DE2022076C3 - Verfahren zur katalytischen Wasserdampfreformierung von Kohlenwasserstoffbeschickungen - Google Patents
Verfahren zur katalytischen Wasserdampfreformierung von KohlenwasserstoffbeschickungenInfo
- Publication number
- DE2022076C3 DE2022076C3 DE19702022076 DE2022076A DE2022076C3 DE 2022076 C3 DE2022076 C3 DE 2022076C3 DE 19702022076 DE19702022076 DE 19702022076 DE 2022076 A DE2022076 A DE 2022076A DE 2022076 C3 DE2022076 C3 DE 2022076C3
- Authority
- DE
- Germany
- Prior art keywords
- reforming
- water vapor
- hydrogen
- steam
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims description 47
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 47
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 22
- 230000008569 process Effects 0.000 title claims description 10
- 238000001193 catalytic steam reforming Methods 0.000 title claims description 4
- 238000002407 reforming Methods 0.000 claims description 47
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- 239000001257 hydrogen Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 26
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
- 238000000629 steam reforming Methods 0.000 description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 12
- 239000001569 carbon dioxide Substances 0.000 description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- -1 carbon dioxide saturated oxygen Chemical class 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03K—PULSE TECHNIQUE
- H03K5/00—Manipulating of pulses not covered by one of the other main groups of this subclass
- H03K5/153—Arrangements in which a pulse is delivered at the instant when a predetermined characteristic of an input signal is present or at a fixed time interval after this instant
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/388—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the heat being generated by superheated steam
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82313069A | 1969-05-08 | 1969-05-08 |
Publications (3)
Publication Number | Publication Date |
---|---|
DE2022076A1 DE2022076A1 (de) | 1970-11-19 |
DE2022076B2 DE2022076B2 (de) | 1979-05-10 |
DE2022076C3 true DE2022076C3 (de) | 1980-01-03 |
Family
ID=25237878
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19702022076 Expired DE2022076C3 (de) | 1969-05-08 | 1970-05-05 | Verfahren zur katalytischen Wasserdampfreformierung von Kohlenwasserstoffbeschickungen |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS4923760B1 (nl) |
CA (1) | CA937759A (nl) |
DE (1) | DE2022076C3 (nl) |
GB (1) | GB1270071A (nl) |
NL (1) | NL166668C (nl) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2148430C2 (de) * | 1970-10-01 | 1984-03-29 | The Lummus Co., 07003 Bloomfield, N.J. | Verfahren zur Reformierung von Kohlenwasserstoffbeschickungen für die Erzeugung von Kohlenmonoxyd und Wasserstoff |
DE2141875A1 (de) * | 1971-08-20 | 1973-03-01 | Metallgesellschaft Ag | Verfahren zur herstellung eines reduktionsgases |
DE2240355C3 (de) * | 1972-08-17 | 1981-09-03 | Dr. C. Otto & Comp. Gmbh, 4630 Bochum | Verfahren zur Umwandlung von Brennstoffen unter Wärmezufuhr |
DK44684D0 (da) * | 1984-02-01 | 1984-02-01 | Topsoee H A S | Fremgangsmaade til fremstilling af en reducerende fremgangsmade til fremstilling af en reducerende ggas as |
US4756750A (en) * | 1987-04-27 | 1988-07-12 | Air Products And Chemicals, Inc. | Process for the direct reduction of iron ore |
US7790059B2 (en) | 2007-10-18 | 2010-09-07 | Air Products And Chemicals, Inc. | Staged hydrocarbon/steam reformer apparatus and method |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1032753A (en) * | 1962-08-22 | 1966-06-15 | Ici Ltd | Improvements in and relating to the steam reforming of hydrocarbons |
DE1209237B (de) * | 1962-11-07 | 1966-01-20 | Metallgesellschaft Ag | Verfahren zur kontinuierlichen Erzeugung von normgerechtem Stadt- oder Ferngas |
FR1529097A (fr) * | 1967-06-21 | 1968-06-14 | Gas Council | Procédé de reforming à la vapeur d'eau |
-
1970
- 1970-05-05 DE DE19702022076 patent/DE2022076C3/de not_active Expired
- 1970-05-06 NL NL7006617A patent/NL166668C/nl not_active IP Right Cessation
- 1970-05-07 CA CA082135A patent/CA937759A/en not_active Expired
- 1970-05-07 JP JP3831070A patent/JPS4923760B1/ja active Pending
- 1970-05-08 GB GB2228770A patent/GB1270071A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS4923760B1 (nl) | 1974-06-18 |
DE2022076B2 (de) | 1979-05-10 |
DE2022076A1 (de) | 1970-11-19 |
NL166668C (nl) | 1981-09-15 |
GB1270071A (en) | 1972-04-12 |
CA937759A (en) | 1973-12-04 |
NL166668B (nl) | 1981-04-15 |
NL7006617A (nl) | 1970-11-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C3 | Grant after two publication steps (3rd publication) | ||
8328 | Change in the person/name/address of the agent |
Free format text: SPLANEMANN, R., DIPL.-ING. REITZNER, B., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 8000 MUENCHEN |
|
AG | Has addition no. |
Ref country code: DE Ref document number: 2148430 Format of ref document f/p: P |
|
8339 | Ceased/non-payment of the annual fee |