DK0422185T4 - Carboxylsyreesterholdige væskeblandinger - Google Patents

Carboxylsyreesterholdige væskeblandinger

Info

Publication number
DK0422185T4
DK0422185T4 DK90906641T DK90906641T DK0422185T4 DK 0422185 T4 DK0422185 T4 DK 0422185T4 DK 90906641 T DK90906641 T DK 90906641T DK 90906641 T DK90906641 T DK 90906641T DK 0422185 T4 DK0422185 T4 DK 0422185T4
Authority
DK
Denmark
Prior art keywords
carboxylic acid
acid ester
containing liquid
ester containing
liquid mixtures
Prior art date
Application number
DK90906641T
Other languages
Danish (da)
English (en)
Other versions
DK0422185T3 (da
Inventor
Scott Ted Jolley
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23344653&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK0422185(T4) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of DK0422185T3 publication Critical patent/DK0422185T3/da
Application granted granted Critical
Publication of DK0422185T4 publication Critical patent/DK0422185T4/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C10M105/38—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008—Lubricant compositions compatible with refrigerants
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/24—Only one single fluoro component present
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/34—Lubricating-sealants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Lubricants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Optical Communication System (AREA)
  • Stereo-Broadcasting Methods (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
DK90906641T 1989-04-25 1990-04-17 Carboxylsyreesterholdige væskeblandinger DK0422185T4 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US34308789A 1989-04-25 1989-04-25
PCT/US1990/002069 WO1990012849A1 (en) 1989-04-25 1990-04-17 Liquid compositions containing carboxylic esters

Publications (2)

Publication Number Publication Date
DK0422185T3 DK0422185T3 (da) 1995-08-14
DK0422185T4 true DK0422185T4 (da) 2008-11-10

Family

ID=23344653

Family Applications (1)

Application Number Title Priority Date Filing Date
DK90906641T DK0422185T4 (da) 1989-04-25 1990-04-17 Carboxylsyreesterholdige væskeblandinger

Country Status (16)

Country Link
EP (1) EP0422185B2 (no)
JP (3) JP2624893B2 (no)
AT (1) ATE123797T1 (no)
AU (1) AU638710B2 (no)
BR (1) BR9006748A (no)
CA (1) CA2015204C (no)
DE (2) DE69020085T3 (no)
DK (1) DK0422185T4 (no)
ES (1) ES2034938T5 (no)
FI (1) FI102082B (no)
HK (1) HK53896A (no)
IL (1) IL94139A0 (no)
MX (1) MX172846B (no)
NO (1) NO300739B1 (no)
WO (1) WO1990012849A1 (no)
ZA (1) ZA903096B (no)

Families Citing this family (74)

* Cited by examiner, † Cited by third party
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US6998065B1 (en) * 1989-12-28 2006-02-14 Nippon Mitsubishi Oil Corporation Fluid compositions containing refrigerator oils and chlorine-free fluorocarbon refrigerants
US6153118A (en) * 1989-12-28 2000-11-28 Nippon Mitsubishi Oil Corp. Fluid compositions containing refrigerator oils and chlorine-free fluorocarbon refrigerants
JPH03217494A (ja) * 1990-01-22 1991-09-25 Kao Corp 冷凍機油
DE69125518T2 (de) * 1990-01-31 1997-11-13 Tonen Corp Ester als Schmiermittel für Haloalkangefriermittel
DE4006827A1 (de) * 1990-03-05 1991-09-12 Hoechst Ag Verwendung von esteroelen als schmiermittel fuer kaeltemittelverdichter
DE4006828A1 (de) * 1990-03-05 1991-09-12 Hoechst Ag Verwendung von komplexen esteroelen als schmiermittel fuer kaeltemittelverdichter
JPH03275799A (ja) * 1990-03-23 1991-12-06 Asahi Denka Kogyo Kk 冷凍機油組成物
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JP2911629B2 (ja) * 1991-03-29 1999-06-23 出光興産株式会社 冷凍機油組成物
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DE4128647A1 (de) * 1991-08-29 1993-03-11 Henkel Kgaa Verwendung von isopalmitinsaeureestern als schmiermittel fuer zweitaktmotoren
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EP0536940B1 (en) 1991-10-11 2001-11-21 Imperial Chemical Industries Plc Working fluids
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US5399279A (en) * 1991-12-23 1995-03-21 Albemarle Corporation Refrigeration compositions
JPH05255680A (ja) * 1992-01-13 1993-10-05 Mitsui Petrochem Ind Ltd ポリカーボネートおよびその用途
US5374366A (en) * 1992-04-15 1994-12-20 Sanken Chemical Co., Ltd. Synthetic lubricating oil
JPH07507345A (ja) * 1992-06-03 1995-08-10 ヘンケル・コーポレイション 高温で運転する冷凍コンプレッサー用ポリオールエステル潤滑剤
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US6183662B1 (en) * 1992-06-03 2001-02-06 Henkel Corporation Polyol ester lubricants, especially those compatible with mineral oils, for refrigerating compressors operating at high temperatures
ATE195545T1 (de) * 1992-06-03 2000-09-15 Henkel Corp Schmiermittel auf basis von polyolester für kälteübertragungsmittel
JP2613526B2 (ja) 1992-07-04 1997-05-28 花王株式会社 冷凍機作動流体用組成物
US5830833A (en) * 1992-08-18 1998-11-03 Rwe-Dea Aktiengesellschaft Fur Mineraloel Und Chemie And Texaco Deutschland Gmbh Synthetic ester lubricants for refrigerator systems
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IL108066A0 (en) * 1993-01-07 1994-04-12 Exxon Chemical Patents Inc Refrigeration working fluid compositions containing difluoroethane or pentafluoroethane
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DE69414185T2 (de) * 1993-06-30 1999-04-22 Nof Corp Synthetisches Schmieröl und Arbeitsmittelzusammensetzung für Kältemaschinen
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US5720895A (en) 1994-08-11 1998-02-24 Kao Corporation Polyol ether derivatives and production methods therefor
US5866030A (en) * 1994-09-07 1999-02-02 Witco Corporation Enhanced hydrocarbon lubricants for use with immiscible refrigerants
US5792383A (en) * 1994-09-07 1998-08-11 Witco Corporation Reduction of enterfacial tension between hydrocarbon lubricant and immiscible liquid refrigerant
US5746933A (en) 1994-11-07 1998-05-05 Nippon Oil Co., Ltd. Lubricating oil and composition for refrigerating machine, and refrigerating machine
US5711895A (en) 1994-12-12 1998-01-27 Nippon Oil Co., Ltd. Fluid composition for use in a refrigerating machine in which the refrigerating machine oil is at least one hydrocarbon compound of a formula consisting of two phenyl groups joined through an alkylene or alkenylene group
CN1062593C (zh) * 1995-03-01 2001-02-28 三菱瓦斯化学株式会社 多羟基酯基润滑剂及其生产方法
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US5705086A (en) * 1996-04-16 1998-01-06 Mobil Oil Corporation Refrigeration oils comprising esters of hindered alcohols
CA2251388A1 (en) * 1997-10-30 1999-04-30 The Lubrizol Corporation Low viscosity energy efficient polyol-ester based refrigerant containing polyether and antioxidant with or without a phosphate
JP4564111B2 (ja) 1998-09-02 2010-10-20 Ｊｘ日鉱日石エネルギー株式会社 冷凍機油
US6374629B1 (en) * 1999-01-25 2002-04-23 The Lubrizol Corporation Lubricant refrigerant composition for hydrofluorocarbon (HFC) refrigerants
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DE69020085D1 (de) 1995-07-20
ES2034938T1 (es) 1993-04-16
JPH10251678A (ja) 1998-09-22
AU638710B2 (en) 1993-07-08
CA2015204C (en) 1998-02-10
FI102082B1 (fi) 1998-10-15
JPH09111229A (ja) 1997-04-28
JPH03505602A (ja) 1991-12-05
NO300739B1 (no) 1997-07-14
NO905529D0 (no) 1990-12-20
DE69020085T3 (de) 2010-04-22
DK0422185T3 (da) 1995-08-14
CA2015204A1 (en) 1990-10-25
ES2034938T5 (es) 2009-01-16
DE69020085T2 (de) 1995-12-21
FI906146A0 (fi) 1990-12-13
WO1990012849A1 (en) 1990-11-01
BR9006748A (pt) 1991-08-06
ES2034938T3 (es) 1995-10-16
AU5448090A (en) 1990-11-16
EP0422185A1 (en) 1991-04-17
NO905529L (no) 1991-02-14
JP2624893B2 (ja) 1997-06-25
HK53896A (en) 1996-04-03
ATE123797T1 (de) 1995-06-15
JP2895001B2 (ja) 1999-05-24
IL94139A0 (en) 1991-01-31
EP0422185B1 (en) 1995-06-14
FI102082B (fi) 1998-10-15
DE422185T1 (de) 1992-11-26
EP0422185B2 (en) 2008-08-06
ZA903096B (en) 1991-02-27
MX172846B (es) 1994-01-17

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