DE2501284C3 - Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe - Google Patents
Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen WertstoffeInfo
- Publication number
- DE2501284C3 DE2501284C3 DE2501284A DE2501284A DE2501284C3 DE 2501284 C3 DE2501284 C3 DE 2501284C3 DE 2501284 A DE2501284 A DE 2501284A DE 2501284 A DE2501284 A DE 2501284A DE 2501284 C3 DE2501284 C3 DE 2501284C3
- Authority
- DE
- Germany
- Prior art keywords
- cobalt
- zinc
- nickel
- copper
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 37
- 239000011572 manganese Substances 0.000 title claims description 34
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims description 30
- 229910052748 manganese Inorganic materials 0.000 title claims description 30
- 239000000126 substance Substances 0.000 title description 11
- 238000011084 recovery Methods 0.000 title description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 64
- 239000011701 zinc Substances 0.000 claims description 40
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 32
- 229910052725 zinc Inorganic materials 0.000 claims description 32
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 29
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 28
- 229910017052 cobalt Inorganic materials 0.000 claims description 28
- 239000010941 cobalt Substances 0.000 claims description 28
- 229910052759 nickel Inorganic materials 0.000 claims description 28
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 24
- 239000010949 copper Substances 0.000 claims description 24
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 23
- 229910052802 copper Inorganic materials 0.000 claims description 23
- 238000002386 leaching Methods 0.000 claims description 19
- 238000000605 extraction Methods 0.000 claims description 15
- 238000001556 precipitation Methods 0.000 claims description 15
- 238000000926 separation method Methods 0.000 claims description 11
- 150000001768 cations Chemical class 0.000 claims description 10
- 238000000638 solvent extraction Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000920 calcium hydroxide Substances 0.000 claims description 7
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 3
- 239000003517 fume Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000004325 8-hydroxyquinolines Chemical class 0.000 claims description 2
- BUZRUIZTMOKRPB-UHFFFAOYSA-N carboxycarbamic acid Chemical group OC(=O)NC(O)=O BUZRUIZTMOKRPB-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- PKSIZOUDEUREFF-UHFFFAOYSA-N cobalt;dihydrate Chemical compound O.O.[Co] PKSIZOUDEUREFF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002923 oximes Chemical class 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 235000002639 sodium chloride Nutrition 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009867 copper metallurgy Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 229960005191 ferric oxide Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical group OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005360 mashing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/01—Preparation or separation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/282—Aliphatic amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
- C22B47/0018—Treating ocean floor nodules
- C22B47/0045—Treating ocean floor nodules by wet processes
- C22B47/0054—Treating ocean floor nodules by wet processes leaching processes
- C22B47/0063—Treating ocean floor nodules by wet processes leaching processes with acids or salt solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
- C22B47/0018—Treating ocean floor nodules
- C22B47/0045—Treating ocean floor nodules by wet processes
- C22B47/0081—Treatment or purification of solutions, e.g. obtained by leaching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/04—Manganese marine modules
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Ocean & Marine Engineering (AREA)
- Oceanography (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2501284A DE2501284C3 (de) | 1975-01-15 | 1975-01-15 | Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe |
| FI753660A FI60237C (fi) | 1975-01-15 | 1975-12-29 | Foerfarande foer upparbetning av manganklumpar och aotervinning av i dem innehaollna vaerdeaemnen |
| JP51001353A JPS5921929B2 (ja) | 1975-01-15 | 1976-01-07 | マンガン団塊を処理してその中に含まれる有価物質を抽出する方法 |
| BE163392A BE837421A (fr) | 1975-01-15 | 1976-01-09 | Procede pour le traitement des nodules de manganese ainsi que pour l'extraction des produits de valeur qu'ils contiennent |
| FR7600437A FR2297923A1 (fr) | 1975-01-15 | 1976-01-09 | Procede pour le trait |
| AU10191/76A AU501375B2 (en) | 1975-01-15 | 1976-01-12 | Method for processing manganese modules and recovering the valves contained therein |
| GB143276A GB1476292A (en) | 1975-01-15 | 1976-01-14 | Process for working up manganese modules and recovery of the contained valuable constituents |
| ZA195A ZA76195B (en) | 1975-01-15 | 1976-01-14 | Process for working up manganese nodules and recovery of contained valuable constituents |
| CA243,535A CA1075015A (en) | 1975-01-15 | 1976-01-14 | Process for working up manganese modules and recovery of the contained valuable constituents |
| US05/649,491 US4008076A (en) | 1975-01-15 | 1976-01-15 | Method for processing manganese nodules and recovering the values contained therein |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2501284A DE2501284C3 (de) | 1975-01-15 | 1975-01-15 | Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2501284A1 DE2501284A1 (de) | 1976-09-09 |
| DE2501284B2 DE2501284B2 (de) | 1979-09-27 |
| DE2501284C3 true DE2501284C3 (de) | 1980-06-12 |
Family
ID=5936425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2501284A Expired DE2501284C3 (de) | 1975-01-15 | 1975-01-15 | Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4008076A (enExample) |
| JP (1) | JPS5921929B2 (enExample) |
| AU (1) | AU501375B2 (enExample) |
| BE (1) | BE837421A (enExample) |
| CA (1) | CA1075015A (enExample) |
| DE (1) | DE2501284C3 (enExample) |
| FI (1) | FI60237C (enExample) |
| FR (1) | FR2297923A1 (enExample) |
| GB (1) | GB1476292A (enExample) |
| ZA (1) | ZA76195B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1036829A (en) * | 1975-07-30 | 1978-08-22 | Kohur N. Subramanian | Two stage sulfuric acid leaching of sea nodules |
| US4130415A (en) * | 1977-06-02 | 1978-12-19 | Nagaraj D R | Copper flotation with anti-5-nonyl-2-hydroxybenxophenone oxime |
| DE2841271C3 (de) * | 1978-09-22 | 1981-11-19 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Aufarbeitung von Buntmetallhydroxidschlammrückständen |
| FR2533587A1 (fr) * | 1982-09-27 | 1984-03-30 | Commissariat Energie Atomique | Procede de traitement de minerais complexes de manganese, en particulier de nodules manganiferes |
| US4606764A (en) * | 1983-08-17 | 1986-08-19 | Resource Technology Associates | Method of recovering metals from ores using a formate reducing agent |
| JP3308345B2 (ja) * | 1992-08-21 | 2002-07-29 | ユニチカ株式会社 | 電解槽の操作方法 |
| US5431788A (en) * | 1993-06-28 | 1995-07-11 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical copper extraction |
| USRE37251E1 (en) | 1993-07-29 | 2001-07-03 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| US5650057A (en) * | 1993-07-29 | 1997-07-22 | Cominco Engineering Services Ltd. | Chloride assisted hydrometallurgical extraction of metal |
| WO1998014623A1 (en) * | 1996-10-02 | 1998-04-09 | International Curator Resources Limited | Hydrometallurgical extraction of copper, zinc and cobalt from ores containing manganese dioxide |
| FR2834980B1 (fr) * | 2002-01-23 | 2005-01-14 | Sarp Ind | Procede de separation du zinc et d'un second metal ne formant pas de complexe anionique en presence d'ions chlorures |
| RU2389533C2 (ru) * | 2004-05-25 | 2010-05-20 | Ферроатлантика, С.Л. | Способ электролитического получения марганца из отходов производства ферросплавов |
| DE102004038693B4 (de) * | 2004-08-10 | 2010-02-25 | Blasberg Werra Chemie Gmbh | Vorrichtung und Verfahren zur Entfernung von Fremdstoffen aus Prozesslösungen und Verfahren zur Regenerierung eines Kationenaustauschers |
| BRPI0604853B1 (pt) * | 2006-10-27 | 2016-03-08 | Vale Do Rio Doce Co | método para produção de cobalto metálico a partir de refinado de extração por solventes de níquel |
| US8043585B2 (en) * | 2008-01-15 | 2011-10-25 | Vale Inco Limited | Liquid and solid effluent treatment process |
| US20110174113A1 (en) * | 2010-01-18 | 2011-07-21 | Gme Resources Ltd. | Acid Recovery |
| US9156136B2 (en) | 2012-11-07 | 2015-10-13 | National Oilwell Varco, L.P. | Systems and methods for vapor pressure leaching polycrystalline diamond cutter elements |
| GB2528786B (en) | 2012-12-31 | 2018-03-28 | Nat Oilwell Varco Lp | Apparatus and methods for high pressure leaching of polycrystalline diamond cutter elements |
| CN106119560B (zh) * | 2016-08-04 | 2018-01-02 | 西北矿冶研究院 | 一种锌钴分离方法 |
| CN109487083A (zh) * | 2018-11-16 | 2019-03-19 | 江苏雄风科技有限公司 | 一种从钴铜矿湿法冶炼工艺中的p204反萃后液分离回收钴铜的方法 |
| KR102652169B1 (ko) * | 2019-08-09 | 2024-03-27 | 유미코아 | 산화 광석으로부터 금속을 회수하는 방법 |
| CN110551898B (zh) * | 2019-09-16 | 2021-07-06 | 中信大锰矿业有限责任公司 | 一种电解锰渣的处理方法 |
| CN110983054B (zh) * | 2019-12-31 | 2021-07-27 | 贵州合众锰业科技有限公司 | 从硫酸锰溶液中分离回收钴镍的方法 |
| CN112609090B (zh) * | 2020-11-19 | 2022-10-14 | 中国恩菲工程技术有限公司 | 一种铜钴氧化矿的分离方法 |
| CN113528823A (zh) * | 2021-05-13 | 2021-10-22 | 西北矿冶研究院 | 一种综合回收含砷中和渣中铜锌钴的生产方法 |
| CN114147053B (zh) * | 2021-10-11 | 2023-04-14 | 北京建筑材料科学研究总院有限公司 | 一种从垃圾焚烧飞灰中同时去除氯和重金属的方法 |
| CN115491496B (zh) * | 2022-09-22 | 2024-01-16 | 郑州大学 | 一种湿法炼锌净化钴渣选择性分离钴锰锌镉的方法 |
| CN116334406B (zh) * | 2023-04-11 | 2025-07-04 | 昆明冶金研究院有限公司 | 一种湿法炼锌贫镉液中回收钴的方法 |
| CN119753374B (zh) * | 2025-03-10 | 2025-06-24 | 东北大学 | 一种微波处理锰结核的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2842427A (en) * | 1955-04-23 | 1958-07-08 | Electro Chimie Metal | Process of separating nickel and cobalt |
| US2971836A (en) * | 1957-04-29 | 1961-02-14 | James D Hall | Separation of nickel and cobalt |
| US2992894A (en) * | 1957-10-01 | 1961-07-18 | Kerr Mc Gee Oil Ind Inc | Process for concentrating copper and zinc values present in aqueous solution |
| US3244513A (en) * | 1962-07-25 | 1966-04-05 | Sherritt Gordon Mines Ltd | Process for the treatment of lateritic ores to obtain cobalt and nickel values |
| US3322532A (en) * | 1963-12-27 | 1967-05-30 | Chemolimpex | Process for recovering the metal content of middlings, slags, low-grade ores, and concentrates |
| US3479378A (en) * | 1967-11-06 | 1969-11-18 | Bunker Hill Co | Liquid ion exchange process for metal recovery |
| DE2150785C2 (de) * | 1971-10-12 | 1973-07-12 | Preussag Ag | Verfahren zur Gewinnung eines Manganoxidkonzentrats,von metallischem Kupfer,Nickel und Kobalt aus Manganerzen |
| US3810827A (en) * | 1972-05-08 | 1974-05-14 | Deepsea Ventures Inc | Method for separating metal values from ocean floor nodule ore |
| US3869360A (en) * | 1972-05-08 | 1975-03-04 | William S Kane | Reduction method for separating metal values from ocean floor nodule ore |
| US3809624A (en) * | 1972-06-06 | 1974-05-07 | Deepsea Ventures Inc | Mixed ore treatment of ocean floor nodule ore and iron sulfidic land based ores |
| US3795596A (en) * | 1972-07-17 | 1974-03-05 | Deepsea Ventures Inc | Method for selectively leaching metal values from ocean floor nodules |
| US3923615A (en) * | 1972-07-17 | 1975-12-02 | Deepsea Ventures Inc | Winning of metal values from ore utilizing recycled acid leaching agent |
| DE2240586A1 (de) * | 1972-08-18 | 1974-02-28 | Krupp Gmbh | Verfahren zur gewinnung von kupfer, nickel, kobalt und mangan aus manganknollen |
-
1975
- 1975-01-15 DE DE2501284A patent/DE2501284C3/de not_active Expired
- 1975-12-29 FI FI753660A patent/FI60237C/fi not_active IP Right Cessation
-
1976
- 1976-01-07 JP JP51001353A patent/JPS5921929B2/ja not_active Expired
- 1976-01-09 FR FR7600437A patent/FR2297923A1/fr active Granted
- 1976-01-09 BE BE163392A patent/BE837421A/xx not_active IP Right Cessation
- 1976-01-12 AU AU10191/76A patent/AU501375B2/en not_active Expired
- 1976-01-14 CA CA243,535A patent/CA1075015A/en not_active Expired
- 1976-01-14 ZA ZA195A patent/ZA76195B/xx unknown
- 1976-01-14 GB GB143276A patent/GB1476292A/en not_active Expired
- 1976-01-15 US US05/649,491 patent/US4008076A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FI60237C (fi) | 1981-12-10 |
| ZA76195B (en) | 1977-01-26 |
| DE2501284A1 (de) | 1976-09-09 |
| AU501375B2 (en) | 1979-06-21 |
| GB1476292A (en) | 1977-06-10 |
| FI60237B (fi) | 1981-08-31 |
| DE2501284B2 (de) | 1979-09-27 |
| JPS5921929B2 (ja) | 1984-05-23 |
| FR2297923B1 (enExample) | 1980-04-11 |
| CA1075015A (en) | 1980-04-08 |
| JPS5193705A (en) | 1976-08-17 |
| FI753660A7 (enExample) | 1976-07-16 |
| US4008076A (en) | 1977-02-15 |
| AU1019176A (en) | 1977-07-21 |
| FR2297923A1 (fr) | 1976-08-13 |
| BE837421A (fr) | 1976-05-03 |
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