 1998-03-27 | 1999-10-07 | Steinbeis Ppl Gmbh | Etiquette de securite a caracteristique garantissant l'inviolabilite |
WO1999050811A3 (fr) * | 1998-03-27 | 1999-12-02 | Steinbeis Ppl Gmbh | Etiquette de securite a caracteristique garantissant l'inviolabilite |
WO2009156588A1 (fr) * | 2008-06-25 | 2009-12-30 | Upm Raflatac Oy | Étiquette pour batterie et batterie |
CN102029683A (zh) * | 2010-10-20 | 2011-04-27 | 天津市中环高科技有限公司 | 镶嵌式金属装饰件应用于模内贴标的工艺 |
Also Published As
Publication number | Publication date |
---|---|
ATE194246T1 (de) | 2000-07-15 |
HK1020634A1 (en) | 2000-05-12 |
DE29513170U1 (de) | 1997-01-02 |
DK0762365T3 (da) | 2000-10-30 |
CN1151059A (zh) | 1997-06-04 |
EA199600054A1 (ru) | 1997-03-31 |
DE59609038D1 (de) | 2002-05-08 |
CA2183593C (fr) | 2000-03-28 |
HK1009302A1 (en) | 1999-05-28 |
US6248427B1 (en) | 2001-06-19 |
JPH10301496A (ja) | 1998-11-13 |
CN1107299C (zh) | 2003-04-30 |
EA000086B1 (ru) | 1998-06-25 |
CA2183593A1 (fr) | 1997-02-17 |
DE59605489D1 (de) | 2000-08-03 |
EP0947971B1 (fr) | 2002-04-03 |
EP0947971A3 (fr) | 1999-11-10 |
ATE215721T1 (de) | 2002-04-15 |
DK0947971T3 (da) | 2002-07-08 |
EP0762365B1 (fr) | 2000-06-28 |
JP2869963B2 (ja) | 1999-03-10 |
EP0947971A2 (fr) | 1999-10-06 |
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