DE1520237A1 - Verfahren zur selektiven Polymerisation von alpha-Olefinen - Google Patents
Verfahren zur selektiven Polymerisation von alpha-OlefinenInfo
- Publication number
- DE1520237A1 DE1520237A1 DE19601520237 DE1520237A DE1520237A1 DE 1520237 A1 DE1520237 A1 DE 1520237A1 DE 19601520237 DE19601520237 DE 19601520237 DE 1520237 A DE1520237 A DE 1520237A DE 1520237 A1 DE1520237 A1 DE 1520237A1
- Authority
- DE
- Germany
- Prior art keywords
- metals
- polymerization
- compounds
- polymers
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 4
- 239000004711 α-olefin Substances 0.000 title description 3
- 229920000642 polymer Polymers 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 150000002739 metals Chemical class 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052776 Thorium Inorganic materials 0.000 claims description 2
- 229910052770 Uranium Inorganic materials 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000003811 acetone extraction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 208000001848 dysentery Diseases 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical class [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT52610154 | 1954-12-03 | ||
| IT1647954 | 1954-12-16 | ||
| IT1057155 | 1955-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1520237A1 true DE1520237A1 (de) | 1969-03-27 |
Family
ID=27272769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19601520237 Pending DE1520237A1 (de) | 1954-12-03 | 1960-09-21 | Verfahren zur selektiven Polymerisation von alpha-Olefinen |
Country Status (10)
| Country | Link |
|---|---|
| BE (2) | BE543259A (en, 2012) |
| CH (2) | CH365222A (en, 2012) |
| CY (1) | CY219A (en, 2012) |
| DE (1) | DE1520237A1 (en, 2012) |
| FR (2) | FR1139806A (en, 2012) |
| GB (2) | GB828791A (en, 2012) |
| IT (1) | IT526101A (en, 2012) |
| LU (1) | LU33991A1 (en, 2012) |
| MY (1) | MY6100061A (en, 2012) |
| NL (2) | NL111136C (en, 2012) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3141872A (en) * | 1954-12-03 | 1964-07-21 | Montedison Spa | Polymerization catalyst and stereospecific polymerization of propylene therewith |
| US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| US2893984A (en) * | 1956-04-02 | 1959-07-07 | Exxon Research Engineering Co | Polymerization of alpha olefins |
| US3009905A (en) * | 1956-06-11 | 1961-11-21 | Ici Ltd | Production of polymers |
| DE1209296B (de) * | 1956-10-17 | 1966-01-20 | Ethyl Corp | Verfahren zur Polymerisation oder Mischpoly-merisation von olefinisch ungesaettigten Kohlen-wasserstoffen mit mindestens drei Kohlenstoff-atomen |
| NL220937A (en, 2012) * | 1956-10-29 | |||
| US2948711A (en) * | 1956-11-27 | 1960-08-09 | Sun Oil Co | Preparation of polyolefins |
| US2935495A (en) * | 1956-11-27 | 1960-05-03 | Sun Oil Co | Manufacture of polyolefins |
| US3107236A (en) * | 1956-12-17 | 1963-10-15 | Sun Oil Co | Preparation of polypropylene |
| GB877050A (en) * | 1958-06-16 | 1961-09-13 | Ici Ltd | Improvements in and relating to the polymerisation of olefines, catalysts for such polymerisation, crystalline materials suitable as components of the catalysts and processes for their preparation |
| BE554685A (en, 2012) * | 1957-02-02 | |||
| GB860647A (en) * | 1957-03-04 | 1961-02-08 | Exxon Research Engineering Co | Method for preparing titanium trichloride containing polymerization catalyst and polymerization process |
| NL227164A (en, 2012) * | 1957-04-27 | |||
| US2976252A (en) * | 1957-05-10 | 1961-03-21 | Exxon Research Engineering Co | Temperature-staged catalyst pretreatment |
| BE598132A (en, 2012) * | 1957-05-28 | |||
| NL108999C (en, 2012) * | 1957-07-16 | |||
| US2918457A (en) * | 1957-09-26 | 1959-12-22 | Sun Oil Co | Copolymer of propylene and butene-1 |
| BE572163A (en, 2012) * | 1957-10-19 | |||
| BE571954A (en, 2012) * | 1957-10-21 | |||
| BE572307A (en, 2012) * | 1957-10-23 | |||
| NL104123B (en, 2012) * | 1957-10-25 | |||
| DE1128662B (de) * | 1957-11-09 | 1962-04-26 | Ruhrchemie Ag | Verfahren zur Herstellung von Polyolefinen |
| BE573749A (en, 2012) * | 1957-12-11 | |||
| NL235592A (en, 2012) * | 1958-02-03 | |||
| DE1240285B (de) * | 1958-02-06 | 1967-05-11 | Hibernia Ag | Verfahren zur Herstellung von hochmolekularen und hochkristallinen Polymerisaten ausOlefinen mit 3 und mehr Kohlenstoffatomen |
| NL102197C (en, 2012) * | 1958-03-21 | |||
| DE1117308B (de) * | 1958-03-31 | 1961-11-16 | Eastman Kodak Co | Verfahren zur Herstellung Aryl- oder alicyclische Reste enthaltender Polyolefine |
| BE578139A (en, 2012) * | 1958-05-05 | |||
| BE580006A (en, 2012) * | 1958-06-27 | |||
| DE1135661B (de) * | 1958-08-02 | 1962-08-30 | Huels Chemische Werke Ag | Verfahren zur Aufarbeitung von Niederdruck-Polypropylen |
| US3082197A (en) * | 1958-12-01 | 1963-03-19 | Phillips Petroleum Co | Polymerization of conjugated diolefins in the presence of transition metal borohydrides |
| BE585154A (en, 2012) * | 1958-12-06 | |||
| BE585563A (en, 2012) * | 1958-12-12 | |||
| DE1105618B (de) * | 1959-01-26 | 1961-04-27 | Huels Chemische Werke Ag | Verfahren zur Herstellung von isotaktischen Polystyrolen |
| US3244678A (en) * | 1959-01-27 | 1966-04-05 | Du Pont | Process for copolymerizing a straight chain alpha olefin with a conjugated diene |
| US2965692A (en) * | 1959-04-06 | 1960-12-20 | Sun Oil Co | Preparation of viscous polymers |
| NZ126521A (en, 2012) * | 1959-06-06 | |||
| BE591405A (en, 2012) * | 1959-06-12 | |||
| DE1183245B (de) * | 1959-06-24 | 1964-12-10 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Polyolefinen einheitlichen Polymerisationsgrades |
| DE1164666B (de) * | 1959-06-29 | 1964-03-05 | Grace W R & Co | Verfahren zur Herstellung von hochmolekularem Polypropylen |
| US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
| US3067189A (en) * | 1959-12-24 | 1962-12-04 | Shell Oil Co | Diene polymerization catalyst |
| DE1201996B (de) * | 1960-05-18 | 1965-09-30 | Grace W R & Co | Verfahren zur Polymerisation oder Mischpolymerisation von Monoolefinen, Diolefinen oder Styrol |
| US3100218A (en) * | 1961-07-20 | 1963-08-06 | Monsanto Chemicals | Purification of diethylaluminum chloride with crystalline titanium trichloride |
| US3324094A (en) * | 1962-11-08 | 1967-06-06 | Mitsubishi Petrochemical Co | Process for the manufacture of polymers and copolymers of isobutylene |
| US3226336A (en) * | 1963-05-08 | 1965-12-28 | Rexall Drug Chemical | Composition and process for preparing a three-component polymerization system |
| DE2930108C2 (de) | 1979-07-25 | 1982-11-25 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von weitgehend amorphen Buten-1 Propen-Ethen-Terpolymeren mit hohem Erweichungspunkt |
| US4472315A (en) * | 1980-01-18 | 1984-09-18 | Montedison S.P.A. | Components of catalysts and catalysts for (Co) polymerizing olefins and process for preparing said components, said components being based on particular chlorinated compounds of trivalent vanadium |
| US6239235B1 (en) | 1997-07-15 | 2001-05-29 | Phillips Petroleum Company | High solids slurry polymerization |
| US7482303B2 (en) | 2001-10-10 | 2009-01-27 | Dominique Bosteels | Catalytic burning reaction |
| US7723257B2 (en) | 2001-10-10 | 2010-05-25 | Dominique Bosteels | Process for the catalytic control of radial reaction |
| WO2008077204A2 (en) * | 2006-12-22 | 2008-07-03 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
| US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
-
0
- IT IT526101D patent/IT526101A/it unknown
- BE BE549638D patent/BE549638A/xx unknown
- BE BE543259D patent/BE543259A/xx unknown
- NL NL202552D patent/NL202552A/xx unknown
- LU LU33991D patent/LU33991A1/xx unknown
- NL NL111136D patent/NL111136C/xx active
-
1955
- 1955-11-19 CH CH2680655A patent/CH365222A/de unknown
- 1955-11-19 CH CH536961A patent/CH365879A/de unknown
- 1955-11-29 GB GB34154/55A patent/GB828791A/en not_active Expired
- 1955-11-30 FR FR1139806D patent/FR1139806A/fr not_active Expired
-
1956
- 1956-07-10 GB GB21373/56A patent/GB836814A/en not_active Expired
- 1956-07-13 FR FR70731D patent/FR70731E/fr not_active Expired
-
1960
- 1960-09-21 DE DE19601520237 patent/DE1520237A1/de active Pending
-
1961
- 1961-04-13 CY CY21961A patent/CY219A/xx unknown
- 1961-12-31 MY MY196161A patent/MY6100061A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE549638A (en, 2012) | |
| IT526101A (en, 2012) | |
| NL111136C (en, 2012) | |
| CH365222A (de) | 1962-10-31 |
| FR1139806A (fr) | 1957-07-05 |
| GB828791A (en) | 1960-02-24 |
| GB836814A (en) | 1960-06-09 |
| BE543259A (en, 2012) | |
| NL202552A (en, 2012) | |
| CH365879A (de) | 1962-11-30 |
| MY6100061A (en) | 1961-12-31 |
| CY219A (en) | 1961-04-13 |
| FR70731E (fr) | 1959-07-10 |
| LU33991A1 (en, 2012) |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SH | Request for examination between 03.10.1968 and 22.04.1971 |