DE60010469D1 - Transparente mikrokugeln - Google Patents

Transparente mikrokugeln

Info

Publication number
DE60010469D1
DE60010469D1 DE60010469T DE60010469T DE60010469D1 DE 60010469 D1 DE60010469 D1 DE 60010469D1 DE 60010469 T DE60010469 T DE 60010469T DE 60010469 T DE60010469 T DE 60010469T DE 60010469 D1 DE60010469 D1 DE 60010469D1
Authority
DE
Germany
Prior art keywords
transparent
microballs
zirconia
silica
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60010469T
Other languages
English (en)
Other versions
DE60010469T2 (de
Inventor
D Budd
Toshihiro Kasai
B Roscoe
Chikafumi Yokoyama
E Bailey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of DE60010469D1 publication Critical patent/DE60010469D1/de
Application granted granted Critical
Publication of DE60010469T2 publication Critical patent/DE60010469T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00Powdered glass; Bead compositions
    • C03C12/02Reflective beads
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/773Nanoparticle, i.e. structure having three dimensions of 100 nm or less
    • Y10S977/775Nanosized powder or flake, e.g. nanosized catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/773Nanoparticle, i.e. structure having three dimensions of 100 nm or less
    • Y10S977/775Nanosized powder or flake, e.g. nanosized catalyst
    • Y10S977/776Ceramic powder or flake
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Glass Compositions (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Silicon Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Liquid Crystal Substances (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
DE60010469T 1999-07-27 2000-07-05 Transparente mikrokugeln Expired - Lifetime DE60010469T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/362,323 US6245700B1 (en) 1999-07-27 1999-07-27 Transparent microspheres
US362323 1999-07-27
PCT/US2000/018439 WO2001007375A1 (en) 1999-07-27 2000-07-05 Transparent microspheres

Publications (2)

Publication Number Publication Date
DE60010469D1 true DE60010469D1 (de) 2004-06-09
DE60010469T2 DE60010469T2 (de) 2005-05-12

Family

ID=23425625

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60010469T Expired - Lifetime DE60010469T2 (de) 1999-07-27 2000-07-05 Transparente mikrokugeln

Country Status (10)

Country Link
US (3) US6245700B1 (de)
EP (1) EP1198428B1 (de)
JP (3) JP4868673B2 (de)
KR (1) KR100707744B1 (de)
CN (1) CN1187278C (de)
AT (1) ATE265992T1 (de)
AU (1) AU5914700A (de)
CA (1) CA2378169A1 (de)
DE (1) DE60010469T2 (de)
WO (1) WO2001007375A1 (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3993269B2 (ja) * 1997-04-18 2007-10-17 スリーエム カンパニー 透明ビーズおよびその製造方法
US6245700B1 (en) * 1999-07-27 2001-06-12 3M Innovative Properties Company Transparent microspheres
DE60129538T2 (de) 2000-03-14 2008-04-10 James Hardie International Finance B.V. Faserzementbaumaterialien mit zusatzstoffen niedriger dichte
US6735789B2 (en) 2000-07-31 2004-05-18 Southern Mills, Inc. Reflective printing on flame resistant fabrics
US7147544B2 (en) * 2001-08-02 2006-12-12 3M Innovative Properties Company Glass-ceramics
CA2454068A1 (en) * 2001-08-02 2003-02-13 3M Innovative Properties Company Al2o3-rare earth oxide-zro2/hfo2 materials, and methods of making and using the same
KR100885328B1 (ko) * 2001-08-02 2009-02-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 알루미나-산화 이트륨-산화 지르코늄/산화 하프늄 물질,및 그의 제조 및 사용 방법
KR20080086542A (ko) * 2001-08-02 2008-09-25 쓰리엠 이노베이티브 프로퍼티즈 캄파니 유리로부터 물품을 제조하는 방법 및 이렇게 제조한 유리 세라믹 물품
US7625509B2 (en) * 2001-08-02 2009-12-01 3M Innovative Properties Company Method of making ceramic articles
US6800574B2 (en) 2001-10-24 2004-10-05 3M Innovative Properties Company Glass beads and uses thereof
US20030090800A1 (en) * 2001-11-01 2003-05-15 3M Innovative Properties Company Reflective elements comprising reinforcement particles dispersed within a core
US7036944B2 (en) * 2002-04-11 2006-05-02 3M Innovative Properties Company Retrochromic articles
US6978896B2 (en) * 2002-04-11 2005-12-27 3M Innovative Properties Company Method of making retrochromic beads and kit thereof
US8056370B2 (en) 2002-08-02 2011-11-15 3M Innovative Properties Company Method of making amorphous and ceramics via melt spinning
AU2003250614B2 (en) 2002-08-23 2010-07-15 James Hardie Technology Limited Synthetic hollow microspheres
US7455798B2 (en) * 2002-08-23 2008-11-25 James Hardie International Finance B.V. Methods for producing low density products
US7993570B2 (en) 2002-10-07 2011-08-09 James Hardie Technology Limited Durable medium-density fibre cement composite
US6984261B2 (en) * 2003-02-05 2006-01-10 3M Innovative Properties Company Use of ceramics in dental and orthodontic applications
US7811496B2 (en) 2003-02-05 2010-10-12 3M Innovative Properties Company Methods of making ceramic particles
US7629967B2 (en) 2003-02-14 2009-12-08 Next Holdings Limited Touch screen signal processing
US8508508B2 (en) 2003-02-14 2013-08-13 Next Holdings Limited Touch screen signal processing with single-point calibration
US8456447B2 (en) 2003-02-14 2013-06-04 Next Holdings Limited Touch screen signal processing
US7292766B2 (en) * 2003-04-28 2007-11-06 3M Innovative Properties Company Use of glasses containing rare earth oxide, alumina, and zirconia and dopant in optical waveguides
US20040259713A1 (en) * 2003-06-11 2004-12-23 3M Innovative Properties Company Microspheres comprising titania and bismuth oxide
US7197896B2 (en) * 2003-09-05 2007-04-03 3M Innovative Properties Company Methods of making Al2O3-SiO2 ceramics
US20060276565A1 (en) * 2003-09-25 2006-12-07 Craig Polta Retroflective polymeric compounds and articles made from them
US20090156385A1 (en) 2003-10-29 2009-06-18 Giang Biscan Manufacture and use of engineered carbide and nitride composites
KR20060126487A (ko) 2003-11-06 2006-12-07 쓰리엠 이노베이티브 프로퍼티즈 캄파니 결합 수지 코어를 포함하는 재귀반사 요소 및 포장도로마킹
EP1709252B1 (de) 2004-01-21 2014-03-26 3M Innovative Properties Company Rückstrahlende elemente und artikel
DE102004003758A1 (de) * 2004-01-23 2005-08-18 Schott Ag Glasformkörper und ein Verfahren zu dessen Herstellung
US7329447B2 (en) * 2004-04-01 2008-02-12 3M Innovative Properties Company Retroreflective sheeting with controlled cap-Y
US7045475B2 (en) * 2004-04-28 2006-05-16 Pq Corporation High refractive index glass beads for high retroreflectivity surfaces
US7998571B2 (en) 2004-07-09 2011-08-16 James Hardie Technology Limited Composite cement article incorporating a powder coating and methods of making same
US7332453B2 (en) * 2004-07-29 2008-02-19 3M Innovative Properties Company Ceramics, and methods of making and using the same
US20060040575A1 (en) * 2004-08-18 2006-02-23 Kelleher Karen A Reflective printing on flame resistant fabrics
AU2006216407A1 (en) 2005-02-24 2006-08-31 James Hardie Technology Limited Alkali resistant glass compositions
US20060274989A1 (en) * 2005-06-06 2006-12-07 Gergely John S Glass microspheres having enhanced resonant light scattering properties
US20060274990A1 (en) * 2005-06-06 2006-12-07 Gergely John S Glass microspheres having optimized resonant light scattering properties
JP2007022832A (ja) * 2005-07-14 2007-02-01 Nippon Electric Glass Co Ltd ガラス粉末の製造方法
EP1912082B1 (de) * 2005-08-03 2012-05-23 Kao Corporation Lichtdiffusionselement
US7513941B2 (en) 2005-11-14 2009-04-07 3M Innovative Properties Company Pavement marking, reflective elements, and methods of making micospheres
AU2006321786B2 (en) 2005-12-06 2012-05-10 James Hardie Technology Limited Engineered low-density heterogeneous microparticles and methods and formulations for producing the microparticles
CN101992141B (zh) * 2006-02-27 2015-07-01 东丽株式会社 使用研磨剂的粉末颗粒的制备方法
AU2007236561B2 (en) 2006-04-12 2012-12-20 James Hardie Technology Limited A surface sealed reinforced building element
KR100773438B1 (ko) 2006-04-17 2007-11-05 박종민 재귀반사용 글라스비드 및 그의 제조방법
US8701441B2 (en) 2006-08-21 2014-04-22 3M Innovative Properties Company Method of making inorganic, metal oxide spheres using microstructured molds
WO2008081821A1 (ja) * 2006-12-27 2008-07-10 Kao Corporation 光拡散性部材
US8292539B2 (en) * 2007-04-10 2012-10-23 Stoncor Group, Inc. Agglomerated retroreflective beads for highway marking and methods for fabrication and use thereof
US9207373B2 (en) 2007-04-10 2015-12-08 Stoncor Group, Inc. Methods for fabrication and highway marking usage of agglomerated retroreflective beads
US20080280034A1 (en) * 2007-05-11 2008-11-13 3M Innovative Properties Company Pavement marking and reflective elements having microspheres comprising lanthanum oxide and aluminum oxide with zirconia, titania, or mixtures thereof
DE102007041065A1 (de) * 2007-08-29 2009-03-05 Sebastian Geerkens Fahrbahn- und Fluchtwegmarkierung
US8209927B2 (en) 2007-12-20 2012-07-03 James Hardie Technology Limited Structural fiber cement building materials
US8496340B2 (en) 2007-12-21 2013-07-30 3M Innovative Properties Company Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers
WO2009105142A2 (en) * 2007-12-21 2009-08-27 3M Innovative Properties Company Retroreflective security articles
EP2232310A1 (de) * 2007-12-21 2010-09-29 3M Innovative Properties Company Rückstrahlende artikel in form von kleidungsstücken, fasern und filamenten
US20090291292A1 (en) * 2008-05-22 2009-11-26 3M Innovative Properties Company Optically active elements including multiple bead layers
CN102574730A (zh) 2009-08-21 2012-07-11 3M创新有限公司 路面标记、反射元件以及制备微球的方法
CN102574729A (zh) 2009-08-21 2012-07-11 3M创新有限公司 路面标记、反射元件以及制备微球的方法
CN101857368B (zh) * 2010-06-30 2011-09-28 张学军 一种用于道路标线的矿石玻璃珠
WO2012054283A1 (en) 2010-10-18 2012-04-26 3M Innovative Properties Company Functional particle transfer liner
CN103842591B (zh) 2011-09-01 2016-03-16 3M创新有限公司 道路标记材料和方法
CN102584004B (zh) * 2012-03-02 2014-04-16 陕西科技大学 一种红色硬质玻璃的制备方法
CN104334661B (zh) 2012-05-29 2018-04-06 3M创新有限公司 道路标记组合物
WO2014070229A1 (en) 2012-10-29 2014-05-08 3M Innovative Properties Company Pavement marking compositions
RU2532784C2 (ru) * 2013-01-11 2014-11-10 Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" Стеклометаллические микрошарики и их способ получения
EP3126414B1 (de) 2014-04-04 2018-06-06 3M Innovative Properties Company Primerzusammensetzung für die bearbeitung von nassen oder feuchten oberflächen
US10138367B2 (en) 2014-04-29 2018-11-27 3M Innovative Properties Company Copolymers of poly(ethylene-co-acrylic acid) and polydiorganosiloxanes
CN104046116A (zh) * 2014-05-06 2014-09-17 湖州远光路标涂料有限公司 道路标线用反光珠
EP3177576B1 (de) 2014-08-08 2023-09-27 3M Innovative Properties Company Rückstrahlende elemente mit teilchen
US9871176B2 (en) 2015-02-02 2018-01-16 Ferro Corporation Glass compositions and glass frit composites for use in optical applications
US20170022676A1 (en) * 2015-04-29 2017-01-26 Michael L. Milano Luminescent raised road marker
WO2016205443A1 (en) 2015-06-18 2016-12-22 3M Innovative Properties Company Thermoplastic pavement marking tapes
CN108025958B (zh) 2015-09-11 2021-04-09 3M创新有限公司 具有小珠共混物的耐用回射元件
CN108027463B (zh) 2015-09-11 2021-12-07 3M创新有限公司 具有离子共聚物芯的耐用回射元件
FR3042792A1 (fr) * 2015-10-21 2017-04-28 Saint-Gobain Centre De Rech Et D'Etudes Europeen Bille en un produit fondu
CN110462136A (zh) 2017-03-20 2019-11-15 3M创新有限公司 白色道路标记
US10988399B2 (en) 2017-05-12 2021-04-27 3M Innovative Properties Company Articles comprising crystalline materials and method of making the same
US20210087116A1 (en) * 2017-07-28 2021-03-25 3M Innovative Properties Company Nanocrystalline ceramic oxide beads
EP3724400A1 (de) 2017-12-14 2020-10-21 3M Innovative Properties Company Fahrbahnmarkierungen und fahrbahnmarkierungssystem zur spuridentifizierung
US11467324B2 (en) 2018-10-26 2022-10-11 Tundra Composits, LLC Complex retroreflective bead
JP2020105041A (ja) 2018-12-26 2020-07-09 スリーエム イノベイティブ プロパティズ カンパニー 透明中実球及びその製造方法
EP4003936A4 (de) * 2019-07-24 2023-08-23 Iluka Resources Limited Aufhellungsverfahren und -zusammensetzungen
CN112480558A (zh) * 2020-12-17 2021-03-12 佛山市大唐新新橡塑有限公司 一种高耐磨橡胶配方
WO2023170516A1 (en) 2022-03-09 2023-09-14 3M Innovative Properties Company Microspheres comprising zirconia and alumina suitable for retroreflective articles
WO2023170515A1 (en) 2022-03-09 2023-09-14 3M Innovative Properties Company Microspheres comprising alumina and zirconia suitable for retroreflective articles
WO2024003637A1 (en) 2022-06-29 2024-01-04 3M Innovative Properties Company Curable adhesive and articles for bonding pavement and concrete

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2354018A (en) 1940-08-03 1944-07-18 Minnesota Mining & Mfg Light reflector sheet
US2963378A (en) 1955-04-25 1960-12-06 Minnesota Mining & Mfg Ass beads hemispherically reflectorled with metallic coating and compositions thereof
US2924533A (en) 1956-05-28 1960-02-09 Carborundum Co Spheroidal refractory material and method of making
US2960594A (en) 1958-06-30 1960-11-15 Plasma Flame Corp Plasma flame generator
US3145114A (en) 1960-10-24 1964-08-18 Prismo Safety Corp Process for increasing the index of refraction of glass and an article made thereby
US3228897A (en) 1961-10-26 1966-01-11 Minnesota Mining & Mfg Reflective coating compositions containing glass beads, metal flake pigment and binder
US3149016A (en) 1962-04-02 1964-09-15 Minnesota Mining & Mfg Nucleated glass particle and process for making it
CA919195A (en) 1963-02-14 1973-01-16 Fang Tung Chi High index glass elements
DE1250977B (de) 1963-04-22 1967-09-28
US3294558A (en) 1963-04-22 1966-12-27 Cataphote Corp Colorless high index glass compositions
FR1404190A (fr) 1964-08-10 1965-06-25 Minnesota Mining & Mfg Perles transparentes
US3416936A (en) 1965-03-01 1968-12-17 Gen Steel Ind Inc Abrasion resistant glass bead with sharp softening range and process for making the same
US3432314A (en) 1966-08-02 1969-03-11 Us Air Force Transparent zirconia composition and process for making same
US3410185A (en) 1966-08-08 1968-11-12 Minnesota Mining & Mfg Marking
US3560074A (en) 1968-10-21 1971-02-02 Cataphote Corp 95% titanium dioxide glass spheroids
US3709706A (en) 1969-05-16 1973-01-09 Minnesota Mining & Mfg Refractory fibers and other articles of zirconia and silica mixtures
US3795524A (en) 1971-03-01 1974-03-05 Minnesota Mining & Mfg Aluminum borate and aluminum borosilicate articles
US3864113A (en) 1973-10-19 1975-02-04 Corning Glass Works Method of Producing Glass by Flame Hydrolysis
US3915771A (en) 1974-03-04 1975-10-28 Minnesota Mining & Mfg Pavement-marking tape
JPS5828210B2 (ja) 1974-11-07 1983-06-14 オノダセメント カブシキガイシヤ コウブツセンイマタハ ビ−ズソセイブツ
US4137086A (en) 1975-05-13 1979-01-30 Pilkington Brothers Limited Glass compositions for use in curable compositions
FR2320276A1 (fr) 1975-08-06 1977-03-04 Prod Refractaires Europ Billes ameliorees en matiere ceramique
US4056602A (en) 1975-08-20 1977-11-01 Thagard Technology Company High temperature chemical reaction processes utilizing fluid-wall reactors
US4095974A (en) 1975-09-24 1978-06-20 Thagard Technology Company High temperature chemical reaction processes utilizing fluid-wall reactors
JPS5939378B2 (ja) 1976-08-13 1984-09-22 旭硝子株式会社 繊維用ガラス組成物
JPS5388815A (en) 1977-01-18 1978-08-04 Tokyo Shibaura Electric Co High reeractiveeindex glass for glass beads
JPS53102325A (en) 1977-02-18 1978-09-06 Obara Optical Glass Abrasionn and chemicallproof glass
US4367919A (en) 1977-08-01 1983-01-11 Minnesota Mining And Manufacturing Company Durable glass elements
CA1105949A (en) * 1977-08-01 1981-07-28 Minnesota Mining And Manufacturing Company Durable glass elements
JPS553352A (en) * 1978-06-22 1980-01-11 Nippon Electric Glass Co Ltd High refractive index glass for glass bead
JPS608983B2 (ja) 1978-07-28 1985-03-07 松下電工株式会社 結晶化能を有する低融点ガラスの製法
JPS5520254A (en) 1978-07-28 1980-02-13 Matsushita Electric Works Ltd Production of low melting point crystallized glass
US4192576A (en) * 1978-11-20 1980-03-11 Minnesota Mining And Manufacturing Company Ultra-high-index glass microspheres and products made therefrom
JPS55126548A (en) 1979-03-20 1980-09-30 Ohara Inc Glass for bead
JPS55126547A (en) 1979-03-20 1980-09-30 Ohara Inc Glass for bead
US4248932A (en) 1979-06-14 1981-02-03 Minnesota Mining And Manufacturing Company Extended-life pavement-marking sheet material
JPS5641852A (en) 1979-09-17 1981-04-18 Ohara Inc Glass for bead
FR2493910A1 (fr) 1980-11-13 1982-05-14 Produits Refractaires Agent de soutenement a base de zircone et de silice pour fractures geologiques profondes
DD209431A1 (de) * 1982-01-11 1984-05-09 Greiner Baer Gerhard Verfahren zur herstellung von mikroglaskugeln mit brechwerten ueber 2,2
US4621936A (en) 1983-10-14 1986-11-11 Corning Glass Works Zirconia pen balls
JPS60215549A (ja) 1984-04-11 1985-10-28 Toshiba Glass Co Ltd 耐摩耗性ガラスビ−ズ
JPS6168349A (ja) 1984-09-07 1986-04-08 Toshiba Glass Co Ltd 耐摩耗性ガラスビ−ズ
US4564556A (en) 1984-09-24 1986-01-14 Minnesota Mining And Manufacturing Company Transparent non-vitreous ceramic particulate
JPH0249259B2 (ja) * 1984-09-26 1990-10-29 Kogyo Gijutsuin Ketsushokagarasutosonoseizohoho
JPS61270235A (ja) 1985-05-24 1986-11-29 Ohara Inc ビ−ズ用ガラス
US4772511A (en) 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
CA1308845C (en) 1986-01-13 1992-10-13 Roger W. Lange Pavement markings containing transparent non-vitreous ceramic microspheres
JP2517710B2 (ja) * 1986-06-13 1996-07-24 株式会社 オハラ ガラスセラミツク製品の製造方法
US4837069A (en) 1987-01-07 1989-06-06 Minnesota Mining And Manufacturing Company Transparent alumina microspheres
JPS63123835A (ja) * 1987-10-22 1988-05-27 Union:Kk 高屈折率ガラスビーズ
US5227221A (en) 1988-06-09 1993-07-13 Minnesota Mining And Manufacturing Company Patterned skid preventative sheet
AU658871B2 (en) 1991-02-28 1995-05-04 Minnesota Mining And Manufacturing Company Pavement markers with silicone adhesive
JPH0585771A (ja) 1991-03-29 1993-04-06 Nippon Electric Glass Co Ltd 中空ガラス球用組成物
US5268789A (en) 1992-02-18 1993-12-07 Minnesota Mining And Manufacturing Company Retroreflective assembly and process for making same
US5286682A (en) 1992-02-19 1994-02-15 Minnesota Mining And Manufacturing Company Yellow retroreflective pavement markings
FR2714905B1 (fr) 1994-01-11 1996-03-01 Produits Refractaires Billes en matière céramique fondue.
ATE200773T1 (de) 1995-04-18 2001-05-15 Minnesota Mining & Mfg Glaskügelchen
US5576097A (en) 1995-04-24 1996-11-19 Brite-Line Industries, Inc. High brightness durable retro-reflecting microspheres and method of making the same
JP3993269B2 (ja) * 1997-04-18 2007-10-17 スリーエム カンパニー 透明ビーズおよびその製造方法
WO1998047830A1 (en) 1997-04-18 1998-10-29 Minnesota Mining And Manufacturing Company Transparent beads and their production method
US6245700B1 (en) * 1999-07-27 2001-06-12 3M Innovative Properties Company Transparent microspheres

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KR100707744B1 (ko) 2007-05-07
US6479417B2 (en) 2002-11-12
JP2011237825A (ja) 2011-11-24
JP2013032279A (ja) 2013-02-14
CA2378169A1 (en) 2001-02-01
US6245700B1 (en) 2001-06-12
EP1198428B1 (de) 2004-05-06
US20020006510A1 (en) 2002-01-17
US6461988B2 (en) 2002-10-08
DE60010469T2 (de) 2005-05-12
EP1198428A1 (de) 2002-04-24
JP4868673B2 (ja) 2012-02-01
KR20020019955A (ko) 2002-03-13
JP2003505328A (ja) 2003-02-12
ATE265992T1 (de) 2004-05-15
US20020013207A1 (en) 2002-01-31
WO2001007375A1 (en) 2001-02-01
CN1361754A (zh) 2002-07-31
JP5197810B2 (ja) 2013-05-15
AU5914700A (en) 2001-02-13
CN1187278C (zh) 2005-02-02

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